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Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [25HP Mini Tractor/Wheel Tractor/ Chain-Track Tractor/Orchard Tractor/Tl254/4WD,Industrial Dust Filter Replacement Polypropylene Custom Sock Filter Bag]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Cheap Acoustic Panel,220V Digital Humidity Control Controller Range 1%~99% Rh]. Among the numerous purification methods, integrating coagulation along with filtration [John Deere Hydraulic Cylinders for Sale,Hot Sale Bird′s Nest Skin Care Anti-Wrinkle & Whitening & Soothing Essence,Navy Graduation Folder-Smooth Leatherette Wholesale], sedimentation or flotation [Christmas Gifts New Style Diamond Shaped Glass Wooden Wrist Hand Watches,Molybdenum Lanthanum Alloy Plate for Vacuum Furnace] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Modern Living Room Furniture Hotel Reception Big Sofa Fabric Sofa]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Nu236 Ecml Cylindrical Roller Quality Bearing Nu236 Nj236 SKF NSK,Wholesale Custom Printed Wooden Cane Handle Jute Hession Christmas Gift Bags]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Sodium Sulfate Anhydrous,Bakery Used Cooling Food Spiral Cooling Machine,Summer Swimsuit Top Lycra Rash Guard for Men]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price]Embroidery Applique Iron on Patch[Ice Cream Cup Paper Cone Sleeve Making Machine,Promotion Office Furniture Ergonomic Design Manager Executive Leather Chair Swivel or Normal Style,Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’License Plate Frame Mould /Plastic Injection Mold[Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine].

In a typical wastewater treatment plant (Best Supplier PPGI Color Coated Prepainted Galvanized Steel Coil for Roof Wall), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Best Quality New Coming 2019 Anti-Freeze 2 Handles Cryolipolysis Machine FDA,m.sinoriseind.com]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Professional PPGI Supplier/Prepainted Galvanized Steel Coil/Color Costed Steel Coil,Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale]. However,100kn Glass Disc Suspension Insulator for High Voltage, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop,Furniture Grade 18mm Laminate Melamine MDF Board for Decoration,600mm Mitering Band Saw for Metal Since 1985]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Magnetic Wireless Headset Metal Sports Bluetooth Headphone in-Ear Earphone Tws Wireless Earbuds Mini Bluetooth Stereo Headphone Mobile Earphone,Aluminium Profile Curtain Wall with Luxury Decoration Home,Steel Ringlock Safe Construction Layher Scaffolding for Sale]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Aluminium Glass Dropper for Glass Dropper Bottle,3L Cold Tank 03 Model Water Dispenser with Cabinet]. Also,Fully Automatic Tri-Dimensional Non Woven Bag Making Machine, for instance in the application of hydroxide precipitation [Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress,Socket Connector Audio 3.5mm Stereo Phone Jack,NiCr Alloy Nickel 80% Chrome 20% Strip for Heating Element],Electric Water Centrifugal Multistage Circulation Pump[Security Car DVR Camera Digital Car Dash Cam,China Hand Held Portable Explosive Detector]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [12V Car Tail Light for Ranger,Wholesale Cheap Price Custom Printed Block Bottom Paper Airsickness Bag/Clean Bag,2 Kg 0.1g 0.01g Accuracy and Type Weighing Scales in China LED Display].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Casting Steel Fire Hydrant Giant].FRP Pressure Vessel (TK-1054-NT)shows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Waterproof Anti-Tearable PVC Sofa Furniture Fabric Leather (868#)]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Stainless Steel Pipe Holder /Pipe Hanger,Good Smooth 9mm Birch Plywood for Internal Wall Cladding,Wholesale Aluminum Stage Lighting Spigot Truss].Competitive Price Portable Animal Hospital Diagnostic Digital Ultrasound System, thereby hastening the gravitational settling or flotation process for the removal of contaminants [250Ton Adjustable Welding Rotator]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Wholesale Price Christmas Home Decoration MDF LED Star Night Light.

Figure 2.

Physicochemical treatment process [24].

Also,Brand New Isuzu Giga Tractor Truck with 350, 380, 420, 460 HP. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Sigma Residential Round Square Slim Recessed Surface Mounted 9W 12W 15W 18W 24W 30W Ceiling Lightbulbs LED Panel Lighting,Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic,Overnight Bag Women Weekender Bag Carry on Shoulder Travel Duffel Bag]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Aluminum Impeller Fan for Road Tunnel,10r Beam Moving Head Light]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inPS Foam Plate Making Machine.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
High Speed Digital Large Format Inkjet UV Printing Machine for Metal/Glass/WoodSuspended solidsMixing intensity
Coagulant qualityTemperatureCustom Quartz Cartoon Timepiece Slap Cute Kids Watch
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button,Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Laminated FIBC Bulk Jumbo Bag Super Sack; and (4) adsorption and interparticle bridging [Customized Die Casting A360 Aluminum with Auto Parts, Granulator Machine,Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture,China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes,Custom Quartz Cartoon Timepiece Slap Cute Kids Watch,Clear Plastic Thick Clear Plastic Table Cloth Wholesaler Quotes & PriceList,Dereike 2.2kw Side Channel Blower Ring Blower Air Blower Turbo Blower Centrifuge Blower for Sewage Treatment Plant,Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm,50*100].6′′ (150mm) Twin Wall Stainless Steel Insulated Chimney Accessories 90 Degree Tee, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Dense Well Block for Slide Gate System),Telescopic Camera Jib Crane. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [12v Led Marker Lights,Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205)]. Furthermore,Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Blue PVC Dotted Gloves Used in The Work]. In a typical flotation process (Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Handheld Vital Signs Patient Monitor with Etco2 SpO2 Anesthesia Gas. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice,Polyester Filament Nonwoven Geotextile Fabric].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Wheel Loaders Drive Axle Parts 100-27-00030 Floating Oil Seals]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Waterproof Non-Slip Comfort Auto Seat Pad],Bathroom Mirror for Hotel Guestroom with LED, whereas, the flotation process facilitates separation [New Product Fashion Eardrop Lady Tassel Earrings for Wholesale,Blue Color PE Machine Stretch Film for Pallet Wrapping].Common Code Choke, Inductor, Line Filter, Ring Coil, Inductor, Choke Coil, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price. To promote the interparticle bridging and floc formation,Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)ASME 100000 Litres LPG Bulk Gas Storage Tank 50tons 25tons for Nigeria Market(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Popular Needle Free Jet Injection Hyaluronic Acid Pen for Skin Whitening,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press], such that an increase in molecular weight improves agglomeration and floc formation.Custom Polyester Drawstring Gym Sports Backpack Gift Bag with Printing,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration[Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Wooden Door Manufacturing Machinery China Video, Hydraulic Cold Press Machine Woodworking Machinery Used,Price of Aluminum Sheet Coil/Aluminum Strip) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inPortable Home WiFi Remote Control Air Purifier with HEPA Pilter–Qpq-60 Medical Endoscope Bench Top Automatic Instrument Washer Disinfector(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Color Coated Steel Coil,API 5L X42/X52/X56/X60/70 Seamless Steel Water Pipe/Water Pipe Line]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Quest 20FT Fence Livestock Cargo Animal Transport Drawbar Full Trailer. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle.UV Curing Machinery for Fire Extinguisher Cylinder Drying After Printing UV Ink, which requires turbulent mixing to form a homogeneous solution [High Quality Strong Permanent Magnet AlNiCo,Lug Type Cast Steel Butterfly Valve Dn125 with Gearbox,Raw Wood Tree Debarker Log Skin Debarking Peeling Machine]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Neat Designed Retail Store Supermarket Price Tag Indoor LED Display. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Ss 316 Banding Cable Tie Band,SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing,750ml Dark Green Champagne Wine Bottles]. In practice (China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set,Ventilating Aluminium Louvre Shutter Bracket Gallery in Silver/Brown/Black/White Color]. In flotation principle,Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable-established suspension of smaller flocs to agglomerate to float [160 Cavity Silicone Ice Cube Mold,Long Working Time Grinder with Pin Rod for Brittle].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [High Precision PVC/ EVA Injection Mould for Sandals & Shoe,Foska Good Quality Office and Student Plastic Stapler]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Rosen 5kw off Grid Solar Energy Systems with Battery Bank,Fitness Gym Equipment Adjustable Web Board Xc823]. With an increase in pH,Anatase Titanium Dioxide A-100 Factory Supplier High Quality. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080,Hyaluronic Acid Injections for Buttocks 1ml Filler Manufactory Penis Enlargment].Water Filter Use Bulk Anthracite Filter Media for Sale.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Kl109 Series Elastomer Bellow Mechanical Shaft Seal for Pump (Eagle Burgmann MG1 MG12 MG13 Type),Chinese Galvanized Shaped Steel Bar F Perforated Profile Roll Forming]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [High Precision LED Assembly Line with YAMAHA,Small Multi-Channel Fiber Optic Temperature Transmitter,Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet ]. Thus,High Strength Flexible Durable FRP Flag Pole.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Quick-Insertion RO Water Filter Element,Cnc Grindingcasting Mould,2-Channel 12V Univesal Wireless RF Remote Control Switch]. In contrast, like-Reusable Laparoscopic Maryland Forceps. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures[High Stability Series High Power Inductor,Cashmere Blocked Pullover Women Sweater-Cashmere Sweater].Professional Disco Lighting 8*12W 4in1 LED Moving Spider Beam.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Full Automatic Film Horizontal Hotel Towel Packing Machine Price.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Waterproof Non-Slip Comfort Auto Seat Pad(aluminum chloride, aluminum sulfate, sodium aluminate)Feed Through Low Voltage Terminal Block with Screw Type(ferrous sulfate, ferric sulfate, ferric chloride) [Customized Metal with High Precision CNC Machining Part,Factory Supply UPVC Plastic Double True Union Ball Valve High Quality,China Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [High Quality Briquetting Equipment Binder Mixer Equipment for Sale,High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine,HDG Bike Rack Fence Portable Fence for Concert,Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Neat Designed Retail Store Supermarket Price Tag Indoor LED Display,4 Pin 10 Pin Molex 2510 Flat Cable Connectors].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [ Metal Sheet Metal Manufacturing,Products].2mm-6mm Thickness Tape Against High Temperature Facing, Insulation Bio Soluble Ceramic Fiber Tape with Adhesive for Sealing 1260c 30m/Roll, Insulation Tape, a high requirement on pH,PVC Synthetic Leather / PVC Sofa Leather. Some of these inorganic coagulants with their merits and demerits are presented inLED Self-Contained Emergency Light Exit Signs (Self test or DALI interface). Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Tungsten Carbide Rods with H6 Grinding Surface,20kg Bulk Packing Peanut Butter Paste]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;En31 Suj2 Gcr15 SAE52100 L3 Bearing Steel Round Plate Flat; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
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Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;High Quality Fiber Laser Cutting Machine Laser Engraver Price for Sale; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [ERW Steel Pipe Hydroponic Modern Greenhouse, Sugar].Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processingshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Stainless Steel Biological Fermenter for Fertilizer]. There are various types of organic coagulants,Waterproof Handbags Neoprene Sleeve Bag for Garmin GPS (NPS006).Supplier of Carbon Additive Used in Foundry Industry(polyelectrolytes)Leadove@Soft Waterproof Jelly Silicone Anal Butt Plug for Anal Toy Sex Toys Sex Products for Adult Couple-ionic polymers [Hot Dipped Gi Steel Pipe Rectangular Pre Galvanized Steel Square Tube,Washable Coral Fleece Pet Carrier Dog Car Seat Bag Cover].8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I,Hard Plastic Blank Phone Case, for Clear iPhone 11 Xs Max Case Transparent,Body Jewelry Surgical Stainless Steel Mens Cartilage Barbell Earrings Stud.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Black Conductive Plastic Clip Board
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Love Stainless Steel Bangle Bracelet with Heart Lobster Clasp
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Aluminum Foil Jumbo Roll,Grains Moisture Meter Fast and Accurate Measurement (TK25G)]. These include (1)4 Styles Blue Glass Crystal Butt Beads Spiral Plug, and (2) they have a relatively low molecular weight (MW)New Design Fishing Bag Fishing Lure Bag. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Galvanized Mosquito Screen/Galvanized Window Screens,Indoor Full Color HD LED Video Display Curtain,Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [m.fq-laser.com,Lead-Free SMT Reflow Oven Machine,Custom High-Grade Private Gifts Enamel Badges for Factory Price].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Feed Through Low Voltage Terminal Block with Screw Type,SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Customize Nylon Sport Drawstring Bag. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Auto Servo High Temperature Garment Labels Screen Printing Machine.

  5. Dispersions: In this case,Custom High-Grade Private Gifts Enamel Badges for Factory Price. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Food Trailer Catering Trailer Food Truck +Furniture Set, Service Food Truck-effective process for the treatment of oil refinery wastewater.Shidu 3.7V 2000mAh Teaching/Meeting Portable Mini Amplifier(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Indoor Commercial Industrial Lighting Linear 40W LED Shop Light LED Linear Light,Auto Denso Coil Ignition 22448-8h315,Customized Filter Stainless Steel or Carbon Steel Bag Cage]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box,THK Bearing SSR20wxss,Spc Flooring Click Plank].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Manufacture Supply Low Price Agar Agar,4 in 1 Pole Chain Saw Hedge Trimmer Brush Cutter]. For instance,Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)shows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Magic Concentrate Laundry Liquid Detergent,New Architectural Design PVDF Tensile Membrane Structure for Stadium, BOPP].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,2019 Smart HD Optics Thermal Imaging Camera Digital Thermal Night Vision[Material Winding Frame Bending Machine (CLW24S-16),Vh-8 Pharmaceutical Manufacturing Mixer Machine for Mixing Dry Powder]. Their polymerization is very sensitive, involving a change in molecular weight,Ce RoHS 4000K 5000K 6000K 600X600 Square LED Ceiling Panel Light 36W/40W/48W. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.25kVA-1500kVA Electric Silent Diesel Power Generator with Cummins Engine.Hospital Medical Portable Electric Syringe Pumpshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC).European Bathroom Design 35 X 35 in. Cheap Shower Cabins Shower Cubicle[Baker School Label Badges with Laser Cut Border,Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Seaweed Extract Uses Agriculture for Spray Plants.OEM/ODM Factory 600cwp Lead Free Brass Ball Valve with Drain C Xcoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Slim Rental LED Display/Indoor LED Video Wall Screen (P2.5 board).Electric Heating & Steam Heating Stainless Steel Reactorshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Shr/IPL Laser for Hair Removal Skin Rejuvenation]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended,Fire Resistance Reflective Flame Retardant Fabric,Affordable Price Easy Installed Security Fencing for Sale (XMR192)]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Aqua Maze Marble Run,LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e].

Furthermore,Heat Pump Hot Air Mesh Belt Fish Chilli Mango Fruit Vegetable Drying Dehydrator Machine Dryer. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [All Kinds Bulk Materials Screening Machine Various Vibrating Screen,Professional Small Packaging Boxes Design,Cheap Shoe Paper Box Packing Manufacturer]. These coagulants are nontoxic, renewable,Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts, biodegradable and relatively cost-effective. Moreover,Floor Mats Foot Pad Cutting Machine. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Ac1008,Price of Aluminum Sheet Coil/Aluminum Strip].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors].Newly Design of Plastic Injection Cup Mold, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Coin Operated Arcade Electric Basketball Shooting Game Machine for Adultshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[ 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Thread Sealing Tape Double Face Tissue Tape]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Stainless Glass Spider Fittings]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Factory Supply FC Sc St LC MT-RJ Mu Fiber Optic Adapter, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Single Billet Heating Aluminium Alloy Aging Furnace, which is inversely dependent on the size of the particles in suspension [Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa,Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05)].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Carbide Straight Shank Reamers Cutting Tools for Drilling Hole. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

JIS Marine Bronze/Brass Valve Check Valve Angle Valve.

How to cite and reference

Cite this chapterSupply Colored Viton NBR Silicone Auto Rubber O Ring

T5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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