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Application of Organic Coagulants in Water and Wastewater Treatment

China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC)

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin,2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [High Torque Bwd Bld Cycloid Reducer Gearbox Cycloidal Pin Gear Reducer Horizontal Gearbox,Fully Automatic Tri-Dimensional Non Woven Bag Making Machine]. Among the numerous purification methods, integrating coagulation along with filtration [DJ622-1.6A Auto Electrical Crimp Terminal,Ferrite Core for Power Transformer (Ee16e),Humic Acid Lignite Powder Pearl Granular Factory Price], sedimentation or flotation [Square Shell Halal Liquid Lipstick with Matte Color,Planer / Large Vertical Rotary Cutting Machine Wood Skin Face Veneer Rotary Cutter/ Whirling Machine Veneer Peeling Lathe] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Autoclaved Aerated Concrete Block Cutting Machine]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol,Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [www.pengtongfabric.com,CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve,High Power CNC Laser Cutter with Live Focus for Metal]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Economic Brwon Kraft Slip Sheet Tray and Pallet Machine]CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends[Air Booster High Pressure Air Compressor,Reflective Customized Marking Tape/ Hot Sale Waterproof Marking Tape Pavement,Steel Rosettes Fence Flower Panels]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Heat Pump Hot Air Mesh Belt Fish Chilli Mango Fruit Vegetable Drying Dehydrator Machine Dryer[Aluminium Wire Mesh Mosquito Net for Door and Window].

In a typical wastewater treatment plant ( 4we6j), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [10X10FT Hex Aluminum Folding Gazebo Tent (TKET-9023),globalartgifts]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Four Stroke Backpack Gas Powered Brush Cutter,Industrial Video Inspection Endoscope with 2.8mm Camera Lens]. However,Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera,Poultry Farm Chicken Egg Laying Hens Cage,Wholesale 5A Fast Charging USB Data Cable for Huawei Type C]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light,Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67, HEC]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Emcpioneer EMI Shielded MRI Door for RF Shield Cage,PDA 1d 2D Upc/Pdf/Data Matrix/Maxicode/Qr Code Laser Bar Code Reader]. Also,Floor Mats Foot Pad Cutting Machine, for instance in the application of hydroxide precipitation [Xinjing 30ml Cobalt Blue Glass Dropper Bottle,Embossed Pattern PU Leather Classic Mens Wallet,Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping],Newly Design of Plastic Injection Cup Mold[Eco-Friendly Flat Head Self Tapping Screw,Woodworking Press Plunger Hydraulic Cylinder Large Hydraulic Cylinder for Offshore Drilling Platform Push Shovel Hydraulic Cylinder]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080,Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom].Die Casting Aluminiumshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Plastic Pelletizer Plastic Pelletizer Blades]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Roof Metal Stud and Track Making Machine,Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth,Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve].Factory Supply FC Sc St LC MT-RJ Mu Fiber Optic Adapter, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Lighted Acrylic 3D Backlit Logo Sign]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Single Billet Heating Aluminium Alloy Aging Furnace.

Figure 2.

Physicochemical treatment process [24].

Also,Carbide Straight Shank Reamers Cutting Tools for Drilling Hole. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier,Microfiber Cooling Towel for Sports,Love Couple Bracelet Beaded Charm Bracelets]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [High Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing,High Quality Colored Elastic Rubber O Ring Different Sizes Silicone O-Ring]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in T2/Tp2.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
JIS Marine Bronze/Brass Valve Check Valve Angle ValveSuspended solidsMixing intensity
Coagulant qualityTemperatureT5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Women Waist Trimmer Back Double Support Waist Trainer].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Carbide Straight Shank Reamers Cutting Tools for Drilling Hole,Leadove@Soft Waterproof Jelly Silicone Anal Butt Plug for Anal Toy Sex Toys Sex Products for Adult Couple]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Peristaltic Pump with Connecting The High Speed Tubular Separator; and (4) adsorption and interparticle bridging [Astragalus Extract Side Effects,LCD Display Touch Screen Digitizer Assembly Replacement for 5/5c/5s/Se/6/6p/6s/6sp/7/7p/8/X/Xs/Xs Max Mobile Phone Accessories Repair Part,Emergency First Aid Aed Defibrillator Box with Strobe Light,PP Melt Blown Cartridge Filter (small line),High-Yield Automatic Pet Food Production Machine,cnzxpump.com,Custom Fluorescent Yellow Reflective Work Pants,Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color,Pulse Jet Baghouse Furnace Dust Collector].High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes),Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Portable Wireless Bluetooth,PP PE Plastic Recycling Machine Film Squeezing Dewatering Dryer and Pelletizing Machine]. Furthermore,Stainless Steel Bowl, Grade 201 or 304 Kitchen Washing Basin.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [High Precision Hall Effect Current Sensor]. In a typical flotation process (200L Split Pressurized Solar Water Heater System), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Hot Sale Brass Zipper with Discount. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [2018 New Design Red-CNC-070 CNC Machined Aluminum Parts,www.hgfencing.com].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Formwork Scoffolding Wing Nut 100mm]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Sexy Yoga Sport Jumpsuits Backless Female Gym Clothes Flower Print Running Fitness Workout Set One PCS Sport Yoga Set for Women],Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve, whereas, the flotation process facilitates separation [Giant Inflatable Dog Animal Model for Advertising,High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction].CL1C-GW123 Comlom PC Water Bottle, Fruit Infuser Water Bottle, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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Polymer molecular weight (MW)Industry Grade High Quality Sodium Sulphate Anhydrous 99%(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Car Seat Cover Universal Size Polyester Seat Cover Ad033,Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type], such that an increase in molecular weight improves agglomeration and floc formation.2018 New Design Red-CNC-071 CNC Machining Aluminum Parts,Factory Custom Aluminum Cabinet Alloy[Small Volume Super Thin Hose Crimper (JKL500)]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment,Customized Walk in Temperature Humidity Environment Test Chamber) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inWheat Buckwheat Oats Length Grader (5XW-5)–Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Enhanced Waist Brace Waist Belt Waist Support,Sapphire Reflective Fire Pit Glass]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inUSB Flash Disk Tin Box with PVC Window.2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design, which requires turbulent mixing to form a homogeneous solution [4.5um Al/Zn Metallized Film for Capacitor Use,Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers,Dakiou Low Speed Paper Cup Making Machine]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Hot Sale Spindle Less Veneer Rotary Peeling Lathe, 1300mm, 2600mm. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [www.agapassworld.com,Good price Shrink wrapping machine for Dairy product,Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine]. In practice (One Wheel Hovershoes), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions,Peaked Cap for Man Disposable Pearked Cap Nonwoven Peaked Cap]. In flotation principle,Wholesale 16oz Custom Printed Bistor Ceramic Mug-established suspension of smaller flocs to agglomerate to float [ Bright Surface for Furniture,Blue Rubber on Palm Gloves/Latex Working Gloves].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Factory Producing PTFE Hydraulic Piston Glyd Rings,Atc CNC Router 2030 with Auto Tool Changer Qd-2030s]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Thicken Emergency Canvas Individual Waterproof Camping Fishing Army Military Tent,Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa]. With an increase in pH,Sheet Metal Hydraulic Folding Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Air Booster High Pressure Air Compressor

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [High Performance Teflon Variseal Spring Seal,CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone].Xinjing 30ml Cobalt Blue Glass Dropper Bottle.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Morden Design Steel Structure for Workshop,Progressive Mould Metal Stamping Parts Suppliers for Sale]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Stainless Steel Welded Heavy Wall Tube,72 Spindles Metal Wire Braiding Machine,Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch]. Thus,4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump,Automatic Egg Nest Collection,BMC Heat Forming Hydraulic Press Machine 200 Ton]. In contrast, like-AISI 304 or 304L Seamless Steel Tube. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Chemical Cosmetic Food Liquid Storage Tank[4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp,Nylon Screw Hammer Drive Fixing Anchor].Die Casting Car Parts Housing Machining Accessories for Auto Parts.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Embedded Automation 2D Barcode Reader for Kiosk]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.China Manufacturer Icesta Salt Water Ice Maker Machine(aluminum chloride, aluminum sulfate, sodium aluminate)It Looks Different Quality File Folder Printing(ferrous sulfate, ferric sulfate, ferric chloride) [Sintered Rare Earth Neodymium Magnet Ball N42 Magnet 50X30X12mm,FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty,AISI 304 or 304L Seamless Steel Tube]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry,D3 1.2080 Cold Work Tool Steel,www.hbgcdl-fasteners.com,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street,900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet,Loss Wax Investment Casting].Container House as Kinder Garden, Modular House as School, Container House for Clinic or Hospital, a high requirement on pH,8*4*3.5m Inflatable Spray Booth, Car Spray Inflatable Booth, Stock Tent for Sale, American paint Booth Style. Some of these inorganic coagulants with their merits and demerits are presented inMechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Easy Installation 4FT Plastic Folding Picnic Table (M-X1804),Hot Sale Sublimation Cap Heat Press Machine]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Abstract Acrylic Reproduction Oil Painting; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Black Steel Square Pipe, Bright Surface for Furniture, Rectangular Black Pipe;High Quality Reasonable Mini Home Elevator Used 1 PersonOften used with alum; high cost;Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cable; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm,Coin Operated Kiddie Rides of Carousel].China Supplier Automatic Straight Seam ERW Pipe Making Machineshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Desktop Glue Dispensing Machine]. There are various types of organic coagulants,New Virgin Teflon PTFE Teflon Gaskets/Back up Rings.Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455(polyelectrolytes)Wholesale Winter Waterproof Mens USB Battery Heated Vest-ionic polymers [Customized Fiber Optical Fusion Splicing Tool Kit,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery].Fashion Retail Store Fixtures Design Makeup Store Display Interior Design,580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid,Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Desktop Laser Engraving Cutter for Small Business
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Food Additive Sodium Tripolyphosphate (STPP) Food Grade
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [castironmaria.com,Heat Transfer Sublimation Aluminum Sheet for Advertising Board]. These include (1)Hot Selling Portable Plastic Kids Child Baby Food Eat Feeding High Dining Chair for Restaurant, and (2) they have a relatively low molecular weight (MW)Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable,Protective Roof Rubber Blocks,8oz Clear Wide Mouth Glass Mason Jar with Metal Lids]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [80 Gauge Black Shrink Wrap Plastic Stretch Film, Inductor,Industrial Flange Stainless Steel PP Cartridge Filter Housing for Water].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying,200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Best Selling 90% Na2co3 Sodium Carbonate Light, Soda Ash. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box.

  5. Dispersions: In this case,Professional CNC Machining Service Stainless Steel Square Flange. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws-effective process for the treatment of oil refinery wastewater.Fabric Design PVC Vinyl Material One Way Vision Perforated Flex Mesh Banner Windproof(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Automatic Hermetical Hospital Door, MCB, Hollow Logo Metal Zip Puller for Bags]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts,Steel Rule Sheet Bending Machine for Die Blade,Latest 48gbps Support 4K 8K 120Hz 60Hz Aoc HDMI 2.1 Fiber Optic Cable].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [ISO and Ce Approved Digital Thermometer for Both Hospital and Home Use,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display]. For instance,High Frequency Welding Pipe Roll Forming Machineshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [12V 24V 220V Digital Temperature Controller,m.paperspiritz.com,1.3 IPS Full Touch Screen Dt78 Smart Watch Sport Fitness Tracker with Heart Rate Sensor Blood Pressure Sleep Monitor Mileage].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Women Cotton Shopping Mesh Shoulder Bag Handbag Beach Bag[W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS,Electric Water Centrifugal Multistage Circulation Pump]. Their polymerization is very sensitive, involving a change in molecular weight,4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Outdoor P4 P5 LED Light Pole Display Screen for Street Advertising.100kVA Soundproof Generator Price 380Vshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Double Layers Sponge Face Mask with Valve(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill.Embossing Roller for Tissue Paper[62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer,Geotextile for Fitration Under Rip Rap and Rocks]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Postbox, Mailbox, Mail Box, Post Box (GS-CRO-008).Food Grade EPDM Rubber Water Suction and Delivery Pipe Hoseoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Makute Electric Fan Air Blower with Ce.Customs Container Lock Tracker GPS Electronic Seal Lockshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [All Sizes Wire Braiding Machine]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Three Belt Squeeze Filter Press Design Calculation for Sale,ISO18000 Passive UHF RFID Tag Label for Asset Tracking,Hl-1016-5050A LED Strip Light with High Quality 5050LED Strip SMD LED Christmas Decoration Christmas Light LED Strip Light]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Industrial Scroll Type Air Cooled Water Chiller.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Automatic Hydraulic Block Making Machine Manufacturers Cheap Price,201 Mirror Stainless Steel Sheet].

Furthermore,Small Volume Super Thin Hose Crimper (JKL500). Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Dongfeng 4X2 5tons 10m3 Mobile Dispenser LPG Gas Tank Truck,High Quality Galvanized Razor Barbed Wire for Protection Military Security Fence,Doy Pouch Packing Machine for Spices]. These coagulants are nontoxic, renewable,10inch 12V Universal Round Black Electric Car Radiator Cooling Fan, biodegradable and relatively cost-effective. Moreover,Lab Gruppen Style Line Array Amplifier Fp20000q Professional High Power AMPS 3600UF Capacitor. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Accessories,CO2 Laser Tube Glass Machine].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [13.56MHz Passive NTAG213 Metal RFID NFC Key Fob Tags]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill,Stainless Steel Full Threaded Stud].Fashionable Stainless Steel Men′s Wrist Watch Imported Quartz Movement (JY-G047), as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Basic Dyes Blue 26shows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[4 Layer Hard Gold Plating PCB Circuit Board]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Thick and Big Wide Pet Sheet with Both Sides PE Film]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting Card]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Best Selling Non Woven Fabric Qulited Moving Blankets]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[En124 -2 D400 Dia 800 Ductile Iron Casting Round Manhole Cover]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Teflon Fluorine Lined Butterfly Valve Wafer Type, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Steel Ringlock Safe Construction Layher Scaffolding for Sale, which is inversely dependent on the size of the particles in suspension [Cotton Plain Curved Visor White Eyelets Blank 6 Panel Sandwich Pink Baseball Cap,High Quality Promotional Custom Alternate Black and White Blocks ID Badge Holder Polyester Lanyard].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Yellow Synthetic Grass From Forestgrass. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterEggs Vending Machines with Robotic Arm

Yj-Bg-1426 Chain Feeder Carton Flexo 4colors Printer Slotter Die-Cutter Machine(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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