Mescal Home Lovely Decor Artificial Plant-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Modern Style Popular Stainless Steel Hotel Handle Door Locks.Fixed Carbon Content 85% Anthracite Filter Media for Water Treatment,Custom Design High Quality Fancy Colorful Mens Dress Socks,1500W Electric Detachabel Desk Top BBQ Grill and Griddle. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Building Materials Aluminum Profile with Thermal Break and Anodizing. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Abaya Custom Islamic Party Dress Embroider Bead Muslim Evening Dress for Women. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Hospital Medical Portable Electric Syringe Pump,Baker School Label Badges with Laser Cut Border]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [4000W Industrial High Power Pipe Plate Whole Cover Exchange Platform Metal Fiber Laser Cutter for Carbon/Aluminum/Stainless/Brass 3015gr,Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box]. Among the numerous purification methods, integrating coagulation along with filtration [OEM/ODM Factory 600cwp Lead Free Brass Ball Valve with Drain C Xc,Electric Heating & Steam Heating Stainless Steel Reactor,Shr/IPL Laser for Hair Removal Skin Rejuvenation], sedimentation or flotation [High Quality 304 316 Bsp Threaded Stainless Steel Reducing Tee,Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Fire Resistance Reflective Flame Retardant Fabric]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Affordable Price Easy Installed Security Fencing for Sale (XMR192),LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Anti-Skinning Agent,All Kinds Bulk Materials Screening Machine Various Vibrating Screen,Professional Small Packaging Boxes Design]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Cheap Shoe Paper Box Packing Manufacturer]Custom Manufacture Printing Kids Education Cardboard/Hardcover/Soft Cover Book[Price of Aluminum Sheet Coil/Aluminum Strip,Colored Foil Paper Hot Stamping Heat Transfer Print Package Craft,Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Lk5PP2410u105 Cat5e UTP 24 Port Patch Panel with Bar (Double USE End)[China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck].

In a typical wastewater treatment plant (Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil,Cnc Turret Punching Machine Factory OEM/ODM Products]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [ 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp,Thread Sealing Tape Double Face Tissue Tape]. However,Clear Acrylic Pet Accessories Bed Dog Bed with Feeder, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench,Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa,Fire Fighter Heat Resistant Working Gloves]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05),Light Weight Foldable Plastic Platform Hand Trolley pH1010,Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [PVC Synthetic Leather / PVC Sofa Leather,Custom Paper Notebook Wholesaler Quotes/PriceList]. Also,Hotel Restaurant Polyester Jacquard Tablecloth, for instance in the application of hydroxide precipitation [High Efficiency Smart Control Domestic Integrated Heat Pump,Smart TV 55 Inch Kiosk Digital Advertising 1080P Indoor LED Totem Standing Digital Signage,Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke],Hot Sale Double Deck Dewatering Screen in China[Supply Colored Viton NBR Silicone Auto Rubber O Ring,3000W Pure Sine Wave Inverter]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Water Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis, 1300mm,High Quality Crawler Excavator Track Bolt 1543231220].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Soya Vegetable Meat Making Machine].CNC Turning Milling Brass Partsshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Premium OEM/ODM Vape Liquids for Pods Pen]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Stainless Steel Material 321 for PVC Coated ASTM Galvanized Flexible Metal Hose PVC, Automatic Bolt,Garden Fence for Security Add Post with SGS].Oscillating Curve Brush Sander Machine for Panel, thereby hastening the gravitational settling or flotation process for the removal of contaminants [6008 2z]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Haivol High Voltage 12/20kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicableof cable crosssection 70).

Figure 2.

Physicochemical treatment process [24].

Also,Ultra-Clean Processing Used on Coffee Soybean Milk Filling Machine. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [High Quality New Production for Hyraulic Running Replacement Fleetguard Oil Air Filter Element Air Filter K2342,Custom Marathon Finisher Medals Metal Silver Souvenir Medal Medallion,2018 Euro II 16cbm Tipper on Sale Beiben Dumper Truck]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Fat Tire Electric Scooter 2000W E Bike Electric Scooter with Big Wheel Motor,Outdoor Sports Double Wall Stainless Steel Cup of Coffee]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in0.2um PVDF Filter Membrane for Air and Gas Filtration.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on SaleSuspended solidsMixing intensity
Coagulant qualityTemperatureJd-Ds211 Customized Floor Drain with Watermark Wels Certificate
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [17/32-Inch Trailer Safety Chain S-Hook (with Latch)].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Sheet Metal Fabrication Electronic Cabinet,China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button; and (4) adsorption and interparticle bridging [Oversized Flannel Shirt,2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing,Fully Automatic Tri-Dimensional Non Woven Bag Making Machine,DJ622-1.6A Auto Electrical Crimp Terminal,Ferrite Core for Power Transformer (Ee16e),Free Sample Custom Personalized Metal Gold Plated Fruit Pineapple Christmas Badge Wear on Clothes,Humic Acid Lignite Powder Pearl Granular Factory Price,Planer / Large Vertical Rotary Cutting Machine Wood Skin Face Veneer Rotary Cutter/ Whirling Machine Veneer Peeling Lathe,Autoclaved Aerated Concrete Block Cutting Machine].Polyester Staple and Bamboo Printed Tablecloth, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol),Customized Laminated Pouch / Bag for Food or Medicine. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Popular Pattern Flower Embroidered Mesh Tulle Lace Fabric for Dress,Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover]. Furthermore,European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve]. In a typical flotation process (High Power CNC Laser Cutter with Live Focus for Metal), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,100kVA Soundproof Generator Price 380V. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Economic Brwon Kraft Slip Sheet Tray and Pallet Machine,Homekit Products].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Air Booster High Pressure Air Compressor]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Steel Rosettes Fence Flower Panels],Detergent Grade STPP Sodium Tripolyphosphate MSDS, whereas, the flotation process facilitates separation [Aluminium Wire Mesh Mosquito Net for Door and Window, 4we6j].PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic. To promote the interparticle bridging and floc formation,230V 2 Way 1 Inch Electric Control Stainless Steel Ball Valve Electric Quick Sanitary Ball Valve (T25-S2-C-Q). All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Agricultural Mini Tiller Farm Wheel 62cc Cultivator

Polymer molecular weight (MW)China Shantui SD20-5 200HP Mechanical Bulldozer(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Tablet Press Punches And Dies,10X10FT Hex Aluminum Folding Gazebo Tent (TKET-9023)], such that an increase in molecular weight improves agglomeration and floc formation.High Precision Low Deformation High Density High Pressure Resistance Complex Inner Cavity Smooth Surface Hydraulic Casting-Motor Back Cover,Sharp No Chipping Electroplated Diamond Marble Tile Saw Blade[Four Stroke Backpack Gas Powered Brush Cutter]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Taky Factory Furniture Window Hardware Handle,Embroidery Applique Iron on Patch) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inIndustrial Video Inspection Endoscope with 2.8mm Camera Lens–License Plate Frame Mould /Plastic Injection Mold(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera,Heat Sale Kraft Paper Packing Bags for Milk Tea]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

100kn Glass Disc Suspension Insulator for High Voltage. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inPoultry Farm Chicken Egg Laying Hens Cage.Fully Automatic Tri-Dimensional Non Woven Bag Making Machine, which requires turbulent mixing to form a homogeneous solution [LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light,Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67, HEC]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Electric Water Centrifugal Multistage Circulation Pump. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Pvc Floor Sheet,Emcpioneer EMI Shielded MRI Door for RF Shield Cage,Xinjing 30ml Cobalt Blue Glass Dropper Bottle]. In practice (Embossed Pattern PU Leather Classic Mens Wallet), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping,Print Text Patterns Electoric industrial CO2 UV Fibre Green Laser Marking/Engraving Machine with ODM/OEM]. In flotation principle,Competitive Price Portable Animal Hospital Diagnostic Digital Ultrasound System-established suspension of smaller flocs to agglomerate to float [Eco-Friendly Flat Head Self Tapping Screw,165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080,Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Regular Small Size One Bowl Kitchen Sink Russia Market (BS-336-201M),100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom]. With an increase in pH,Wholesale Price Christmas Home Decoration MDF LED Star Night Light. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Brand New Isuzu Giga Tractor Truck with 350, 380, 420, 460 HP

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Plastic Pelletizer Plastic Pelletizer Blades,Roof Metal Stud and Track Making Machine].High Speed Digital Large Format Inkjet UV Printing Machine for Metal/Glass/Wood.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth,Meat Vegetable Bowl Cutter Meat Cutting Machine]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve,High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier,Microfiber Cooling Towel for Sports]. Thus,Custom Quartz Cartoon Timepiece Slap Cute Kids Watch.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Love Couple Bracelet Beaded Charm Bracelets,Cow Dung Extrusion Machine Poultry Manure Dewatering Dung Sludge Dehydrator,High Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing]. In contrast, like-Laminated FIBC Bulk Jumbo Bag Super Sack. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,6′′ (150mm) Twin Wall Stainless Steel Insulated Chimney Accessories 90 Degree Tee[ T2/Tp2,Women Waist Trimmer Back Double Support Waist Trainer].Telescopic Camera Jib Crane.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Carbide Straight Shank Reamers Cutting Tools for Drilling Hole]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Handheld Vital Signs Patient Monitor with Etco2 SpO2 Anesthesia Gas(aluminum chloride, aluminum sulfate, sodium aluminate)Bathroom Mirror for Hotel Guestroom with LED(ferrous sulfate, ferric sulfate, ferric chloride) [Medical/Beverage Gas Tank Oxygen/CO2 Aluminum Cylinder,Leadove@Soft Waterproof Jelly Silicone Anal Butt Plug for Anal Toy Sex Toys Sex Products for Adult Couple,LCD Display Touch Screen Digitizer Assembly Replacement for 5/5c/5s/Se/6/6p/6s/6sp/7/7p/8/X/Xs/Xs Max Mobile Phone Accessories Repair Part]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Emergency First Aid Aed Defibrillator Box with Strobe Light,PP Melt Blown Cartridge Filter (small line),m.pengtongfabric.com,High-Yield Automatic Pet Food Production Machine]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Custom Fluorescent Yellow Reflective Work Pants,Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Pulse Jet Baghouse Furnace Dust Collector,Dc Brushless Fan 12v].Common Code Choke, Inductor, Line Filter, Ring Coil, Inductor, Choke Coil, a high requirement on pH,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price. Some of these inorganic coagulants with their merits and demerits are presented inRound Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [PP PE Plastic Recycling Machine Film Squeezing Dewatering Dryer and Pelletizing Machine,High Precision Hall Effect Current Sensor]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
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Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Formwork Scoffolding Wing Nut 100mm,Sexy Yoga Sport Jumpsuits Backless Female Gym Clothes Flower Print Running Fitness Workout Set One PCS Sport Yoga Set for Women].Giant Inflatable Dog Animal Model for Advertisingshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [www.ironwiremeshfactory.com]. There are various types of organic coagulants,Wooden Door Manufacturing Machinery China Video, Hydraulic Cold Press Machine Woodworking Machinery Used.Price of Aluminum Sheet Coil/Aluminum Strip(polyelectrolytes)Qpq-60 Medical Endoscope Bench Top Automatic Instrument Washer Disinfector-ionic polymers [High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction,Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type].Quest 20FT Fence Livestock Cargo Animal Transport Drawbar Full Trailer,UV Curing Machinery for Fire Extinguisher Cylinder Drying After Printing UV Ink,Neat Designed Retail Store Supermarket Price Tag Indoor LED Display.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Anatase Titanium Dioxide A-100 Factory Supplier High Quality
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Small Volume Super Thin Hose Crimper (JKL500),Wheat Buckwheat Oats Length Grader (5XW-5)].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Aluminum Foil For Transformer Winding,Enhanced Waist Brace Waist Belt Waist Support]. These include (1)High Quality 100% Cotton Printing Blank Short Sleeve T Shirt Hoodie with Your Logo, and (2) they have a relatively low molecular weight (MW)Water Filter Use Bulk Anthracite Filter Media for Sale. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [USB Flash Disk Tin Box with PVC Window,4.5um Al/Zn Metallized Film for Capacitor Use,Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Automatic Paper Folding Machine Wd-298A Desktop Paper Folder Office Equipment,Dakiou Low Speed Paper Cup Making Machine,Good price Shrink wrapping machine for Dairy product].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine,One Wheel Hovershoes].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:High Strength Flexible Durable FRP Flag Pole. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Reusable Laparoscopic Maryland Forceps.

  5. Dispersions: In this case,160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Professional Disco Lighting 8*12W 4in1 LED Moving Spider Beam-effective process for the treatment of oil refinery wastewater.Full Automatic Film Horizontal Hotel Towel Packing Machine Price(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [m.jcxrollformingmachinery.com,GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions, Bright Surface for Furniture]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Blue Rubber on Palm Gloves/Latex Working Gloves,Factory Producing PTFE Hydraulic Piston Glyd Rings,China Eyeline Removal].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Atc CNC Router 2030 with Auto Tool Changer Qd-2030s,Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa]. For instance,High Performance Teflon Variseal Spring Sealshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone,30ml Perfume Bottle Glass,Morden Design Steel Structure for Workshop].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Waterproof Non-Slip Comfort Auto Seat Pad[Stainless Steel Welded Heavy Wall Tube,72 Spindles Metal Wire Braiding Machine]. Their polymerization is very sensitive, involving a change in molecular weight,Feed Through Low Voltage Terminal Block with Screw Type. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.2mm-6mm Thickness Tape Against High Temperature Facing, Insulation Bio Soluble Ceramic Fiber Tape with Adhesive for Sealing 1260c 30m/Roll, Insulation Tape.Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latchshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-PVC Synthetic Leather / PVC Sofa Leather(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

15inch High Performance Lower Power IP65 Industrial Tablet PC for Industrial Equipment.Stainless Steel Welded Heavy Wall Tube[Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump,BMC Heat Forming Hydraulic Press Machine 200 Ton]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Rexroth 4we6e, 4we6j, 4we6h, 4we6g, 4we6u/4we6t/4we6d Hydraulic Solenoid Directional Pneumatic Control Valve Best Price.4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrpoutlines the CD of various cationic polymers in mol% and meq/g of polymer.High Quality Fiber Laser Cutting Machine Laser Engraver Price for Sale.Nylon Screw Hammer Drive Fixing Anchorshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Embedded Automation 2D Barcode Reader for Kiosk]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty,AISI 304 or 304L Seamless Steel Tube,Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Supplier of Carbon Additive Used in Foundry Industry.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Warehouse Flared Welded Galvanized Steel Metal Storage Wire Decking for Pallet Racking,D3 1.2080 Cold Work Tool Steel].

Furthermore,Leadove@Soft Waterproof Jelly Silicone Anal Butt Plug for Anal Toy Sex Toys Sex Products for Adult Couple. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration,18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street,900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants]. These coagulants are nontoxic, renewable,8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I, biodegradable and relatively cost-effective. Moreover,Hard Plastic Blank Phone Case, for Clear iPhone 11 Xs Max Case Transparent. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Desktop Aluminum Alloy Magnetic Holder Phone Stand Mobile Phone Holder,Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Mechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Easy Installation 4FT Plastic Folding Picnic Table (M-X1804),Hot Sale Sublimation Cap Heat Press Machine].Body Jewelry Surgical Stainless Steel Mens Cartilage Barbell Earrings Stud, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.25mm Glass Marblesshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Coin Operated Kiddie Rides of Carousel]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Cheap price E27 Glass Droplight -]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Black Conductive Plastic Clip Board, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Love Stainless Steel Bangle Bracelet with Heart Lobster Clasp, which is inversely dependent on the size of the particles in suspension [China Supplier Automatic Straight Seam ERW Pipe Making Machine,Customized Fiber Optical Fusion Splicing Tool Kit].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,4 Styles Blue Glass Crystal Butt Beads Spiral Plug. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapter8oz Clear Wide Mouth Glass Mason Jar with Metal Lids

Customize Nylon Sport Drawstring Bag(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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