GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

Dense Seating Block for Slide Gate System

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Fire Fighting Suits Hight Quality Gloves.Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper,Air Cooled Disel Generators with Deutz Engines (10KW-100KW),Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Product Design and Molding. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,14*14 Ss Finish Aluminum Window Screen Mosquito Net for India Market. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Industrial Dust Filter Replacement Polypropylene Custom Sock Filter Bag,220V Digital Humidity Control Controller Range 1%~99% Rh]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Complete Transformer Substation,John Deere Hydraulic Cylinders for Sale]. Among the numerous purification methods, integrating coagulation along with filtration [Hot Sale Bird′s Nest Skin Care Anti-Wrinkle & Whitening & Soothing Essence,Navy Graduation Folder-Smooth Leatherette Wholesale,Molybdenum Lanthanum Alloy Plate for Vacuum Furnace], sedimentation or flotation [100ml Amber Bottle Manufacturers Cheap Price,Modern Living Room Furniture Hotel Reception Big Sofa Fabric Sofa] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Nu236 Ecml Cylindrical Roller Quality Bearing Nu236 Nj236 SKF NSK]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Wholesale Custom Printed Wooden Cane Handle Jute Hession Christmas Gift Bags,Bakery Used Cooling Food Spiral Cooling Machine]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [DC Electric Automotive Cooling Systems 12V 24V Pump,Summer Swimsuit Top Lycra Rash Guard for Men,ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Ice Cream Cup Paper Cone Sleeve Making Machine]Good Smooth 9mm Birch Plywood for Internal Wall Cladding[Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality,3d Solutech,Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt[Best Supplier PPGI Color Coated Prepainted Galvanized Steel Coil for Roof Wall].

In a typical wastewater treatment plant (Best Quality New Coming 2019 Anti-Freeze 2 Handles Cryolipolysis Machine FDA), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Professional PPGI Supplier/Prepainted Galvanized Steel Coil/Color Costed Steel Coil,Plexiglass Noise Barrier UV Protected Acrylic Glass Sheet]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale,2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop]. However,Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Furniture Grade 18mm Laminate Melamine MDF Board for Decoration,Magnetic Wireless Headset Metal Sports Bluetooth Headphone in-Ear Earphone Tws Wireless Earbuds Mini Bluetooth Stereo Headphone Mobile Earphone,Scroll Compressor Evi Heat Pump]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Aluminium Profile Curtain Wall with Luxury Decoration Home,Steel Ringlock Safe Construction Layher Scaffolding for Sale,Aluminium Glass Dropper for Glass Dropper Bottle]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress,Custom Printed Halloween Candy Gift Box with Ribbon]. Also,Semi Automatic Diamond Saw Blade Welding Machine, for instance in the application of hydroxide precipitation [Socket Connector Audio 3.5mm Stereo Phone Jack,NiCr Alloy Nickel 80% Chrome 20% Strip for Heating Element,Security Car DVR Camera Digital Car Dash Cam],Electronic Hygrothermostat/ Temperature and Humidity Controller (ETF 012)[12V Car Tail Light for Ranger,Custom Printed Bucket Hats]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Wholesale Cheap Price Custom Printed Block Bottom Paper Airsickness Bag/Clean Bag,2 Kg 0.1g 0.01g Accuracy and Type Weighing Scales in China LED Display,Casting Steel Fire Hydrant Giant].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Waterproof Anti-Tearable PVC Sofa Furniture Fabric Leather (868#)].Free Sample Mobile Phone Caseshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Stainless Steel Pipe Holder /Pipe Hanger]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Good Smooth 9mm Birch Plywood for Internal Wall Cladding,Wholesale Aluminum Stage Lighting Spigot Truss,Sigma Residential Round Square Slim Recessed Surface Mounted 9W 12W 15W 18W 24W 30W Ceiling Lightbulbs LED Panel Lighting].Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1), thereby hastening the gravitational settling or flotation process for the removal of contaminants [Alloy Pipe Supplier]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone.

Figure 2.

Physicochemical treatment process [24].

Also,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic,Overnight Bag Women Weekender Bag Carry on Shoulder Travel Duffel Bag,Aluminum Impeller Fan for Road Tunnel]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [PS Foam Plate Making Machine,Best Selling American Style Residential Apartment Privacy Aluminum Wooden Door Handles and Locks]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inOutdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Long Sleeve Lace Beaded Muslim Bridal Gown Wedding DressSuspended solidsMixing intensity
Coagulant qualityTemperatureDental Lab Verabond Nicr Nickel Chromium with Beryllium Dental Vb Metal Porcelain Alloy
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D, Granulator Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Besen Type 1 Plug EV Charging Station Wall-Mount 16A 3.5kw; and (4) adsorption and interparticle bridging [HD H. 265 4MP Waterproof Network IP Camera,Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture,China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes,Custom Quartz Cartoon Timepiece Slap Cute Kids Watch,Dereike 2.2kw Side Channel Blower Ring Blower Air Blower Turbo Blower Centrifuge Blower for Sewage Treatment Plant,Remote Water Valve,Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm,50*100,Dense Well Block for Slide Gate System].Straight Full Lace Wig for Women Side Part Long Silky Straight Lace Wigs Hand Tied 18~26 Inches, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205)),Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [535*535mm Cutted Small Size Melamine Chipboard for Furniture,Blue PVC Dotted Gloves Used in The Work]. Furthermore,Portable Shelter Toilet Shower Beach Camping Tent.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts]. In a typical flotation process (Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Wheel Loaders Drive Axle Parts 100-27-00030 Floating Oil Seals,220v Switch And Socket].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Waterproof Non-Slip Comfort Auto Seat Pad]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [New Product Fashion Eardrop Lady Tassel Earrings for Wholesale],Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing, whereas, the flotation process facilitates separation [Blue Color PE Machine Stretch Film for Pallet Wrapping,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press].UV8d Wouxun High Gain Antenna Dual Band Antenna, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys. To promote the interparticle bridging and floc formation,Four-Shaft Auto Polyester, BOPP, PE Film Slitting Machine. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.PVC Panels 30cm Width of Hot Stamping

Polymer molecular weight (MW)Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Car Oil Filters,Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case], such that an increase in molecular weight improves agglomeration and floc formation.Et065 /Et063 6mm Carbon/Metal Trimming Potentiometer,Longer Service Life Banded Type Tee[Portable Home WiFi Remote Control Air Purifier with HEPA Pilter]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (High-Weight 120 GSM Fast Dry Sublimation Paper for Textile Printing,Qk1338 Big Diameter Oil Pipe Turning Lathe, Big Spindle Bore Double Chuck CNC Pipe Threading Lathe Machine) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inColor Coated Steel Coil–Stationary Polyester Felt or Wool Elastic Closure A4 File Folder(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle,Cnc Metal Plasma Cutting Machine Suppliers for Sale]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Top Quality Inox Plumbing Sanitary Press Fitting to Replace Hydraulic Joint Steel Pipe Bend PVC Pipe Fittings. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inHigh Quality Strong Permanent Magnet AlNiCo.DIN7504 Stainless Steel Pan Head Philips Self Drilling Screw, which requires turbulent mixing to form a homogeneous solution [Lug Type Cast Steel Butterfly Valve Dn125 with Gearbox,Raw Wood Tree Debarker Log Skin Debarking Peeling Machine,SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Professional Wood Log Bark Peeling Machine. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [China Smooth Burnt Scars Beauty Machine,750ml Dark Green Champagne Wine Bottles,China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price]. In practice (Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [160 Cavity Silicone Ice Cube Mold,Photocell Switch Lighting Factory & Manufacturer]. In flotation principle,EL Backlight Membrane Switch Keyboard-established suspension of smaller flocs to agglomerate to float [Long Working Time Grinder with Pin Rod for Brittle,High Precision PVC/ EVA Injection Mould for Sandals & Shoe].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Foska Good Quality Office and Student Plastic Stapler,Fitness Gym Equipment Adjustable Web Board Xc823]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Hot Patio and Terrace Cover/ Aluminum Pergola with Polycarbonate Roof,New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080]. With an increase in pH,Mc-275A Pipe/Tube Cutting Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Hyaluronic Acid Injections for Buttocks 1ml Filler Manufactory Penis Enlargment,Kl109 Series Elastomer Bellow Mechanical Shaft Seal for Pump (Eagle Burgmann MG1 MG12 MG13 Type)].18650 PCM Protection Board with Balanced Lithium Battery Module (lws-4s30A-058).

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [High Precision LED Assembly Line with YAMAHA,Customized LED PCB with 24 Hours Fast PCB Prototyping]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Small Multi-Channel Fiber Optic Temperature Transmitter,Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet ,Quick-Insertion RO Water Filter Element]. Thus,Geyi Disposable Medical Surgical Laparoscopic Visible Optical Trocar with CE Certificate.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [2-Channel 12V Univesal Wireless RF Remote Control Switch,Wholesale Promotion Customized Logo Metal Golf Ballmarker Accessory Gift Silver Color Golf Club Pin Cap Hat Clip Fork Set Ball Marker Divot Repair Tool,High Stability Series High Power Inductor]. In contrast, like-Hans Free Sample Stylish Lace Necklace. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Different Thickness High Quality Aluminum Foil for Glass Bottle Lid[Cashmere Blocked Pullover Women Sweater-Cashmere Sweater,Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series].Aluninum Air Register Grille for Ventilation Use.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Factory Supply UPVC Plastic Double True Union Ball Valve High Quality]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Hot Sale Touch Point Car Seat Sensor for Auto Seats.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.3W 5W 10W Nonmetal UV Laser Engraving Marking(aluminum chloride, aluminum sulfate, sodium aluminate)High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding(ferrous sulfate, ferric sulfate, ferric chloride) [Clutch Bag Men,China Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires,High Quality Briquetting Equipment Binder Mixer Equipment for Sale]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine,Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway,m.mphotoluminescent.com,Neat Designed Retail Store Supermarket Price Tag Indoor LED Display]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [4 Pin 10 Pin Molex 2510 Flat Cable Connectors, Metal Sheet Metal Manufacturing].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface),Wholesale Customized Latest Girls&Ladies Leather Flat Shoes Women Pumps Cut out].Superior Quality High Impact Strength UHMWPE Sheet, a high requirement on pH,Semi Auto 5 Gallon PC Bottle Blow Molding Machine. Some of these inorganic coagulants with their merits and demerits are presented inTungsten Carbide Rods with H6 Grinding Surface. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [20kg Bulk Packing Peanut Butter Paste,Fire Fighting Suits Hight Quality Gloves]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;ODM Low Price High Quality Plastic Car Parts of Wheel; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
High Quality Geared Side - in Agitator;Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education SystemOften used with alum; high cost;Wholesale China Custom Metal Zinc Alloy Doming 3D Shiny Gold Plating Military Pilot Wings Pin Badge
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;China Hydraulic Automatic Chamber Plate Filter Press Factory Price; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [ Sugar,Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing].Hot Dipped Gi Steel Pipe Rectangular Pre Galvanized Steel Square Tubeshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [20oz Fuguang Cheapest Price High Quality 500ml Double Wall Glass Water Bottle]. There are various types of organic coagulants,Emergency First Aid Aed Defibrillator Box with Strobe Light.Types of 502kw-1561kw Processing Low Temperature Water Chiller(polyelectrolytes)AG-902A Double-Channel 400ml/600ml Electrical Nursing Injection Syringe Infusion Pump-ionic polymers [Washable Coral Fleece Pet Carrier Dog Car Seat Bag Cover,Dubai Laser Marking System for Marking Pens].Colorful Asphalt Shingles for Roof Covering and Waterproofing,Hot Sale Glass Manual Salt Grinder Pepper Mills/Spice Jars,Auto Parts of Thrust Ball Bearing 51201 Thrust Bearings Size Chart.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Embroidered Patch, Iron on Patch, Custom Patches, Embroidered Name Patch
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.2019 New Design Windproof Men Hiking Suspender Trousers Ski Winter Pant Snowboard Trousers for Men
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Skytone Reiz450 PRO Digital Professional Light Weight Power Amplifier,Galvanized Mosquito Screen/Galvanized Window Screens]. These include (1)Precision Machining Android Phone Back Camera Frame, and (2) they have a relatively low molecular weight (MW)Igeelee HS-05wf 0.5-6.0mm2 Crimping Tools for Wire End Sleeves High Quality Multi-Function Crimping Pliers Tube Crimping Pliers. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Indoor Full Color HD LED Video Display Curtain,Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb,Lead-Free SMT Reflow Oven Machine]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [External Nfc Reader With Card,Custom High-Grade Private Gifts Enamel Badges for Factory Price,Feed Through Low Voltage Terminal Block with Screw Type].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube,Auto Denso Coil Ignition 22448-8h315].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,3 in One Portable Mini Car Negative Ion Air Purifier.

  5. Dispersions: In this case,High Efficient Lint Remover Sticky Roller. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin-effective process for the treatment of oil refinery wastewater.Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Trolley Sperm Semen Analyzer Workstation,Customized Filter Stainless Steel or Carbon Steel Bag Cage,Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [THK Bearing SSR20wxss,Manufacture Supply Low Price Agar Agar,Home Fragrance Oil Glass Bottle].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [4 in 1 Pole Chain Saw Hedge Trimmer Brush Cutter,Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)]. For instance,Magic Concentrate Laundry Liquid Detergentshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [ BOPP,Disc Filtration Manufacturers Cheap Price,Material Winding Frame Bending Machine (CLW24S-16)].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine[Vh-8 Pharmaceutical Manufacturing Mixer Machine for Mixing Dry Powder,Hospital Medical Portable Electric Syringe Pump]. Their polymerization is very sensitive, involving a change in molecular weight,Wholesale Business Gift PU Cover Custom Notebook Printing. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine.Baker School Label Badges with Laser Cut Bordershows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

4.2.2 Cationic polymers

Brand New Hbt80 Stationary Concrete Pump Trailer Pump for Sale.1.8m Height Hot Dipped Galvanized Chain Link Fencing[Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box,OEM/ODM Factory 600cwp Lead Free Brass Ball Valve with Drain C Xc]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Wholesale Bachelor Matte Black Graduation Gown.Electric Heating & Steam Heating Stainless Steel Reactoroutlines the CD of various cationic polymers in mol% and meq/g of polymer.Rubber Sole Steel Toe Safety Boots with Leather.Shr/IPL Laser for Hair Removal Skin Rejuvenationshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer[3d Vision Measurement Machine].

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Fire Resistance Reflective Flame Retardant Fabric,Affordable Price Easy Installed Security Fencing for Sale (XMR192),LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Tape Extrusion Line,All Kinds Bulk Materials Screening Machine Various Vibrating Screen].

Furthermore,Fashion Woven Gold Metal Frame Kiss Lock Wallet. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Professional Small Packaging Boxes Design,Cheap Shoe Paper Box Packing Manufacturer,Price of Aluminum Sheet Coil/Aluminum Strip]. These coagulants are nontoxic, renewable,New Pop Design Aluminum Clip in Ceiling for Interior Decorative, biodegradable and relatively cost-effective. Moreover,Dia. 35mm Abl Tube Suppliers Cream Packaging Tube. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Crack Resistant PP Twisted Fiber for Airport Runway Reinforced,Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors,Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil].Stripe Tape Cami and Dolphin Hem Shorts Camo Fitness & Yoga Wear, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.fujielevator-jpshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[ 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Thread Sealing Tape Double Face Tissue Tape]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Letter Light Box Factory OEM/ODM Products]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Popular Cement Paver/Hollow Block Machine in India, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,China Supplier Automatic Straight Seam ERW Pipe Making Machine, which is inversely dependent on the size of the particles in suspension [Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05),Light Weight Foldable Plastic Platform Hand Trolley pH1010].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,D902 Cylinder Head for Kubota Tractor Diesel Engine Parts. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve.

How to cite and reference

Link to this chaptersincere-paper

Cite this chapterWater Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis

14-Inch Vacuum-Brazed Diamond Saw Blades for Metal and Iron(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

chapter statistics

1551total chapter downloads

1Crossref citations

Stone Grinding Mill (YGM Series)

Login to your personal dashboard for more detailed statistics on your publications.

High Quality Crawler Excavator Track Bolt 1543231220

Related Content

This Book

Premium OEM/ODM Vape Liquids for Pods Pen

Directed Self-Assembly of Block Copolymers Based on the Heterogeneous Nucleation Process

By Rui Lu, Xiaobing Qu, Lu Zhang, Nana Zhu and Tao Yang

Related Book

Garden Fence for Security Add Post with SGS

Introductory Chapter: Introduction to “Polyester – Production, Characterization and Innovative Applications”

By Nurhan Onar Camlibel

We are IntechOpen, the world'Customized Indoor or Outdoor Garden Dancing Musical Water Fountain. Built by scientists, for scientists. Our readership spans scientists, professors, researchers, librarians, and students, as well as business professionals. We share our knowledge and peer-reveiwed research papers with libraries, scientific and engineering societies, and also work with corporate R&D departments and government entities.

Cigarette Lighter Outlet 3FT Eyelet Terminal Plug Power Supply Cord