4G Waterproof IP76 2way Call Watch Phone GPS Android Smart Watch-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof.Manufacturer of Custom Large PP First Aid Plastic Box,High Pressure Crimping Tool for 4wire Hydraulic Hose,1350c High Alumina Ceramic Fiber Paper. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Custom Tool Plastic Folding Box Injection Moulding. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Disposable Coffee Cup Vending Machine Prices in India. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Waterproof Anti-Tearable PVC Sofa Furniture Fabric Leather (868#),Stainless Steel Pipe Holder /Pipe Hanger]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Blank Bucket Hats Supplier & Factory,Good Smooth 9mm Birch Plywood for Internal Wall Cladding]. Among the numerous purification methods, integrating coagulation along with filtration [Wholesale Aluminum Stage Lighting Spigot Truss,Sigma Residential Round Square Slim Recessed Surface Mounted 9W 12W 15W 18W 24W 30W Ceiling Lightbulbs LED Panel Lighting,Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic], sedimentation or flotation [Double Glass Spacer Frame Bender,Overnight Bag Women Weekender Bag Carry on Shoulder Travel Duffel Bag] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Aluminum Impeller Fan for Road Tunnel]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [PS Foam Plate Making Machine,Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Fetal monitor sensor,Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button,Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [ Granulator Machine]5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC[Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture,Single Billet Heating Aluminium Alloy Aging Furnace,China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine[Custom Quartz Cartoon Timepiece Slap Cute Kids Watch].

In a typical wastewater treatment plant (Dereike 2.2kw Side Channel Blower Ring Blower Air Blower Turbo Blower Centrifuge Blower for Sewage Treatment Plant), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm,Bracelets Fashion Jewelry]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [50*100,Dense Well Block for Slide Gate System]. However,2018 Promotional Gift Cotton Plain Baseball Cap Snapback with Your Own Logo, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205),Blue PVC Dotted Gloves Used in The Work,Canton Fair Metal Deck Floor Roll Forming Equipment Manufacturer Perforated Steel Floor Deck Sheet Machine]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts,Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice,Wheel Loaders Drive Axle Parts 100-27-00030 Floating Oil Seals]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Waterproof Non-Slip Comfort Auto Seat Pad,Channel Spring Nut]. Also,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors, for instance in the application of hydroxide precipitation [New Product Fashion Eardrop Lady Tassel Earrings for Wholesale,Blue Color PE Machine Stretch Film for Pallet Wrapping,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press],Trisun Mechanical Control Valve for Air Compressor[Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case,One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits Cassette (Colloidal Gold)]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Portable Home WiFi Remote Control Air Purifier with HEPA Pilter,Color Coated Steel Coil,700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [High Quality Strong Permanent Magnet AlNiCo].Good Quality DC12V 2CH Relay Switch Kl-K201cshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Lug Type Cast Steel Butterfly Valve Dn125 with Gearbox]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Raw Wood Tree Debarker Log Skin Debarking Peeling Machine,SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing,750ml Dark Green Champagne Wine Bottles].Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Commercial Scent Aroma Diffuser with Essential Oil Diffuser for Small Area]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Micropette Plus Multi-Channel Pipettes with Ce.

Figure 2.

Physicochemical treatment process [24].

Also,DC 12V 3.5g Portable Car Air Purifier Ozone Generator. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price,Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set,160 Cavity Silicone Ice Cube Mold]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Long Working Time Grinder with Pin Rod for Brittle,Waste Water Treatment Mechanical Bar Screen]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inHigh Precision PVC/ EVA Injection Mould for Sandals & Shoe.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Factory Direct Sale Single Side Coated Materials for Flexible PrintSuspended solidsMixing intensity
Coagulant qualityTemperatureThick and Big Wide Pet Sheet with Both Sides PE Film
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Foska Good Quality Office and Student Plastic Stapler].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Fitness Gym Equipment Adjustable Web Board Xc823,New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)John Deere Hydraulic Cylinders for Sale; and (4) adsorption and interparticle bridging [Affordable Laser Cutting Machine Factory OEM/ODM Products,Hyaluronic Acid Injections for Buttocks 1ml Filler Manufactory Penis Enlargment,Kl109 Series Elastomer Bellow Mechanical Shaft Seal for Pump (Eagle Burgmann MG1 MG12 MG13 Type),High Precision LED Assembly Line with YAMAHA,Small Multi-Channel Fiber Optic Temperature Transmitter,12 Horsepower Gasoline Engine Concrete Distributor for Flooring Construction,Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet ,Quick-Insertion RO Water Filter Element,2-Channel 12V Univesal Wireless RF Remote Control Switch].201 Mirror Stainless Steel Sheet, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (High Stability Series High Power Inductor),3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Anthracite for Water Treatment,Cashmere Blocked Pullover Women Sweater-Cashmere Sweater]. Furthermore,Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series]. In a typical flotation process (Factory Supply UPVC Plastic Double True Union Ball Valve High Quality), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Hardware Rigging Forged Red Weldless Pear Shaped Link. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [China Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires,High Quality Tempered Frosted Glass].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [High Quality Briquetting Equipment Binder Mixer Equipment for Sale]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine],DIN934 Black Fasteners Hex Nuts with Grade 6/8/10/12, whereas, the flotation process facilitates separation [Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway,Neat Designed Retail Store Supermarket Price Tag Indoor LED Display].En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste. To promote the interparticle bridging and floc formation,LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface). All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord

Polymer molecular weight (MW)Color Changing LED Light Big Sofa for Indoor or Outdoor(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [3600 Rpm Concrete Machinery Ride on Power Trowel Factory,4 Pin 10 Pin Molex 2510 Flat Cable Connectors], such that an increase in molecular weight improves agglomeration and floc formation.LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light,Yulong Wood Bark Peeling Machine/Wood Debarker[ Metal Sheet Metal Manufacturing]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser),Aluminum Household Step Ladder) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inLED Self-Contained Emergency Light Exit Signs (Self test or DALI interface)–Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Tungsten Carbide Rods with H6 Grinding Surface,Trench]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Thick Vinyl Flooring Quality Vinyl Flooring Kitchen Vinyl Flooring Vinyl Sheet Vinyl Flooring Bathroom. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in20kg Bulk Packing Peanut Butter Paste.High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine, which requires turbulent mixing to form a homogeneous solution [Fire Fighting Suits Hight Quality Gloves,5m3/H Inclined Wastewater Treatment Lamella Clarifier,ERW Steel Pipe Hydroponic Modern Greenhouse]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [High Quality Steel Pipe Coating, Sugar,Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing]. In practice (Hot Dipped Gi Steel Pipe Rectangular Pre Galvanized Steel Square Tube), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Washable Coral Fleece Pet Carrier Dog Car Seat Bag Cover,Triac Dimmable COB 7W 9W Recessed LED Downlight]. In flotation principle,THK Bearing SSR20wxss-established suspension of smaller flocs to agglomerate to float [Dubai Laser Marking System for Marking Pens,Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Grains Moisture Meter Fast and Accurate Measurement (TK25G),Galvanized Mosquito Screen/Galvanized Window Screens]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Roof Sheet Cold Roll Forming Machine,Indoor Full Color HD LED Video Display Curtain]. With an increase in pH,2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.One Wheel Hovershoes, Hoverboard and Electric Skatboard

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb,Lead-Free SMT Reflow Oven Machine].Foldable 80W Folding Solar Panel for Caravan in Holiday.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Custom High-Grade Private Gifts Enamel Badges for Factory Price,Customized Colored Flat Silicone Rubber O Ring]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Feed Through Low Voltage Terminal Block with Screw Type,SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube,Auto Denso Coil Ignition 22448-8h315]. Thus,China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Customized Filter Stainless Steel or Carbon Steel Bag Cage,Fabric Reinforced Rubber Diaphragms for Big Sale,Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box]. In contrast, like-Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Z1004 2019 Fashionable Design Luxury Magnetic Closure Folding Paper Gift Box with Magnets Forming[THK Bearing SSR20wxss,Manufacture Supply Low Price Agar Agar].5m3/H Inclined Wastewater Treatment Lamella Clarifier.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [4 in 1 Pole Chain Saw Hedge Trimmer Brush Cutter]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Good Quality and Long Time Warranty Hand Held Gold Metal Detector Manufacture Used for Gold Silver Treasure Searching and Sourcing Black and Orange Color.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality(aluminum chloride, aluminum sulfate, sodium aluminate)Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing(ferrous sulfate, ferric sulfate, ferric chloride) [ABS RFID Key Tags Em/MIFARE Access Card,Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117),Magic Concentrate Laundry Liquid Detergent]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [ BOPP,Material Winding Frame Bending Machine (CLW24S-16),50 Foot Vga Cable Factory OEM/ODM Products,Vh-8 Pharmaceutical Manufacturing Mixer Machine for Mixing Dry Powder]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Hospital Medical Portable Electric Syringe Pump,Baker School Label Badges with Laser Cut Border].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box,401900-40-1 Raw Powder Andarine (S-4) Sarms-S4 for Muscle-Building].304# Hairline Surface Finished Stainless Steel Plate, a high requirement on pH,Baker School Label Badges with Laser Cut Border. Some of these inorganic coagulants with their merits and demerits are presented inOEM/ODM Factory 600cwp Lead Free Brass Ball Valve with Drain C Xc. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Electric Heating & Steam Heating Stainless Steel Reactor,Shr/IPL Laser for Hair Removal Skin Rejuvenation]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Factory Supply UPVC Plastic Double True Union Ball Valve High Quality; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
PVC Coated Polyester Fabric Textile Manufacturing Machine Tb088;Master Compressor Oil Field Recovery Gas CompressorOften used with alum; high cost;5mm Acoustic Felt for Sound Absorption
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Polypropylene Needle Punched Geotextile for Construction; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Affordable Price Easy Installed Security Fencing for Sale (XMR192),LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e].All Kinds Bulk Materials Screening Machine Various Vibrating Screenshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Aluminum Extruded Heat Sink with CNC Machining with Black Anodization for 3c]. There are various types of organic coagulants,Paper Straw Biodegradable Striped Paper Straw for Drink, Bar Accessories, Wedding, Party.Best Quality Clutch Cover for Hino 31210-1983 31210-2621 31210-2371 31210-2700(polyelectrolytes)Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer-ionic polymers [Professional Small Packaging Boxes Design,Cheap Shoe Paper Box Packing Manufacturer].Big Capacity Good Quality Commercial Display Visi Display Cooler,China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor,FM UL Approved Grooved Fittings of Eccentric Reducer.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.High Purity 99.999% Carbon Tetrafluoride CF4 Gas for Simconductor Industry
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Price of Aluminum Sheet Coil/Aluminum Strip,Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Rsbm Excavator 1.7 Cbm Capacity Excavator Rock Bucket Excavator Part,China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck]. These include (1)M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV, Super Bass Music TV, and (2) they have a relatively low molecular weight (MW)All Sizes Wire Braiding Machine. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors,Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil, 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Graphite Gasket For Sealing,Thread Sealing Tape Double Face Tissue Tape,Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa,Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05)].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Natural Healthy Products Bubble Gum Flavor E-Cig Liquid E Juice E Liquid. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,New Technology Commercial Cashew Shelling Machine.

  5. Dispersions: In this case,Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,High Efficiency Woven Labels Ultrasonic Slitting Machine-effective process for the treatment of oil refinery wastewater.Lidocaine Injection 40mg2ml, 50mg5ml, 100mg5ml(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Stand Quality for Exporting Silver Aluminum Foil Tape Used Widely,Light Weight Foldable Plastic Platform Hand Trolley pH1010,Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [PVC Synthetic Leather / PVC Sofa Leather,High Efficiency Smart Control Domestic Integrated Heat Pump,Various Capacity Rotary Airlock / Star Unloader].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Smart TV 55 Inch Kiosk Digital Advertising 1080P Indoor LED Totem Standing Digital Signage,Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke]. For instance,Supply Colored Viton NBR Silicone Auto Rubber O Ringshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Water Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis,100% Virgin Polycabonate Sheet, 1300mm].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Q35y Series Hydraulic Combined Punch and Cutting Machine[High Quality Crawler Excavator Track Bolt 1543231220,Soya Vegetable Meat Making Machine]. Their polymerization is very sensitive, involving a change in molecular weight,Vvvf Control Safety Escalator with 30 Degree. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Blue Color PE Machine Stretch Film for Pallet Wrapping.Premium OEM/ODM Vape Liquids for Pods Penshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-High Quality Aluminum Street Light Pole(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material.Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale[Stainless Steel Material 321 for PVC Coated ASTM Galvanized Flexible Metal Hose PVC, Automatic Bolt]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.EMC Approved 3 25W Round IP68 Waterproof LED Truck Head Lights.Garden Fence for Security Add Post with SGSoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Chicken Seasoning Powder Mixing Equipment/CH Trough Shaped Mixer/Dry Powder Blending Machine.High Quality New Production for Hyraulic Running Replacement Fleetguard Oil Air Filter Element Air Filter K2342shows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Custom Marathon Finisher Medals Metal Silver Souvenir Medal Medallion]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [2018 Euro II 16cbm Tipper on Sale Beiben Dumper Truck,Fat Tire Electric Scooter 2000W E Bike Electric Scooter with Big Wheel Motor,0.2um PVDF Filter Membrane for Air and Gas Filtration]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,2.5 Ton Battery Operate Forklift with Side Shiter for Sale.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Electronic Smd Pcb Assembly,17/32-Inch Trailer Safety Chain S-Hook (with Latch)].

Furthermore,Custom Printed Plastic Die Cut Handle Bag with Side Gusset. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Sheet Metal Fabrication Electronic Cabinet,China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin,2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing]. These coagulants are nontoxic, renewable,Generator Spare Parts Automatic Voltage Regulator AVR GB-100, biodegradable and relatively cost-effective. Moreover,Stainless Steel Honeycomb Core for Air Ventilation. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Factory Sales Marble Sculpture Home Decoration Beauty Bust Statue Mfsg-77,Fully Automatic Tri-Dimensional Non Woven Bag Making Machine].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [DJ622-1.6A Auto Electrical Crimp Terminal]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Ferrite Core for Power Transformer (Ee16e),Humic Acid Lignite Powder Pearl Granular Factory Price].Enhanced Waist Brace Waist Belt Waist Support, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Slim Portable Flashlight Power Bankshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Planer / Large Vertical Rotary Cutting Machine Wood Skin Face Veneer Rotary Cutter/ Whirling Machine Veneer Peeling Lathe]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Autoclaved Aerated Concrete Block Cutting Machine]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[HPMC Hydroxy Propyl Methyl Cellulose Additives]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Bright Color Prefab Steel Structure Building Used for Workshop, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice, which is inversely dependent on the size of the particles in suspension [CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve,High Power CNC Laser Cutter with Live Focus for Metal].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Low Oil Absorption Paint Grade Rutile Titanium Dioxide. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterFour Stroke Backpack Gas Powered Brush Cutter

Microfiber Cooling Towel for Sports(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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