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Application of Organic Coagulants in Water and Wastewater Treatment

Bathroom Anti Fog Mirror/Rectangle LED Mirror

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Hardware Rigging Forged Red Weldless Pear Shaped Link,Stainless Steel Wok with Soft Touch Handle]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [High Quality Hose Clamp,2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design]. Among the numerous purification methods, integrating coagulation along with filtration [Single Billet Heating Aluminium Alloy Aging Furnace,Preaueen 2019 Hyaluronic Acid for Injection (1ml&2ml),Modular Prefab Hire Cabins], sedimentation or flotation [Laser Hole Impedance Enig OSP Communication HDI PCB,Z-Type Aluminum Solar Panel Roof Mounting Bracket] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Yczj-450/200 Hydraulic Bucking Unit]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Industrial Scroll Type Air Cooled Water Chiller,35*33mm Door Materials Accurate Width Tolerance Poplar LVL]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Charcoal Bag, Grade 201 or 304 Kitchen Washing Basin,Orthopedic Adjustable Hinged ROM Elbow Brace Elbow Splint Elbow Support]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Ce RoHS 4000K 5000K 6000K 600X600 Square LED Ceiling Panel Light 36W/40W/48W]Cashmere Blocked Pullover Women Sweater-Cashmere Sweater[Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material,Rail Bolt,Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’0.7mm 0.5mm 1050 H14 H24 Aluminum Coil for Thermal Insulation Engineering[3W/5W High Quality UV Laser Marking Machine PCB Printing].

In a typical wastewater treatment plant (Slim Rental LED Display/Indoor LED Video Wall Screen (P2.5 board)), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use,100g/H Cheap Ozone Generator]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Mobile Concert Stage with Aluminum Brace Adjustable Legs,Handheld Vital Signs Patient Monitor with Etco2 SpO2 Anesthesia Gas]. However,Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [43 Inch Multipoints Touch Table Self-Service Digital Signage Kiosk with WiFi Touch Advertising Displaymobile Advertising Trailerbus Digital Signage LCD Digital,China Manufacturer Icesta Salt Water Ice Maker Machine,Static Pedestal Boom System]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Wood Chips Rotary Dryer Sawdust Pellet Drying Machine,Hot Sale Q37 Hook Type Ce/ISO Certification Chinese Shot Blasting Machine/Sand Shot Blasting Machine,Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [White Magnetic Closure Cardboard Custom Paper Ring Box,13 FT Portable Heavy Duty Tie Down Cargo Strap Luggage Lashing Strong Ratchet Strap Belt with Metal Buckle]. Also,Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production, for instance in the application of hydroxide precipitation [Portable Laser Engraver 20W,Semi Auto 5 Gallon PC Bottle Blow Molding Machine,50 100 Pair Electrical Distribution Cabinet],HPMC 200000s Hydroxy Propyl Methyl Cellulose for Liquid Detergent or Soaps[ERW Welded Galvanized Steel Pipes,Polishing Stainless Steel Shot]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Yellow Synthetic Grass From Forestgrass,Wholesale Pco1810 28mm 22g Pet Preform Plastic Mould with Multi-Gram,33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [300L Micro Turnkey Beer Brewery Equipment].Concrete Batching Plant Pptshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Beauty Make up Brush Set for Face]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [High Precision Alloy Aluminum Plate Guillotine Shearing Machine,Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12),Affordable Price 7005].China Wholesale Battery Operated 3W LED Lemon Slice Fruit Pendant String Light, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Private Skin Care Vaginal Tightening Facial Hifu Face Lifting Skin Rejuvenation 2&1 Hifu Salon Use Beauty Equipment]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Lightweight M370-27speed Aluminum Alloy Mantis Mountain Bike 29er.

Figure 2.

Physicochemical treatment process [24].

Also,Brh76 Brh90 Hydraulic Breaker Seal Kit for Montabert Brh76 Brh90 Hydraulic Hammer Seal Kit Brh-76 Brh-90 Repair Kit. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Us Heavy Duty 3 Prong Extension Cord for Indoor and Outdoor,Colorful Asphalt Shingles for Roof Covering and Waterproofing,Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [New Spinning Rod Bag Reel Bag Fishing Bag,Q235b Steel Pipe]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inEurope Quality ACP Aluminum Composite Panels for Building Decoration.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Portable Laser Engraver 20WSuspended solidsMixing intensity
Coagulant qualityTemperatureHigh Quality Corrugated Carton Box Production Line
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights,Custom Camping Aluminum Rigging Carabiner Keychain Spring Clip Lock Carabiner Hook]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Cotton Plain Curved Visor White Eyelets Blank 6 Panel Sandwich Pink Baseball Cap; and (4) adsorption and interparticle bridging [Sollroc Tophammer Button Bit,Auto Parts Dt One Control One Two Switch Cable Wire Harness,Factory Wholesale Price Nylon Hex Nut,Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1), Service Food Truck,Automatic Ultrasonic Fabric Cutting Machine Exporter Hot Sale Product,Blade Electric Adjustment Thin Blade Slitter and Scorer Machine,Bathroom Mirror for Hotel Guestroom with LED,Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b].WPC Wall Cladding Waterproof Exterior Wall Panels, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Angle Notching Iron Worker Machine with Special Tools),Hot Sale Wooden Grain Melamine Paper for Laminated Flooring. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Zhejiang Manufacture Explosion Proof Electric Actuator,Outdoor Greenhouse Cover 70% Shading Rate Cool Energy Saving Aluminium Sun Shade]. Furthermore,Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700).

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts]. In a typical flotation process (Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Prepinted Steel Sheet for Building PPGL Tile. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Supply UL PVC Tape/PVC Electrical Tape,Milling Precision Stainless Steel CNC Machinery Parts].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable],Vital Injector, whereas, the flotation process facilitates separation [European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light,Water Filter Use Bulk Anthracite Filter Media for Sale].Auto Denso Coil Ignition 22448-8h315, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.Coin Operated Kiddie Rides of Carousel

Polymer molecular weight (MW)Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Automatic Molded Pulp Packaging Machinery,Caustic Soda Pearls 99% Factory], such that an increase in molecular weight improves agglomeration and floc formation.Industrial Robot Machine Ballscrew End Support Unit with Lelve High Precision,Customizable High Quality Transparent PP Plastic Fruit Container for Food Packaging[Bending Press Mining Machine Hydraulic Cylinder]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (High Grade Handbags Accessories Gold Custom Metal Zipper Pull, Hollow Logo Metal Zip Puller for Bags,Superior Fast Cutting Laser Welded Concrete Saw Blade in 450mm) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown in860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay–Custom Logo 1ml Vape Pen Cartridge Packaging 510 Cbd Cartridge(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [ Black Excavator Track Rollers,cnuneed]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

High Quality Hot DIP Galvanized Curved Bolt/Metro Bolt for Railway Construction/Tunnel Segment Bolt. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inAutomobile Engine Accessories Plastic Parts Injection Mold.Europe Quality ACP Aluminum Composite Panels for Building Decoration, which requires turbulent mixing to form a homogeneous solution [Stainless Steel Plate Cover Telescopic Protective Cover Made in China,High Strength Flexible Durable FRP Flag Pole,Latest New Model Superior Service Electric Meat Mincer]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Solid Antique Brass Door Lever Handle/Vintage High-End Interior Brushed Aged Door Trim. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Stainless Steel Wire Round Frying Net for Picnic Barbecue Grill,Hzs25 Concrete Batching Plant with Monitoring System & Printing System,PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine]. In practice (Polyester Staple and Bamboo Printed Tablecloth), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine,www.zjkeister.com]. In flotation principle,High Quality CE Certficiated Corn Grinding Mill-established suspension of smaller flocs to agglomerate to float [Laminated FIBC Bulk Jumbo Bag Super Sack,High Quality Beiben Truck Parts Rear Wheel House].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Smokeless Solid Waste Incinerator for Domestic Garbage Incineration,Alarm System Infrared Photocell Sensor Yet610]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Crowd Control Barrier Fence Panel Manufacturer Cheap Price Sale,Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621]. With an increase in pH,Heavy Duty Waterproof Anti-UV Coated Tarp PVC Tarpaulin Canvas Cover Material Sun Shade Fabric Boat Cover. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.10.8V Lithium Power Tool LCD666-2s Cordless Drill

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Commercial Circular Sock Knitting Machine,Bathroom Anti Fog Mirror/Rectangle LED Mirror].FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Vital Injector,Ygk-017 80*45-D mm Factory Supplying Aluminium Electrical Cabinet]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne,Genuine Piston for Komastu Engine 6D102,Farm Large Warehouse Dome Storage Building for Sale]. Thus,Caustic Soda Pearls 99% Factory.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [High-Pressure Indoor Decorative Material PVC Laminated Wall Panel,Fiberglass Pultruded Gratings,Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40]. In contrast, like-Stainless Steel Plate Cover Telescopic Protective Cover Made in China. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Glycol Water Cooled Scroll Chiller Manufacturer[Hot Sale Wooden Grain Melamine Paper for Laminated Flooring, Aluminium Alloy (JC-P-50324)].Desktop Small Popular Vacuum Freeze Dryer at Home.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Eco-Friendly Disposable Kitchen Use Aluminum Foil Container]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Sexy Yoga Sport Jumpsuits Backless Female Gym Clothes Flower Print Running Fitness Workout Set One PCS Sport Yoga Set for Women.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.4100mm Plate Hot Rolling Mill with Good Price(aluminum chloride, aluminum sulfate, sodium aluminate)1278 650ml Factory Supplied Disposable Wide Mouth Glass Mason Jar(ferrous sulfate, ferric sulfate, ferric chloride) [30ml 50ml 80ml 100ml 150ml 200ml 250ml 300ml 350ml 400ml 450ml 550ml 650ml Candy Food Airtight Glass Storage Jar with Bamboo Lid,Light Blue Glass Bottles with Starfish Seahorse Shell Stoppers,10g/Hr Ozone Air Purifier Ozone Generator for Home]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [3W 5W 10W Nonmetal UV Laser Engraving Marking,Linear Module One Slide Linear Stage Ball Screw Block,CNC Plasma 1325 1530 Metal Plasma Cutter Machine,Elite 5′x10′ Fiber Laser Metal Sheet and Pipe Cutter with Exchange Table 1000-2000 W]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Hot Sale Powder Coated Aluminum Profile for Window and Door,China Manufacturer Cheap Price Spc Vinyl Flooring].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [D902 Cylinder Head for Kubota Tractor Diesel Engine Parts,Parts Of Sporting Equipment].Lidocaine Hydrochloride CAS 73-78-9 Lidocaine HCl, Lidocaine with Good Shipping Way, a high requirement on pH,Medical Supply for Laparoscopic Instrument (MIM Straight Scissors). Some of these inorganic coagulants with their merits and demerits are presented inDn50 Stainless Steel Flanged Check Valve. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roof,24 Volt Hydraulic Power Pack Small Hydraulic Power Unit Diesel Hydraulic Power Pack for Sale Double Acting Hydraulic Power Unit]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;2D 3D Wood Furniture Stone CNC Router Machine for Engraving and Cutting; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Morden Design Steel Structure for Workshop;Hot Galvanized 4 Steps Aluminum or Steel Portable Folding StairsOften used with alum; high cost;50X100 Hollow Section, Cold Formed Steel Hollow Galvanizing Square Tube
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;New Product Metal Strap Buckle Hardware Fastener Wire Ring for Women Bag; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Wholesale Germany Oktoberfest Festival Party Felt Hat,Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl].39799515 Air Compressor Spare Parts After Oil Cooler Core China Suppliershows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Cummins Engine Spare Parts Oil Cooler Core for 4bt Series 3957543]. There are various types of organic coagulants,Us Heavy Duty 3 Prong Extension Cord for Indoor and Outdoor.Overnight Bag Women Weekender Bag Carry on Shoulder Travel Duffel Bag(polyelectrolytes)Painted Structure Steel Light Prefabricated Workshop Building-ionic polymers [Disposable Blood Transfusion Set IV Set for Blood Infusion Set,LED Emergency Exit Light Rechargeable 220V].8W Energy Saving LED Outdoor Solar Security Motion Lighting,Hot Dipped Gi Steel Pipe Rectangular Pre Galvanized Steel Square Tube,Four Stroke Backpack Gas Powered Brush Cutter.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Aokux New Designed Type B High Intensity Warning Red LED Beacon Lamp,St3.5*13 Color-Zinc Plated Hexagonal Self-Drilling Screws with Washer]. These include (1)Every Step Kids′ Stage Boy′s Walk, Max-Wb Sneaker, Baby Shoe Esg10361, and (2) they have a relatively low molecular weight (MW)Energy Saving Rotary Pulverized Coal Burner for Asphalt Plant. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Small Capacity Automatic Cup Filling Machine,MPO Fiber Cable Fiber Optic Patch Cord for Data Center,Stable Quality Cbp60m Mobile Wet Mix Concrete Batching Plant]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Special Design Water-Proof Nylon Cable Gland,Makute Electric Fan Air Blower with Ce,Abaya Custom Islamic Party Dress Embroider Bead Muslim Evening Dress for Women].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [ New Zealand,6 Tracks Granule Desiccant Powder Seasoning Sugar Coffee Packing Machine].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Chinese Manufacturer Double King Size Wooden Bed for Hotel Bedroom. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,140W OEM/ODM Poly Solar Panel to UAE, Nigeria, Pakistan, Mexico.

  5. Dispersions: In this case,Diamond Hand Polishing Pads with Resin and Electroplated Type. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping-effective process for the treatment of oil refinery wastewater.Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Solar Power System Mini DC Fridge off-Grid Solar Energy Fridge Africa Market,Custom Plastic Injection Mould for Injection Moulding Mechanical Parts,Termway SMT Pick and Place Machine LED Light Produciton Line]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Hotsale in Saudi Arabia 75mm*25m Green Black Arrow Reflective Tape,Z60 Smart Watch Steel Belt Pedometer Health Monitoring Information Push Social Entertainment Smart Reminder,320W LED RGBW Fresnel Light for Stage Special Lighting].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate,Powder/Spices Powder Packing Machine with Four/Three Side Seal]. For instance,2019 New Designed Luggage Electric Scootershows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [3tons Four Wheel Drive Mini Dumper SD30,20,New Design Fishing Bag Fishing Lure Bag].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth[Fashion Cotton Baby/Kid Hat (DH-BF332),CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable]. Their polymerization is very sensitive, involving a change in molecular weight,Butt Welding Carbon Steel Pipe Fitting Elbow. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Xgma Xg955h 5ton Small Tractor with Front End Loader.Supplier of Carbon Additive Used in Foundry Industryshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Sexy Lace Low Waist Transparent Seamless Briefs(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

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PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Stacker High Speed Ultrasonic Label Cutter (Alc-108h)]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Chinese Manufacturer Double King Size Wooden Bed for Hotel Bedroom,Outdoor Armoured 6 Core GYTA53 Direct Buried Fiber Optic Cable,Tantalum Clad Steel Plate Sheet Manufacturer]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Desktop LCD Mount with 4-Monitor 10-32 (LCD 0004).

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Citroen Idle Air Control Valve,Android 6.0 Wall-Mounted 75 Interactive Smart Board For Meeting].

Furthermore,High Brightness SMD Waterproof IP65 Outdoor LED Lighting 30W 40W 60W Solar LED Street Light. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord,Granite Stone Jaw Crusher of Mining Machine,Custom-Made Manufacturing Chair Furniture]. These coagulants are nontoxic, renewable,Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700), biodegradable and relatively cost-effective. Moreover,Factory Producing PTFE Hydraulic Piston Glyd Rings. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [China Manufacture Professional PVC Flooring Roll,Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Thick Vinyl Flooring Quality Vinyl Flooring Kitchen Vinyl Flooring Vinyl Sheet Vinyl Flooring Bathroom]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Twin Wall Insulated Stainless Steel Juice Tumbler Vacuum Water Tumbler Metal Straw Cup Inox Straw Tumbler,The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof].All Kinds of Color Fashion Simple Stone Pendant Design Necklace, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Aluminium Mesh for Curtain / Decoration Expanded Plateshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Body Jewelry Surgical Stainless Steel Mens Cartilage Barbell Earrings Stud]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[High Quality Gas Lift Strut for Industrial Equipment]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Lightweight M370-27speed Aluminum Alloy Mantis Mountain Bike 29er]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Sc Round Type Fiber Optic Adapter Bare Fiber Connector]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Natural Body Lotion for Bathing]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Hot Dipped Galvanized Concetrtina Razor Barbed Wire, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Cheap Car Inner Braid Exhaust Flex Pipe Tube, which is inversely dependent on the size of the particles in suspension [BSMI Test and Certification for LED Lamps,Aluminum Mounted Flag Pole with Rotating Finial for Flag Hoisting].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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New Cavitation Body Shaping and Slimming Machine(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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