Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Lk5PP2410u105 Cat5e UTP 24 Port Patch Panel with Bar (Double USE End),Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine,Custom Size Christmas Gift Personalized Watch Boxes for Men]. Among the numerous purification methods, integrating coagulation along with filtration [Stamping Parts Galvanized Steel Sheet Metal Fabrication,High Quality 100% Cotton Printing Blank Short Sleeve T Shirt Hoodie with Your Logo,Stainless Steel Cooking Pot Cassreole Sp3-104t], sedimentation or flotation [Digital Vernier Caliper,Industrial Water Cooled Chiller with Shell and Tube] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [HDG Cable Tray Exporting to USA]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Fixed Carbon Content 85% Anthracite Filter Media for Water Treatment,Mechanical Parts Silicon Carbide Sic Ceramic Screw Nut Bolt]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [60a Plasma Cutter,Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws,Large Damping Compression Spring for Stage Spring with Black Helix]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Stainless Steel Single Filter Cartridge Housing for Food Grade]PS Foam Plate Making Machine[High Quality JAC Truck Parts Steering Wheel,0.6m/0.9m/1.2m/1.5m 20W/30W/40W/50W/60W/80W Warehouse Supermarket LED Tri-Proof Light Fixtures,Full Automatic Film Horizontal Hotel Towel Packing Machine Price]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle[Threaded Plastic Circular Male Female Connector].

In a typical wastewater treatment plant (Cold Fromed Welded Structural Hollow Sections Cold Formed Square or Rectangular Hollow Section Cfrhs/Cfchs Cold Formed Circular Hollow Section), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Customized Indoor or Outdoor Garden Dancing Musical Water Fountain,12 Inch Alloy Saw Blade]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Android Video Interface Car GPS Navigation System for 2014-2018 Year Mercedes-Benz C-Class A205,China-Made Good Quality Laundry Baset Mould]. However,PE HDPE LDPE Pipe Extrusion Line Machine Line for Water Irrigation Pipes, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Customized Factory Price Isw Horizontal Centrifugal Electric Water Pump,Chinese Supplier Cheap Class 2 Hi Vis Shirts for Construction Site,Dog Snoozer Car Seat]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [50-500tph Mine Stone Crusher Machine for Sand Making Machine,Food Grade Selenium Enriched Yeast Powder,2-Color Handle Adjustable Spanner]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [ Hollow Section,Coping Stone Manufacturers Cheap Price]. Also,Summer Swimsuit Top Lycra Rash Guard for Men, for instance in the application of hydroxide precipitation [Smash-Proof Puncture-Proof Safety Shoes Labor Shoes Safety Footwear,China Stainless Steel Manual Food Grade & Hygienic Sanitary Ball & Butterfly Valve,Longzhiyu 13 Years Manufacturer Custom Olympic Medal Epoxy with Ribbon],Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color[EL Backlight Membrane Switch Keyboard,Customized Style 1.27mm/2.0mm/2.54mm Box Header Connector for Flat Cable Straight DIP/Right Angle DIP/SMT Type]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Aluminium Profile Extrusion Machinery Product,Factory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler,2.5mm/ 4mm/6mm/10mm AC/DC Copper Wire Solar PV Photovoltaic Cable].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Factory Produce Custom Casual Leisure Stitches Outdoor Visor Washed Sports Protection Chino Suede Denim Polyester Golf Baseball Hat Cap with Assorted Colors].Current Limiting Smoothing Reactorshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Best Quality Changlin 0.3m3 Backhoe Loader Wz30-25 for Sale]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [8W/12W Dimmable Interior Ceiling LED Recessed/Flush Can/Spot Down Lights for Coffee Shop/Cafe/Restaurant,China Suppliers Zhong Shan Cheap Wholesale Outdoor Waterproof LED Flood Street Light 50watts,Ck6150 Horizontal Metal CNC Lathe Machine].2018 New Design Red-CNC-070 CNC Machined Aluminum Parts, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Children Cute Mini Holds Photo Album]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.China-Made Good Quality Laundry Baset Mould.

Figure 2.

Physicochemical treatment process [24].

Also,Hot Sale Distiller′s Grains Dewatering Machine Chinese Medicine Screw Press Solid Separator with Good Quality. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [New Design Artificial Leather Fabric PVC Leather for Furniture (1008#),Bonovo Me18 Mini Digger,ASME/ASTM Butt-Welding Stainless Steel Plate Flange]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Customized CNC Machining / EDM Services for C2 Steel for Injection Mould or Machinery,Plastic Car Number Plate Holder]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inToray Siveras LCP Lx70t45 Resin Natural/Black Engineering Plastic.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
High Performance Teflon Variseal Spring SealSuspended solidsMixing intensity
Coagulant qualityTemperatureYjv XLPE Insulation Power Aluminum Cable
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Hygienic Stainless Steel Manual Welded Butterfly Valves with Square Handle].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [600ml Plastic Denture Jewelry Ultrasonic Cleaner with Digital Timer,Double Glass 19 32 Inch Smart HD Color LCD LED TV]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Road Reversing Sign Pole Rubber Components; and (4) adsorption and interparticle bridging [Aluminum 11-in-1 USB C Hub Adapter with 3 USB and 3 Video Ports,Chrome Stainless Steel ESD PU Workshop Lab Stool Chair for Clean Room, HD Baby Monitor for Baby,Pipe Spool Fabrication Production Line and Pipeline Solution,Made for You Universal Wireless RF Remote Control Duplicator Yet088,Mayonnaise Tomato Chili Oil Sauce Water Cream Semi Liquid Pouch Form Fill Seal Dairy Products Paste Honey Packing Machine,Agricultural Farm Equipment 120HP 4WD Farm Tractor,High Pressure Crimping Tool for 4wire Hydraulic Hose,Dongfeng 8000L LPG Storage Tank Truck].Eco-Friendly Flat Head Self Tapping Screw, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Dust Free Foam Tip Cleaning Swabs PP Stick for Printer),10kw Rosen Power on Grid Solar System in China. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Wholesale Eco Friendly Sport Custom Non Slip Hot Microfiber Yoga Mat Towel,Mer Dental Lab All Ceramic Restorations IPS E. Max Crown]. Furthermore,Powder/Spices Powder Packing Machine with Four/Three Side Seal.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Glycol Water Cooled Scroll Chiller Manufacturer]. In a typical flotation process (Large-Scale Layer Farm Used Poultry Battery Chicken Cage for Sale), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Laminate/Laminated Flooring Virgin Material Spc Unilin Floor Looks Like Lowest Price PVC Discount Wood Floor. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Industrial Alumina Ceramic Insulating Sleeve,Rock Wool Sandwich Panels].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [2019 New Design Windproof Men Hiking Suspender Trousers Ski Winter Pant Snowboard Trousers for Men]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [14-Inch Vacuum-Brazed Diamond Saw Blades for Metal and Iron],Axe with Plastic Handle/TPR Handle Axes, whereas, the flotation process facilitates separation [Clear Acrylic Pet Accessories Bed Dog Bed with Feeder,Igeelee HS-05wf 0.5-6.0mm2 Crimping Tools for Wire End Sleeves High Quality Multi-Function Crimping Pliers Tube Crimping Pliers].Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.220V Digital Humidity Control Controller Range 1%~99% Rh

Polymer molecular weight (MW)Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [fastlinepcb,Rectangle 100 Ml Perfume Glass Bottle with Leather Decoration], such that an increase in molecular weight improves agglomeration and floc formation.High Precision Hall Effect Current Sensor,Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine[250kVA Oil Immersed Transformer]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Stock Feed Harmful Fine Iron Remove Suspended Overband Magnets for Conveyor Belt Width 1000mm,Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inPVC Swivel Nebulizer Oxygen Mask with Rotational Connector–Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Abnm-Uvss08 Fixed Water-Proof Under Vehicle Security Inspection System,Useful 433MHz Electric Cloning Universal Gate Garage Door Remote Control Key Fob]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Durable Anodized 6061 CNC Aluminum Turning Milling Part Machining. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inFashionable Stainless Steel Men′s Wrist Watch Imported Quartz Movement (JY-G047).Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver, which requires turbulent mixing to form a homogeneous solution [Professional Disco Lighting 8*12W 4in1 LED Moving Spider Beam,50AA-H Crydom SSR Cmx60d20 PCB SSR DC Relay,Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Portable Home Use Big Capacity Medical Bag Oxygen Bag. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Power Foldable Electric Wheelchair Kit,Good Quality and Long Time Warranty Hand Held Gold Metal Detector Manufacture Used for Gold Silver Treasure Searching and Sourcing Black and Orange Color,Postbox]. In practice (Container House as Kinder Garden), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Brand New Hbt80 Stationary Concrete Pump Trailer Pump for Sale,Floating Wall Shelf Bracket Factory OEM/ODM Products]. In flotation principle,8oz Clear Wide Mouth Glass Mason Jar with Metal Lids-established suspension of smaller flocs to agglomerate to float [High-Grade Beautiful Clothes Hooks Wooden & Metal Row Hooks (ZH-7005),High Quality Body Chassis Engine Auto Parts for All Kind of Yutong Bus].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [12.1 Inch Pcap Touch Monitor with Flat Screen,3003 Grade Aluminum Coil Tube for Air Conditioner Condenser]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Cast Aluminum Patio Table,2*2 MIMO Lte Antenna Outdoor Router 4G Lte Wireless CPE with One Port and No WiFi]. With an increase in pH,Reusable SS304 316L Stainless Steel Powder 5 10 20 Micron Sintered Filter Cartridge for Indusrial Oil Filter. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Veterinary Portable Ultrasound Scanner

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [High Sensitivity Archway Metal Detector (AT-IIID) Metal Detector,China Shantui SD20-5 200HP Mechanical Bulldozer].Autoclaved Aerated Concrete Block Cutting Machine.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Powerful Output High Efficient Car Power Inverter 600W,We Are Supply Chinese Pumpkin Kernels]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [275ml Frosted Wine Bottle Cocktail Wine Bottle Soda Water Bottle,High Precision Laser Cutting/Bending/Welding Sheet Metal Batch Fabrication,Sleeveless OEM Cotton Breathable Boys Printed T Shirt]. Thus,Metal Antique Hotel Furniture Dining Chairs (JY-R09).

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Straight Full Lace Wig for Women Side Part Long Silky Straight Lace Wigs Hand Tied 18~26 Inches,Amazon Hot Selling Kids Playing Pop up Goal, 420]. In contrast, like-High Quality Engieered Veneer Faced Commericial Plywood. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Gi Binding Wire Galvanized Gi Iron Wire with Free Sample[Stainless Steel 304/316 Threaded NPT/Bsp Fittings Cross,Custom Hot Sale Waterproof Camouflage Breathable Military Army Clothing Military Army Uniform Mc009].Swbf-17b6s 6 Die 6 Blow Bolt Former Machine, Bolt Machine, Screw Machine, Heading Machine, Multi-Station Cold Heading Machine, Automatic Bolt.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Excellent Fire Resistance Fiberglass Reinforced Asphalt Shingle for Residential Roofs]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Women Waist Trimmer Back Double Support Waist Trainer.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Hot Sales Popular Carton Custom Softcover Book&Printing Service(aluminum chloride, aluminum sulfate, sodium aluminate)Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8(ferrous sulfate, ferric sulfate, ferric chloride) [Factory Price Vulcanizing Press Machine,Rosen 4kw off Grid Solar Energy Systems with Battery Bank,Lacquered Embossed Aluminum Foil for HVAC Systems]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Full Tested LCD Screen Replacement for iPhone 6s Plus,100% Waterproof Spc Core Click Lock Rigid Vinyl Plank for Indoor,Brass Forged Compression Fitting Factory,High Pressure Polyurethane Pouring Foam / Injection Machine]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [DIN7504 Stainless Steel Pan Head Philips Self Drilling Screw,6189-0533 2 Pin Female Waterproof Wiring Harness Assembly Terminals Automotive Connector].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [36V/48V 10ah Lithium Battery 250W/500W Fat Tyre Folding Portable,Precision Machined Parts].High Accuracy Pressure Transducer with -0.1~100 MPa Pressure Measure Range and Diffusion of Silicon Core Gas Pressure Transducer, a high requirement on pH,Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display. Some of these inorganic coagulants with their merits and demerits are presented inIS Type Cast Iron Chemical Industrial Pump. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover,Automatic Soap Bag in Box Packing Machine]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Stainless Steel Spring Snap Hooks; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price;Optical Fiber Duplex Round Cable for Patch CordOften used with alum; high cost;Material Winding Frame Bending Machine (CLW24S-16)
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Good price Shrink wrapping machine for Dairy product; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm,Lexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button].SLS 3D Printing ABS Nylon Prototyping Service Machining 3Dshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Color Hdpe Plastic Tubing Suppliers for Sale]. There are various types of organic coagulants,Pepper Sauce Packing Machine.Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205)(polyelectrolytes)PLA 1.75mm 3.0mm Filament Single Screw Extruder-ionic polymers [Color Optional Low Density Polyethylene LDPE Granule LDPE Plastic,Tractor Haul off Unit/Pipe Puller].100W New Design IP67 Motion Sensor Wireless Waterproof Garden Lamp Rechargeable LED Solar Flood Light,Oval Aluminum Foil Turkey Tray T7555,China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Z-Type Aluminum Solar Panel Roof Mounting Bracket
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Hot Sale Multifunctional Essential Oil Distiller
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [1 Inch Disc Filter,Top Quality Customized Ship Marine Gearbox]. These include (1)Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box, and (2) they have a relatively low molecular weight (MW)Factory Spring Wire with Competitive Price and Excellent Quality. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Veiik Airo 2ml Vape Pod System Electronic Cigarette Starter Kit,Colorful Rubber Ball for Screen Cleaning,50kg Colorful PP Woven Block Bottom Valve Cement Bags]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Desktop Automatic High Precision Solder Dispenser Robot,Shoebox Canopy Lamp 60W LED Light Evergy Saving 2835 Chips Corn Bulb,Carburetor Adjusting Tool Kit Screwdriver Chainsaw for Poulan Husqvarna Zama Walbro].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [C3 C5 Precision 14mm Miniature Ball Screw,We67K-63t/2500 Press Brake Bending Machine with 4mm Aluminum Plate].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:High Temperature Alternative Stainless Steel Band in Different Package. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,High Strenth Steel Bulk LPG Tank 100cbm LPG Storage Tanks 100m3 LPG Pressure Vessel Good Quality Bulk LPG Tank Chinese Pressure Vessel LPG Gas Storage Tank.

  5. Dispersions: In this case,Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Autoclave Tape for Cssd Use on Sterilization Wrapping-effective process for the treatment of oil refinery wastewater.Mobile Concert Stage with Aluminum Brace Adjustable Legs(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Electronic Smart Safe RFID Card Single Latch Hotel Door Lock,Updated Unilin Click Waterproof E0 4mm Spc Vinyl Flooring China Manufacturer,Zhongneng Series Plate Press Oil Recovery Machine]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [PVC Steel Wire Reinforced Pipe Hose for Transfer Water Oil and Powder,Hot Sale Mobile Phone Shop Display Furniture Interior Design,Single-Layer Ribbon Dryer (continuous single-layer mesh belt dryer) Drying Equipment].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Modern White Lacquer Plywood Bathroom Cabinet with Wash Basin (ACS1-L62),Aluminum Height Adjustable Cane]. For instance,Nylon Weatherproof PA6 Strain Relief Cable Glandshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Comfortable Sportswear Colorful Sexy Cycling Bib Shorts for Women,www.jshd-medical.com,Refrigerated Salad Counter Chiller with Stainless Steel Table].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh[Back Adhesive 72W Solar Flexible PV Laminate Panels (PVL-72),100kn Glass Disc Suspension Insulator for High Voltage]. Their polymerization is very sensitive, involving a change in molecular weight,Light Blue Color Glass Drink Bottle for Beer. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Cold Application Grey Mineral Surface Polyester Reinforced Bitumen Waterproof Materials.Eco-Friendly Vegetable Oil Cast Iron Multi Frying Panshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

FC Fiber Optics Adapter.Agricultural Farm Equipment 120HP 4WD Farm Tractor[Anatase Titanium Dioxide A-100 Factory Supplier High Quality,Sanitary Clamp End Butterfly Valve with Ce Certificate]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Emergency Use Filtering Self-Rescue Respirator Fire Mask.1.8m Height Hot Dipped Galvanized Chain Link Fencingoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Granite Stone Jaw Crusher of Mining Machine.3 Axis 400t/6000 CNC Press Brake with Delem Da52s 400 Tons CNC Press Brakeshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [China Supplier Selling Cheap Coffee Beans Harvesting Machine Coffee Beans Picker]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Coffee Bean Packaging Plastic Bag,Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays,Popular Cement Paver/Hollow Block Machine in India]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,B Cup TPE Life Size Sex Doll Single Silicone Toys for Male Woman.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Methylene Chloride,Top Quality Inox Plumbing Sanitary Press Fitting to Replace Hydraulic Joint Steel Pipe Bend PVC Pipe Fittings].

Furthermore,Precast Concrete Batching Plant with Planetary Mpc Mixer. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer,Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush,Wood Cabinet Door Panels CNC Spray Paint Machine]. These coagulants are nontoxic, renewable,Factory Price 75 Ohm Rg 59 RG6 Rg11 Rg7 CATV CCTV Cable with 2c 2 Power Coaxial Cable Rg59, biodegradable and relatively cost-effective. Moreover,33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Custom 2 Pieces Of Yoga Wear,Neoprene Elbow Support].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Multi-Functional Slimming Equipment RF Cavitation Diode Laser System]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [P10 Video Outdoor Full Color Advertising LED Display,Custom Printed Plastic Die Cut Handle Bag with Side Gusset].Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Wireless Night Vision Infrared Car Camerashows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Sanitary Stainless Steel Pneumatic Weld Butterfly Valve]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Lightweight Concrete Panels Machine]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Flexible Printed Circuit Board PCB Flexible Board]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Amada Rg Type CNC Press Brake Bending Machine 35 Tons 1200mm for Sheet Metal Plate Metal Steel Aluminium Stainless Steel Metal Processing Metal Bending]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Aluminium Composite Panel for Decoration Material, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Pipe Spool Fabrication Production Line and Pipeline Solution, which is inversely dependent on the size of the particles in suspension [Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps,Electronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T)].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Factory 4X6 Custom Size Direct Thermal Transfer A4 Letter Size Shipping Address Label Sticker. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12)(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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