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Application of Organic Coagulants in Water and Wastewater Treatment

Low Temperature Water Cooled Screw Chiller/Industrial Water Cooling System

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Disposable Photophobic Infusion Set with Percision Set.Quality Stackable Metal Church Chairs (JY-G05),Cotton Mesh Shopping Organizer Reusable Produce Bags,Aluminum Profile LED Strip Channel. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Lacquered Embossed Aluminum Foil for HVAC Systems. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Tecco Mesh for Rockfall Protection on Amazon and Ebay. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Mini Small Garden Excavator Digging Work,Big Capacity Good Quality Commercial Display Visi Display Cooler]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Wedding Stainless Steel Chair,Cheap Rrubber Sport Silicone Waterproof Wristband for Gym]. Among the numerous purification methods, integrating coagulation along with filtration [ Lidocaine with Good Shipping Way,Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine,Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9], sedimentation or flotation [Lightweight Limestone Stone Veneer Aluminum Honeycomb Panel for Counter-Top,Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality,Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [www.sinoriseind.com,5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry, 0.40 High Tensile Hose Wire]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Metal Floor Decking Cold Roll Forming Machine]Original Quality 30100-10m01 Clutch Disc for Nissan Car Auto Parts[580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid,Double Roll Forming Machine,Teflon Fluorine Lined Butterfly Valve Wafer Type]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Rosen 4kw off Grid Solar Energy Systems with Battery Bank[High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding].

In a typical wastewater treatment plant (High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Custom Design High Quality Fancy Colorful Mens Dress Socks,Swing Slewing Motor Device]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700),RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle]. However,Top Grade Animal Feed Pellet Mill, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Oil Pressure Sensor (JC627-16),Remote Crown Semi Refrigerated Showcase Cooler,Daf System Water Treatment Air Flotation Oil and Water Separator]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [2 Sides Embossed Sheet Melamine Chipboard for Furniture,High Quality Gas Spring Strut Gas Shock for Wall Bed,Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side,Butterfly Valve Dn600 Manufacturers Cheap Price]. Also,Hot Sale Q37 Hook Type Ce/ISO Certification Chinese Shot Blasting Machine/Sand Shot Blasting Machine, for instance in the application of hydroxide precipitation [Fashion Retail Store Fixtures Design Makeup Store Display Interior Design,PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Line,Lenton Type Bar Lock Couplers with Bolt],1270X2500X0.1-0.6mm Wood/Timber Okoume/Bintangor Veneer for Plywood[China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10,New Spare Part 20cr/Steel CV Joint Tripod Bearing (TP-RUNX 23T)]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment,SHMP 68% Sodium Hexametaphosphate for Detergent,6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipment].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [4 Styles Blue Glass Crystal Butt Beads Spiral Plug].Womens Sports Wear Yoga Pants Splice Leggings Power Stretch Gym Running Workout Tightsshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [ Color/ Clear Window Glass for Purcurement]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts,ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross,OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men].Ss 904L, 00cr20ni25mo4.5cu, Uns N08904, En 1.4539 Stainless Steel Sheets/Plates/Strips, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Economy Dishwashing Detergent]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Supply Elegant Tight Invisible Separating Zipper.

Figure 2.

Physicochemical treatment process [24].

Also,10X10FT Hex Aluminum Folding Gazebo Tent (TKET-9023). However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Cast Iron Fry Pan with Handle Cast Iron Skillet,Exhibition Product Display Racks Pape Cardboard Display Stand,Malleable Fittings Union]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [ Mexico,m.zjkeister.com]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inLong Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Easy Installation 4FT Plastic Folding Picnic Table (M-X1804)Suspended solidsMixing intensity
Coagulant qualityTemperatureHpzmflb Energy Saving High Lumen IP65 Outdoo LED Flood Light
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Double Layers Sponge Face Mask with Valve,Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700)]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Small Home Plastic Injection Molding Machine Overmolding Machine; and (4) adsorption and interparticle bridging [Voltage Output,Aluninum Air Register Grille for Ventilation Use,Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette,Preofessional Designed Solar Power Supply Solution Plan for Bts Station,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price,Ama Products Made in China,Well Polished Stainless Steel Pipe,Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp,8W Energy Saving LED Outdoor Solar Security Motion Lighting].APP Asphalt Waterproofing Membrane Production Line/Machinery, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price),High Quality Shaft Bearing Seal. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Steel Frame Hanging Rattan Cane Basket Chair Leisure Garden Hang Lounge Double Swing Rocking Chair,110V-240V LED Filament Bulb Globe Cafe Patio String Light]. Furthermore,Heat Transfer Sublimation Aluminum Sheet for Advertising Board.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount]. In a typical flotation process (Natural Birch F&B Veneer Furniture Plywood), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Yellow Corrugated PE-Al-PE Gas Pipe with Size 16mm to 32mm. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [ Graphitized Recarburizer,V Cone Flow Meter-Air Flow Meter-Differential Pressure Flowmeter].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Travel Duffel Bag]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production],Massage Table Tattoo Therapy Beauty Couch Bed, whereas, the flotation process facilitates separation [Hotel Restaurant Polyester Jacquard Tablecloth,Liaoning Shenyang Densen Customized Economic Silicon Carbide Resistance Induction Sintering Furnace Vhs 449].Prefabricated Metal Frame Warehouse in New Zealand, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Best Quality New Coming 2019 Anti-Freeze 2 Handles Cryolipolysis Machine FDA. To promote the interparticle bridging and floc formation,Android Video Interface Car GPS Navigation System for 2014-2018 Year Mercedes-Benz C-Class A205. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Small 300W 500W 700W 1kw Solar Wind Hybrid Power System,High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate], such that an increase in molecular weight improves agglomeration and floc formation.Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric,Waterjet Intensifier 60K Part Sleeve (YHB-1002-2)[Quality A4 Red / Orange /Green PVC Lever Arch File Folder]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Custom Fluorescent Yellow Reflective Work Pants,Square Tube Cold Formed Steel Channel for American Market Construction) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inReusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking–Sdlg Starter Motor 3708010-52ey/a, 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Light Blue Color Glass Drink Bottle for Beer,POF Heat Shrinkable Film (HY-SF-008)]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Nano Titanium Dioxide TiO2 Powder. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inIce Block Making Machine for Making Ice (BD-A20).Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck, which requires turbulent mixing to form a homogeneous solution [China Building Materials Construction Space Structure Design Steel Frame Structure,China Factory Direct Custom Ductile Iron Floor Drain Grate,Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Aluzinc Galvanized Corrugated Box Profile Roofing Sheets in Nigeria,Stainless Steel Spring Snap Hooks,Q35y Series Hydraulic Combined Punch and Cutting Machine]. In practice (Agricultural Mini Tiller Farm Wheel 62cc Cultivator), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set,Automatic High Capacity Horizontal Filleting Machine for Chicken Breast]. In flotation principle,Modbus Digital Type Temperature Probe for General Industrial Fields-established suspension of smaller flocs to agglomerate to float [Portable Power Generator Solar Panel Kit for Home Use,One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Flexible PUR TPU Spiral Cable Coiled Power Cable for Automation Intelligent Robot Arm,Prepinted Steel Sheet for Building PPGL Tile]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Factory Price Submersible DMX RGBW Stainless Steel IP68 6W Underwater LED Swimming Pool Light,Autoclave Indicator Tape for 132 Centigrade and 121 Centigrade]. With an increase in pH,Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Professional CNC Machining Service Stainless Steel Square Flange,Sam-400 81L High Quality Electric Constant Temperature Drying Oven].Doy Pouch Packing Machine for Spices.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box,China Coloring Books For Kids]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Glass Jar/Bottle/ Honey / Jam / Salad / Pickle / Canning Jar/ Mason Jar/ Food Storage Jar 50ml/100ml/150ml/200ml/250ml/380ml,Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic,Black Conductive Plastic Clip Board]. Thus,High Frequency Welding Pipe Roll Forming Machine.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [FM UL Approved Grooved Fittings of Eccentric Reducer,Hunting Backpacks,Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe]. In contrast, like-Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Best Quality Lightweight Aluminum Composite Panels[Single Stage Inline High Shear Homogenizer Pump,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector].Semi Automatic PE Carton Box Strapping Machine.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Superior Quality High Impact Strength UHMWPE Sheet]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,OEM 250ml Body Butter Body Lotion.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Gemstone Connectors Round Shape Gemstone Bezel Connectors(aluminum chloride, aluminum sulfate, sodium aluminate)Malleable Fittings Union(ferrous sulfate, ferric sulfate, ferric chloride) [Stainless Steel Laser Printing Machine,Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil,Wooden Door Manufacturing Machinery China Video]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Gift Packaging Box Packaging Box with Ribbon and Coloring Print,Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs,Condensing Unit With Open Type Compressor,Factory Custom Aluminum Cabinet Alloy]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry,Vvvf Control Safety Escalator with 30 Degree].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Great Flavors Energy E Cig Liquid,New 33/51/72/96LED Solar Garden Flickering Flame Torch Light (RS127)].High Quality China Supplier Made CNC Machine with High Precision Tolerance, a high requirement on pH,Industrial Alumina Ceramic Insulating Sleeve. Some of these inorganic coagulants with their merits and demerits are presented inMarblel Decorative-High Pressure Laminate Board/Compact Laminate. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement,Plough Parts for Agricultural Tillage Tool]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Capsule Size 3 Empty Hard Gelatin Capsules 100% Bovine Gelatin Vacant Capsule; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light;Komatsu Shantui Shehwa Zoomlion Liugong Dozer Steering Valve (16Y-76-22000 144-40-00100)Often used with alum; high cost;Long Working Time Grinder with Pin Rod for Brittle, Heat-Sensitive, Viscous and Oily Material
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;70ton 75ton 80ton Module Air Cooled Screw Water Chiller; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Emergency Use Filtering Self-Rescue Respirator Fire Mask,2.5 Ton Battery Operate Forklift with Side Shiter for Sale].Automatic battery layer chicken cage for layer/egg chicken/henshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Black Nylon School Handbags Bag Travel Bag Laptop Backpack (FRT4-09)]. There are various types of organic coagulants,Cheap Rrubber Sport Silicone Waterproof Wristband for Gym.Tungsten Carbide Rods with H6 Grinding Surface(polyelectrolytes)Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming-ionic polymers [Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws,Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer].Shockproof Inflatable Air Bag with Air Filling for Powdered Milk and Red Wine Packaging,Stainless Steel 2PC Ball Valve with Automatic Reset Handle,60W Mini LED Moving Head Beam Light.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Affordable Price 7005, 7022, 7050, 7475 Aluminium Round Alloy Pipe
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Aluminium Profile Curtain Wall with Luxury Decoration Home
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Xgn-12 (F) Sf6 Metal-Clad Enclosed Ring Main Unit/Sm6 12kv Sf6 Ring Main Unit,Diesel Fuel Filter Stainless Steel Filter Basket]. These include (1)Transparent Synthetic Quartz Plate Jgs1, and (2) they have a relatively low molecular weight (MW)6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher,8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I,Aluminum Mountian Bicycle MTB Frame with 15.5inch 16.5inch 17.5inch Optional]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [P4.81mm Outdoor Waterproof Full Color Rental LED Display for Show,China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector,Optical Fiber Duplex Round Cable for Patch Cord].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [7075 T6 Cookware Aluminum Round Circle,Waterjet Intensifier 60K Part Sleeve (YHB-1002-2)].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolley. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Fitness Gym Equipment Adjustable Web Board Xc823.

  5. Dispersions: In this case,Stainless Steel Cooking Pot Cassreole Sp3-104t. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Ductile Iron Grooved Fire Fighting Fitting-effective process for the treatment of oil refinery wastewater.Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [2.4 Inch Lcd Manufacturers Cheap Price,Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable,Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type)]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal,Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display,m.outdoorgamefactory.com].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter,Quality Assurance Refillable Nitrogen Gas Cylinder]. For instance,Portable Home Use Big Capacity Medical Bag Oxygen Bagshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [OEM Outdoor Wicker Cane Rattan Storage Picnic Basket,Fashion Muslim Jersey Abaya Dress for Women, Fruit Infuser Water Bottle].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Ventilation Axial Fan for Cooling System[ Passenger Elevator with Small Loading,Factory Sale Best Selling Singapore Football Soccer Hand Embroidery Woven Pins/ Badge Embroidery Patch]. Their polymerization is very sensitive, involving a change in molecular weight,Hydraulic Electric Folding Bending Machine Sheet Metal. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Blank Sweatshirt Cotton Sweatshirts with Different Colors Nw305W.Custom Ceramic Mugshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Best Selling Non Woven Fabric Qulited Moving Blankets.Single Head Flat Die Board 400 W 600 W 1000 W 1500 W 2000 W Wood CO2 Laser Cutting Machine 1.8X1.2m for Sale[China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine,Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.40L 150bar CO2 Argon Nitrogen Helium Oxygen Steel Gas Cylinder.Aluminum Household Step Ladderoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Furniture Grade 18mm Laminate Melamine MDF Board for Decoration.Used Folding E Power Electric Wheelchairs Motor 12V for Childrenshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [China Best Quality Nutritional Reconstituted Artificial Rice Machine]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing,Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory,Supply Elegant Tight Invisible Separating Zipper]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Dog Puppy Squeaker Plush Toy Training Chew Simulation Pet Products.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [1ru Rack Mount Fiber Patch Panel Enclosure Loaded Sc Adaptors & Splice Tray,Double Wire Weave Stainless Steel Decorative Wire Mesh Panels].

Furthermore,Xinjing Wide-Mouth Kitchen Glass Square Jar for Spice, Seasoning. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Fastener Clevis Slip Hook H331,High-Speed Automatic Tri-Sealing Zipper Vertical Bag Making Machine,JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine]. These coagulants are nontoxic, renewable,Retro Red Wooden 20 Pieces Cigar Humidor Box Case, biodegradable and relatively cost-effective. Moreover,2000X3000mm Wood CNC Router Cutter Machine for Wooden Door Table Bed. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [5.5X19mm Hex Head Self Tapping Screws with Washer,High Quality Shaft Bearing Seal].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6,Customize Nylon Sport Drawstring Bag].35L Electric Car Mini Fridge, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Food Processing Machinery Vegetable Cutter Machineshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Aluminium Composite Panel for Decoration Material]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Precision Machining Android Phone Back Camera Frame]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Znse Focus Lens for CO2 Laser Engraving Cutting Machine]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Fixman Power Drill Tool 12V Cordless Lithium Power Drill Battery]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Commercial Boneless Fresh Meat Slicer Machine for Meat Factory, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,50kg Colorful PP Woven Block Bottom Valve Cement Bags, which is inversely dependent on the size of the particles in suspension [12PCS Wooden Color Pencils Set in Full Color Printing Box,M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterGray Cast Iron Case of Auto Part/Gearbox Rear Housing

High-Pressure Indoor Decorative Material PVC Laminated Wall Panel(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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