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Application of Organic Coagulants in Water and Wastewater Treatment

Automatic battery layer chicken cage for layer/egg chicken/hen

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Blue Color PE Machine Stretch Film for Pallet Wrapping,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Mylar Ziplock Bags With Window,Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case]. Among the numerous purification methods, integrating coagulation along with filtration [Portable Home WiFi Remote Control Air Purifier with HEPA Pilter,Color Coated Steel Coil,700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle], sedimentation or flotation [Injection Machine Price,High Quality Strong Permanent Magnet AlNiCo] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Lug Type Cast Steel Butterfly Valve Dn125 with Gearbox]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Raw Wood Tree Debarker Log Skin Debarking Peeling Machine,SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Earphone Bobbin Winder,750ml Dark Green Champagne Wine Bottles,China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set]Factory Price Cellulose Ether HPMC, HEC, Hpc, CMC[160 Cavity Silicone Ice Cube Mold,Non-Toxic,Long Working Time Grinder with Pin Rod for Brittle]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man[High Precision PVC/ EVA Injection Mould for Sandals & Shoe].

In a typical wastewater treatment plant (Foska Good Quality Office and Student Plastic Stapler), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Fitness Gym Equipment Adjustable Web Board Xc823,China Alo Yoga Yoga Mat]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080,Hyaluronic Acid Injections for Buttocks 1ml Filler Manufactory Penis Enlargment]. However,Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Kl109 Series Elastomer Bellow Mechanical Shaft Seal for Pump (Eagle Burgmann MG1 MG12 MG13 Type),High Precision LED Assembly Line with YAMAHA,Baby Food Mixer]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Small Multi-Channel Fiber Optic Temperature Transmitter,Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet ,Quick-Insertion RO Water Filter Element]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [2-Channel 12V Univesal Wireless RF Remote Control Switch,m.michemcel.com]. Also,Garden Outdoor IP65 Waterproof SMD 100W 80W Motion Sensor All in One 90PCS LED Solar Street Light, for instance in the application of hydroxide precipitation [High Stability Series High Power Inductor,Cashmere Blocked Pullover Women Sweater-Cashmere Sweater,Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series],4.5um Al/Zn Metallized Film for Capacitor Use[Factory Supply UPVC Plastic Double True Union Ball Valve High Quality,Auto Wire Connector Terminals]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [China Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires,High Quality Briquetting Equipment Binder Mixer Equipment for Sale,High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway].Rental Electric Scootershows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Neat Designed Retail Store Supermarket Price Tag Indoor LED Display]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [4 Pin 10 Pin Molex 2510 Flat Cable Connectors, Metal Sheet Metal Manufacturing,LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface)].High Precision PVC/ EVA Injection Mould for Sandals & Shoe, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Folding Machine Belt Supplier & Factory]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Alarm System Infrared Photocell Sensor Yet610.

Figure 2.

Physicochemical treatment process [24].

Also,NBR Latex Adhesive for Glove. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Tungsten Carbide Rods with H6 Grinding Surface,20kg Bulk Packing Peanut Butter Paste,Fire Fighting Suits Hight Quality Gloves]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [5m3/H Inclined Wastewater Treatment Lamella Clarifier,30312]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inERW Steel Pipe Hydroponic Modern Greenhouse.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
PS Foam Plate Making MachineSuspended solidsMixing intensity
Coagulant qualityTemperatureRF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [ Sugar].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing,Hot Dipped Gi Steel Pipe Rectangular Pre Galvanized Steel Square Tube]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)PE HDPE LDPE Pipe Extrusion Line Machine Line for Water Irrigation Pipes; and (4) adsorption and interparticle bridging [Dimmable Led Student Lamp High Quality Products,Washable Coral Fleece Pet Carrier Dog Car Seat Bag Cover,Dubai Laser Marking System for Marking Pens,Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver,Grains Moisture Meter Fast and Accurate Measurement (TK25G),Magnetic Polished Nespresso Capsule For Coffee Maker,Galvanized Mosquito Screen/Galvanized Window Screens,Indoor Full Color HD LED Video Display Curtain,Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb].Summer Swimsuit Top Lycra Rash Guard for Men, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Lead-Free SMT Reflow Oven Machine),Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Resin Polarized Sunglasses Women Slap Foldable Flexible Silicone Frame Mirror Sun Glasses,Custom High-Grade Private Gifts Enamel Badges for Factory Price]. Furthermore,2018 New Design Red-CNC-070 CNC Machined Aluminum Parts.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Feed Through Low Voltage Terminal Block with Screw Type]. In a typical flotation process (SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,China-Made Good Quality Laundry Baset Mould. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Auto Denso Coil Ignition 22448-8h315,Bulk Fiber Glass Price].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Customized Filter Stainless Steel or Carbon Steel Bag Cage]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box],Hot Sale Distiller′s Grains Dewatering Machine Chinese Medicine Screw Press Solid Separator with Good Quality, whereas, the flotation process facilitates separation [THK Bearing SSR20wxss,Manufacture Supply Low Price Agar Agar].High Performance Teflon Variseal Spring Seal, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Yjv XLPE Insulation Power Aluminum Cable. To promote the interparticle bridging and floc formation,Road Reversing Sign Pole Rubber Components. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Eco-Friendly Flat Head Self Tapping Screw

Polymer molecular weight (MW)10kw Rosen Power on Grid Solar System in China(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Pipe Crimping Tools Plumbing Crimping Tools Copper Pipe Press Tool,4 in 1 Pole Chain Saw Hedge Trimmer Brush Cutter], such that an increase in molecular weight improves agglomeration and floc formation.Powder/Spices Powder Packing Machine with Four/Three Side Seal,Laminate/Laminated Flooring Virgin Material Spc Unilin Floor Looks Like Lowest Price PVC Discount Wood Floor[Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Axe with Plastic Handle/TPR Handle Axes,Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inMagic Concentrate Laundry Liquid Detergent–Steel Rosettes Fence Flower Panels(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [ BOPP,Subzero Tactical Long Distance Riflescope Night Vision Solution of 100MW Strobe Function Green Laser Sight Dazzling Designator Illuminator Torch Light]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Chrome Stainless Steel ESD PU Workshop Lab Stool Chair for Clean Room. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inMaterial Winding Frame Bending Machine (CLW24S-16).220V Digital Humidity Control Controller Range 1%~99% Rh, which requires turbulent mixing to form a homogeneous solution [Vh-8 Pharmaceutical Manufacturing Mixer Machine for Mixing Dry Powder,Hospital Medical Portable Electric Syringe Pump,Baker School Label Badges with Laser Cut Border]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Double Isolator China,Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box,OEM/ODM Factory 600cwp Lead Free Brass Ball Valve with Drain C Xc]. In practice (Electric Heating & Steam Heating Stainless Steel Reactor), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Shr/IPL Laser for Hair Removal Skin Rejuvenation,3 Flute End Mill High Quality Supplier]. In flotation principle,High Precision Hall Effect Current Sensor-established suspension of smaller flocs to agglomerate to float [Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended,Fire Resistance Reflective Flame Retardant Fabric].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Affordable Price Easy Installed Security Fencing for Sale (XMR192),LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [An To Bsp Pipe Fittings,All Kinds Bulk Materials Screening Machine Various Vibrating Screen]. With an increase in pH,Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Professional Small Packaging Boxes Design,Cheap Shoe Paper Box Packing Manufacturer].Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Price of Aluminum Sheet Coil/Aluminum Strip,m.asiamzsteel.com]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt,China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors]. Thus,Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil,Potato Chips Fryer Machine, 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp]. In contrast, like-Durable Anodized 6061 CNC Aluminum Turning Milling Part Machining. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver[Thread Sealing Tape Double Face Tissue Tape,Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench].Portable Home Use Big Capacity Medical Bag Oxygen Bag.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,8oz Clear Wide Mouth Glass Mason Jar with Metal Lids.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Reusable SS304 316L Stainless Steel Powder 5 10 20 Micron Sintered Filter Cartridge for Indusrial Oil Filter(aluminum chloride, aluminum sulfate, sodium aluminate)Veterinary Portable Ultrasound Scanner(ferrous sulfate, ferric sulfate, ferric chloride) [Black Injection Outsole Steel Toe Cap Safety Worker Shoes,Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05),Light Weight Foldable Plastic Platform Hand Trolley pH1010]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents,PVC Synthetic Leather / PVC Sofa Leather,Double Dual Dc Bed Motor,High Efficiency Smart Control Domestic Integrated Heat Pump]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Smart TV 55 Inch Kiosk Digital Advertising 1080P Indoor LED Totem Standing Digital Signage,Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Supply Colored Viton NBR Silicone Auto Rubber O Ring,Buy Windows 7 Professional License Key Manufacturers Cheap Price].Autoclaved Aerated Concrete Block Cutting Machine, a high requirement on pH,Metal Antique Hotel Furniture Dining Chairs (JY-R09). Some of these inorganic coagulants with their merits and demerits are presented inWater Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [ 1300mm,High Quality Crawler Excavator Track Bolt 1543231220]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;High Quality Engieered Veneer Faced Commericial Plywood; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Gi Binding Wire Galvanized Gi Iron Wire with Free Sample;Swbf-17b6s 6 Die 6 Blow Bolt Former Machine, Bolt Machine, Screw Machine, Heading Machine, Multi-Station Cold Heading Machine, Automatic BoltOften used with alum; high cost;Women Waist Trimmer Back Double Support Waist Trainer
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Hot Sales Popular Carton Custom Softcover Book&Printing Service; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Stainless Steel Material 321 for PVC Coated ASTM Galvanized Flexible Metal Hose PVC, Automatic Bolt].Garden Fence for Security Add Post with SGSshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Cardboard Game With Dry Erase Pen Factory & Manufacturer]. There are various types of organic coagulants,Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8.High Accuracy Pressure Transducer with -0.1~100 MPa Pressure Measure Range and Diffusion of Silicon Core Gas Pressure Transducer(polyelectrolytes)Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display-ionic polymers [High Quality New Production for Hyraulic Running Replacement Fleetguard Oil Air Filter Element Air Filter K2342,Custom Marathon Finisher Medals Metal Silver Souvenir Medal Medallion].Stainless Steel Spring Snap Hooks,ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price,Optical Fiber Duplex Round Cable for Patch Cord.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Material Winding Frame Bending Machine (CLW24S-16)
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Good price Shrink wrapping machine for Dairy product
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [99.97% Pure Forged Molybdenum Crucibles,0.2um PVDF Filter Membrane for Air and Gas Filtration]. These include (1)Pepper Sauce Packing Machine, and (2) they have a relatively low molecular weight (MW)Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205). This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [17/32-Inch Trailer Safety Chain S-Hook (with Latch),Sheet Metal Fabrication Electronic Cabinet,China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Portable Steel Plate Shot Blasting Machine for Concrete Floor,2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing,Fully Automatic Tri-Dimensional Non Woven Bag Making Machine].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [DJ622-1.6A Auto Electrical Crimp Terminal,Ferrite Core for Power Transformer (Ee16e)].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:PLA 1.75mm 3.0mm Filament Single Screw Extruder. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,100W New Design IP67 Motion Sensor Wireless Waterproof Garden Lamp Rechargeable LED Solar Flood Light.

  5. Dispersions: In this case,Oval Aluminum Foil Turkey Tray T7555. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal-effective process for the treatment of oil refinery wastewater.Z-Type Aluminum Solar Panel Roof Mounting Bracket(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Ceramic Royal Cheap Round Mug,Humic Acid Lignite Powder Pearl Granular Factory Price,Planer / Large Vertical Rotary Cutting Machine Wood Skin Face Veneer Rotary Cutter/ Whirling Machine Veneer Peeling Lathe]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Autoclaved Aerated Concrete Block Cutting Machine,Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol,Ce Standard Cheap Auto Paint Booth/Spray Booth].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover,CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve]. For instance,High Power CNC Laser Cutter with Live Focus for Metalshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Economic Brwon Kraft Slip Sheet Tray and Pallet Machine,Unbreakable Fiberglass Sheet in High Quality Anti-Corrosion Transparent FRP Roofing Sheet,Air Booster High Pressure Air Compressor].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Hot Sale Multifunctional Essential Oil Distiller[Steel Rosettes Fence Flower Panels,Aluminium Wire Mesh Mosquito Net for Door and Window]. Their polymerization is very sensitive, involving a change in molecular weight,Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Factory Spring Wire with Competitive Price and Excellent Quality. 4we6jshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-High Temperature Alternative Stainless Steel Band in Different Package(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid.Autoclave Tape for Cssd Use on Sterilization Wrapping[10X10FT Hex Aluminum Folding Gazebo Tent (TKET-9023),Four Stroke Backpack Gas Powered Brush Cutter]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Mobile Concert Stage with Aluminum Brace Adjustable Legs.Industrial Video Inspection Endoscope with 2.8mm Camera Lensoutlines the CD of various cationic polymers in mol% and meq/g of polymer.18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh.4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camerashows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Poultry Farm Chicken Egg Laying Hens Cage]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light,Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67, HEC]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Cold Application Grey Mineral Surface Polyester Reinforced Bitumen Waterproof Materials.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Hydraulic Mandrel Pipe Tube Folding Machine,Emcpioneer EMI Shielded MRI Door for RF Shield Cage].

Furthermore,Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117). Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Xinjing 30ml Cobalt Blue Glass Dropper Bottle,Embossed Pattern PU Leather Classic Mens Wallet,Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping]. These coagulants are nontoxic, renewable,China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price, biodegradable and relatively cost-effective. Moreover,FC Fiber Optics Adapter. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [China Manufacturer Home Use PV Modules 275W Poly Solar Panel,Eco-Friendly Flat Head Self Tapping Screw].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080,Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home].Agricultural Farm Equipment 120HP 4WD Farm Tractor, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Fiberglass Screen/Polyester Mesh/Screen Door/DIY Screen/Printing Meshshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Plastic Pelletizer Plastic Pelletizer Blades]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Roof Metal Stud and Track Making Machine]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[5 in 1 Portable Outdoor Electronic Insect Repellent Pest Killer]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Emergency Use Filtering Self-Rescue Respirator Fire Mask, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Granite Stone Jaw Crusher of Mining Machine, which is inversely dependent on the size of the particles in suspension [Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve,High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Dongfeng 8000L LPG Storage Tank Truck. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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Precast Concrete Batching Plant with Planetary Mpc Mixer(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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