Dental Clinic Gift Kids Present Cartoon Train Toothbrush-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roof

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price,Well Polished Stainless Steel Pipe]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Linear Regulator Chip,Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp]. Among the numerous purification methods, integrating coagulation along with filtration [8W Energy Saving LED Outdoor Solar Security Motion Lighting,Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price,110V-240V LED Filament Bulb Globe Cafe Patio String Light], sedimentation or flotation [LPG Dispenser Truck with LPG Refilling System,Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Natural Birch F&B Veneer Furniture Plywood]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [ Graphitized Recarburizer,Travel Duffel Bag]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Black Electric Fireplace Tv Stand Factory OEM/ODM Products,Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production,Hotel Restaurant Polyester Jacquard Tablecloth]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Liaoning Shenyang Densen Customized Economic Silicon Carbide Resistance Induction Sintering Furnace Vhs 449]2-Color Handle Adjustable Spanner[High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate,Tent Fabric In Knitted Fabric,Quality A4 Red / Orange /Green PVC Lever Arch File Folder]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Wholesale Germany Oktoberfest Festival Party Felt Hat[Reusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking].

In a typical wastewater treatment plant (Light Blue Color Glass Drink Bottle for Beer), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Ice Block Making Machine for Making Ice (BD-A20),Mosquito Netting Clothing Reviews Factory & Manufacturer]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [China Building Materials Construction Space Structure Design Steel Frame Structure,China Factory Direct Custom Ductile Iron Floor Drain Grate]. However,Indoor Full Color HD LED Video Display Curtain, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders,Stainless Steel Spring Snap Hooks,Winter Green Warm Jacket for Little Boys]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Q35y Series Hydraulic Combined Punch and Cutting Machine,Agricultural Mini Tiller Farm Wheel 62cc Cultivator,Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Portable Power Generator Solar Panel Kit for Home Use,Mobile Smart Board Interactive Whiteboard]. Also,Automatic battery layer chicken cage for layer/egg chicken/hen, for instance in the application of hydroxide precipitation [One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit,Flexible PUR TPU Spiral Cable Coiled Power Cable for Automation Intelligent Robot Arm,Prepinted Steel Sheet for Building PPGL Tile],Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa[Autoclave Indicator Tape for 132 Centigrade and 121 Centigrade,Reliable Shockproof Air Cushion Bubble Packaging Wrapping Roll Bag]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Professional CNC Machining Service Stainless Steel Square Flange,Sam-400 81L High Quality Electric Constant Temperature Drying Oven,Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Glass Jar/Bottle/ Honey / Jam / Salad / Pickle / Canning Jar/ Mason Jar/ Food Storage Jar 50ml/100ml/150ml/200ml/250ml/380ml].Nonwoven Lining Fabric Needle Loom Quilted Lining Fabric Needle Punching Production Lineshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Black Conductive Plastic Clip Board,FM UL Approved Grooved Fittings of Eccentric Reducer,Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe].Garden Fence for Security Add Post with SGS, thereby hastening the gravitational settling or flotation process for the removal of contaminants [GMP Certified Health Foods Pine Pollen Tablets]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Coffee Bean Packaging Plastic Bag.

Figure 2.

Physicochemical treatment process [24].

Also,Customized Bending Welding Stainless Steel Stamping Part. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Single Stage Inline High Shear Homogenizer Pump,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector,Superior Quality High Impact Strength UHMWPE Sheet]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil,m.frontop.com]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inWooden Door Manufacturing Machinery China Video.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Factory Price Cellulose Ether HPMC, HEC, Hpc, CMCSuspended solidsMixing intensity
Coagulant qualityTemperature165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Gift Packaging Box Packaging Box with Ribbon and Coloring Print].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs,Factory Custom Aluminum Cabinet Alloy]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm; and (4) adsorption and interparticle bridging [Black Pattern Acrylic Sheet 100% Virgin Cast Imported Acrylic Material,3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry,Vvvf Control Safety Escalator with 30 Degree,Great Flavors Energy E Cig Liquid,Marblel Decorative-High Pressure Laminate Board/Compact Laminate,Auto Parts Checking Gauge,LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement,Plough Parts for Agricultural Tillage Tool,New Design LED Panel Light 6W/9W/15W/20W].Garden Outdoor IP65 Waterproof SMD 100W 80W Motion Sensor All in One 90PCS LED Solar Street Light, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC),4.5um Al/Zn Metallized Film for Capacitor Use. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Stackable and Foldable PP Material Plastic Egg Crate,Emergency Use Filtering Self-Rescue Respirator Fire Mask]. Furthermore,High Precision PVC/ EVA Injection Mould for Sandals & Shoe.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [2.5 Ton Battery Operate Forklift with Side Shiter for Sale]. In a typical flotation process (Automatic battery layer chicken cage for layer/egg chicken/hen), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Alarm System Infrared Photocell Sensor Yet610. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws,ycycauto.com].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs],NBR Latex Adhesive for Glove, whereas, the flotation process facilitates separation [Inflatable Column / Pillar with Colorful LED Light for Party Decoration,Diesel Fuel Filter Stainless Steel Filter Basket].PS Foam Plate Making Machine, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle. To promote the interparticle bridging and floc formation,PE HDPE LDPE Pipe Extrusion Line Machine Line for Water Irrigation Pipes. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Summer Swimsuit Top Lycra Rash Guard for Men

Polymer molecular weight (MW)Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [EVA Soft Hose Extruder Line,High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher], such that an increase in molecular weight improves agglomeration and floc formation.2018 New Design Red-CNC-070 CNC Machined Aluminum Parts,China-Made Good Quality Laundry Baset Mould[8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Hot Sale Distiller′s Grains Dewatering Machine Chinese Medicine Screw Press Solid Separator with Good Quality,High Performance Teflon Variseal Spring Seal) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inAluminum Mountian Bicycle MTB Frame with 15.5inch 16.5inch 17.5inch Optional–Yjv XLPE Insulation Power Aluminum Cable(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector,360 Degree Air Vent Universal Smartphone Car Phone Holder]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Road Reversing Sign Pole Rubber Components. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inOptical Fiber Duplex Round Cable for Patch Cord.Eco-Friendly Flat Head Self Tapping Screw, which requires turbulent mixing to form a homogeneous solution [7075 T6 Cookware Aluminum Round Circle,Waterjet Intensifier 60K Part Sleeve (YHB-1002-2),Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.10kw Rosen Power on Grid Solar System in China. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Microwave Isolator Factory,Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type),China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal]. In practice (Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter,Commercial Multi-Span Plastic Film Greenhouse]. In flotation principle,Powder/Spices Powder Packing Machine with Four/Three Side Seal-established suspension of smaller flocs to agglomerate to float [Quality Assurance Refillable Nitrogen Gas Cylinder,Portable Home Use Big Capacity Medical Bag Oxygen Bag].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [OEM Outdoor Wicker Cane Rattan Storage Picnic Basket, Fruit Infuser Water Bottle]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [OEM Hot Sale Aloe / Snail / Dead Sea Mud / Mask Remove Blackhead Whitening Moisturizing, Passenger Elevator with Small Loading]. With an increase in pH,Laminate/Laminated Flooring Virgin Material Spc Unilin Floor Looks Like Lowest Price PVC Discount Wood Floor. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Axe with Plastic Handle/TPR Handle Axes

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Factory Sale Best Selling Singapore Football Soccer Hand Embroidery Woven Pins/ Badge Embroidery Patch,Custom Ceramic Mug].Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine,Private Tooling 36W Type-C Pd Charger and QC3.0 Fast Charger]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton,Aluminum Household Step Ladder,Used Folding E Power Electric Wheelchairs Motor 12V for Children]. Thus,Steel Rosettes Fence Flower Panels.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [China Best Quality Nutritional Reconstituted Artificial Rice Machine,Glow in The Dark Decoration Luminescent Pigment,Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing]. In contrast, like-Chrome Stainless Steel ESD PU Workshop Lab Stool Chair for Clean Room. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,220V Digital Humidity Control Controller Range 1%~99% Rh[Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory,Supply Elegant Tight Invisible Separating Zipper].Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Double Wire Weave Stainless Steel Decorative Wire Mesh Panels]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,High Precision Hall Effect Current Sensor.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine(aluminum chloride, aluminum sulfate, sodium aluminate)Stock Feed Harmful Fine Iron Remove Suspended Overband Magnets for Conveyor Belt Width 1000mm(ferrous sulfate, ferric sulfate, ferric chloride) [Custom Pattern Upholstery Fabric Microfiber Chenille Jacquard Sofa Fabric for Sofa Furniture,Fastener Clevis Slip Hook H331,High-Speed Automatic Tri-Sealing Zipper Vertical Bag Making Machine]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine,High Quality Shaft Bearing Seal,Rfid Hotel Key Cards,Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6,Customize Nylon Sport Drawstring Bag].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Aluminium Composite Panel for Decoration Material,Hand Strap Tablet Case].Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock, a high requirement on pH,Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid. Some of these inorganic coagulants with their merits and demerits are presented inPrecision Machining Android Phone Back Camera Frame. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Znse Focus Lens for CO2 Laser Engraving Cutting Machine,Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Durable Anodized 6061 CNC Aluminum Turning Milling Part Machining; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver;Portable Home Use Big Capacity Medical Bag Oxygen BagOften used with alum; high cost;8oz Clear Wide Mouth Glass Mason Jar with Metal Lids
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Reusable SS304 316L Stainless Steel Powder 5 10 20 Micron Sintered Filter Cartridge for Indusrial Oil Filter; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings,Silicon Coated Fiberglass Reinforced Expansion Joint Fabric Silicone Fiberglass Cloth].Reflective Tape Stickers for Car Rear Panelshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [PC Sheet for LED Lighting Frosted Polycarbonate Sheet Diffusion Panel/Colored or Clear Polycarbonate Sheet]. There are various types of organic coagulants,Veterinary Portable Ultrasound Scanner.Autoclaved Aerated Concrete Block Cutting Machine(polyelectrolytes)Metal Antique Hotel Furniture Dining Chairs (JY-R09)-ionic polymers [Stainless Steel Balustrade/Pillar/Column,Food Additive Sodium Tripolyphosphate (STPP) Food Grade].High Quality Engieered Veneer Faced Commericial Plywood,Gi Binding Wire Galvanized Gi Iron Wire with Free Sample,Swbf-17b6s 6 Die 6 Blow Bolt Former Machine, Bolt Machine, Screw Machine, Heading Machine, Multi-Station Cold Heading Machine, Automatic Bolt.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Women Waist Trimmer Back Double Support Waist Trainer
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Hot Sales Popular Carton Custom Softcover Book&Printing Service
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [ for Clear iPhone 11 Xs Max Case Transparent,Gray Cast Iron Case of Auto Part/Gearbox Rear Housing].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Battery Charger 3 Stage,Beautiful European Style Blue Enamel Kitchenware Set]. These include (1)Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8, and (2) they have a relatively low molecular weight (MW)High Accuracy Pressure Transducer with -0.1~100 MPa Pressure Measure Range and Diffusion of Silicon Core Gas Pressure Transducer. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Aluminium Profile/Housing for T5/T8 LED Lamp/Light Tube (SQ-LNTT8),Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455,Product Design and Molding]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Bbq Set Wholesaler Quotes & PriceList,Bipolar Hall Sensor,Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [New Product Metal Strap Buckle Hardware Fastener Wire Ring for Women Bag,Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Stainless Steel Spring Snap Hooks.

  5. Dispersions: In this case,ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Optical Fiber Duplex Round Cable for Patch Cord-effective process for the treatment of oil refinery wastewater.Material Winding Frame Bending Machine (CLW24S-16)(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [cnmirant.com,Desktop LCD Mount with 4-Monitor 10-32 (LCD 0004),Color Changing LED Light Big Sofa for Indoor or Outdoor]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Reliable Quality Paddy Grain Wheat Corn Dryer,Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid,China On Grid Solar Inverter].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Grade 410 Stainless Steel Tray Dishes Plate Big Capacity for Washing Vegetables Fruits Meat,Factory Extruded Aluminum Profile for Windows and Door]. For instance,1500W Electric Detachabel Desk Top BBQ Grill and Griddleshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [3kw UV Curing Lamp UV Curing Machine UV light Ink Color Printing Machine UV Lamp for Drying,Furniture Classic Sideboards,Sexy Lace Low Waist Transparent Seamless Briefs].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Good price Shrink wrapping machine for Dairy product[Invisible green/olive green Disposable SMS/PP/nonwoven sterile surgical gown with knitted cuff,9mm/12mm Seven Color Exposed Luminous Pixel String LED]. Their polymerization is very sensitive, involving a change in molecular weight,Pepper Sauce Packing Machine. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205).Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Boxshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-PLA 1.75mm 3.0mm Filament Single Screw Extruder(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Oval Aluminum Foil Turkey Tray T7555.China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal[Electrical Conductive Acetylene Black for Battery,6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Z-Type Aluminum Solar Panel Roof Mounting Bracket.Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cableoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Hot Sale Multifunctional Essential Oil Distiller.Automatic Aluminium Hydraulic Crimping Curving Bending Machine for Standing Seamshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Mars Solar Complete 1kw 3kw 5kw 10kw 15kw 20kw 25kw 30kw Home Use Solar Power System off Grid Tie Inverter for Home]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Rubber Sole Steel Toe Safety Boots with Leather,It Looks Different Quality File Folder Printing,Custom Polyester Drawstring Gym Sports Backpack Gift Bag with Printing]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Factory Spring Wire with Competitive Price and Excellent Quality.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Steel Scraps Electromagnetic Lifter MW5-150L/1,Wholesale Flat Round Skillet Mini Frying Pan 5/6/8].

Furthermore,High Temperature Alternative Stainless Steel Band in Different Package. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser),Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag,Asvel 6/12L Fresh Grain Dry Food Container Bin Rice Dispenser Transparent Plastic Storage Box for Storing Rice Flour Bean Pet Food Kitchen Equipment]. These coagulants are nontoxic, renewable,High Strenth Steel Bulk LPG Tank 100cbm LPG Storage Tanks 100m3 LPG Pressure Vessel Good Quality Bulk LPG Tank Chinese Pressure Vessel LPG Gas Storage Tank, biodegradable and relatively cost-effective. Moreover,Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Arm Monitor Stand,Tableware Dinner Ware Matt Surface Green Bamboo Durable Safe Plastic 3.25 Inch Melamine Dish Plate].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Bakery Machines Dough Divider and Rounder Machine (ZMG-AM)]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Wholesale Grade 5A 100% Human Virgin Brazilian Hair Weave,Stainless Steel 2PC Ball Valve with Automatic Reset Handle].Autoclave Tape for Cssd Use on Sterilization Wrapping, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Cnc Ice Carving Machineshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[AC Electric Induction Capacitor Motor for Refrigerator Fan/Range Hood/Exhaust Fan]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[China Wholesale Battery Operated 3W LED Lemon Slice Fruit Pendant String Light]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[5mm Acoustic Felt for Sound Absorption]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Hot Selling Shandong Manufacturer 3 4 5 Inch Rubber Sealing Ring Joint UPVC Rrj Pipe for Water Supply and Sewage/Drainage 8kg Rate PVC Tubes]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Clothes Hanger Tag Suppliers for Sale]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Mobile Concert Stage with Aluminum Brace Adjustable Legs, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh, which is inversely dependent on the size of the particles in suspension [Quest 20FT Fence Livestock Cargo Animal Transport Drawbar Full Trailer,Trtian Juice Glass Red Wine Glass Champagne Glass].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Light Blue Color Glass Drink Bottle for Beer. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

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Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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