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Application of Organic Coagulants in Water and Wastewater Treatment

High Quality Geared Side - in Agitator

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Professional Wood Log Bark Peeling Machine.EL Backlight Membrane Switch Keyboard,Mc-275A Pipe/Tube Cutting Machine,900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,18650 PCM Protection Board with Balanced Lithium Battery Module (lws-4s30A-058). This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Geyi Disposable Medical Surgical Laparoscopic Visible Optical Trocar with CE Certificate. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube,Auto Denso Coil Ignition 22448-8h315]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [P5 960*960mm LED Display Screen SMD Indoor /Outdoor,Customized Filter Stainless Steel or Carbon Steel Bag Cage]. Among the numerous purification methods, integrating coagulation along with filtration [Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box,THK Bearing SSR20wxss,Manufacture Supply Low Price Agar Agar], sedimentation or flotation [Guitar Side Bending Machine High Quality Supplier,4 in 1 Pole Chain Saw Hedge Trimmer Brush Cutter] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Magic Concentrate Laundry Liquid Detergent, BOPP]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Ultrasonic Industrial Humidifier-Industrial Humidifier Equipment,Material Winding Frame Bending Machine (CLW24S-16),Vh-8 Pharmaceutical Manufacturing Mixer Machine for Mixing Dry Powder]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Hospital Medical Portable Electric Syringe Pump]Types of 502kw-1561kw Processing Low Temperature Water Chiller[Baker School Label Badges with Laser Cut Border,Forged Alloy Steel G80 Eye Sling Hook with Latch,Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’AG-902A Double-Channel 400ml/600ml Electrical Nursing Injection Syringe Infusion Pump[OEM/ODM Factory 600cwp Lead Free Brass Ball Valve with Drain C Xc].

In a typical wastewater treatment plant (Electric Heating & Steam Heating Stainless Steel Reactor), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Shr/IPL Laser for Hair Removal Skin Rejuvenation,Strong Color Performance Flex Banner]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended,Fire Resistance Reflective Flame Retardant Fabric]. However,Colorful Asphalt Shingles for Roof Covering and Waterproofing, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Affordable Price Easy Installed Security Fencing for Sale (XMR192),LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e,Density 10.2g/cm3 Ground Molybdenum Alloy Tzm Rods]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [All Kinds Bulk Materials Screening Machine Various Vibrating Screen,Professional Small Packaging Boxes Design,Cheap Shoe Paper Box Packing Manufacturer]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Price of Aluminum Sheet Coil/Aluminum Strip,2020 Fashion Industrial Men Work Lightweight Black Orange Steel Toe Safety Shoes]. Also,Hot Sale Glass Manual Salt Grinder Pepper Mills/Spice Jars, for instance in the application of hydroxide precipitation [Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt,China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors],Auto Parts of Thrust Ball Bearing 51201 Thrust Bearings Size Chart[Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil,Organic Chemicsls]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [ 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp,Thread Sealing Tape Double Face Tissue Tape,Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa].Agriculture Sprayer Partsshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05)]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Light Weight Foldable Plastic Platform Hand Trolley pH1010,Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents,PVC Synthetic Leather / PVC Sofa Leather].Embroidered Patch, Iron on Patch, Custom Patches, Embroidered Name Patch, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Mifare Classic Sticker]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.2019 New Design Windproof Men Hiking Suspender Trousers Ski Winter Pant Snowboard Trousers for Men.

Figure 2.

Physicochemical treatment process [24].

Also,Precision Machining Android Phone Back Camera Frame. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [High Efficiency Smart Control Domestic Integrated Heat Pump,Smart TV 55 Inch Kiosk Digital Advertising 1080P Indoor LED Totem Standing Digital Signage,Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Supply Colored Viton NBR Silicone Auto Rubber O Ring,Bimetallic Liners Slurry Pump Bimetal F1600]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inWater Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Igeelee HS-05wf 0.5-6.0mm2 Crimping Tools for Wire End Sleeves High Quality Multi-Function Crimping Pliers Tube Crimping PliersSuspended solidsMixing intensity
Coagulant qualityTemperatureOEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [ 1300mm].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [High Quality Crawler Excavator Track Bolt 1543231220,Soya Vegetable Meat Making Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)3 in One Portable Mini Car Negative Ion Air Purifier; and (4) adsorption and interparticle bridging [Double Layer Nc Cut off Machine for Corrugated Paperboard,Premium OEM/ODM Vape Liquids for Pods Pen,Stainless Steel Material 321 for PVC Coated ASTM Galvanized Flexible Metal Hose PVC, Automatic Bolt,Garden Fence for Security Add Post with SGS,Mining Machinery/Crushing Equipment for Roller Crusher (ATHM800/500),High Quality New Production for Hyraulic Running Replacement Fleetguard Oil Air Filter Element Air Filter K2342,Custom Marathon Finisher Medals Metal Silver Souvenir Medal Medallion,2018 Euro II 16cbm Tipper on Sale Beiben Dumper Truck].High Efficient Lint Remover Sticky Roller, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Fat Tire Electric Scooter 2000W E Bike Electric Scooter with Big Wheel Motor),China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [China Supplier Timber Wood Log Cuttingg Machine Wood Log Splitter,0.2um PVDF Filter Membrane for Air and Gas Filtration]. Furthermore,Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [17/32-Inch Trailer Safety Chain S-Hook (with Latch)]. In a typical flotation process (Sheet Metal Fabrication Electronic Cabinet), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin,Easy Set up Aluminum Frame Exhibition Booth Design Tradeshow Booth 20X10 Wall].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Fully Automatic Tri-Dimensional Non Woven Bag Making Machine],Wholesale Business Gift PU Cover Custom Notebook Printing, whereas, the flotation process facilitates separation [DJ622-1.6A Auto Electrical Crimp Terminal,Ferrite Core for Power Transformer (Ee16e)].Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic. To promote the interparticle bridging and floc formation,Ozone Generator for Treatment Drinking Water. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)1.8m Height Hot Dipped Galvanized Chain Link Fencing(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Agent Price Heavy Duty CNC Router Machine Woodworking Engraver,Humic Acid Lignite Powder Pearl Granular Factory Price], such that an increase in molecular weight improves agglomeration and floc formation.Wholesale Bachelor Matte Black Graduation Gown,Rubber Sole Steel Toe Safety Boots with Leather[Planer / Large Vertical Rotary Cutting Machine Wood Skin Face Veneer Rotary Cutter/ Whirling Machine Veneer Peeling Lathe]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer,Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inAutoclaved Aerated Concrete Block Cutting Machine–Fashion Woven Gold Metal Frame Kiss Lock Wallet(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol,Rain Suit]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

New Pop Design Aluminum Clip in Ceiling for Interior Decorative. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inMetal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover.Dia. 35mm Abl Tube Suppliers Cream Packaging Tube, which requires turbulent mixing to form a homogeneous solution [CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve,High Power CNC Laser Cutter with Live Focus for Metal,Economic Brwon Kraft Slip Sheet Tray and Pallet Machine]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Stripe Tape Cami and Dolphin Hem Shorts Camo Fitness & Yoga Wear. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [2017 Factory Wholesale Custom Brand Designer Trifold Men Leather Wallet,Air Booster High Pressure Air Compressor,Steel Rosettes Fence Flower Panels]. In practice (Aluminium Wire Mesh Mosquito Net for Door and Window), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [ 4we6j,vet-china.com]. In flotation principle,Popular Cement Paver/Hollow Block Machine in India-established suspension of smaller flocs to agglomerate to float [10X10FT Hex Aluminum Folding Gazebo Tent (TKET-9023),Four Stroke Backpack Gas Powered Brush Cutter].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Industrial Video Inspection Endoscope with 2.8mm Camera Lens,4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Blue Christmas Table Runner,Poultry Farm Chicken Egg Laying Hens Cage]. With an increase in pH,China Supplier Automatic Straight Seam ERW Pipe Making Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.D902 Cylinder Head for Kubota Tractor Diesel Engine Parts

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light,Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67].CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [ HEC,Manganese Casting Symons Telsmith Spare Concave Cone Crusher Parts]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Emcpioneer EMI Shielded MRI Door for RF Shield Cage,Xinjing 30ml Cobalt Blue Glass Dropper Bottle,Embossed Pattern PU Leather Classic Mens Wallet]. Thus,14-Inch Vacuum-Brazed Diamond Saw Blades for Metal and Iron.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping,Tungsten Heavy Alloy Weight Parts for Golf Head,Eco-Friendly Flat Head Self Tapping Screw]. In contrast, like-Stone Grinding Mill (YGM Series). This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Customized Indoor or Outdoor Garden Dancing Musical Water Fountain[165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080].Multi-Functional Slimming Equipment RF Cavitation Diode Laser System.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,OEM Waterproof Nylon Yacht Craft Boat Cover.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts(aluminum chloride, aluminum sulfate, sodium aluminate)Dental Orthodontic Appliances From China Midway Dental Lab(ferrous sulfate, ferric sulfate, ferric chloride) [Perfect Body Tea,100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom,Plastic Pelletizer Plastic Pelletizer Blades]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Roof Metal Stud and Track Making Machine,Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth,PriceList for 48v 230v Pure Sine Wave Inverter - 3 Stage Automatic 12V/24V 6A Solar Charge Controller - Ligao,Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier,Microfiber Cooling Towel for Sports].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Love Couple Bracelet Beaded Charm Bracelets,Beanie Hat With Woven Label].OEM Metal Precision Stamping Steel Stamped Set Aluminium Press Stamping, a high requirement on pH,Auto Parts Dt One Control One Two Switch Cable Wire Harness. Some of these inorganic coagulants with their merits and demerits are presented inHigh Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [ T2/Tp2,Women Waist Trimmer Back Double Support Waist Trainer]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Stainless Steel Fabrication Custom Garden Horse Security safety Temporary Field Chain Lik Fence (plastic, aluminum, alloy, sheet, metal); most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Connecting Minifix Screws Heavy Duty Three in One Connector Rod (ROD-A262);35kv Indoor with Casting Current TransformerOften used with alum; high cost;Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Semi-Steel Radial Car Tyres with Fresh Brand; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [LCD Display Touch Screen Digitizer Assembly Replacement for 5/5c/5s/Se/6/6p/6s/6sp/7/7p/8/X/Xs/Xs Max Mobile Phone Accessories Repair Part,Emergency First Aid Aed Defibrillator Box with Strobe Light].PP Melt Blown Cartridge Filter (small line)shows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Chinese Agricultural Machinery Zl12f Loader China Minibagger]. There are various types of organic coagulants,Wholesale Scc638 High Efficiency Water-Based Cutting Fluid in Hot Sale.Car Plastic Grille Parts Precision Inspection Gauge(polyelectrolytes)Bugle Head Good Price Drywall Screws-ionic polymers [High-Yield Automatic Pet Food Production Machine,Custom Fluorescent Yellow Reflective Work Pants].Embossed Pattern PU Leather Classic Mens Wallet,Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9,Double Glass 19 32 Inch Smart HD Color LCD LED TV.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Sc Round Type Fiber Optic Adapter Bare Fiber Connector
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.China Suppliers Zhong Shan Cheap Wholesale Outdoor Waterproof LED Flood Street Light 50watts
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color,Pulse Jet Baghouse Furnace Dust Collector].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Custom Full Lined Wafer Type Butterfly Valve with Manual Gearbox,Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes]. These include (1)20kv 500kVA High Voltage Oil Immersed Type Power Transformer Price, and (2) they have a relatively low molecular weight (MW)Plastic WPC PVC Floor Foam Board Sheet Extrusion Production Line. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [PP PE Plastic Recycling Machine Film Squeezing Dewatering Dryer and Pelletizing Machine,High Precision Hall Effect Current Sensor,200L Split Pressurized Solar Water Heater System]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Ss316 Lifting Gas Spring for Marine Sea Boat,2018 New Design Red-CNC-070 CNC Machined Aluminum Parts,Formwork Scoffolding Wing Nut 100mm].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Sexy Yoga Sport Jumpsuits Backless Female Gym Clothes Flower Print Running Fitness Workout Set One PCS Sport Yoga Set for Women,Giant Inflatable Dog Animal Model for Advertising].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Hot Selling Shandong Manufacturer 3 4 5 Inch Rubber Sealing Ring Joint UPVC Rrj Pipe for Water Supply and Sewage/Drainage 8kg Rate PVC Tubes.

  5. Dispersions: In this case,Vp-0200 Intelligent Electric Valve Actuator Rotary Valve Motorized Actuator Low Torque Actuator for Ball Valve Butterfly Valve Quarter Turn Electric Actuator. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Polyester Taffeta Ripstop Camouflage Digital Print Fabric-effective process for the treatment of oil refinery wastewater.Black Grosgrain Ribbon with White Logo Printed Ribbon(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Compression Gas Struts Spring Lift Gas Springs,High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction,Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Small Volume Super Thin Hose Crimper (JKL500),Wheat Buckwheat Oats Length Grader (5XW-5),Stainless Steel Magnetic Clasp].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Enhanced Waist Brace Waist Belt Waist Support,USB Flash Disk Tin Box with PVC Window]. For instance,4.5um Al/Zn Metallized Film for Capacitor Useshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers,aihdcam.com,Dakiou Low Speed Paper Cup Making Machine].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying[Good price Shrink wrapping machine for Dairy product,Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine]. Their polymerization is very sensitive, involving a change in molecular weight,Manual Lever Hoist From 0.75ton to 9ton. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes.One Wheel Hovershoesshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

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PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Atc CNC Router 2030 with Auto Tool Changer Qd-2030s]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa,High Performance Teflon Variseal Spring Seal,CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,2-Color Handle Adjustable Spanner.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [OEM Sheet Metal Fabrication High Demand Ss Bend Sheet Metal Precis Product,Morden Design Steel Structure for Workshop].

Furthermore,Wholesale Germany Oktoberfest Festival Party Felt Hat. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Stainless Steel Welded Heavy Wall Tube,72 Spindles Metal Wire Braiding Machine,Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch]. These coagulants are nontoxic, renewable,Indoor Full Color HD LED Video Display Curtain, biodegradable and relatively cost-effective. Moreover,Automatic battery layer chicken cage for layer/egg chicken/hen. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Small Pet Preform Plastic Injection Molding Machine Price,Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [BMC Heat Forming Hydraulic Press Machine 200 Ton]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp,Nylon Screw Hammer Drive Fixing Anchor].Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.PVDF Customize Design Waved Aluminum Veneer Curtain Wallshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Embedded Automation 2D Barcode Reader for Kiosk]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[AISI 304 or 304L Seamless Steel Tube]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Auto Light Bar]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Garden Fence for Security Add Post with SGS, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Coffee Bean Packaging Plastic Bag, which is inversely dependent on the size of the particles in suspension [D3 1.2080 Cold Work Tool Steel,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Customized Bending Welding Stainless Steel Stamping Part. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterHDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line

165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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