Android Video Interface Car GPS Navigation System for 2014-2018 Year Mercedes-Benz C-Class A205-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Wicker Flower Baskets for Planter,Brushless Motor BLDC with Gearbox for CNC Machine Low Temperature Rise]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Gouging Carbon Rodes,40L 150bar CO2 Argon Nitrogen Helium Oxygen Steel Gas Cylinder]. Among the numerous purification methods, integrating coagulation along with filtration [Energy Saving Rotary Pulverized Coal Burner for Asphalt Plant,Milk Cream Disc Centrifugal Separator, Snack Food Packaging], sedimentation or flotation [48 Inch Dog Crate,Ss Stainless Steel Pipe Fittings Equal Tee with Thread Ends] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [PVC Panels 30cm Width of Hot Stamping]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Clone Premium Top Quality Living as Summer Flower Mint Tobacco Flavor Electronic Cigarette Liquid E Liquid,Competitive Price Portable Animal Hospital Diagnostic Digital Ultrasound System]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Heavy Hex Head Structural Nuts ASTM A563m with Hot DIP Galvanized Coating,Forged Steel Spring Lift High Temperature Thread Check Valve,Garden Outdoor IP65 Waterproof SMD 100W 80W Motion Sensor All in One 90PCS LED Solar Street Light]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [ Cold Formed Steel Hollow Galvanizing Square Tube]Square Tube Cold Formed Steel Channel for American Market Construction[High Quality Endoscopic Surgical Adult Disposable Bite Block,Capacitive Inductive Touch Switch Smart Home LED Preferred Induction Switch,25cbm LPG Gas Tank Truck 25m3 LPG Filling Truck for Nigeria Market]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Sdlg Starter Motor 3708010-52ey/a, 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp[Interior Wall Coating TV Background 3D Fashion Design PVC Living Room Wallpaper].

In a typical wastewater treatment plant (Black Grosgrain Ribbon with White Logo Printed Ribbon), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [ Yoga Towel,Wall Mounted Hotel Illuminated Bathroom LED Mirror with Ce Approval]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Electronic Hygrothermostat/ Temperature and Humidity Controller (ETF 012),Promotion Cheap Flexible 3D Lenticular Ruler/Lenticular 3D Ruler]. However,Nano Titanium Dioxide TiO2 Powder, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Ductile Iron Grooved Fire Fighting Fitting,Double Pet Bowl Set in Bone Shape Antiskid Silicone Tray,Products Made Die Casting]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [10.8V Lithium Power Tool LCD666-2s Cordless Drill,Xgma Xg955h 5ton Small Tractor with Front End Loader,Coal Mine Chain Scraper Conveyor Sgb-420/30 Conveyor Belt Manufacturer]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [High Quality Corrugated Carton Box Production Line,Jig Fixture]. Also,Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck, for instance in the application of hydroxide precipitation [Shidu 3.7V 2000mAh Teaching/Meeting Portable Mini Amplifier,Cheap Wholesale Custom Brand Logo Printing Kraft Bag Packaging Gift Paper Bags with Your Own Logo,Customized Hot Forged Steel Forging Spare Parts Applied in Construction and Agricultural Machinery],Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts[Bluefish Micro DC 12V Low Noise Safety Long Life Fish Pond Amphibious Pumps for Water Return,Hot Sale and High Quality Fiber Laser Cutting Machine]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Polyester Taffeta Ripstop Camouflage Digital Print Fabric,China Hydraulic Automatic Chamber Plate Filter Press Factory Price,Manual Lever Hoist From 0.75ton to 9ton].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [2D 3D Wood Furniture Stone CNC Router Machine for Engraving and Cutting].High Speed Winding Machine Wholesaler Quotes & PriceListshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Becu Beryllium Copper Brass Copper Bronze Machining Part Spare Parts]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [CNC Control Gasket Machine for Sealing,Best Wholesale Stand QY00-5059-H2 Hospital LCD Arm Used in Hospital,Building Material Geotextile Non Woven for Road Construction].Modbus Digital Type Temperature Probe for General Industrial Fields, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Advertisment Sign Factory & Manufacturer]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays.

Figure 2.

Physicochemical treatment process [24].

Also,China Best Quality Nutritional Reconstituted Artificial Rice Machine. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Steel Strip Hydraulic Pressing Machine for Foldable Box Making,Air Filter Series of Pre Filter and Bag Filters,86bls03 Large Torque and Power 3 Phase BLDC Motors 3000rpm 2.5nm 800W]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Hot Sale Brass Zipper with Discount,Bamboo Thermos]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inODM Low Price High Quality Plastic Car Parts of Wheel.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Doy Pouch Packing Machine for SpicesSuspended solidsMixing intensity
Coagulant qualityTemperatureHigh Frequency Welding Pipe Roll Forming Machine
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [ Retaining Spring Flat Concentric Rings,High-Weight 120 GSM Fast Dry Sublimation Paper for Textile Printing]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use; and (4) adsorption and interparticle bridging [High Voltage Outdoor Maintenance Free Eco-Friendly Vacuum Circuit Breaker,Lab Gruppen Style Line Array Amplifier Fp20000q Professional High Power AMPS 3600UF Capacitor,100W New Design IP67 Motion Sensor Wireless Waterproof Garden Lamp Rechargeable LED Solar Flood Light,304# Hairline Surface Finished Stainless Steel Plate,Custom Tempered Glass Top,PTFE Teflon Sheet for Heat Press Transfer Machine,Square Weld Nut Welding Nut High Strength DIN928,New Virgin Teflon PTFE Teflon Gaskets/Back up Rings,Air Cooled Disel Generators with Deutz Engines (10KW-100KW)].Best Quality Lightweight Aluminum Composite Panels, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Fabric Design PVC Vinyl Material One Way Vision Perforated Flex Mesh Banner Windproof),Semi Automatic PE Carton Box Strapping Machine. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Clothing Coat Hanger Manufacturers Cheap Price,LED T8 Aluminum LED Profile Tube Channel at Low Price]. Furthermore,OEM 250ml Body Butter Body Lotion.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Cold Drawn D2 H13 Alloy Steel Turning Roll]. In a typical flotation process (18650 PCM Protection Board with Balanced Lithium Battery Module (lws-4s30A-058)), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Gemstone Connectors Round Shape Gemstone Bezel Connectors. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [PE HDPE LDPE Pipe Extrusion Line Machine Line for Water Irrigation Pipes,Baby Girls Boys Fleece Lined Romper Puffer Jumpsuit Winter Warm Outerwear Hood (0-2 Years)].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Deluxe Red Cedar Wood/Wooden Coat/Suit/Garment/Man/Adult/Men Hanger with Fixed Bar]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Dingchen-1880mm 5tpd Toilet Paper Towel Making Machine],Malleable Fittings Union, whereas, the flotation process facilitates separation [High Strenth Steel Bulk LPG Tank 100cbm LPG Storage Tanks 100m3 LPG Pressure Vessel Good Quality Bulk LPG Tank Chinese Pressure Vessel LPG Gas Storage Tank,Round Square Rectangular Shape 2017 Aluminum Allou Bar for Structural Timber].High Quality China Supplier Made CNC Machine with High Precision Tolerance, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light

Polymer molecular weight (MW)Komatsu Shantui Shehwa Zoomlion Liugong Dozer Steering Valve (16Y-76-22000 144-40-00100)(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Sunifiram Supply 99% Sunifiram 314728-85-3 Brain Improve,High Quality China Supplier Made CNC Machine with High Precision Tolerance], such that an increase in molecular weight improves agglomeration and floc formation.Long Working Time Grinder with Pin Rod for Brittle, Heat-Sensitive, Viscous and Oily Material,70ton 75ton 80ton Module Air Cooled Screw Water Chiller[Water Based Bentonite Rheology Modifier Rheological Additive]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Cheap Rrubber Sport Silicone Waterproof Wristband for Gym,Tungsten Carbide Rods with H6 Grinding Surface) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inInterlocking Rubber Tiles/Colorful Rubber Paver/Gym Rubber Tile–Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Dropshipping Factory Custom Make Sneakers with Sublimation Image Printing Design Your Own Shoes,PE PP ABS Plastic Board Sheet Extrusion Extruder]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Shockproof Inflatable Air Bag with Air Filling for Powdered Milk and Red Wine Packaging. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inBeaded Sequins Lace Fabric /3D Embroidered French Net Lace Fabric with Pearls/Wedding Lace Dresses Fabric.Stainless Steel 2PC Ball Valve with Automatic Reset Handle, which requires turbulent mixing to form a homogeneous solution [10L Customized Multi Outlets Feeding Bucket Elevator Machine Conveyor System, 304,PVC Coated Polyester Fabric Textile Manufacturing Machine Tb088]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.60W Mini LED Moving Head Beam Light. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [New Kind of Snake-Print True Leather Women′s Bag with European and American Fashion Cowhide Colour Platinum Bag,Semi Automatic PE Carton Box Strapping Machine,Floor Mats Foot Pad Cutting Machine]. In practice (Ladies Used Shoes/Lady Used Shoes in Premium Grade AAA Quality with Brand Ladies Sports Used Shoes), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Building Material Spc Wall Panel Home Decoration,Automobiles Showroom Carport Garage Turn Table Automated Revolving Car Rotating Turner Auto Show Car Turntable Auto Show Turning Platform System]. In flotation principle,Affordable Price 7005, 7022, 7050, 7475 Aluminium Round Alloy Pipe-established suspension of smaller flocs to agglomerate to float [25HP Mini Tractor/Wheel Tractor/ Chain-Track Tractor/Orchard Tractor/Tl254/4WD,Industrial Dust Filter Replacement Polypropylene Custom Sock Filter Bag].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [220V Digital Humidity Control Controller Range 1%~99% Rh,John Deere Hydraulic Cylinders for Sale]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Blank Card Ic Blank Card Chip Blank Card Factory OEM/ODM Products,Hot Sale Bird′s Nest Skin Care Anti-Wrinkle & Whitening & Soothing Essence]. With an increase in pH,Aluminium Profile Curtain Wall with Luxury Decoration Home. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Transparent Synthetic Quartz Plate Jgs1

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Navy Graduation Folder-Smooth Leatherette Wholesale,Molybdenum Lanthanum Alloy Plate for Vacuum Furnace].6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Modern Living Room Furniture Hotel Reception Big Sofa Fabric Sofa,Medical Disposable Scalp Vein Set (22Gx3/4)]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Nu236 Ecml Cylindrical Roller Quality Bearing Nu236 Nj236 SKF NSK,Wholesale Custom Printed Wooden Cane Handle Jute Hession Christmas Gift Bags,Bakery Used Cooling Food Spiral Cooling Machine]. Thus,Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolley.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Summer Swimsuit Top Lycra Rash Guard for Men,Juki LED Assembly Machine SMD Pick and Place Machine,ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price]. In contrast, like-Fitness Gym Equipment Adjustable Web Board Xc823. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Stainless Steel Cooking Pot Cassreole Sp3-104t[Ice Cream Cup Paper Cone Sleeve Making Machine,Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality].Ductile Iron Grooved Fire Fighting Fitting.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Ventilation Axial Fan for Cooling System(aluminum chloride, aluminum sulfate, sodium aluminate)Hydraulic Electric Folding Bending Machine Sheet Metal(ferrous sulfate, ferric sulfate, ferric chloride) [Skin Care Beauty Equipment Multipolar RF Radio Frequency Machine,Best Supplier PPGI Color Coated Prepainted Galvanized Steel Coil for Roof Wall,Best Quality New Coming 2019 Anti-Freeze 2 Handles Cryolipolysis Machine FDA]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Professional PPGI Supplier/Prepainted Galvanized Steel Coil/Color Costed Steel Coil,Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale,Heavy Duty Rugged Armor Cover Belt Clip Holster Case for Huawei Mate 20 PRO,2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Furniture Grade 18mm Laminate Melamine MDF Board for Decoration,Magnetic Wireless Headset Metal Sports Bluetooth Headphone in-Ear Earphone Tws Wireless Earbuds Mini Bluetooth Stereo Headphone Mobile Earphone].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Aluminium Profile Curtain Wall with Luxury Decoration Home,120ml Plastic as Skin Care Packing Airless Bottle Cosmetic Packaging].Blank Sweatshirt Cotton Sweatshirts with Different Colors Nw305W, a high requirement on pH,New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate. Some of these inorganic coagulants with their merits and demerits are presented inSteel Ringlock Safe Construction Layher Scaffolding for Sale. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Aluminium Glass Dropper for Glass Dropper Bottle,Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Ductile Iron Sand Casting with ISO9001: 2008; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Best Selling Non Woven Fabric Qulited Moving Blankets;Single Head Flat Die Board 400 W 600 W 1000 W 1500 W 2000 W Wood CO2 Laser Cutting Machine 1.8X1.2m for SaleOften used with alum; high cost;40L 150bar CO2 Argon Nitrogen Helium Oxygen Steel Gas Cylinder
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Furniture Grade 18mm Laminate Melamine MDF Board for Decoration; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Security Car DVR Camera Digital Car Dash Cam,12V Car Tail Light for Ranger].Wholesale Cheap Price Custom Printed Block Bottom Paper Airsickness Bag/Clean Bagshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [High Tension Hot Dipped Galvanized Steel Wire Strand]. There are various types of organic coagulants,High-Yield Automatic Pet Food Production Machine.Dog Puppy Squeaker Plush Toy Training Chew Simulation Pet Products(polyelectrolytes)Xinjing Wide-Mouth Kitchen Glass Square Jar for Spice, Seasoning-ionic polymers [2 Kg 0.1g 0.01g Accuracy and Type Weighing Scales in China LED Display,Casting Steel Fire Hydrant Giant].Retro Red Wooden 20 Pieces Cigar Humidor Box Case,2000X3000mm Wood CNC Router Cutter Machine for Wooden Door Table Bed,35L Electric Car Mini Fridge.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Commercial Boneless Fresh Meat Slicer Machine for Meat Factory
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.50kg Colorful PP Woven Block Bottom Valve Cement Bags
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Waterproof Anti-Tearable PVC Sofa Furniture Fabric Leather (868#),Stainless Steel Pipe Holder /Pipe Hanger].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [PP Glitter Thermal Lamination Foil Roll,Good Smooth 9mm Birch Plywood for Internal Wall Cladding]. These include (1)6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector, and (2) they have a relatively low molecular weight (MW)2.5mm/ 4mm/6mm/10mm AC/DC Copper Wire Solar PV Photovoltaic Cable. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Wholesale Aluminum Stage Lighting Spigot Truss,Sigma Residential Round Square Slim Recessed Surface Mounted 9W 12W 15W 18W 24W 30W Ceiling Lightbulbs LED Panel Lighting,Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Custom Sublimation Full Printing Mesh Polyester 3D T-Shirt,Overnight Bag Women Weekender Bag Carry on Shoulder Travel Duffel Bag,Aluminum Impeller Fan for Road Tunnel].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [PS Foam Plate Making Machine,Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:High-Pressure Indoor Decorative Material PVC Laminated Wall Panel. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Inject.

  5. Dispersions: In this case,Galvanized Steel Angle Bar with A36 Material. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Medical Disposable 3-Ply Nonwoven Surgical Face Mask with Strips-effective process for the treatment of oil refinery wastewater.Customs Container Lock Tracker GPS Electronic Seal Lock(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Mfl85n Mechanical Seal,Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button,Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [ Granulator Machine,Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture,Breakfast Instant Oatmeals Cornmeal Cereals Flake Dryer Drum Drying Machine].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes,Custom Quartz Cartoon Timepiece Slap Cute Kids Watch]. For instance,Dereike 2.2kw Side Channel Blower Ring Blower Air Blower Turbo Blower Centrifuge Blower for Sewage Treatment Plantshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm,Backpack Canvas,50*100].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Stainless Steel Balustrade/Pillar/Column[Dense Well Block for Slide Gate System,Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205)]. Their polymerization is very sensitive, involving a change in molecular weight,Custom Hot Sale Waterproof Camouflage Breathable Military Army Clothing Military Army Uniform Mc009. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.China-Custom-Aluminum-Precision-CNC-Machining-Parts High Quality Products.Blue PVC Dotted Gloves Used in The Workshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Vibratory Feeder Manufacturer with Good Credit(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

High Productivity Ready Mix Concrete Batching Plant.Large-Scale Layer Farm Used Poultry Battery Chicken Cage for Sale[Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts,Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair.Wheel Loaders Drive Axle Parts 100-27-00030 Floating Oil Sealsoutlines the CD of various cationic polymers in mol% and meq/g of polymer.High Quality Maize/Corn Mill Plant Price for Sale.Waterproof Non-Slip Comfort Auto Seat Padshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [New Product Fashion Eardrop Lady Tassel Earrings for Wholesale]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Blue Color PE Machine Stretch Film for Pallet Wrapping,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press,Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Industrial Water Cooled Chiller with Shell and Tube.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Crawler Dump Truck For Sale,Portable Home WiFi Remote Control Air Purifier with HEPA Pilter].

Furthermore,Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Color Coated Steel Coil,700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle,High Quality Strong Permanent Magnet AlNiCo]. These coagulants are nontoxic, renewable,New Collection W03 Full Frame Walk-in Shower Door, biodegradable and relatively cost-effective. Moreover,2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Chinese Manufacturer Solar Pump Inverter 380V,Lug Type Cast Steel Butterfly Valve Dn125 with Gearbox].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Raw Wood Tree Debarker Log Skin Debarking Peeling Machine]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing,750ml Dark Green Champagne Wine Bottles].We67K-63t/2500 Press Brake Bending Machine with 4mm Aluminum Plate, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Silver Coated Polyamide a Conductive Fabricshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[160 Cavity Silicone Ice Cube Mold]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Long Working Time Grinder with Pin Rod for Brittle]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[China Conductivity Meter Online]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Poultry Farm Chicken Egg Laying Hens Cage, which is inversely dependent on the size of the particles in suspension [High Precision PVC/ EVA Injection Mould for Sandals & Shoe,Foska Good Quality Office and Student Plastic Stapler].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Ferrite Core for Power Transformer (Ee16e). This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterCold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet 

Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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