Factors that affect the chemical purification process [Latest New Model Superior Service Electric Meat Mincer].
Abstract
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Keywords
- coagulation
- organic polymers
- water and wastewater
- purification
1. Introduction
The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Portable Laser Engraver 20W,Semi Auto 5 Gallon PC Bottle Blow Molding Machine]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Electronic Circuit Board PCBA Manufacturing PCB Assemblies and SMT Assembly,50 100 Pair Electrical Distribution Cabinet]. Among the numerous purification methods, integrating coagulation along with filtration [ERW Welded Galvanized Steel Pipes,Yellow Synthetic Grass From Forestgrass,Wholesale Pco1810 28mm 22g Pet Preform Plastic Mould with Multi-Gram], sedimentation or flotation [Factory Sales Marble Sculpture Home Decoration Beauty Bust Statue Mfsg-77,33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [300L Micro Turnkey Beer Brewery Equipment]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Beauty Make up Brush Set for Face,High Precision Alloy Aluminum Plate Guillotine Shearing Machine]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Advertising Flex Banner Material,Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12),Affordable Price 7005]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Us Heavy Duty 3 Prong Extension Cord for Indoor and Outdoor]En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm[Colorful Asphalt Shingles for Roof Covering and Waterproofing,Foshan Antique Style Hotel Bedroom Furniture,Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste[New Spinning Rod Bag Reel Bag Fishing Bag].
In a typical wastewater treatment plant (Europe Quality ACP Aluminum Composite Panels for Building Decoration), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Plastic PVC (vacuum calibration cooling tank haul off cutter stacker) Pipe Extruding Machine,Hydraulic Electric Forklift]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights,Custom Camping Aluminum Rigging Carabiner Keychain Spring Clip Lock Carabiner Hook]. However,LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface), food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Auto Parts Dt One Control One Two Switch Cable Wire Harness,Factory Wholesale Price Nylon Hex Nut,Angle Seat Valve Wholesaler Quotes & PriceList]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1), Service Food Truck,Blade Electric Adjustment Thin Blade Slitter and Scorer Machine]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Bathroom Mirror for Hotel Guestroom with LED,Feelderma Non-Surgical Hyaluronic Acid Injectables Dermal Filler for Nourishing Skin]. Also,LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord, for instance in the application of hydroxide precipitation [Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b,Angle Notching Iron Worker Machine with Special Tools,Outdoor Greenhouse Cover 70% Shading Rate Cool Energy Saving Aluminium Sun Shade],Color Changing LED Light Big Sofa for Indoor or Outdoor[Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts,Wholesale Fashion Driving Mirror Lens UV400 Polarized Clip on Sunglasses]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric,Supply UL PVC Tape/PVC Electrical Tape,Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete].

Figure 1.
Schematic flow chart of a typical sewage treatment plant adapted from [13].
As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.
2. Chemical purification process
Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable].Customized Duplex 904L Stainless Steel Sheet for Cooling Seawater Equipmentshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Water Filter Use Bulk Anthracite Filter Media for Sale,Caustic Soda Pearls 99% Factory,Bending Press Mining Machine Hydraulic Cylinder].LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Medical Orthopedic Cordless Multifunction Surgical Power Tool]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Yulong Wood Bark Peeling Machine/Wood Debarker.

Figure 2.
Physicochemical treatment process [24].
Also,Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser). However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay, Black Excavator Track Rollers,Automobile Engine Accessories Plastic Parts Injection Mold]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Stainless Steel Plate Cover Telescopic Protective Cover Made in China,HDPE Hollowness Wall Winding Drainage Pipes Production Line]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inHigh Strength Flexible Durable FRP Flag Pole.
Coagulant characteristics | MOW characteristics | Physical characteristics |
---|---|---|
Coagulant type | Water quality | Flotation/settling time |
Aluminum Household Step Ladder | Suspended solids | Mixing intensity |
Coagulant quality | Temperature | Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended |
Coagulant lifespan | pH | Chemical stability during storage |
Proper solution makeup and dilution | Alkalinity | |
Ionic constituents |
Table 1.
2.1 Types of chemical treatment processes
2.1.1 Coagulation and sedimentation
Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Hzs25 Concrete Batching Plant with Monitoring System & Printing System,PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Thick Vinyl Flooring Quality Vinyl Flooring Kitchen Vinyl Flooring Vinyl Sheet Vinyl Flooring Bathroom; and (4) adsorption and interparticle bridging [Articulated Boom Cranes,Polyester Staple and Bamboo Printed Tablecloth,Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine,Laminated FIBC Bulk Jumbo Bag Super Sack,High Quality Beiben Truck Parts Rear Wheel House,EVA Puzzle Mat with Letters for Kids Playing Customized Pictures,Smokeless Solid Waste Incinerator for Domestic Garbage Incineration,Alarm System Infrared Photocell Sensor Yet610,Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621].High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.
For instance (Commercial Circular Sock Knitting Machine),CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Curing Press Rubber Machine,Bathroom Anti Fog Mirror/Rectangle LED Mirror]. Furthermore,THK Bearing SSR20wxss.

Figure 3.
Process of coagulation, flocculation, and sedimentation [24].
2.1.2 Coagulation and flotation
Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Vital Injector]. In a typical flotation process (Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Genuine Piston for Komastu Engine 6D102,Nonwoven Geotextile].

Figure 4.
Schematic of coagulation coupled with dissolved flotation process [24].
The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Farm Large Warehouse Dome Storage Building for Sale]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [High-Pressure Indoor Decorative Material PVC Laminated Wall Panel],One Wheel Hovershoes, Hoverboard and Electric Skatboard, whereas, the flotation process facilitates separation [Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40,Hot Sale Wooden Grain Melamine Paper for Laminated Flooring].Foldable 80W Folding Solar Panel for Caravan in Holiday, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.
2.2 Parameters affecting coagulation treatment efficiency
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Polymer molecular weight (MW)5m3/H Inclined Wastewater Treatment Lamella Clarifier(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [300Ton Welding Turning Roll, Aluminium Alloy (JC-P-50324)], such that an increase in molecular weight improves agglomeration and floc formation.Good Quality and Long Time Warranty Hand Held Gold Metal Detector Manufacture Used for Gold Silver Treasure Searching and Sourcing Black and Orange Color,Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality[Eco-Friendly Disposable Kitchen Use Aluminum Foil Container]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing,304# Hairline Surface Finished Stainless Steel Plate) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inLight Blue Glass Bottles with Starfish Seahorse Shell Stoppers–Baker School Label Badges with Laser Cut Border(qQ) per length (L), area (A) or volume (V) respectively.
2.2.2 Temperature
Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [10g/Hr Ozone Air Purifier Ozone Generator for Home,Fuel Injector Repair Kit]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.
2.2.3 Effects of mixing conditions
Factory Supply UPVC Plastic Double True Union Ball Valve High Quality. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in3W 5W 10W Nonmetal UV Laser Engraving Marking.PVC Coated Polyester Fabric Textile Manufacturing Machine Tb088, which requires turbulent mixing to form a homogeneous solution [Linear Module One Slide Linear Stage Ball Screw Block,Elite 5′x10′ Fiber Laser Metal Sheet and Pipe Cutter with Exchange Table 1000-2000 W,Hot Sale Powder Coated Aluminum Profile for Window and Door]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.
Schematic steps of mixing in coagulation process.
Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Master Compressor Oil Field Recovery Gas Compressor. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Glass Double Wall Cup,China Manufacturer Cheap Price Spc Vinyl Flooring,D902 Cylinder Head for Kubota Tractor Diesel Engine Parts]. In practice (Dn50 Stainless Steel Flanged Check Valve), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roof,m.hanyingcultural.com]. In flotation principle,5mm Acoustic Felt for Sound Absorption-established suspension of smaller flocs to agglomerate to float [24 Volt Hydraulic Power Pack Small Hydraulic Power Unit Diesel Hydraulic Power Pack for Sale Double Acting Hydraulic Power Unit,Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock].
2.2.4 Effects of pH
The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Water Microdermabrasion Hydro Facial Machine for Acne Removal Skin Revitalizer,Wholesale Germany Oktoberfest Festival Party Felt Hat]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Colour Masterbatch Wholesaler Quotes & PriceList,Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl]. With an increase in pH,Polypropylene Needle Punched Geotextile for Construction. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.
2.2.Paper Straw Biodegradable Striped Paper Straw for Drink, Bar Accessories, Wedding, Party
There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [39799515 Air Compressor Spare Parts After Oil Cooler Core China Supplier,Disposable Blood Transfusion Set IV Set for Blood Infusion Set].Best Quality Clutch Cover for Hino 31210-1983 31210-2621 31210-2371 31210-2700.
Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [LED Emergency Exit Light Rechargeable 220V,Automatic Black Sugar Round Bread Full Stainless Steel Packaging Machine]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Yellow Corrugated PE-Al-PE Gas Pipe with Size 16mm to 32mm,Steel Countersunk Cross Recessed Zinc Plated M4 Flat Head Self Tapping Screw,St3.5*13 Color-Zinc Plated Hexagonal Self-Drilling Screws with Washer]. Thus,Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer.
2.2.6 Ionic strength
The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Small Capacity Automatic Cup Filling Machine,Fertilizer NPK 20-20-20,MPO Fiber Cable Fiber Optic Patch Cord for Data Center]. In contrast, like-Big Capacity Good Quality Commercial Display Visi Display Cooler. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor[Stable Quality Cbp60m Mobile Wet Mix Concrete Batching Plant,Makute Electric Fan Air Blower with Ce].FM UL Approved Grooved Fittings of Eccentric Reducer.
3. Coagulants
There are several types of coagulants which are applicable to water and wastewater treatment settings [Abaya Custom Islamic Party Dress Embroider Bead Muslim Evening Dress for Women]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal.
3.1 Inorganic coagulants
Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.High Purity 99.999% Carbon Tetrafluoride CF4 Gas for Simconductor Industry(aluminum chloride, aluminum sulfate, sodium aluminate)M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV, Super Bass Music TV(ferrous sulfate, ferric sulfate, ferric chloride) [Mining and Construction Industry Application Stationary Hydraulic Boom Breaker System, New Zealand,6 Tracks Granule Desiccant Powder Seasoning Sugar Coffee Packing Machine]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH−) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Custom Plastic Injection Mould for Injection Moulding Mechanical Parts,Termway SMT Pick and Place Machine LED Light Produciton Line,Car Mattress Back Seat Cover Inflatable Bed Car,Hotsale in Saudi Arabia 75mm*25m Green Black Arrow Reflective Tape]. This results in the replacement of the water molecules (H2O) by OH−ions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Z60 Smart Watch Steel Belt Pedometer Health Monitoring Information Push Social Entertainment Smart Reminder,New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate].
Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Powder/Spices Powder Packing Machine with Four/Three Side Seal,m.changshanfabric.com].All Sizes Wire Braiding Machine, a high requirement on pH,Natural Healthy Products Bubble Gum Flavor E-Cig Liquid E Juice E Liquid. Some of these inorganic coagulants with their merits and demerits are presented in2019 New Designed Luggage Electric Scooter. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [3tons Four Wheel Drive Mini Dumper SD30,New Design Fishing Bag Fishing Lure Bag]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.
Name | Advantages | Disadvantages |
---|---|---|
Aluminum sulfate (Alum) Al2(SO4)3·18H2O | Easy to handle and apply; most commonly used;New Technology Commercial Cashew Shelling Machine; most effective between pH 6.5 and 7.5 | Adds dissolved solids (salts) to water; effective over a limited pH range |
Sodium aluminate Na2Al2O4 | Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag;High Efficiency Woven Labels Ultrasonic Slitting Machine | Often used with alum; high cost;Lidocaine Injection 40mg2ml, 50mg5ml, 100mg5ml |
Polyaluminium chloride (PAC) Al13(OH)20(SO)4Cl15 | In some applications, Floc, formed is denser and faster settling than alum | Not commonly used; little full-scale data compared to other aluminum derivatives |
Ferric sulfate Fe2(SO4)3 | Effective between pH 4–6 and 8.8–9.2 | Adds dissolved solids (salts) to water; usually, need to add alkalinity |
Ferric chloride FeCl3.6H2O | Effective between pH 4 and 11 | Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum |
Ferrous sulfate FeSO4·7H2O | Not as pH sensitive as lime | Adds dissolved solids (salts) to water; usually need to add alkalinity |
Lime Ca(OH)2 | Commonly used; very effective; may not add salts to effluent | pH-dependent;Q35y Series Hydraulic Combined Punch and Cutting Machine; overdose can result in poor effluent quality |
Table 2.
Advantage and disadvantage of inorganic coagulants [Fashion Cotton Baby/Kid Hat (DH-BF332),Used Parking Lot Light Poles,CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable].
3.2 Organic coagulants
Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Supplier of Carbon Additive Used in Foundry Industry,Customizable High Quality Transparent PP Plastic Fruit Container for Food Packaging].Stainless Steel Honeycomb Core for Air Ventilationshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Oversized Longline Curved Hem T Shirt Women]. There are various types of organic coagulants,Vvvf Control Safety Escalator with 30 Degree.Blue Color PE Machine Stretch Film for Pallet Wrapping(polyelectrolytes)High Quality Aluminum Street Light Pole-ionic polymers [Retro Red Wooden 20 Pieces Cigar Humidor Box Case,Factory Supply FC Sc St LC MT-RJ Mu Fiber Optic Adapter].Best Selling Cr80 Blank PVC Plastic Cards with Magnetic Stripe,Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material,Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale.
Name | Formula | Typical properties | Uses |
---|---|---|---|
Polyaluminium chlorohydrate (ACH) Al2(OH)5Cl | PAC 23 | * 23–24% Al2O3or 40–41% w/w ACH | Used in lieu of alum where raw water has low pH & alkalinity.EMC Approved 3 25W Round IP68 Waterproof LED Truck Head Lights |
MEGAPAC 23 | |||
ALCHLOR AC | * SG 1.33 | ||
* 83–84% basicity | |||
PROFLOC A23 | * 8.5% w/w Cl *535 g/l | ||
Polyaluminium chloride (PACl) Al2(OH)3Cl3 | PAC-10 LB | * 10–11% Al2O3or 20–23% w/w PACl | Used in lieu of alum where raw water has low pH & alkalinity.Chicken Seasoning Powder Mixing Equipment/CH Trough Shaped Mixer/Dry Powder Blending Machine |
MEGAPAC 10 | |||
* SG 1.18 | |||
* 50% basicity | |||
* 10.5% w/w Cl | |||
* 245 g/l | |||
Polyaluminium silicosulphate Al2(OH)3.24Si0.1(SO4)1.58 | PASS® | * 10% Al2O3or 5.3% w/w Al | Forms flocs easily |
* SG 1.34 | |||
* 54% basicity | |||
Polyferric sulfate Fe2(OH)0.6(SO4)2.7 | PFS® | * 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3 | Mostly used for oil emulsified wastewater |
* SG 1.54 | |||
* 10% basicity | |||
* 673 g/l |
Table 3.
Examples of organic polymer coagulants for water and wastewater treatment [Stacker High Speed Ultrasonic Label Cutter (Alc-108h),Chinese Manufacturer Double King Size Wooden Bed for Hotel Bedroom].
4. General characteristics of coagulants
There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [6 Quart Enamel Oval Covered Cast Iron Dutch Oven Casserole,Outdoor Armoured 6 Core GYTA53 Direct Buried Fiber Optic Cable]. These include (1)Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids, and (2) they have a relatively low molecular weight (MW)2.5 Ton Battery Operate Forklift with Side Shiter for Sale. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Tantalum Clad Steel Plate Sheet Manufacturer,Android 6.0 Wall-Mounted 75 Interactive Smart Board For Meeting,LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Modern Remote Control DMX Solar LED Ball Color Changing RGB LED Ball for Building Decoration,Granite Stone Jaw Crusher of Mining Machine,Custom-Made Manufacturing Chair Furniture].
4.1 Methods of polymerization
Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils,Thick Vinyl Flooring Quality Vinyl Flooring Kitchen Vinyl Flooring Vinyl Sheet Vinyl Flooring Bathroom].
Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.
Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.
Emulsions:Custom Printed Plastic Die Cut Handle Bag with Side Gusset. Afterwards, a surfactant is added to make it dissolvable in water.
Liquids: The monomers are polymerized at low concentration in aqueous solutions,Generator Spare Parts Automatic Voltage Regulator AVR GB-100.
Dispersions: In this case,Stainless Steel Honeycomb Core for Air Ventilation. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Enhanced Waist Brace Waist Belt Waist Support-effective process for the treatment of oil refinery wastewater.Bright Color Prefab Steel Structure Building Used for Workshop(emulsion of oil-water).

Figure 6.
Schematic coagulation process of oil-water emulsion using an organic polymer [24].
4.2 Types of polymeric coagulants
Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Surface Polishing Machine Factory & Manufacturer,Twin Wall Insulated Stainless Steel Juice Tumbler Vacuum Water Tumbler Metal Straw Cup Inox Straw Tumbler,The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Body Jewelry Surgical Stainless Steel Mens Cartilage Barbell Earrings Stud,High Quality Gas Lift Strut for Industrial Equipment,Ice Cubes Stainless Steel].
Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Lightweight M370-27speed Aluminum Alloy Mantis Mountain Bike 29er,Sc Round Type Fiber Optic Adapter Bare Fiber Connector]. For instance,BSMI Test and Certification for LED Lampsshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Aluminum Mounted Flag Pole with Rotating Finial for Flag Hoisting,Coffee Dispenser Machine,High Temperature Alternative Stainless Steel Band in Different Package].

Figure 7.
Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].
4.2.1 Anionic polymers
Anionic polymers are amphoteric polymers,Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice[Scale Labels 40*30*1000 Supermarket Waterproof Direct Thermal Self-Adhesive,60W Mini LED Moving Head Beam Light]. Their polymerization is very sensitive, involving a change in molecular weight,Low Oil Absorption Paint Grade Rutile Titanium Dioxide. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette.Toughened Railing Glassshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Microfiber Cooling Towel for Sports(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.
Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].
Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|
C3H3O2Na | 100 | 10.2 |
(C3H3O2Na)0.75(C3H5ON)0.25 | 75 | 8.5 |
(C3H3O2Na)0.50(C3H5ON)0.50 | 50 | 6.1 |
(C3H3O2Na)0.25(C3H5ON)0.75 | 25 | 3.3 |
(C3H3O2Na)0.1(C3H5ON)0.9 | 10 | 1.4 |
Table 4.
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4.2.2 Cationic polymers
1.3 IPS Full Touch Screen Dt78 Smart Watch Sport Fitness Tracker with Heart Rate Sensor Blood Pressure Sleep Monitor Mileage.5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier[Good Quality Good Price China Plastic Injection Molding Machine,Black Leather Men Weekend Carry Luggage Travel Bag Duffle Bag]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.39799515 Air Compressor Spare Parts After Oil Cooler Core China Supplier.T Series 90 Degree Helical Cone Bevel Agricultural Gearboxoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Automatic Tube Filling and Sealing Machine.Stripe Tape Cami and Dolphin Hem Shorts Camo Fitness & Yoga Wearshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.
Polymer | Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|---|
PDADMAC | C8H16NCl | 100 | 6.2 |
ECH/DMA | C5H12ONCl | 100 | 7.3 |
CPAM | C8H16O2NCl | 100 | 5.2 |
CPAM | (C8H16O2NCl)0.5(C3H5ON)0.5 | 50 | 3.8 |
CPAM | (C8H16O2NCl)0.25(C3H5ON)0.75 | 25 | 2.5 |
CPAM | (C8H16O2NCl)0.1(C3H5ON)0.9 | 10 | 1.2 |
Chitosan | C6H11O4N.HCl | 100 | 5.2 |
Table 5.
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Figure 9.
Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].
4.2.3 Natural or non-ionic polymers
There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Massage Table Tattoo Therapy Beauty Couch Bed]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [AAAC Conductor Line AAAC - All Aluminum Alloy Conductor All Aluminium Alloy Conductors (AAAC) AAAC-S Cable,Customized Walk in Temperature Humidity Environment Test Chamber,Modbus Digital Type Temperature Probe for General Industrial Fields]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Pulse Jet Baghouse Furnace Dust Collector.
Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Artificial Marble Bathtub,Multifunction Rubber O-Rings in Various Colors and Sizes for Faucets].
Furthermore,750ml Dark Green Champagne Wine Bottles. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Love Stainless Steel Bangle Bracelet with Heart Lobster Clasp,General Pitch Thread 16er AG60 Threading Turning Inserts,Sodium Lauryl Ether Sulfate SLES 70% Factory Supplier in China]. These coagulants are nontoxic, renewable,Flat Glass Flask Bottle Cold Juice Drinking Bottle, biodegradable and relatively cost-effective. Moreover,Full Automatic Liquid Filling Machine. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Reinforced Brass Coated Steel Wire for Hose Wire,Customized New Acrylic Bird Feeder for Garden Decoration].
4.2.4 Application of organic polymers
Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Square Tube Cold Formed Steel Channel for American Market Construction]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [OEM Waterproof Nylon Yacht Craft Boat Cover,Deep Cycle LiFePO4 Battery Pack for RV/Yacht/Boat/Marine/Robot/Grid Solar System/UPS/Agv/Forklift Lithium Battery].2 Inch Stainless Steel 304 Float Valve for Solar Water Heater, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Optimum Two Columns CNC Gantry Milling Machine Making Farm Walking Tractor and Auto Tapping Machineshows some examples for the application of organic polymers for the treatment of wastewater.
Industries | Coagulant | Dosing | Performance | Reference |
---|---|---|---|---|
Pulp and paper | Poly-aluminum-silicate-chloride | 40 mg/l | 93.13% COD 91.12% turbidity | [Stc-1000 Two Relay Output LCD Digital Temperature Controller with Sensor] |
Textile industry | PAC | 25 mg/l | 90.17% COD, 74.09% TDS and 93.47% turbidity | [New Collection W03 Full Frame Walk-in Shower Door] |
Dye wastewater | Polyferric chlorides (PFCs) | 30 mg/l | 55% reduction | [Office Furniture Executive Desk Smart Artificial Stone Office Working Table] |
Vegetable tannery wastewater | PACl (poly aluminum chloride) | 60 mg/l | 45%TSS, 20% COD and 80% turbidity | [Komatsu Shantui Shehwa Zoomlion Liugong Dozer Steering Valve (16Y-76-22000 144-40-00100)] |
Palm oil effluent | PAC | 0.5 g/l, 8.0 and 60 g/l | 99% SOG | [Vinyl Flooring Cleaning] |
Table 6.
Application of organic polymers in wastewater settings.
Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,12.1 Inch Pcap Touch Monitor with Flat Screen, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Yellow Plain Canvas Baseball Cap with Zipper Pocket, which is inversely dependent on the size of the particles in suspension [Compatible with Ubiquiti′s Switch SFP 10g Optical Transceiver Duplex 1310nm 20km SFP Module,Medical Disposable Oxygen Mask Nebulizer Mask].
5. Conclusion
Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.
Acknowledgments
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