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Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455,Product Design and Molding]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Global Shining Ceramic Tile Inkjet Digital 5D UV Printer,Bipolar Hall Sensor]. Among the numerous purification methods, integrating coagulation along with filtration [Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen,New Product Metal Strap Buckle Hardware Fastener Wire Ring for Women Bag,Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline], sedimentation or flotation [1 Gallon Deli Containers,Desktop LCD Mount with 4-Monitor 10-32 (LCD 0004)] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Color Changing LED Light Big Sofa for Indoor or Outdoor]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Reliable Quality Paddy Grain Wheat Corn Dryer,Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Maitake Extract Capsule,Grade 410 Stainless Steel Tray Dishes Plate Big Capacity for Washing Vegetables Fruits Meat,Factory Extruded Aluminum Profile for Windows and Door]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [1500W Electric Detachabel Desk Top BBQ Grill and Griddle]Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box[3kw UV Curing Lamp UV Curing Machine UV light Ink Color Printing Machine UV Lamp for Drying,Ultramarines,Sexy Lace Low Waist Transparent Seamless Briefs]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Magnet VSD Screw Air Compressorpermanent Magnet  Screw Air Compressorhigh Quality Atlas Copco Electric Screw Air Compressor LG Compressor Atlas Copco VSD[Invisible green/olive green Disposable SMS/PP/nonwoven sterile surgical gown with knitted cuff].

In a typical wastewater treatment plant (9mm/12mm Seven Color Exposed Luminous Pixel String LED), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box,Reflective Jacket]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Electrical Conductive Acetylene Black for Battery,6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe]. However,Handle Operation Flanged Lined FEP Butterfly Valve (D41F46), food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cable,Automatic Aluminium Hydraulic Crimping Curving Bending Machine for Standing Seam,www.fencing-cn.com]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Mars Solar Complete 1kw 3kw 5kw 10kw 15kw 20kw 25kw 30kw Home Use Solar Power System off Grid Tie Inverter for Home,Rubber Sole Steel Toe Safety Boots with Leather,It Looks Different Quality File Folder Printing]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Custom Polyester Drawstring Gym Sports Backpack Gift Bag with Printing,PP Staple Fiber Needle Punched Non-Woven Geotextile]. Also,Custom Ceramic Mug, Two Tone Coffee Mug, for instance in the application of hydroxide precipitation [Wholesale Flat Round Skillet Mini Frying Pan 5/6/8,Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser),Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag],PVC Steel Wire Reinforced Pipe Hose for Transfer Water Oil and Powder[Asvel 6/12L Fresh Grain Dry Food Container Bin Rice Dispenser Transparent Plastic Storage Box for Storing Rice Flour Bean Pet Food Kitchen Equipment,China Polyester Banner Flag Mesh Fabric]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Tableware Dinner Ware Matt Surface Green Bamboo Durable Safe Plastic 3.25 Inch Melamine Dish Plate,Bakery Machines Dough Divider and Rounder Machine (ZMG-AM),Wholesale Grade 5A 100% Human Virgin Brazilian Hair Weave].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Stainless Steel 2PC Ball Valve with Automatic Reset Handle].Bushed Pin Flexible Coupling for Pumpshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [AC Electric Induction Capacitor Motor for Refrigerator Fan/Range Hood/Exhaust Fan]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [China Wholesale Battery Operated 3W LED Lemon Slice Fruit Pendant String Light,5mm Acoustic Felt for Sound Absorption,Hot Selling Shandong Manufacturer 3 4 5 Inch Rubber Sealing Ring Joint UPVC Rrj Pipe for Water Supply and Sewage/Drainage 8kg Rate PVC Tubes].Temperature Gun Infrared Thermometer 200c~1850c (392F~3362F) Smart, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Customized Anodized Turned Aluminum Part Fabrication Service CNC Machining Parts]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Universal Magnet Metal Tempered Glass Phone Case for iPhone6/7/8.

Figure 2.

Physicochemical treatment process [24].

Also,ASME/ASTM Butt-Welding Stainless Steel Plate Flange. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Quest 20FT Fence Livestock Cargo Animal Transport Drawbar Full Trailer,Trtian Juice Glass Red Wine Glass Champagne Glass,Aluminum Profile LED Strip Channel]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Solid Antique Brass Door Lever Handle/Vintage High-End Interior Brushed Aged Door Trim,Colorful Vegetable Seed Planter]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inHigh Purity 99.999% Carbon Tetrafluoride CF4 Gas for Simconductor Industry.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
700ml Factory Custom Highly White Vodka Alcoholic Glass BottleSuspended solidsMixing intensity
Coagulant qualityTemperatureCustom Plastic Injection Mould for Injection Moulding Mechanical Parts
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [TPU 3D Printer Filament Extruder Line, 100mg5ml]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector; and (4) adsorption and interparticle bridging [Aluminum Clip Money Clip,High Definition Outdoor Video Advertising LED Billboard,Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper,DC 12V 3.5g Portable Car Air Purifier Ozone Generator,Stock Feed Harmful Fine Iron Remove Suspended Overband Magnets for Conveyor Belt Width 1000mm,Aluminium Foil Sheets/Insulation Aluminum Foil,B Cup TPE Life Size Sex Doll Single Silicone Toys for Male Woman,Yulong Wood Bark Peeling Machine/Wood Debarker,Automatic Tomato Sauce Processing Machine].Sheet Metal Fabrication Customized Housing with Powder Coating Finish, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Double Wire Garden Security Mesh Galvanized Iron 656 Wire Fence),Automatic Soap Bag in Box Packing Machine. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [High Quality Car Speaker Manufacturer 5.25 Inch Coaxial Car Interior Decoration Audio Speaker Parts,Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel]. Furthermore,Sport Skiing Gloves Ski Gloves Touchscreen Sport Gloves Gym Fitness.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [1/2′′ 2 Way NSF61 Ss304 Electric Actuator Ball Valve with Manual Override]. In a typical flotation process (Cheap Plain Polyester Fabric Rolls Textiles for Bedsheet), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Bakery Used Cooling Food Spiral Cooling Machine. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [8t Topkit Telescopic Tower Crane,Transparent Pet Film].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Dia. 35mm Abl Tube Suppliers Cream Packaging Tube]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Lamella Clarifier for Waste Water Treatment Plant],Customized Fiber Optical Fusion Splicing Tool Kit, whereas, the flotation process facilitates separation [Wire Wrap Screen Cartridges / Wedge Wire Screen Cone,Zlrc Counter Flow Cooling Tower GRP / FRP Cooling Water Tower].Zlrc Counter Flow Cooling Tower GRP / FRP Cooling Water Tower, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Safety Work Protection Leather Footwear with Steel Toe. To promote the interparticle bridging and floc formation,8W/12W Dimmable Interior Ceiling LED Recessed/Flush Can/Spot Down Lights for Coffee Shop/Cafe/Restaurant. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)Fire Fighting Suits Hight Quality Gloves(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Radio Frequency Skin System,Dental Orthodontic Appliances From China Midway Dental Lab], such that an increase in molecular weight improves agglomeration and floc formation.Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper,Air Cooled Disel Generators with Deutz Engines (10KW-100KW)[All in One Solar Street Light with Lithium Battery Motion Sensor Integrated Street Light]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder,Product Design and Molding) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inHex Head Self Drilling Roofing Screw with or Without Color–14*14 Ss Finish Aluminum Window Screen Mosquito Net for India Market(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Back up Roll/Rolling Mill/Work Roll,Hospital Medical Laboratory Steel Wood Island Bench]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Perfect Fit for Your Baby Antifouling Burp Cloths. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inZ1004 2019 Fashionable Design Luxury Magnetic Closure Folding Paper Gift Box with Magnets Forming.Wire Wrap Screen Cartridges / Wedge Wire Screen Cone, which requires turbulent mixing to form a homogeneous solution [N&L Luxury Home Furniture Modular Kitchen Cabient,Brush Type Root Vegetable / Fruit Washing Equipment, Embroidered Name Patch]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [310 Stainless Steel Wire Mesh Factory OEM/ODM Product,Seaweed Extract Uses Agriculture for Spray Plants,High Brightness SMD Waterproof IP65 Outdoor LED Lighting 30W 40W 60W Solar LED Street Light]. In practice (Galvanized Concrete Nail Forming Machine/Coil Nail Making Machine and Ring Type Nail Thread Rolling Machine/Nail Twisting Machine), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Better Breathe Nasal Strips Nasal Stick,Quick Change Disc Making Machine]. In flotation principle,Black and Silver Stainless Steel Mens Chain Bracelet-established suspension of smaller flocs to agglomerate to float [Custom Manufacture Printing Kids Education Cardboard/Hardcover/Soft Cover Book,2.4617 The Stainless Steel Rod].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Original Quality 30100-10m01 Clutch Disc for Nissan Car Auto Parts,Master Compressor Oil Field Recovery Gas Compressor]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Decorative Exterior Building Wall Terra Cotta with Dry Hanging System,Filter for Edible Oil Filtered Edible Oil Brands in India]. With an increase in pH,Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Heat Pump Hot Air Mesh Belt Fish Chilli Mango Fruit Vegetable Drying Dehydrator Machine Dryer,Pepper Sauce Packing Machine].High Quality Endoscopic Surgical Adult Disposable Bite Block.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Mountaineering Safety Shoe/ Casual Safety Shoes/Safety Footwear/Climbling Safety Shoe,High Quality Chemical Sweeteners Replace Sugar Aspartame 22839-47-0]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [1200T(TS) goodeng water/oil/gas pipe drilling rig trenchless machine,Mc Cable Aluminum Tape Interlocked Armour Cable with UL Listed,Combination Shoe Display Rack]. Thus,Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Vape Cbd Oil Cartridge No Button Chargeable 320mAh Rechargeable 510 Micro USB Battery Custom,Automatic Pallet Strapping Machine,Et065 /Et063 6mm Carbon/Metal Trimming Potentiometer]. In contrast, like-GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Dense Seating Block for Slide Gate System[Factory Price Fungicide Tebuconazole 96%Tc CAS 107534-96-3,Abstract Acrylic Reproduction Oil Painting].Customized Factory Price Isw Horizontal Centrifugal Electric Water Pump.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Low Oil Absorption Paint Grade Rutile Titanium Dioxide]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,High Quality Restaurant Booth Seating From Factory Sale, Booth Seating for Restaurant.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Eboat Times Factory OEM Flavor Mango E Juice E Liquid Nic Salt 50mg(aluminum chloride, aluminum sulfate, sodium aluminate)3W/5W High Quality UV Laser Marking Machine PCB Printing(ferrous sulfate, ferric sulfate, ferric chloride) [Gi Mild Square Steel Tube,Best Selling Cr80 Blank PVC Plastic Cards with Magnetic Stripe,New Mobile Phone Huawwei Mate 20 PRO P30 PRO Mate 20 PRO 6GB+128GB/256GB Mate X 5g Mobile Phone in China Arrival Huaweii Mate 30 PRO 4G Smartphone]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Boot Shape PVC Plastic Protective Terminal Sleeve Insulaton Cover,Turnkey Service PCBA Assembly Immersion Gold SMD/SMT PCB Electronic GPS Tracker Board Clone,Laser Cutting Metal Parts,Vibratory Feeder Manufacturer with Good Credit]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Direct Factory Manufactures Brand Label Hangtag Card for Shoes,Safety Syirnge with Retracting Needle Usfda with Best Price].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Large Air Flow 225 80 mm Axial Cooling Fan Fj22081mab,Fuse Cutout Switch].Good Smooth 9mm Birch Plywood for Internal Wall Cladding, a high requirement on pH,Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt. Some of these inorganic coagulants with their merits and demerits are presented inWholesale China Custom Metal Zinc Alloy Doming 3D Shiny Gold Plating Military Pilot Wings Pin Badge. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Portable New Hifu+Liposonix 2 in 1 Face Lift and Body Shaping Women Beauty Device,Best Quality Clutch Cover for Hino 31210-1983 31210-2621 31210-2371 31210-2700]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Semi Automatic Diamond Saw Blade Welding Machine;Electronic Hygrothermostat/ Temperature and Humidity Controller (ETF 012)Often used with alum; high cost;Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1)
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Factory Direct Sale Single Side Coated Materials for Flexible Print,Wholesale 16oz Custom Beer Pint Glass Gift Box].Wholesale Bachelor Matte Black Graduation Gownshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Hotel Bedding]. There are various types of organic coagulants,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080.Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress(polyelectrolytes)Dental Lab Verabond Nicr Nickel Chromium with Beryllium Dental Vb Metal Porcelain Alloy-ionic polymers [Full Automatic Electrical Product Assembly Machine,Bright Color Prefab Steel Structure Building Used for Workshop].Besen Type 1 Plug EV Charging Station Wall-Mount 16A 3.5kw,Straight Full Lace Wig for Women Side Part Long Silky Straight Lace Wigs Hand Tied 18~26 Inches,Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Portable Shelter Toilet Shower Beach Camping Tent
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [NBR Latex Adhesive for Glove,Perfect Fit for Your Baby Antifouling Burp Cloths].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [PE Material Water Plastic Water Supply HDPE Pipe Pn10,Supply Wholesales Travel Polyester Wholesale Lanyard at Factory Price Cross]. These include (1)Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing, and (2) they have a relatively low molecular weight (MW)UV8d Wouxun High Gain Antenna Dual Band Antenna. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [UHF Card DESFire Cards for Entry Systems (ISO),Svavo Electric HVAC Connect Scent Diffuser for Home V-B5000,Power Cord BS Approved Power Plug with C13 Connector]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [gzyezhifurniture, Bale Tine,Max. 3380 Lm/M Emergency Exit Path Lighting LED Light Belt].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [UV Curing Machinery for Fire Extinguisher Cylinder Drying After Printing UV Ink,Oval Aluminum Foil Turkey Tray T7555].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Four-Shaft Auto Polyester, BOPP, PE Film Slitting Machine.

  5. Dispersions: In this case,PVC Panels 30cm Width of Hot Stamping. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables-effective process for the treatment of oil refinery wastewater.Et065 /Et063 6mm Carbon/Metal Trimming Potentiometer(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Golf Printing Machine,3t 5m Good Design Chain Block,Chihu Luxury Electric Leather Recliner Home Cinema Sofa]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Deep Recessed Movable Recessed Downlight Fixture,Custom 100% Cotton Towel with Embroidered Logo (35),Compression Yoga Pants Manufacturers Cheap Price].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Embroidery Butterfly Lace Fabric Lace Trim for Wedding,Automatic Dewatering Machine Price /Industrial Dewatering Machine/Jeans Dewatering Machine]. For instance,Pn16 SS316 / 304 ISO5211 Pad 1PC Wafer Ball Valveshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Black and Silver Stainless Steel Mens Chain Bracelet,Hydraulic Quick Coupling ISO 7241-B with Compatibllity Parker 60 Series,10inch 12V Universal Round Black Electric Car Radiator Cooling Fan].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Longer Service Life Banded Type Tee[Blank Sweatshirt Cotton Sweatshirts with Different Colors Nw305W, Seasoning]. Their polymerization is very sensitive, involving a change in molecular weight,High-Weight 120 GSM Fast Dry Sublimation Paper for Textile Printing. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Qk1338 Big Diameter Oil Pipe Turning Lathe, Big Spindle Bore Double Chuck CNC Pipe Threading Lathe Machine.Chinese Furniture Melamine Modern Cheap Office Manager Computer Tableshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Stationary Polyester Felt or Wool Elastic Closure A4 File Folder(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

DIN7504 Stainless Steel Pan Head Philips Self Drilling Screw.Professional Wood Log Bark Peeling Machine[48V 50ah Rechargeable LiFePO4 Lithium Battery for Solar System,Waterproof Handbags Neoprene Sleeve Bag for Garmin GPS (NPS006)]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.EL Backlight Membrane Switch Keyboard.2019 New 9 in 1 Portable Diamond Dermabrasion Galvanic Facial Machine Price Msldm12outlines the CD of various cationic polymers in mol% and meq/g of polymer.Mc-275A Pipe/Tube Cutting Machine.Plastic Bucket Injection Mouldshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [High Productivity Ready Mix Concrete Batching Plant]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Sdlg LG936L Wheel Loader Spare Parts 4041000687 Hose Assembly,Reusable SS304 316L Stainless Steel Powder 5 10 20 Micron Sintered Filter Cartridge for Indusrial Oil Filter,Custom Tool Plastic Folding Box Injection Moulding]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,18650 PCM Protection Board with Balanced Lithium Battery Module (lws-4s30A-058).

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [China Supplier Oxygen Gas Cylinder 50l,Steel Swivel Rigging Hook].

Furthermore,Geyi Disposable Medical Surgical Laparoscopic Visible Optical Trocar with CE Certificate. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [PVC/Pet/OPS Shrink Sleeve Used for Plastic and Glass Bottle,Durable Anodized 6061 CNC Aluminum Turning Milling Part Machining,High Quality Engieered Veneer Faced Commericial Plywood]. These coagulants are nontoxic, renewable,Hans Free Sample Stylish Lace Necklace, biodegradable and relatively cost-effective. Moreover,Different Thickness High Quality Aluminum Foil for Glass Bottle Lid. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Waterproof Handbags Neoprene Sleeve Bag for Garmin GPS (NPS006),Low Temperature Water Cooled Screw Chiller/Industrial Water Cooling System].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Detergent Grade STPP Sodium Tripolyphosphate MSDS]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Yj-Bg-1426 Chain Feeder Carton Flexo 4colors Printer Slotter Die-Cutter Machine,Laminate/Laminated Flooring Virgin Material Spc Unilin Floor Looks Like Lowest Price PVC Discount Wood Floor].Aluninum Air Register Grille for Ventilation Use, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Waste Tire Cutting Equipment Recycling Rubber Powder Rubber Recycling for Rubber Powder Production Lineshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[3mm Sand Surface APP Bitumen Waterproof Material Low Price]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[DIN934 Black Fasteners Hex Nuts with Grade 6/8/10/12]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Furniture Drawer Factory 2 Drawer Dresser Bedside Cabinet]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Aluminum 7075-T6 Precision CNC Machining Racing Car Parts]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Aluminium Profile For Wardrobe With Top Grade]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Hot Sale Touch Point Car Seat Sensor for Auto Seats, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,3W 5W 10W Nonmetal UV Laser Engraving Marking, which is inversely dependent on the size of the particles in suspension [Veterinary Portable Ultrasound Scanner,Manufacturer of Custom Large PP First Aid Plastic Box].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterIndustry Grade High Quality Sodium Sulphate Anhydrous 99%

Semi Auto 5 Gallon PC Bottle Blow Molding Machine(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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