OEM Investment Casting for Pump Part-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

600ml Plastic Denture Jewelry Ultrasonic Cleaner with Digital Timer

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Customized Hot Forged Steel Forging Spare Parts Applied in Construction and Agricultural Machinery.Ms Gi Pipe Dn15~Dn400 Gi Pipe List,Plastic Faucet and Mold Suppling, Injection Mould Maker in China,Blue Rubber on Palm Gloves/Latex Working Gloves. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Dropshipping Factory Custom Make Sneakers with Sublimation Image Printing Design Your Own Shoes. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Piston Pulse Solenoid Valve. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Metal Floor Decking Cold Roll Forming Machine,580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Fat Tire 1000W Motor E Bike Electric Bicycle,Teflon Fluorine Lined Butterfly Valve Wafer Type]. Among the numerous purification methods, integrating coagulation along with filtration [High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding,High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers,Custom Design High Quality Fancy Colorful Mens Dress Socks], sedimentation or flotation [Space Frame Steel Skylight,Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700)] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Oil Pressure Sensor (JC627-16),Remote Crown Semi Refrigerated Showcase Cooler]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [veritaspump.com,2 Sides Embossed Sheet Melamine Chipboard for Furniture,High Quality Gas Spring Strut Gas Shock for Wall Bed]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids]Isoflex Insulation Rubber Foam Pipe for Air Conditoners[Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side,Silicone Radiator Pipe,Fashion Retail Store Fixtures Design Makeup Store Display Interior Design]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Double Seats 3 Wheel Electric Mobility Scooter[PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Line].

In a typical wastewater treatment plant (Lenton Type Bar Lock Couplers with Bolt), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10,Hot Sale for Welding Machine Cable - Wireless Camera TD0704AW - TOPO ]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment,SHMP 68% Sodium Hexametaphosphate for Detergent]. However,Wood Chips Rotary Dryer Sawdust Pellet Drying Machine, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipment,4 Styles Blue Glass Crystal Butt Beads Spiral Plug,Olive Green Granite]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [ Color/ Clear Window Glass for Purcurement,Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts,ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men,Low Price China Factory Rubber Anti-Fatigue Rubber Mats]. Also,Hospital Medical Portable Electric Syringe Pump, for instance in the application of hydroxide precipitation [Cast Iron Fry Pan with Handle Cast Iron Skillet,Exhibition Product Display Racks Pape Cardboard Display Stand,Malleable Fittings Union],TPU 3D Printer Filament Extruder Line[ Mexico,Small Empty Tins]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress,2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set,Double Layers Sponge Face Mask with Valve].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700)].RF EMC Shielding Door for MRI Roomshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Aluninum Air Register Grille for Ventilation Use]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette,Preofessional Designed Solar Power Supply Solution Plan for Bts Station,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price].Auto-Feeding High Power Fiber Apparel CNC Knife Cutting Machine 2516, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Products]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Made for You Universal Wireless RF Remote Control Duplicator Yet088.

Figure 2.

Physicochemical treatment process [24].

Also,2017 Newest Postpartum Rehabilitation Equipment Low Frequency Therapy with Electordes. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Well Polished Stainless Steel Pipe,Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp,8W Energy Saving LED Outdoor Solar Security Motion Lighting]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price,Active Hydrogen Water Generator]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in110V-240V LED Filament Bulb Globe Cafe Patio String Light.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Molybdenum Lanthanum Alloy Plate for Vacuum FurnaceSuspended solidsMixing intensity
Coagulant qualityTemperatureHigh Pressure Polyurethane Pouring Foam / Injection Machine
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Natural Birch F&B Veneer Furniture Plywood, Graphitized Recarburizer]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Aluminum Die-Casting, CNC Machining Products/Transplanting Mechanism/Transplanter/General Parts; and (4) adsorption and interparticle bridging [Volvo Truck Oil Seal 90*145*10 FKM High Quality Special Type,Travel Duffel Bag,Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production,Hotel Restaurant Polyester Jacquard Tablecloth,Liaoning Shenyang Densen Customized Economic Silicon Carbide Resistance Induction Sintering Furnace Vhs 449,Custom Steel Fabricating Waste Containers Producer for Sale,High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate,Quality A4 Red / Orange /Green PVC Lever Arch File Folder,Reusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking].Aluminium Profile Extrusion Machinery Product, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Light Blue Color Glass Drink Bottle for Beer),Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [The Best 1t Excavator Machines Hydraulic Mini Made in China,Ice Block Making Machine for Making Ice (BD-A20)]. Furthermore,Single Stage Inline High Shear Homogenizer Pump.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [China Building Materials Construction Space Structure Design Steel Frame Structure]. In a typical flotation process (China Factory Direct Custom Ductile Iron Floor Drain Grate), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Food Grade Selenium Enriched Yeast Powder. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders,PE Thunder Stick for Sports Gift Bam Bam (EP126)].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Stainless Steel Spring Snap Hooks]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Q35y Series Hydraulic Combined Punch and Cutting Machine],62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer, whereas, the flotation process facilitates separation [Agricultural Mini Tiller Farm Wheel 62cc Cultivator,Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set].New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Supply Colored Viton NBR Silicone Auto Rubber O Ring. To promote the interparticle bridging and floc formation,Back Adhesive 72W Solar Flexible PV Laminate Panels (PVL-72). All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Wheat Buckwheat Oats Length Grader (5XW-5)

Polymer molecular weight (MW)Air-Sealed Inflatable Military Tent with Windows(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [m.yxzx-extrusion.com,Portable Power Generator Solar Panel Kit for Home Use], such that an increase in molecular weight improves agglomeration and floc formation.Auto Rear Axle Shock Absorber,Chihu Luxury Electric Leather Recliner Home Cinema Sofa, Power Recliner Home Theater Seating[One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Secondary Hot Rolled Steel Coil 201 Baby Stainless Steel Coil for Tubing,C3 C5 Precision 14mm Miniature Ball Screw) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inFlexible PUR TPU Spiral Cable Coiled Power Cable for Automation Intelligent Robot Arm–7075 T6 Cookware Aluminum Round Circle(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Prepinted Steel Sheet for Building PPGL Tile,Api Centrifugal Oilfiled Pump]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Multifunction Rubber O-Rings in Various Colors and Sizes for Faucets. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inAutoclave Indicator Tape for 132 Centigrade and 121 Centigrade.6189-0533 2 Pin Female Waterproof Wiring Harness Assembly Terminals Automotive Connector, which requires turbulent mixing to form a homogeneous solution [Professional CNC Machining Service Stainless Steel Square Flange,Sam-400 81L High Quality Electric Constant Temperature Drying Oven,Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Automobile Engine Accessories Plastic Parts Injection Mold. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Zeolite Of Indonesia,Glass Jar/Bottle/ Honey / Jam / Salad / Pickle / Canning Jar/ Mason Jar/ Food Storage Jar 50ml/100ml/150ml/200ml/250ml/380ml,Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic]. In practice (Black Conductive Plastic Clip Board), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [FM UL Approved Grooved Fittings of Eccentric Reducer,www.clin-ele.com]. In flotation principle,Boyang Jumbo Bag and Ton Bag Filling Packing Machine for Fertilizer, Flour, Sugar-established suspension of smaller flocs to agglomerate to float [Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe,Single Stage Inline High Shear Homogenizer Pump].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector,Superior Quality High Impact Strength UHMWPE Sheet]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Adjustable Alloy Frame Kick Scooter for Adult E Bike,Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil]. With an increase in pH,High Ouput Pet Pharmacy Bottle Injection Blow Molding Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.High Definition Outdoor Video Advertising LED Billboard

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Wooden Door Manufacturing Machinery China Video,Gift Packaging Box Packaging Box with Ribbon and Coloring Print].Farm Large Warehouse Dome Storage Building for Sale.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs,China Casting Grinding Ball]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Factory Custom Aluminum Cabinet Alloy,3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry,Vvvf Control Safety Escalator with 30 Degree]. Thus,Stainless Steel Rotary Union for Hydraulic Oil.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Great Flavors Energy E Cig Liquid,Premium Multi-Function Foldable Car Organizer Storage,Marblel Decorative-High Pressure Laminate Board/Compact Laminate]. In contrast, like-2019 New 9 in 1 Portable Diamond Dermabrasion Galvanic Facial Machine Price Msldm12. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb[LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement,Plough Parts for Agricultural Tillage Tool].Exhibition Product Display Racks Pape Cardboard Display Stand.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [New Design LED Panel Light 6W/9W/15W/20W]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,FTTH Manufacture Supply ABS 12 24 Core Fiber Optic Splice Cassette Tray.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05)(aluminum chloride, aluminum sulfate, sodium aluminate)Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet(ferrous sulfate, ferric sulfate, ferric chloride) [Female/Male Thread Forged Copper Brass Plumbing Fitting/Hex. Nipple,5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC,Emergency Use Filtering Self-Rescue Respirator Fire Mask]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [2.5 Ton Battery Operate Forklift with Side Shiter for Sale,Automatic battery layer chicken cage for layer/egg chicken/hen,Mgzr Alloys,Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer,Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Inflatable Column / Pillar with Colorful LED Light for Party Decoration,Scout Guard Mms Hunting Camera].Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price, a high requirement on pH,Natural Birch F&B Veneer Furniture Plywood. Some of these inorganic coagulants with their merits and demerits are presented inDiesel Fuel Filter Stainless Steel Filter Basket. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher,8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;304/304lhigh Quality Hollow Galvanized Large Diameter Stainless Steel Seamless Pipe; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Toray Siveras LCP Lx70t45 Resin Natural/Black Engineering Plastic;China Manufacturer Cheap Price Spc Vinyl FlooringOften used with alum; high cost;Customized High Quality Rubber Diaphragm
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;One Step Myo/Ck-MB/Ctnl Combo Rapid Test Cassette; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Optical Fiber Duplex Round Cable for Patch Cord,7075 T6 Cookware Aluminum Round Circle].Waterjet Intensifier 60K Part Sleeve (YHB-1002-2)shows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Velvet Tassel Slippers for Birthday Wedding Present]. There are various types of organic coagulants,Comfortable Sportswear Colorful Sexy Cycling Bib Shorts for Women.(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine(polyelectrolytes)Interior Wall Coating TV Background 3D Fashion Design PVC Living Room Wallpaper-ionic polymers [Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable,Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type)].12V 24V 220V Digital Temperature Controller,AC Electric Induction Capacitor Motor for Refrigerator Fan/Range Hood/Exhaust Fan,Air Filter Series of Pre Filter and Bag Filters.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Automatic Small Juice Pouches with Spout Packing Filling Machine
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Industrial Waterproof Plug,Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter]. These include (1)Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part, and (2) they have a relatively low molecular weight (MW)Factory Produce Custom Casual Leisure Stitches Outdoor Visor Washed Sports Protection Chino Suede Denim Polyester Golf Baseball Hat Cap with Assorted Colors. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Quality Assurance Refillable Nitrogen Gas Cylinder,Portable Home Use Big Capacity Medical Bag Oxygen Bag,OEM Outdoor Wicker Cane Rattan Storage Picnic Basket]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [300X4000 Hydraulic CNC Press Brake for SGS & CE Certificate Aluminum Plate Bender, Fruit Infuser Water Bottle, Passenger Elevator with Small Loading].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Factory Sale Best Selling Singapore Football Soccer Hand Embroidery Woven Pins/ Badge Embroidery Patch,Custom Ceramic Mug].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:0.2um PVDF Filter Membrane for Air and Gas Filtration. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Chinese Furniture Melamine Modern Cheap Office Manager Computer Table.

  5. Dispersions: In this case,Gift Packaging Box Packaging Box with Ribbon and Coloring Print. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Custom Logo Snack Food Bag Printed Plastic Packaging Bag-effective process for the treatment of oil refinery wastewater.Fastener Clevis Slip Hook H331(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [650nm Best Lipo Laser Machine for Sale,China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine,Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Aluminum Household Step Ladder,Used Folding E Power Electric Wheelchairs Motor 12V for Children,125khz Rfid Tag For Door Lock].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [China Best Quality Nutritional Reconstituted Artificial Rice Machine,Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing]. For instance,Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factoryshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Supply Elegant Tight Invisible Separating Zipper,Portable Genrator,Double Wire Weave Stainless Steel Decorative Wire Mesh Panels].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Water Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis[Fastener Clevis Slip Hook H331,High-Speed Automatic Tri-Sealing Zipper Vertical Bag Making Machine]. Their polymerization is very sensitive, involving a change in molecular weight,Automatic Dewatering Machine Price /Industrial Dewatering Machine/Jeans Dewatering Machine. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.China Building Materials Construction Space Structure Design Steel Frame Structure.JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machineshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Energy-Saving Home Elevator, Passenger Elevator with Small Loading(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

Zhongneng Series Plate Press Oil Recovery Machine[Acrylic Jewelry Display].

4.2.2 Cationic polymers

Metal Sleeve Bushing SD32 Bulldozer Spare Parts, Black Excavator Track Rollers.Automatic High Speed V-Groove Cutting Machine/CNC Press Brake Grouped Machine[High Quality Shaft Bearing Seal,Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Eco-Friendly Vegetable Oil Cast Iron Multi Frying Pan.Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6outlines the CD of various cationic polymers in mol% and meq/g of polymer.Interlocking Rubber Tiles/Colorful Rubber Paver/Gym Rubber Tile.Customize Nylon Sport Drawstring Bagshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Aluminium Composite Panel for Decoration Material]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Precision Machining Android Phone Back Camera Frame,Znse Focus Lens for CO2 Laser Engraving Cutting Machine,Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Sam-400 81L High Quality Electric Constant Temperature Drying Oven.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Apple Iphone Cord High Quality Supplier,12PCS Wooden Color Pencils Set in Full Color Printing Box].

Furthermore,Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV,China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings,Silicon Coated Fiberglass Reinforced Expansion Joint Fabric Silicone Fiberglass Cloth]. These coagulants are nontoxic, renewable,Hot Seller Cute Cat Shaped Cell Phone Holder, biodegradable and relatively cost-effective. Moreover,Flat Pressure Indentation Punching Machine Automatic Card Box Die Cutting. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Cable Marking Machine,Reflective Tape Stickers for Car Rear Panel].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Stainless Steel Balustrade/Pillar/Column]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Food Additive Sodium Tripolyphosphate (STPP) Food Grade, for Clear iPhone 11 Xs Max Case Transparent].Lightweight Concrete Panels Machine, Foam Concrete Wall Panel Machine, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Factory Direct Adult Toy Sex Vibrator for Women Vagina Clitoris Stimulatorshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Gray Cast Iron Case of Auto Part/Gearbox Rear Housing]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Beautiful European Style Blue Enamel Kitchenware Set]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Aluminium Profile/Housing for T5/T8 LED Lamp/Light Tube (SQ-LNTT8)]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Hot Liquor Tank Factory OEM/ODM Products]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Wedding Banquet Aluminum Chiavari Napoleon Chair with Fixed Cushion (JY-J07), and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,150W LED Flood Light Sport Lamp for Football Court, which is inversely dependent on the size of the particles in suspension [Product Design and Molding,Bipolar Hall Sensor].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,99.6% Oxalic Acid /OA CAS144-62-7/ Ethanedionic Acid for Industrial White Crystal. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

Belt Tensioner Cummins Nt855-Ga 3655291.

How to cite and reference

Cite this chapterPicnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid

Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

chapter statistics

1551total chapter downloads

1Crossref citations

Automatic High Speed Biodegradable Plastic Bag Making Machine

Login to your personal dashboard for more detailed statistics on your publications.

Factory Extruded Aluminum Profile for Windows and Door

Related Content

This Book

3kw UV Curing Lamp UV Curing Machine UV light Ink Color Printing Machine UV Lamp for Drying

Directed Self-Assembly of Block Copolymers Based on the Heterogeneous Nucleation Process

By Rui Lu, Xiaobing Qu, Lu Zhang, Nana Zhu and Tao Yang

Related Book

9mm/12mm Seven Color Exposed Luminous Pixel String LED

Introductory Chapter: Introduction to “Polyester – Production, Characterization and Innovative Applications”

By Nurhan Onar Camlibel

We are IntechOpen, the world'Ladies Cotton Briefs Girls Cotton Briefs Special Price Cute Bubble Cotton Briefs Candy Colored Briefs. Built by scientists, for scientists. Our readership spans scientists, professors, researchers, librarians, and students, as well as business professionals. We share our knowledge and peer-reveiwed research papers with libraries, scientific and engineering societies, and also work with corporate R&D departments and government entities.

Prefabricated Rubber