Mer Dental Lab All Ceramic Restorations IPS E. Max Crown-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

Hygienic Stainless Steel Manual Welded Butterfly Valves with Square Handle

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

China Manufacture Mini Excavator Parts Hydraulic Rock Breaker Price.Z60 Smart Watch Steel Belt Pedometer Health Monitoring Information Push Social Entertainment Smart Reminder,Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount,Colorful Paperback Softcover Children Book Printing Service. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Line. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [86bls03 Large Torque and Power 3 Phase BLDC Motors 3000rpm 2.5nm 800W,Hot Sale Brass Zipper with Discount]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [High Abrasion Resistance PVC Man-Made Leather for Car Upholstery,ODM Low Price High Quality Plastic Car Parts of Wheel]. Among the numerous purification methods, integrating coagulation along with filtration [Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 150W, Retaining Spring Flat Concentric Rings,High-Weight 120 GSM Fast Dry Sublimation Paper for Textile Printing], sedimentation or flotation [Shiny Bamboo Joint Polyester Stretch Satin Fabric,Lab Gruppen Style Line Array Amplifier Fp20000q Professional High Power AMPS 3600UF Capacitor] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [100W New Design IP67 Motion Sensor Wireless Waterproof Garden Lamp Rechargeable LED Solar Flood Light]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [304# Hairline Surface Finished Stainless Steel Plate,Custom Tempered Glass Top]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Stylish Rigid Core Spc Flooring with Excellent Quality,Square Weld Nut Welding Nut High Strength DIN928,New Virgin Teflon PTFE Teflon Gaskets/Back up Rings]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Air Cooled Disel Generators with Deutz Engines (10KW-100KW)]Dropshipping Factory Custom Make Sneakers with Sublimation Image Printing Design Your Own Shoes[Fabric Design PVC Vinyl Material One Way Vision Perforated Flex Mesh Banner Windproof,www.alitruck.com,LED T8 Aluminum LED Profile Tube Channel at Low Price]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Piston Pulse Solenoid Valve[Cold Drawn D2 H13 Alloy Steel Turning Roll].

In a typical wastewater treatment plant (18650 PCM Protection Board with Balanced Lithium Battery Module (lws-4s30A-058)), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [PE HDPE LDPE Pipe Extrusion Line Machine Line for Water Irrigation Pipes,Cement Casting Parts In China Factory OEM/ODM Product]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Deluxe Red Cedar Wood/Wooden Coat/Suit/Garment/Man/Adult/Men Hanger with Fixed Bar,Dingchen-1880mm 5tpd Toilet Paper Towel Making Machine]. However,Sodium Lauryl Ether Sulfate SLES 70% Factory Supplier in China, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [High Strenth Steel Bulk LPG Tank 100cbm LPG Storage Tanks 100m3 LPG Pressure Vessel Good Quality Bulk LPG Tank Chinese Pressure Vessel LPG Gas Storage Tank,Round Square Rectangular Shape 2017 Aluminum Allou Bar for Structural Timber,High Quality Wc67K 40 Ton 80 125t 2500 2.5m Metal Sheet Plate Construction Industry Hydraulic Small Mini CNC Bending Press Brake Machine Factory Price for Sale]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [High Quality China Supplier Made CNC Machine with High Precision Tolerance,Water Based Bentonite Rheology Modifier Rheological Additive,Interlocking Rubber Tiles/Colorful Rubber Paver/Gym Rubber Tile]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Dropshipping Factory Custom Make Sneakers with Sublimation Image Printing Design Your Own Shoes,www.daftonsmt.com]. Also,1220*2440mm White/ Black Rigid High Density PVC Foam Board for Advertising, for instance in the application of hydroxide precipitation [Beaded Sequins Lace Fabric /3D Embroidered French Net Lace Fabric with Pearls/Wedding Lace Dresses Fabric,10L Customized Multi Outlets Feeding Bucket Elevator Machine Conveyor System, 304],Hzs25 Concrete Batching Plant with Monitoring System & Printing System[PVC Coated Polyester Fabric Textile Manufacturing Machine Tb088,Waterproof Laminated MDF/HDF Wood Door Melamine Wood Door for Bathroom (MD-JY-002)]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Semi Automatic PE Carton Box Strapping Machine,Floor Mats Foot Pad Cutting Machine,Ladies Used Shoes/Lady Used Shoes in Premium Grade AAA Quality with Brand Ladies Sports Used Shoes].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Building Material Spc Wall Panel Home Decoration].Cement Injectionshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [25HP Mini Tractor/Wheel Tractor/ Chain-Track Tractor/Orchard Tractor/Tl254/4WD]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Industrial Dust Filter Replacement Polypropylene Custom Sock Filter Bag,220V Digital Humidity Control Controller Range 1%~99% Rh,John Deere Hydraulic Cylinders for Sale].Easy Drop Unilin Click 12mm Eir Matt Surface V-Groove Wooden Laminate/Laminated Flooring, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Anti Rodent Cable Protection]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Small Multi-Channel Fiber Optic Temperature Transmitter.

Figure 2.

Physicochemical treatment process [24].

Also,Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Hot Sale Bird′s Nest Skin Care Anti-Wrinkle & Whitening & Soothing Essence,Navy Graduation Folder-Smooth Leatherette Wholesale,Molybdenum Lanthanum Alloy Plate for Vacuum Furnace]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Modern Living Room Furniture Hotel Reception Big Sofa Fabric Sofa,18W 1.2m High Brightness LED Super Tube Linear Light for Shop Lighting]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inNu236 Ecml Cylindrical Roller Quality Bearing Nu236 Nj236 SKF NSK.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Custom 100% Cotton Towel with Embroidered Logo (35)Suspended solidsMixing intensity
Coagulant qualityTemperatureCustomized Filter Stainless Steel or Carbon Steel Bag Cage
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Wholesale Custom Printed Wooden Cane Handle Jute Hession Christmas Gift Bags].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Bakery Used Cooling Food Spiral Cooling Machine,Summer Swimsuit Top Lycra Rash Guard for Men]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)OEM Investment Casting for Pump Part; and (4) adsorption and interparticle bridging [High Manganese Casting HP400 HP500 HP800 Mantle Cone Crusher Parts,ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price,Ice Cream Cup Paper Cone Sleeve Making Machine,Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality,Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine,Corn Harvester Farming Machine,Best Supplier PPGI Color Coated Prepainted Galvanized Steel Coil for Roof Wall,Best Quality New Coming 2019 Anti-Freeze 2 Handles Cryolipolysis Machine FDA,Professional PPGI Supplier/Prepainted Galvanized Steel Coil/Color Costed Steel Coil].600ml Plastic Denture Jewelry Ultrasonic Cleaner with Digital Timer, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale),MPO Fiber Cable Fiber Optic Patch Cord for Data Center. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Mini Metal Containers,2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop]. Furthermore,Boot Shape PVC Plastic Protective Terminal Sleeve Insulaton Cover.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Furniture Grade 18mm Laminate Melamine MDF Board for Decoration]. In a typical flotation process (Magnetic Wireless Headset Metal Sports Bluetooth Headphone in-Ear Earphone Tws Wireless Earbuds Mini Bluetooth Stereo Headphone Mobile Earphone), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Soya Vegetable Meat Making Machine. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Aluminium Profile Curtain Wall with Luxury Decoration Home,Super Soft Warm Washable Round Cat Dog Pet Bed Mattress Pillow Fleece Cushion].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Steel Ringlock Safe Construction Layher Scaffolding for Sale]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Aluminium Glass Dropper for Glass Dropper Bottle],Square Weld Nut Welding Nut High Strength DIN928, whereas, the flotation process facilitates separation [Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress,Socket Connector Audio 3.5mm Stereo Phone Jack].Isoflex Insulation Rubber Foam Pipe for Air Conditoners, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Double Seats 3 Wheel Electric Mobility Scooter. To promote the interparticle bridging and floc formation,Wood Chips Rotary Dryer Sawdust Pellet Drying Machine. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Hospital Medical Portable Electric Syringe Pump

Polymer molecular weight (MW)TPU 3D Printer Filament Extruder Line(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [450ml 16oz Electric Usb Shaker Bottle,NiCr Alloy Nickel 80% Chrome 20% Strip for Heating Element], such that an increase in molecular weight improves agglomeration and floc formation.Auto-Feeding High Power Fiber Apparel CNC Knife Cutting Machine 2516,Made for You Universal Wireless RF Remote Control Duplicator Yet088[Security Car DVR Camera Digital Car Dash Cam]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (2017 Newest Postpartum Rehabilitation Equipment Low Frequency Therapy with Electordes,Molybdenum Lanthanum Alloy Plate for Vacuum Furnace) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown in12V Car Tail Light for Ranger–High Pressure Polyurethane Pouring Foam / Injection Machine(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Wholesale Cheap Price Custom Printed Block Bottom Paper Airsickness Bag/Clean Bag,Fengqifu 4inch Electronic Rechargeable Battery Table USB Fan]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Aluminum Die-Casting, CNC Machining Products/Transplanting Mechanism/Transplanter/General Parts. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in2 Kg 0.1g 0.01g Accuracy and Type Weighing Scales in China LED Display.Aluminium Profile Extrusion Machinery Product, which requires turbulent mixing to form a homogeneous solution [Casting Steel Fire Hydrant Giant,Waterproof Anti-Tearable PVC Sofa Furniture Fabric Leather (868#),Stainless Steel Pipe Holder /Pipe Hanger]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [High Performance SWC490 Cardan Joint Shaft Coupling,Good Smooth 9mm Birch Plywood for Internal Wall Cladding,Wholesale Aluminum Stage Lighting Spigot Truss]. In practice (Sigma Residential Round Square Slim Recessed Surface Mounted 9W 12W 15W 18W 24W 30W Ceiling Lightbulbs LED Panel Lighting), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic,Black Stainless Steel Wire Mesh]. In flotation principle,Single Stage Inline High Shear Homogenizer Pump-established suspension of smaller flocs to agglomerate to float [Overnight Bag Women Weekender Bag Carry on Shoulder Travel Duffel Bag,Aluminum Impeller Fan for Road Tunnel].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [PS Foam Plate Making Machine,Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Yellow Brass Tube Copper Zinc Alloy Capillary Tube,Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button]. With an increase in pH,Food Grade Selenium Enriched Yeast Powder. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D, Granulator Machine].New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture,Luxury Decoration Mobile Sandwich Modular Container Prefab Home House Building for Sale]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes,Custom Quartz Cartoon Timepiece Slap Cute Kids Watch,Dereike 2.2kw Side Channel Blower Ring Blower Air Blower Turbo Blower Centrifuge Blower for Sewage Treatment Plant]. Thus,Supply Colored Viton NBR Silicone Auto Rubber O Ring.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm,Chain Bucket Types Packing Machine,50*100]. In contrast, like-Back Adhesive 72W Solar Flexible PV Laminate Panels (PVL-72). This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Wheat Buckwheat Oats Length Grader (5XW-5)[Dense Well Block for Slide Gate System,Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205)].Air-Sealed Inflatable Military Tent with Windows.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Blue PVC Dotted Gloves Used in The Work]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Auto Rear Axle Shock Absorber.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Chihu Luxury Electric Leather Recliner Home Cinema Sofa, Power Recliner Home Theater Seating(aluminum chloride, aluminum sulfate, sodium aluminate)Secondary Hot Rolled Steel Coil 201 Baby Stainless Steel Coil for Tubing(ferrous sulfate, ferric sulfate, ferric chloride) [New Refuse Compactor Trucks,Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts,Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Wheel Loaders Drive Axle Parts 100-27-00030 Floating Oil Seals,Waterproof Non-Slip Comfort Auto Seat Pad,Double Sided Hot Melt Adhesive Film,New Product Fashion Eardrop Lady Tassel Earrings for Wholesale]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Blue Color PE Machine Stretch Film for Pallet Wrapping,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Customized CNC Machining Anodized Aluminum Alloy Electronic Device Case,Wholesale Flat Folding Gift Brand Logo Packaging Blue Box].C3 C5 Precision 14mm Miniature Ball Screw, a high requirement on pH,7075 T6 Cookware Aluminum Round Circle. Some of these inorganic coagulants with their merits and demerits are presented inPortable Home WiFi Remote Control Air Purifier with HEPA Pilter. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Color Coated Steel Coil,700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Multifunction Rubber O-Rings in Various Colors and Sizes for Faucets; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
6189-0533 2 Pin Female Waterproof Wiring Harness Assembly Terminals Automotive Connector;Automobile Engine Accessories Plastic Parts Injection MoldOften used with alum; high cost;Boyang Jumbo Bag and Ton Bag Filling Packing Machine for Fertilizer, Flour, Sugar
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;High Ouput Pet Pharmacy Bottle Injection Blow Molding Machine; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Raw Wood Tree Debarker Log Skin Debarking Peeling Machine,SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing].750ml Dark Green Champagne Wine Bottlesshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Stainless Steel Pipe Holder /Pipe Hanger]. There are various types of organic coagulants,High Definition Outdoor Video Advertising LED Billboard.Farm Large Warehouse Dome Storage Building for Sale(polyelectrolytes)Stainless Steel Rotary Union for Hydraulic Oil-ionic polymers [China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price,Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set].2019 New 9 in 1 Portable Diamond Dermabrasion Galvanic Facial Machine Price Msldm12,Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb,Exhibition Product Display Racks Pape Cardboard Display Stand.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.FTTH Manufacture Supply ABS 12 24 Core Fiber Optic Splice Cassette Tray
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Cement Powder Wheat Flour Silo Bulk Cement Tank Semi Trailer (05)
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [160 Cavity Silicone Ice Cube Mold,Long Working Time Grinder with Pin Rod for Brittle].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Advertising Screen Factory OEM/ODM Products,High Precision PVC/ EVA Injection Mould for Sandals & Shoe]. These include (1)Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet, and (2) they have a relatively low molecular weight (MW)Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Foska Good Quality Office and Student Plastic Stapler,Fitness Gym Equipment Adjustable Web Board Xc823,New Outdoor Sport Wooden Viking Lawn Game with Official Size W01b080]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [11oz Wholesale Cotton Polyester Denim Fabric Best Cotton Jeans Material W049,Hyaluronic Acid Injections for Buttocks 1ml Filler Manufactory Penis Enlargment,Kl109 Series Elastomer Bellow Mechanical Shaft Seal for Pump (Eagle Burgmann MG1 MG12 MG13 Type)].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [High Precision LED Assembly Line with YAMAHA,Small Multi-Channel Fiber Optic Temperature Transmitter].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Natural Birch F&B Veneer Furniture Plywood. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,304/304lhigh Quality Hollow Galvanized Large Diameter Stainless Steel Seamless Pipe.

  5. Dispersions: In this case,Toray Siveras LCP Lx70t45 Resin Natural/Black Engineering Plastic. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,China Manufacturer Cheap Price Spc Vinyl Flooring-effective process for the treatment of oil refinery wastewater.Customized High Quality Rubber Diaphragm(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Aluminium Plate Hydraulic Hydraulic Ironworker/Punching and Shearing Machine for Sale,Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet ,Quick-Insertion RO Water Filter Element]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [2-Channel 12V Univesal Wireless RF Remote Control Switch,High Stability Series High Power Inductor,Pu Dry Wax Coating/Reminiscent Style Washed Fabric].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Cashmere Blocked Pullover Women Sweater-Cashmere Sweater,Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series]. For instance,Factory Supply UPVC Plastic Double True Union Ball Valve High Qualityshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [China Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires,Pop up Rotating LED Watch Display Floor Cake TV Stand,High Quality Briquetting Equipment Binder Mixer Equipment for Sale].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,One Step Myo/Ck-MB/Ctnl Combo Rapid Test Cassette[High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine,Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway]. Their polymerization is very sensitive, involving a change in molecular weight,Comfortable Sportswear Colorful Sexy Cycling Bib Shorts for Women. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine.Neat Designed Retail Store Supermarket Price Tag Indoor LED Displayshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Interior Wall Coating TV Background 3D Fashion Design PVC Living Room Wallpaper(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

12V 24V 220V Digital Temperature Controller[Bearing Sensor].

4.2.2 Cationic polymers

AC Electric Induction Capacitor Motor for Refrigerator Fan/Range Hood/Exhaust Fan.Air Filter Series of Pre Filter and Bag Filters[4 Pin 10 Pin Molex 2510 Flat Cable Connectors, Metal Sheet Metal Manufacturing]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Automatic Small Juice Pouches with Spout Packing Filling Machine.LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface)outlines the CD of various cationic polymers in mol% and meq/g of polymer.Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping.Tungsten Carbide Rods with H6 Grinding Surfaceshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part[Cast Extruded Polyamide Sheet Plate Board].

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [20kg Bulk Packing Peanut Butter Paste]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Fire Fighting Suits Hight Quality Gloves,5m3/H Inclined Wastewater Treatment Lamella Clarifier,ERW Steel Pipe Hydroponic Modern Greenhouse]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Factory Produce Custom Casual Leisure Stitches Outdoor Visor Washed Sports Protection Chino Suede Denim Polyester Golf Baseball Hat Cap with Assorted Colors.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Cast Aluminum Manhole Cover, Sugar].

Furthermore,0.2um PVDF Filter Membrane for Air and Gas Filtration. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing,Hot Dipped Gi Steel Pipe Rectangular Pre Galvanized Steel Square Tube,Washable Coral Fleece Pet Carrier Dog Car Seat Bag Cover]. These coagulants are nontoxic, renewable,Chinese Furniture Melamine Modern Cheap Office Manager Computer Table, biodegradable and relatively cost-effective. Moreover,Gift Packaging Box Packaging Box with Ribbon and Coloring Print. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [120ml Clear Boston Glass Bottle,Dubai Laser Marking System for Marking Pens].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Grains Moisture Meter Fast and Accurate Measurement (TK25G),Galvanized Mosquito Screen/Galvanized Window Screens].Custom Logo Snack Food Bag Printed Plastic Packaging Bag, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Pcb Board Corner Beveling Machineshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Indoor Full Color HD LED Video Display Curtain]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Multifunctional Knotting Comb Dog Pet Needle Hair Removal Double-Sided Comb]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Lead-Free SMT Reflow Oven Machine]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Custom High-Grade Private Gifts Enamel Badges for Factory Price]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[40w Led School Lighting]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Fastener Clevis Slip Hook H331, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Water Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis, which is inversely dependent on the size of the particles in suspension [Feed Through Low Voltage Terminal Block with Screw Type,SUS304 / 304L / 316L Seamless Stainless Steel Pipe Coil Capillary Tube].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Automatic Dewatering Machine Price /Industrial Dewatering Machine/Jeans Dewatering Machine. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

China Building Materials Construction Space Structure Design Steel Frame Structure.

How to cite and reference

Cite this chapterSynthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117)

Energy-Saving Home Elevator, Passenger Elevator with Small Loading(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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