Factors that affect the chemical purification process [Lk5PP2410u105 Cat5e UTP 24 Port Patch Panel with Bar (Double USE End)].
Abstract
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Keywords
- coagulation
- organic polymers
- water and wastewater
- purification
1. Introduction
The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1,Customized High Quality Rubber Diaphragm]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Cake Making Machine Price,Durable and Fireproof PVC Laminated Gypsum Ceiling Tiles]. Among the numerous purification methods, integrating coagulation along with filtration [35L Electric Car Mini Fridge,Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder,ASME 100000 Litres LPG Bulk Gas Storage Tank 50tons 25tons for Nigeria Market], sedimentation or flotation [m.flsygroup.com,Waterproof Night Vision USA License Plate Frame Rearview Reverse Camera] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [1220*2440mm White/ Black Rigid High Density PVC Foam Board for Advertising]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor,Quality Stackable Metal Church Chairs (JY-G05)]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [T8 Led Energy Saving Tube Light,EMC Approved 3 25W Round IP68 Waterproof LED Truck Head Lights,APP Asphalt Waterproofing Membrane Production Line/Machinery]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display]High Performance Teflon Variseal Spring Seal[Tractor and Implements Disc Plough Harrow Mower Slasher 4 in 1 Front Loader Agricultural Equipments,A4 Size Paper Cutting Machine,Metal Antique Hotel Furniture Dining Chairs (JY-R09)]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Yjv XLPE Insulation Power Aluminum Cable[(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine].
In a typical wastewater treatment plant (Kinds of Colors Agate Pear Pendant Agate Necklace), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [New Technology Commercial Cashew Shelling Machine,m.fessiecookware.com]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Easy Drop Unilin Click 12mm Eir Matt Surface V-Groove Wooden Laminate/Laminated Flooring,OEM Service for Motorcycle Hoist in China]. However,Road Reversing Sign Pole Rubber Components, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Ductile Iron Sand Casting with ISO9001: 2008,Cotton Mesh Shopping Organizer Reusable Produce Bags,4200mbps Whole Home Wifi Mesh]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Chinese Factory Best Quality Aluminum Alloy Profiles LED Strip Light for Decoration,Wholesale Business Gift PU Cover Custom Notebook Printing,Haivol High Voltage 12/20kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicableof cable crosssection 70)]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Flexible Transparent PVC Spiral Steel Wire Reinforced Hose,Teflon Shield Cable]. Also,Eco-Friendly Flat Head Self Tapping Screw, for instance in the application of hydroxide precipitation [Magnet VSD Screw Air Compressorpermanent Magnet Screw Air Compressorhigh Quality Atlas Copco Electric Screw Air Compressor LG Compressor Atlas Copco VSD,Generator Spare Parts Automatic Voltage Regulator AVR GB-100,230V 2 Way 1 Inch Electric Control Stainless Steel Ball Valve Electric Quick Sanitary Ball Valve (T25-S2-C-Q)],10kw Rosen Power on Grid Solar System in China[Diamond Hand Polishing Pads with Resin and Electroplated Type,Ms Angle Iron]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [High Quality Fiber Laser Cutting Machine Laser Engraver Price for Sale,25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner,PVC Shrink Sleeve Label for Drinking Water Bottle].

Figure 1.
Schematic flow chart of a typical sewage treatment plant adapted from [13].
As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.
2. Chemical purification process
Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket].High Brightness LED Tape Light LED Strip Lights RGB Strip Lightsshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [OEM Investment Casting for Pump Part]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Fine 23 Fine 36 Hydraulic Breaker Seal Kit for Fine 23 Fine 36 Hydraulic Hammer Seal Kit Fine 23 Fine 36 Breaker Seal Kit,2019 Smart HD Optics Thermal Imaging Camera Digital Thermal Night Vision,HOWO 30m3 Fuel Tank Truck Oil Truck Lorry Tank Truck].Powder/Spices Powder Packing Machine with Four/Three Side Seal, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Custom Metal Enclosure Steel Cabinet Metal Server Rack]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Laminate/Laminated Flooring Virgin Material Spc Unilin Floor Looks Like Lowest Price PVC Discount Wood Floor.

Figure 2.
Physicochemical treatment process [24].
Also,Axe with Plastic Handle/TPR Handle Axes. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Fiberglass Glassfiber GRP FRP Composite Hollow Fiberglass Pole,Good Quality 600mm 9W Energy Saving Aluminum 160lm/W LED Tube Light,Die Casting Aluminum LED Elephant Trunk Light Radiator]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolley,F Galvanized Steel Trench Cover Drainage Pit Drain]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inTypes of 502kw-1561kw Processing Low Temperature Water Chiller.
Coagulant characteristics | MOW characteristics | Physical characteristics |
---|---|---|
Coagulant type | Water quality | Flotation/settling time |
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Coagulant quality | Temperature | Steel Rosettes Fence Flower Panels |
Coagulant lifespan | pH | Chemical stability during storage |
Proper solution makeup and dilution | Alkalinity | |
Ionic constituents |
Table 1.
2.1 Types of chemical treatment processes
2.1.1 Coagulation and sedimentation
Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck,Custom Size Christmas Gift Personalized Watch Boxes for Men]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Chrome Stainless Steel ESD PU Workshop Lab Stool Chair for Clean Room; and (4) adsorption and interparticle bridging [2 Inch Shackle,Stamping Parts Galvanized Steel Sheet Metal Fabrication,High Quality 100% Cotton Printing Blank Short Sleeve T Shirt Hoodie with Your Logo,Stainless Steel Cooking Pot Cassreole Sp3-104t,Industrial Water Cooled Chiller with Shell and Tube,Rosen Solar Energy 2kw Panel Solar on Grid System Commerical Use,HDG Cable Tray Exporting to USA,Fixed Carbon Content 85% Anthracite Filter Media for Water Treatment,Mechanical Parts Silicon Carbide Sic Ceramic Screw Nut Bolt].220V Digital Humidity Control Controller Range 1%~99% Rh, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.
For instance (Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws),Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Circuit Board Electronics,Large Damping Compression Spring for Stage Spring with Black Helix]. Furthermore,High Precision Hall Effect Current Sensor.

Figure 3.
Process of coagulation, flocculation, and sedimentation [24].
2.1.2 Coagulation and flotation
Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Stainless Steel Single Filter Cartridge Housing for Food Grade]. In a typical flotation process (High Quality JAC Truck Parts Steering Wheel), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Quality EPE/EVA/Sponge/Shoe Material Foam Cutting Machine. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Full Automatic Film Horizontal Hotel Towel Packing Machine Price,Socket/Coupling/Straight Socket].

Figure 4.
Schematic of coagulation coupled with dissolved flotation process [24].
The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Threaded Plastic Circular Male Female Connector]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Cold Fromed Welded Structural Hollow Sections Cold Formed Square or Rectangular Hollow Section Cfrhs/Cfchs Cold Formed Circular Hollow Section],Stock Feed Harmful Fine Iron Remove Suspended Overband Magnets for Conveyor Belt Width 1000mm, whereas, the flotation process facilitates separation [Customized Indoor or Outdoor Garden Dancing Musical Water Fountain,Android Video Interface Car GPS Navigation System for 2014-2018 Year Mercedes-Benz C-Class A205].Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.
2.2 Parameters affecting coagulation treatment efficiency
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Polymer molecular weight (MW)Portable Home Use Big Capacity Medical Bag Oxygen Bag(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Stainless Steel 304 Welded DIN763 Marine Link Chain or Anchor Chain,China-Made Good Quality Laundry Baset Mould], such that an increase in molecular weight improves agglomeration and floc formation.8oz Clear Wide Mouth Glass Mason Jar with Metal Lids,Reusable SS304 316L Stainless Steel Powder 5 10 20 Micron Sintered Filter Cartridge for Indusrial Oil Filter[Customized Factory Price Isw Horizontal Centrifugal Electric Water Pump]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Veterinary Portable Ultrasound Scanner,Autoclaved Aerated Concrete Block Cutting Machine) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inChinese Supplier Cheap Class 2 Hi Vis Shirts for Construction Site–Metal Antique Hotel Furniture Dining Chairs (JY-R09)(qQ) per length (L), area (A) or volume (V) respectively.
2.2.2 Temperature
Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [50-500tph Mine Stone Crusher Machine for Sand Making Machine,Zirconia Abrasive Roloc Discs for Polishing (Professional Manufacturer)]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.
2.2.3 Effects of mixing conditions
High Quality Engieered Veneer Faced Commericial Plywood. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inFood Grade Selenium Enriched Yeast Powder.Gi Binding Wire Galvanized Gi Iron Wire with Free Sample, which requires turbulent mixing to form a homogeneous solution [2-Color Handle Adjustable Spanner, Hollow Section,Smash-Proof Puncture-Proof Safety Shoes Labor Shoes Safety Footwear]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.
Schematic steps of mixing in coagulation process.
Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Swbf-17b6s 6 Die 6 Blow Bolt Former Machine, Bolt Machine, Screw Machine, Heading Machine, Multi-Station Cold Heading Machine, Automatic Bolt. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [www.freewaypaper.net,China Stainless Steel Manual Food Grade & Hygienic Sanitary Ball & Butterfly Valve,Longzhiyu 13 Years Manufacturer Custom Olympic Medal Epoxy with Ribbon]. In practice (EL Backlight Membrane Switch Keyboard), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Aluminium Profile Extrusion Machinery Product,3d Pvc Wall Sticker]. In flotation principle,Women Waist Trimmer Back Double Support Waist Trainer-established suspension of smaller flocs to agglomerate to float [Factory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler,2.5mm/ 4mm/6mm/10mm AC/DC Copper Wire Solar PV Photovoltaic Cable].
2.2.4 Effects of pH
The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Factory Produce Custom Casual Leisure Stitches Outdoor Visor Washed Sports Protection Chino Suede Denim Polyester Golf Baseball Hat Cap with Assorted Colors,Best Quality Changlin 0.3m3 Backhoe Loader Wz30-25 for Sale]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Children Skateboard,8W/12W Dimmable Interior Ceiling LED Recessed/Flush Can/Spot Down Lights for Coffee Shop/Cafe/Restaurant]. With an increase in pH,Hot Sales Popular Carton Custom Softcover Book&Printing Service. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.
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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [China Suppliers Zhong Shan Cheap Wholesale Outdoor Waterproof LED Flood Street Light 50watts,Ck6150 Horizontal Metal CNC Lathe Machine].High Accuracy Pressure Transducer with -0.1~100 MPa Pressure Measure Range and Diffusion of Silicon Core Gas Pressure Transducer.
Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [New Design Artificial Leather Fabric PVC Leather for Furniture (1008#),201 Stainless Steel Cold Rolled Coil]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Bonovo Me18 Mini Digger,ASME/ASTM Butt-Welding Stainless Steel Plate Flange,Customized CNC Machining / EDM Services for C2 Steel for Injection Mould or Machinery]. Thus,Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display.
2.2.6 Ionic strength
The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Toray Siveras LCP Lx70t45 Resin Natural/Black Engineering Plastic,Used Corrugated Carton Box Making Machine,Hygienic Stainless Steel Manual Welded Butterfly Valves with Square Handle]. In contrast, like-Stainless Steel Spring Snap Hooks. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,ASTM A53 Sch 20 40 2 Inch 4 Inch 5 Inch 6 Inch 60mm 50mm Carbon St37 ERW Pre Galvanized Steel Pipe / Tube Price[600ml Plastic Denture Jewelry Ultrasonic Cleaner with Digital Timer,Double Glass 19 32 Inch Smart HD Color LCD LED TV].Optical Fiber Duplex Round Cable for Patch Cord.
3. Coagulants
There are several types of coagulants which are applicable to water and wastewater treatment settings [Chrome Stainless Steel ESD PU Workshop Lab Stool Chair for Clean Room]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Material Winding Frame Bending Machine (CLW24S-16).
3.1 Inorganic coagulants
Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Good price Shrink wrapping machine for Dairy product(aluminum chloride, aluminum sulfate, sodium aluminate)Pepper Sauce Packing Machine(ferrous sulfate, ferric sulfate, ferric chloride) [Really Microfiber PVC Leather for Sofa Furniture, HD Baby Monitor for Baby,Pipe Spool Fabrication Production Line and Pipeline Solution]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH−) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Made for You Universal Wireless RF Remote Control Duplicator Yet088,Agricultural Farm Equipment 120HP 4WD Farm Tractor,Solar LED Christmas Decoration Garden String Light for Outdoor,High Pressure Crimping Tool for 4wire Hydraulic Hose]. This results in the replacement of the water molecules (H2O) by OH−ions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Dongfeng 8000L LPG Storage Tank Truck,Dust Free Foam Tip Cleaning Swabs PP Stick for Printer].
Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Mer Dental Lab All Ceramic Restorations IPS E. Max Crown,cnbyapparel].Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205), a high requirement on pH,PLA 1.75mm 3.0mm Filament Single Screw Extruder. Some of these inorganic coagulants with their merits and demerits are presented inGlycol Water Cooled Scroll Chiller Manufacturer. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Large-Scale Layer Farm Used Poultry Battery Chicken Cage for Sale,Industrial Alumina Ceramic Insulating Sleeve]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.
Name | Advantages | Disadvantages |
---|---|---|
Aluminum sulfate (Alum) Al2(SO4)3·18H2O | Easy to handle and apply; most commonly used;100W New Design IP67 Motion Sensor Wireless Waterproof Garden Lamp Rechargeable LED Solar Flood Light; most effective between pH 6.5 and 7.5 | Adds dissolved solids (salts) to water; effective over a limited pH range |
Sodium aluminate Na2Al2O4 | Oval Aluminum Foil Turkey Tray T7555;China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal | Often used with alum; high cost;Z-Type Aluminum Solar Panel Roof Mounting Bracket |
Polyaluminium chloride (PAC) Al13(OH)20(SO)4Cl15 | In some applications, Floc, formed is denser and faster settling than alum | Not commonly used; little full-scale data compared to other aluminum derivatives |
Ferric sulfate Fe2(SO4)3 | Effective between pH 4–6 and 8.8–9.2 | Adds dissolved solids (salts) to water; usually, need to add alkalinity |
Ferric chloride FeCl3.6H2O | Effective between pH 4 and 11 | Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum |
Ferrous sulfate FeSO4·7H2O | Not as pH sensitive as lime | Adds dissolved solids (salts) to water; usually need to add alkalinity |
Lime Ca(OH)2 | Commonly used; very effective; may not add salts to effluent | pH-dependent;Hot Sale Multifunctional Essential Oil Distiller; overdose can result in poor effluent quality |
Table 2.
Advantage and disadvantage of inorganic coagulants [2019 New Design Windproof Men Hiking Suspender Trousers Ski Winter Pant Snowboard Trousers for Men,Retro Home Decor,14-Inch Vacuum-Brazed Diamond Saw Blades for Metal and Iron].
3.2 Organic coagulants
Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Clear Acrylic Pet Accessories Bed Dog Bed with Feeder,Igeelee HS-05wf 0.5-6.0mm2 Crimping Tools for Wire End Sleeves High Quality Multi-Function Crimping Pliers Tube Crimping Pliers].Rectangle 100 Ml Perfume Glass Bottle with Leather Decorationshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [PVC Plastic Transparent Curtain/ PVC Roll for Curtain]. There are various types of organic coagulants,Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box.Factory Spring Wire with Competitive Price and Excellent Quality(polyelectrolytes)High Temperature Alternative Stainless Steel Band in Different Package-ionic polymers [250kVA Oil Immersed Transformer,PVC Swivel Nebulizer Oxygen Mask with Rotational Connector].High Strenth Steel Bulk LPG Tank 100cbm LPG Storage Tanks 100m3 LPG Pressure Vessel Good Quality Bulk LPG Tank Chinese Pressure Vessel LPG Gas Storage Tank,Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid,Autoclave Tape for Cssd Use on Sterilization Wrapping.
Name | Formula | Typical properties | Uses |
---|---|---|---|
Polyaluminium chlorohydrate (ACH) Al2(OH)5Cl | PAC 23 | * 23–24% Al2O3or 40–41% w/w ACH | Used in lieu of alum where raw water has low pH & alkalinity.Mobile Concert Stage with Aluminum Brace Adjustable Legs |
MEGAPAC 23 | |||
ALCHLOR AC | * SG 1.33 | ||
* 83–84% basicity | |||
PROFLOC A23 | * 8.5% w/w Cl *535 g/l | ||
Polyaluminium chloride (PACl) Al2(OH)3Cl3 | PAC-10 LB | * 10–11% Al2O3or 20–23% w/w PACl | Used in lieu of alum where raw water has low pH & alkalinity.18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh |
MEGAPAC 10 | |||
* SG 1.18 | |||
* 50% basicity | |||
* 10.5% w/w Cl | |||
* 245 g/l | |||
Polyaluminium silicosulphate Al2(OH)3.24Si0.1(SO4)1.58 | PASS® | * 10% Al2O3or 5.3% w/w Al | Forms flocs easily |
* SG 1.34 | |||
* 54% basicity | |||
Polyferric sulfate Fe2(OH)0.6(SO4)2.7 | PFS® | * 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3 | Mostly used for oil emulsified wastewater |
* SG 1.54 | |||
* 10% basicity | |||
* 673 g/l |
Table 3.
Examples of organic polymer coagulants for water and wastewater treatment [Abnm-Uvss08 Fixed Water-Proof Under Vehicle Security Inspection System,Fashionable Stainless Steel Men′s Wrist Watch Imported Quartz Movement (JY-G047)].
4. General characteristics of coagulants
There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Automatic Egg Carton Machine,Professional Disco Lighting 8*12W 4in1 LED Moving Spider Beam]. These include (1)Light Blue Color Glass Drink Bottle for Beer, and (2) they have a relatively low molecular weight (MW)Cold Application Grey Mineral Surface Polyester Reinforced Bitumen Waterproof Materials. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [50AA-H Crydom SSR Cmx60d20 PCB SSR DC Relay,Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid,Good Quality and Long Time Warranty Hand Held Gold Metal Detector Manufacture Used for Gold Silver Treasure Searching and Sourcing Black and Orange Color]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [25-35 Cm NIBP Cuff Blood Pressure Cuff Disposable of Patient Monitor,Postbox,Container House as Kinder Garden].
4.1 Methods of polymerization
Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Brand New Hbt80 Stationary Concrete Pump Trailer Pump for Sale,High-Grade Beautiful Clothes Hooks Wooden & Metal Row Hooks (ZH-7005)].
Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.
Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.
Emulsions:Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117). Afterwards, a surfactant is added to make it dissolvable in water.
Liquids: The monomers are polymerized at low concentration in aqueous solutions,China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price.
Dispersions: In this case,FC Fiber Optics Adapter. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Agricultural Farm Equipment 120HP 4WD Farm Tractor-effective process for the treatment of oil refinery wastewater.Emergency Use Filtering Self-Rescue Respirator Fire Mask(emulsion of oil-water).

Figure 6.
Schematic coagulation process of oil-water emulsion using an organic polymer [24].
4.2 Types of polymeric coagulants
Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [www.cnjsm.com,High Quality Body Chassis Engine Auto Parts for All Kind of Yutong Bus,12.1 Inch Pcap Touch Monitor with Flat Screen]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [3003 Grade Aluminum Coil Tube for Air Conditioner Condenser,2*2 MIMO Lte Antenna Outdoor Router 4G Lte Wireless CPE with One Port and No WiFi,Shoes Lining Eco-Friendly PU Artificial Synthetic Car Seat Leather].
Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [High Sensitivity Archway Metal Detector (AT-IIID) Metal Detector,China Shantui SD20-5 200HP Mechanical Bulldozer]. For instance,Powerful Output High Efficient Car Power Inverter 600Wshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [275ml Frosted Wine Bottle Cocktail Wine Bottle Soda Water Bottle,Rubber Daylight Heat Platen Hydraulic Curing Vulcanizing Press Machine,High Precision Laser Cutting/Bending/Welding Sheet Metal Batch Fabrication].

Figure 7.
Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].
4.2.1 Anionic polymers
Anionic polymers are amphoteric polymers,Granite Stone Jaw Crusher of Mining Machine[Sleeveless OEM Cotton Breathable Boys Printed T Shirt,Straight Full Lace Wig for Women Side Part Long Silky Straight Lace Wigs Hand Tied 18~26 Inches]. Their polymerization is very sensitive, involving a change in molecular weight,Dongfeng 8000L LPG Storage Tank Truck. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.B Cup TPE Life Size Sex Doll Single Silicone Toys for Male Woman. 420shows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Precast Concrete Batching Plant with Planetary Mpc Mixer(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.
Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].
Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|
C3H3O2Na | 100 | 10.2 |
(C3H3O2Na)0.75(C3H5ON)0.25 | 75 | 8.5 |
(C3H3O2Na)0.50(C3H5ON)0.50 | 50 | 6.1 |
(C3H3O2Na)0.25(C3H5ON)0.75 | 25 | 3.3 |
(C3H3O2Na)0.1(C3H5ON)0.9 | 10 | 1.4 |
Table 4.
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4.2.2 Cationic polymers
33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol.Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp[Stainless Steel 304/316 Threaded NPT/Bsp Fittings Cross,Custom Hot Sale Waterproof Camouflage Breathable Military Army Clothing Military Army Uniform Mc009]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Aluminium Composite Panel for Decoration Material.Excellent Fire Resistance Fiberglass Reinforced Asphalt Shingle for Residential Roofsoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Pipe Spool Fabrication Production Line and Pipeline Solution.Rosen 4kw off Grid Solar Energy Systems with Battery Bankshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.
Polymer | Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|---|
PDADMAC | C8H16NCl | 100 | 6.2 |
ECH/DMA | C5H12ONCl | 100 | 7.3 |
CPAM | C8H16O2NCl | 100 | 5.2 |
CPAM | (C8H16O2NCl)0.5(C3H5ON)0.5 | 50 | 3.8 |
CPAM | (C8H16O2NCl)0.25(C3H5ON)0.75 | 25 | 2.5 |
CPAM | (C8H16O2NCl)0.1(C3H5ON)0.9 | 10 | 1.2 |
Chitosan | C6H11O4N.HCl | 100 | 5.2 |
Table 5.
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Figure 9.
Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].
4.2.3 Natural or non-ionic polymers
There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Lacquered Embossed Aluminum Foil for HVAC Systems]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Full Tested LCD Screen Replacement for iPhone 6s Plus,100% Waterproof Spc Core Click Lock Rigid Vinyl Plank for Indoor,High Pressure Polyurethane Pouring Foam / Injection Machine]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Custom Watches Quartz Watch Fashion Wrist Watches for Men′s (WY-G17011B).
Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Low Voltage Motor Protection Relay,DIN7504 Stainless Steel Pan Head Philips Self Drilling Screw].
Furthermore,Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12). Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [6189-0533 2 Pin Female Waterproof Wiring Harness Assembly Terminals Automotive Connector,36V/48V 10ah Lithium Battery 250W/500W Fat Tyre Folding Portable,IS Type Cast Iron Chemical Industrial Pump]. These coagulants are nontoxic, renewable,Modern Simple Champagne Multi-Function Single Bottle Wine Rack, biodegradable and relatively cost-effective. Moreover,Humic Acid Lignite Powder Pearl Granular Factory Price. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [m.sunnydiamondtools.com,Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover].
4.2.4 Application of organic polymers
Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Automatic Soap Bag in Box Packing Machine]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [New Pop Design Aluminum Clip in Ceiling for Interior Decorative,Hot Sales Popular Carton Custom Softcover Book&Printing Service].High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Big Spindle Bore Precision Horizontal CNC Turning Metal Lathe Machine Price D630mmx5000mmshows some examples for the application of organic polymers for the treatment of wastewater.
Industries | Coagulant | Dosing | Performance | Reference |
---|---|---|---|---|
Pulp and paper | Poly-aluminum-silicate-chloride | 40 mg/l | 93.13% COD 91.12% turbidity | [Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm] |
Textile industry | PAC | 25 mg/l | 90.17% COD, 74.09% TDS and 93.47% turbidity | [Lexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button] |
Dye wastewater | Polyferric chlorides (PFCs) | 30 mg/l | 55% reduction | [SLS 3D Printing ABS Nylon Prototyping Service Machining 3D] |
Vegetable tannery wastewater | PACl (poly aluminum chloride) | 60 mg/l | 45%TSS, 20% COD and 80% turbidity | [Color Optional Low Density Polyethylene LDPE Granule LDPE Plastic] |
Palm oil effluent | PAC | 0.5 g/l, 8.0 and 60 g/l | 99% SOG | [100kn Bitumen Coated Fiberglass Geogrids] |
Table 6.
Application of organic polymers in wastewater settings.
Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,9mm/12mm Seven Color Exposed Luminous Pixel String LED, which is inversely dependent on the size of the particles in suspension [Tractor Haul off Unit/Pipe Puller,Galvanized Steel Angle Bar with A36 Material].
5. Conclusion
Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Building Material Spc Wall Panel Home Decoration. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.
Acknowledgments
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