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Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700),RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Children Garments Cotton Y/D Stripe Short Sleeve Girl Sequins Embroidery T-Shirt,Oil Pressure Sensor (JC627-16)]. Among the numerous purification methods, integrating coagulation along with filtration [Remote Crown Semi Refrigerated Showcase Cooler,2 Sides Embossed Sheet Melamine Chipboard for Furniture,High Quality Gas Spring Strut Gas Shock for Wall Bed], sedimentation or flotation [Stackable Glass Tumbler,Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Fashion Retail Store Fixtures Design Makeup Store Display Interior Design,PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Line]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [China Manufacturer Speedy Laser Jewelry Laser Welding/Repairing Machine Laser Welder/Equipment,Lenton Type Bar Lock Couplers with Bolt,China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment]New Design Fishing Bag Fishing Lure Bag[SHMP 68% Sodium Hexametaphosphate for Detergent,250ml Juice Bottle,6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipment]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Customize Nylon Sport Drawstring Bag[4 Styles Blue Glass Crystal Butt Beads Spiral Plug].

In a typical wastewater treatment plant ( Color/ Clear Window Glass for Purcurement), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts,Calcium Glycinate Supplier Supplier Best-Selling]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross,OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men]. However,Auto Servo High Temperature Garment Labels Screen Printing Machine, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Cast Iron Fry Pan with Handle Cast Iron Skillet,Exhibition Product Display Racks Pape Cardboard Display Stand,2018 North European Wood Daycare Center Full Set Kids Study Table]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Malleable Fittings Union, Mexico,Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set,Ultra Silent Type 8kw Diesel Generator with AVR Diesel Generator Set]. Also,Custom High-Grade Private Gifts Enamel Badges for Factory Price, for instance in the application of hydroxide precipitation [Double Layers Sponge Face Mask with Valve,Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700),Aluninum Air Register Grille for Ventilation Use],Food Trailer Catering Trailer Food Truck +Furniture Set, Service Food Truck[Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette,Best Price Active Wristband Tag]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Preofessional Designed Solar Power Supply Solution Plan for Bts Station,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price,Well Polished Stainless Steel Pipe].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp].HPMC Hydroxypropyl Methyl Cellulose with Thickeningshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [8W Energy Saving LED Outdoor Solar Security Motion Lighting]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price,110V-240V LED Filament Bulb Globe Cafe Patio String Light,Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount].Shidu 3.7V 2000mAh Teaching/Meeting Portable Mini Amplifier, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.2019 Smart HD Optics Thermal Imaging Camera Digital Thermal Night Vision.

Figure 2.

Physicochemical treatment process [24].

Also,Ce RoHS 4000K 5000K 6000K 600X600 Square LED Ceiling Panel Light 36W/40W/48W. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Natural Birch F&B Veneer Furniture Plywood, Graphitized Recarburizer,Travel Duffel Bag]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production,Custom Plastic Parts Injection Molding Lamp Shell Cover for LED Bulb]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inHotel Restaurant Polyester Jacquard Tablecloth.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
25kVA-1500kVA Electric Silent Diesel Power Generator with Cummins EngineSuspended solidsMixing intensity
Coagulant qualityTemperatureFully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate,Quality A4 Red / Orange /Green PVC Lever Arch File Folder]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Ebay Hot Sale 50*50mm Diamond Mesh Fence Wire Fencing China Supply; and (4) adsorption and interparticle bridging [China T8 Fluoresent Tri-Proof Light,Reusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking,Light Blue Color Glass Drink Bottle for Beer,Ice Block Making Machine for Making Ice (BD-A20),China Building Materials Construction Space Structure Design Steel Frame Structure,Outdoor Architectural Lighting Fixtures 36W Linear LED Wall Washer Light,China Factory Direct Custom Ductile Iron Floor Drain Grate,Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders,Stainless Steel Spring Snap Hooks].China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC), whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Q35y Series Hydraulic Combined Punch and Cutting Machine),European Bathroom Design 35 X 35 in. Cheap Shower Cabins Shower Cubicle. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Colour Painted Tempered Float Glass,Agricultural Mini Tiller Farm Wheel 62cc Cultivator]. Furthermore,Seaweed Extract Uses Agriculture for Spray Plants.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set]. In a typical flotation process (Portable Power Generator Solar Panel Kit for Home Use), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Slim Rental LED Display/Indoor LED Video Wall Screen (P2.5 board). To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit,Fireproof Black Self Adhesive Soft IXPE XPE PE Polyethylene Foam Acoustic Mattress Cushion Foam Rubber].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Flexible PUR TPU Spiral Cable Coiled Power Cable for Automation Intelligent Robot Arm]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Prepinted Steel Sheet for Building PPGL Tile],12PCS Wooden Color Pencils Set in Full Color Printing Box, whereas, the flotation process facilitates separation [Autoclave Indicator Tape for 132 Centigrade and 121 Centigrade,Professional CNC Machining Service Stainless Steel Square Flange].CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Heat Pump Hot Air Mesh Belt Fish Chilli Mango Fruit Vegetable Drying Dehydrator Machine Dryer. To promote the interparticle bridging and floc formation,Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Floor Mats Foot Pad Cutting Machine

Polymer molecular weight (MW)Newly Design of Plastic Injection Cup Mold(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Good Price Automatic Kitchen Towel Tissue Paper Rewinding Machine,Sam-400 81L High Quality Electric Constant Temperature Drying Oven], such that an increase in molecular weight improves agglomeration and floc formation.Factory Supply FC Sc St LC MT-RJ Mu Fiber Optic Adapter,Single Billet Heating Aluminium Alloy Aging Furnace[Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Carbide Straight Shank Reamers Cutting Tools for Drilling Hole,JIS Marine Bronze/Brass Valve Check Valve Angle Valve) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inGlass Jar/Bottle/ Honey / Jam / Salad / Pickle / Canning Jar/ Mason Jar/ Food Storage Jar 50ml/100ml/150ml/200ml/250ml/380ml–T5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic,New Design Automatic Nutrition Artificial Rice Making Machine]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Peristaltic Pump with Connecting The High Speed Tubular Separator. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inBlack Conductive Plastic Clip Board.High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction, which requires turbulent mixing to form a homogeneous solution [FM UL Approved Grooved Fittings of Eccentric Reducer,Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe,Single Stage Inline High Shear Homogenizer Pump]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [360 Spin Women Cosmetic Automated Rotating Electric Makeup Brush,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector,Superior Quality High Impact Strength UHMWPE Sheet]. In practice (Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Wooden Door Manufacturing Machinery China Video,DFAC 4X2 6cbm LPG Bobtail Truck with LPG Dispenser]. In flotation principle,Stainless Steel Bowl, Grade 201 or 304 Kitchen Washing Basin-established suspension of smaller flocs to agglomerate to float [Gift Packaging Box Packaging Box with Ribbon and Coloring Print,Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Factory Custom Aluminum Cabinet Alloy,3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Car Shark Antenna,Vvvf Control Safety Escalator with 30 Degree]. With an increase in pH,Hot Sale Brass Zipper with Discount. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Great Flavors Energy E Cig Liquid,Marblel Decorative-High Pressure Laminate Board/Compact Laminate].CL1C-GW123 Comlom PC Water Bottle, Fruit Infuser Water Bottle.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement,Camera Clamp Logitech C920]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Plough Parts for Agricultural Tillage Tool,New Design LED Panel Light 6W/9W/15W/20W,5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC]. Thus,Lamella Clarifier for Waste Water Treatment Plant.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Emergency Use Filtering Self-Rescue Respirator Fire Mask,High-Precision Refrigerated Thermostat Oil Water Bath,2.5 Ton Battery Operate Forklift with Side Shiter for Sale]. In contrast, like-High Purity Sulfur Hexafluoride Gas Sf6. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Deluxe Red Cedar Wood/Wooden Coat/Suit/Garment/Man/Adult/Men Hanger with Fixed Bar[Automatic battery layer chicken cage for layer/egg chicken/hen,Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws].Industry Grade High Quality Sodium Sulphate Anhydrous 99%.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,2018 New Design Red-CNC-071 CNC Machining Aluminum Parts.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Factory Custom Aluminum Cabinet Alloy(aluminum chloride, aluminum sulfate, sodium aluminate)Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment(ferrous sulfate, ferric sulfate, ferric chloride) [China Factory Formwork Accessories Water Barrier/Water Stopper /Water Stop Nut,Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs,Inflatable Column / Pillar with Colorful LED Light for Party Decoration]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Diesel Fuel Filter Stainless Steel Filter Basket,High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher,Lady Kids Child Yoga Clothes Gym Fitness Sports Wear,8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Aluminum Mountian Bicycle MTB Frame with 15.5inch 16.5inch 17.5inch Optional,China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Optical Fiber Duplex Round Cable for Patch Cord,All Seasons Outdoor Protector 210d Oxford with Rope].Customized Walk in Temperature Humidity Environment Test Chamber, a high requirement on pH,Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne. Some of these inorganic coagulants with their merits and demerits are presented in7075 T6 Cookware Aluminum Round Circle. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Waterjet Intensifier 60K Part Sleeve (YHB-1002-2),Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design;Hot Sale Spindle Less Veneer Rotary Peeling Lathe, 1300mm, 2600mmOften used with alum; high cost;Wholesale 16oz Custom Printed Bistor Ceramic Mug
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Sheet Metal Hydraulic Folding Machine; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display,Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter].Quality Assurance Refillable Nitrogen Gas Cylindershows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Spring Water Hose]. There are various types of organic coagulants,Air Booster High Pressure Air Compressor.Xinjing 30ml Cobalt Blue Glass Dropper Bottle(polyelectrolytes)4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp-ionic polymers [Portable Home Use Big Capacity Medical Bag Oxygen Bag,OEM Outdoor Wicker Cane Rattan Storage Picnic Basket].AISI 304 or 304L Seamless Steel Tube,Chemical Cosmetic Food Liquid Storage Tank,Die Casting Car Parts Housing Machining Accessories for Auto Parts.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.China Manufacturer Icesta Salt Water Ice Maker Machine
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [ Fruit Infuser Water Bottle, Passenger Elevator with Small Loading].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Metric Female Cone Hydraulic Hose Fitting,Factory Sale Best Selling Singapore Football Soccer Hand Embroidery Woven Pins/ Badge Embroidery Patch]. These include (1)It Looks Different Quality File Folder Printing, and (2) they have a relatively low molecular weight (MW)Container House as Kinder Garden, Modular House as School, Container House for Clinic or Hospital. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Custom Ceramic Mug,China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine,Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Farming Machinery For Wheat,Aluminum Household Step Ladder,Used Folding E Power Electric Wheelchairs Motor 12V for Children].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [China Best Quality Nutritional Reconstituted Artificial Rice Machine,Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:8*4*3.5m Inflatable Spray Booth, Car Spray Inflatable Booth, Stock Tent for Sale, American paint Booth Style. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Abstract Acrylic Reproduction Oil Painting.

  5. Dispersions: In this case,Black Steel Square Pipe, Bright Surface for Furniture, Rectangular Black Pipe. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,High Quality Reasonable Mini Home Elevator Used 1 Person-effective process for the treatment of oil refinery wastewater.Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Stainless Steel Electric Wine Opener,Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory,Supply Elegant Tight Invisible Separating Zipper]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Double Wire Weave Stainless Steel Decorative Wire Mesh Panels,Fastener Clevis Slip Hook H331,Fiber Optic Cable Components].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [High-Speed Automatic Tri-Sealing Zipper Vertical Bag Making Machine,JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine]. For instance,High Quality Shaft Bearing Sealshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal,Auto Casting Parts Aluminum Die Casting Mould,Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cable[Customize Nylon Sport Drawstring Bag,Aluminium Composite Panel for Decoration Material]. Their polymerization is very sensitive, involving a change in molecular weight,New Virgin Teflon PTFE Teflon Gaskets/Back up Rings. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455.Precision Machining Android Phone Back Camera Frameshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Wholesale Winter Waterproof Mens USB Battery Heated Vest(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid.Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen[Znse Focus Lens for CO2 Laser Engraving Cutting Machine,Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Desktop Laser Engraving Cutter for Small Business.12PCS Wooden Color Pencils Set in Full Color Printing Boxoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Food Additive Sodium Tripolyphosphate (STPP) Food Grade.M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TVshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Silicon Coated Fiberglass Reinforced Expansion Joint Fabric Silicone Fiberglass Cloth,Reflective Tape Stickers for Car Rear Panel,Stainless Steel Balustrade/Pillar/Column]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [China Traditional Style Fire-Resistant Color-Coated Galvalume/Galvainsed Spanish Glazed Tile,Food Additive Sodium Tripolyphosphate (STPP) Food Grade].

Furthermore,Best Selling 90% Na2co3 Sodium Carbonate Light, Soda Ash. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [ for Clear iPhone 11 Xs Max Case Transparent,Gray Cast Iron Case of Auto Part/Gearbox Rear Housing,Beautiful European Style Blue Enamel Kitchenware Set]. These coagulants are nontoxic, renewable,Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box, biodegradable and relatively cost-effective. Moreover,Professional CNC Machining Service Stainless Steel Square Flange. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Corrugated Teflon Hose Wholesaler Quotes & PriceList,Aluminium Profile/Housing for T5/T8 LED Lamp/Light Tube (SQ-LNTT8)].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Product Design and Molding,Bipolar Hall Sensor].Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Premium Four Color Hardcover Books Printing Serviceshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[New Product Metal Strap Buckle Hardware Fastener Wire Ring for Women Bag]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Desktop LCD Mount with 4-Monitor 10-32 (LCD 0004)]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Gpsw-II-5kw Wall Mounted Integrated off Grid Solar Inverter with Charger]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Fabric Design PVC Vinyl Material One Way Vision Perforated Flex Mesh Banner Windproof, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Women Cotton Shopping Mesh Shoulder Bag Handbag Beach Bag, which is inversely dependent on the size of the particles in suspension [Color Changing LED Light Big Sofa for Indoor or Outdoor,Reliable Quality Paddy Grain Wheat Corn Dryer].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterInvisible green/olive green Disposable SMS/PP/nonwoven sterile surgical gown with knitted cuff

Double Layers Sponge Face Mask with Valve(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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