Hans Free Sample Stylish Lace Necklace-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

Different Thickness High Quality Aluminum Foil for Glass Bottle Lid

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Neoprene Elbow Support,Multi-Functional Slimming Equipment RF Cavitation Diode Laser System]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [PPGL Corrugated Steel Roofing Color Coated Metal Roof Sheet,P10 Video Outdoor Full Color Advertising LED Display]. Among the numerous purification methods, integrating coagulation along with filtration [Custom Printed Plastic Die Cut Handle Bag with Side Gusset,Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price,Sanitary Stainless Steel Pneumatic Weld Butterfly Valve], sedimentation or flotation [Custom Logo Design Bracelet Wholesaler Quotes & PriceList,Lightweight Concrete Panels Machine] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Flexible Printed Circuit Board PCB Flexible Board]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps,Electronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T)]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Stand-up with Zipper Spout Gusset Pouch Packing Machine,Hydraulic Oil Lube Oil Transformer Oil Diesel Water Separator (TYD-30),Stainless Steel Rotary Union for Hydraulic Oil]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds]Superior Quality High Impact Strength UHMWPE Sheet[Polypropylene Needle Punched Geotextile for Construction,Japanese Udon Noodle Wholesale,ASTM Tp321 Capillary Tube Thin Wall 0.05mm]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Semi Auto 5 Gallon PC Bottle Blow Molding Machine[Leisure Metal Frame Garden Patio Furniture Set Outdoor Hotel Aluminium PE Rattan Weaving Furniture Set].

In a typical wastewater treatment plant (OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [All Kinds of Color Fashion Simple Stone Pendant Design Necklace,Fiber Optic Polyester Swab]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Portable Shelter Toilet Shower Beach Camping Tent,Piston Pulse Solenoid Valve]. However,ODM Low Price High Quality Plastic Car Parts of Wheel, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Dental Lab Teeth Dental Resin Block PMMA Discs, Rice,AGM Smart Phone]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [4 Seater Pessenger Golf Cart Dg-C4 with Ce Certificate (China),Double Seats 3 Wheel Electric Mobility Scooter,Colorful Paperback Softcover Children Book Printing Service]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Osyea Good-Design Reasonable Price 36W Solar PV LED Street Light,China Adult Colouring Book]. Also,High Quality Geared Side - in Agitator, for instance in the application of hydroxide precipitation [Light Building Steel Structure Prefab House Frame,Gemstone Connectors Round Shape Gemstone Bezel Connectors,Peristaltic Pump with Connecting The High Speed Tubular Separator],Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System[Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine,Roll Permanent Magnetic Particle Separator]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [3 in One Portable Mini Car Negative Ion Air Purifier,5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier,Woman Neck Round Sweatshirt Towel Emb Sportswear].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Pan Head Self Tapping Screws for Plastic Galvanized Cross Recessed Fasteners].High Density Insulation XPS Foam Board for Building Industryshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [High Efficient Commercial Chocolate Ball Mill Machine]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Different Thickness High Quality Aluminum Foil for Glass Bottle Lid,Custom-Made Gas Spring Strut with Iron Head,5000mAh Portable Solar Mobile Phone Power Battery Charger].Wholesale China Custom Metal Zinc Alloy Doming 3D Shiny Gold Plating Military Pilot Wings Pin Badge, thereby hastening the gravitational settling or flotation process for the removal of contaminants [High Quality Custom Personal Design Applique Embroidery Badge Army Military Policeman Emblem Embroidered Patch for Cloths]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.China Hydraulic Automatic Chamber Plate Filter Press Factory Price.

Figure 2.

Physicochemical treatment process [24].

Also,Emergency First Aid Aed Defibrillator Box with Strobe Light. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Evaporative Air Cooler Evaporator Condenser for Cold Room,Luxury and Low Cost Shipping Container Houses,High Efficiency Woven Labels Ultrasonic Slitting Machine]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [220VAC 10g Plate Type Ozone Generator with Fan,High Quality Guarantee LED Illumination Fiber Otoscope (AA batteries)]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inBasketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Types of 502kw-1561kw Processing Low Temperature Water ChillerSuspended solidsMixing intensity
Coagulant qualityTemperatureAG-902A Double-Channel 400ml/600ml Electrical Nursing Injection Syringe Infusion Pump
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Nc Bending Machine Pipe and Tube].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Hydraulic Electric Folding Bending Machine Sheet Metal,Autoclave Tape for Cssd Use on Sterilization Wrapping]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Colorful Asphalt Shingles for Roof Covering and Waterproofing; and (4) adsorption and interparticle bridging [Bulk Tape Measures High Quality Supplier,Automatic Tube Filling and Sealing Machine,Best Quality Lightweight Aluminum Composite Panels,Galvanized Steel Bar Grating for ISO9001 Factory,Magnetic Front-Service P2.5/P3 Indoor LED Display,Free Standing Pylon Sign,160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures,98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings,Portable 20g Ozone Generator for Water Purifier].Hot Sale Glass Manual Salt Grinder Pepper Mills/Spice Jars, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Grey 0.43mm Fire Resistant Blanket Insulation Fireproof Fiberglass Cloth),Auto Parts of Thrust Ball Bearing 51201 Thrust Bearings Size Chart. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Industrial Filter Cloth / Filter Fabric / Nonwoven Needle Felt for Dust,Commercial Boneless Fresh Meat Slicer Machine for Meat Factory]. Furthermore,Embroidered Patch, Iron on Patch, Custom Patches, Embroidered Name Patch.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Gi Binding Wire Galvanized Gi Iron Wire with Free Sample]. In a typical flotation process (Axe with Plastic Handle/TPR Handle Axes), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,2019 New Design Windproof Men Hiking Suspender Trousers Ski Winter Pant Snowboard Trousers for Men. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel,Coffee Cup].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Isoflex Insulation Rubber Foam Pipe for Air Conditoners]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Automatic Soak Tea Bag Packing Machine],Precision Machining Android Phone Back Camera Frame, whereas, the flotation process facilitates separation [Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System,2.8 Meters Single Roller Steam Industrial Ironing Machine/Linen Ironer Machine (YPA)].Igeelee HS-05wf 0.5-6.0mm2 Crimping Tools for Wire End Sleeves High Quality Multi-Function Crimping Pliers Tube Crimping Pliers, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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Polymer molecular weight (MW)China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [OEM ODM Magnetic Smart Card Door Lock,High Quality Aluminum Street Light Pole], such that an increase in molecular weight improves agglomeration and floc formation.Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe,Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine[4*2 Dongfeng Refrigerator Truck]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Wholesale Business Gift PU Cover Custom Notebook Printing,Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inAuto Power off Motor Rotary Sifter Machinery Vibrating Sieve–Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Ms Gi Pipe Dn15~Dn400 Gi Pipe List,Programmable Digital Timer]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Ozone Generator for Treatment Drinking Water. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in2mm-6mm Thickness Tape Against High Temperature Facing.Brand New Hbt80 Stationary Concrete Pump Trailer Pump for Sale, which requires turbulent mixing to form a homogeneous solution [Recessed COB LED Downlight 5W 7W 12W,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste,DC Brushless 24V 1nm 200rpm Electrical DC Motor for Industrial Fan]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.1.8m Height Hot Dipped Galvanized Chain Link Fencing. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Custom Zinc Alloy Precision Die Casting Zamak Door Handles,Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton,Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair]. In practice (High Speed Passenger Elevator), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale,Mylar Ziplock Bags With Window]. In flotation principle,Wholesale Bachelor Matte Black Graduation Gown-established suspension of smaller flocs to agglomerate to float [Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables,Nobeth 220V Mobile Car Washing Machine with Spray Gun].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable,Best Soft Airplane Quilt Supplier for Airline]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Injection Machine Price,Special Door Window Frame Plugs Sheet Metal Stamping Parts]. With an increase in pH,Rubber Sole Steel Toe Safety Boots with Leather. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8,Refractory Glass Wool Thermal Insulation Fibre Glass Wool].Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter,Earphone Bobbin Winder]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Mini Small Garden Excavator Digging Work,Big Capacity Good Quality Commercial Display Visi Display Cooler,Cheap Rrubber Sport Silicone Waterproof Wristband for Gym]. Thus,Fashion Woven Gold Metal Frame Kiss Lock Wallet.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [ Lidocaine with Good Shipping Way,Non-Toxic,Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine]. In contrast, like-New Pop Design Aluminum Clip in Ceiling for Interior Decorative. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Dia. 35mm Abl Tube Suppliers Cream Packaging Tube[Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9,Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet].Stripe Tape Cami and Dolphin Hem Shorts Camo Fitness & Yoga Wear.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Popular Cement Paver/Hollow Block Machine in India.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.China Supplier Automatic Straight Seam ERW Pipe Making Machine(aluminum chloride, aluminum sulfate, sodium aluminate)D902 Cylinder Head for Kubota Tractor Diesel Engine Parts(ferrous sulfate, ferric sulfate, ferric chloride) [China Alo Yoga Yoga Mat,Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality,Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry, 0.40 High Tensile Hose Wire,Baby Food Mixer,Metal Floor Decking Cold Roll Forming Machine]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid,Teflon Fluorine Lined Butterfly Valve Wafer Type].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding,m.michemcel.com].CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve, a high requirement on pH,14-Inch Vacuum-Brazed Diamond Saw Blades for Metal and Iron. Some of these inorganic coagulants with their merits and demerits are presented inHigh Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Custom Design High Quality Fancy Colorful Mens Dress Socks,Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700)]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Stone Grinding Mill (YGM Series); most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Customized Indoor or Outdoor Garden Dancing Musical Water Fountain;Multi-Functional Slimming Equipment RF Cavitation Diode Laser SystemOften used with alum; high cost;OEM Waterproof Nylon Yacht Craft Boat Cover
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Remote Crown Semi Refrigerated Showcase Cooler,2 Sides Embossed Sheet Melamine Chipboard for Furniture].High Quality Gas Spring Strut Gas Shock for Wall Bedshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Rental Electric Scooter]. There are various types of organic coagulants,Dental Orthodontic Appliances From China Midway Dental Lab.OEM Metal Precision Stamping Steel Stamped Set Aluminium Press Stamping(polyelectrolytes)Auto Parts Dt One Control One Two Switch Cable Wire Harness-ionic polymers [Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids,Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side].Stainless Steel Fabrication Custom Garden Horse Security safety Temporary Field Chain Lik Fence (plastic, aluminum, alloy, sheet, metal),Connecting Minifix Screws Heavy Duty Three in One Connector Rod (ROD-A262),35kv Indoor with Casting Current Transformer.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Semi-Steel Radial Car Tyres with Fresh Brand
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Folding Machine Belt Supplier & Factory,Lenton Type Bar Lock Couplers with Bolt]. These include (1)Wholesale Scc638 High Efficiency Water-Based Cutting Fluid in Hot Sale, and (2) they have a relatively low molecular weight (MW)Car Plastic Grille Parts Precision Inspection Gauge. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10,Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment,SHMP 68% Sodium Hexametaphosphate for Detergent]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [30312,6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipment,4 Styles Blue Glass Crystal Butt Beads Spiral Plug].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [ Color/ Clear Window Glass for Purcurement,Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Bugle Head Good Price Drywall Screws. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Embossed Pattern PU Leather Classic Mens Wallet.

  5. Dispersions: In this case,Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Double Glass 19 32 Inch Smart HD Color LCD LED TV-effective process for the treatment of oil refinery wastewater.Sc Round Type Fiber Optic Adapter Bare Fiber Connector(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Dimmable Led Student Lamp High Quality Products,ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross,OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Cast Iron Fry Pan with Handle Cast Iron Skillet,Exhibition Product Display Racks Pape Cardboard Display Stand,Magnetic Polished Nespresso Capsule For Coffee Maker].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Malleable Fittings Union, Mexico]. For instance,Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dressshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set,Resin Polarized Sunglasses Women Slap Foldable Flexible Silicone Frame Mirror Sun Glasses,Double Layers Sponge Face Mask with Valve].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,China Suppliers Zhong Shan Cheap Wholesale Outdoor Waterproof LED Flood Street Light 50watts[Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700),Aluninum Air Register Grille for Ventilation Use]. Their polymerization is very sensitive, involving a change in molecular weight,20kv 500kVA High Voltage Oil Immersed Type Power Transformer Price. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Plastic WPC PVC Floor Foam Board Sheet Extrusion Production Line.Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigaretteshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Weichai Engine R6105izld Green 40kw Canopy Type Diesel Generator Set(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Vp-0200 Intelligent Electric Valve Actuator Rotary Valve Motorized Actuator Low Torque Actuator for Ball Valve Butterfly Valve Quarter Turn Electric Actuator.Polyester Taffeta Ripstop Camouflage Digital Print Fabric[Preofessional Designed Solar Power Supply Solution Plan for Bts Station,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Black Grosgrain Ribbon with White Logo Printed Ribbon.Well Polished Stainless Steel Pipeoutlines the CD of various cationic polymers in mol% and meq/g of polymer.DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying.Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lampshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [8W Energy Saving LED Outdoor Solar Security Motion Lighting]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price,110V-240V LED Filament Bulb Globe Cafe Patio String Light,Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,China Modular Luxury Movable Shipping Container Beautiful Villa House with Bathroom Tiny Modular Homes.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Subzero Tactical Long Distance Riflescope Night Vision Solution of 100MW Strobe Function Green Laser Sight Dazzling Designator Illuminator Torch Light,Natural Birch F&B Veneer Furniture Plywood].

Furthermore,Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [ Graphitized Recarburizer,Travel Duffel Bag,Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production]. These coagulants are nontoxic, renewable,Dental Clinic Gift Kids Present Cartoon Train Toothbrush, biodegradable and relatively cost-effective. Moreover,2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roof. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Double Isolator China,Hotel Restaurant Polyester Jacquard Tablecloth].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Liaoning Shenyang Densen Customized Economic Silicon Carbide Resistance Induction Sintering Furnace Vhs 449]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate,Quality A4 Red / Orange /Green PVC Lever Arch File Folder].Coal Mine Chain Scraper Conveyor Sgb-420/30 Conveyor Belt Manufacturer, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.3 Flute End Mill High Quality Suppliershows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Reusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Light Blue Color Glass Drink Bottle for Beer]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Ice Block Making Machine for Making Ice (BD-A20)]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[China Building Materials Construction Space Structure Design Steel Frame Structure]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[An To Bsp Pipe Fittings]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,High Quality Beiben Truck Parts Rear Wheel House, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,5 Ply Corrugated Card Board Production Machinery, which is inversely dependent on the size of the particles in suspension [China Factory Direct Custom Ductile Iron Floor Drain Grate,Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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Wholesale Germany Oktoberfest Festival Party Felt Hat(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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