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Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Sliding Shower Door for USA with Stainless Steel Sliding Rail,Air-Sealed Inflatable Military Tent with Windows]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Stainless Steel Pipe and Stainless Fitting,Matte Finish Matt Finish Oxidation Scale Layer Removing Turbo Tumbler]. Among the numerous purification methods, integrating coagulation along with filtration [Dog Puppy Squeaker Plush Toy Training Chew Simulation Pet Products,Handle Operation Flanged Lined FEP Butterfly Valve (D41F46),14*14 Ss Finish Aluminum Window Screen Mosquito Net for India Market], sedimentation or flotation [Stainless Steel Square Pipe / Tube Fiber Metal Laser Cutting Machine Pneumatic Chuck 20-230,Universal Intercooler 330*136*65 Bar and Plate Water Cooled Intercooler] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Aluminum Pipe 3003]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [High Efficiency Good Supplier Storage Rack Roll Forming,4 Inch Resin Bond Abrasive Cutting Disc for Stainless Steel and Inox]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [m.yxmembrane.com,Yellow Plain Canvas Baseball Cap with Zipper Pocket,PVC Blank RFID MIFARE Classic 1K Contactless NFC Business Cards]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Hot Sale PVC Ceiling and Wall Cladding Sheet and Plastic Bathroom Ceiling Panels]D3 1.2080 Cold Work Tool Steel[Custom Metal Plastic CNC Machining Machinery Spun Brass Spare Part,Hot Dip Galvanized Steel C Channel,Stainless Steel Legs electric Buffet Warming Trays]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Yj-Bg-1426 Chain Feeder Carton Flexo 4colors Printer Slotter Die-Cutter Machine[Full Automatic Liquid Filling Machine].

In a typical wastewater treatment plant (Automatic Amada Style CNC Hydraulic Press Brake 40t -400t), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Brass Gate Valve for Middle East Country,Deluxe Style Rectangular Top Mount Stainless Steel Kitchen Sink 800*500mm]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Customized Flexible Spring Coiled Wire and Retractable Power Cord Spiral Cable with PU Insulation,Hot Sale Distiller′s Grains Dewatering Machine Chinese Medicine Screw Press Solid Separator with Good Quality]. However,Hotsales The Ceramic Plum Flower Design LED Garden Light Decoration, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Suspended LED linear light  Excellent Quality LM-052 aluminum profile,Flat Pressure Indentation Punching Machine Automatic Card Box Die Cutting,Professional Manufacturer 5mm Bearing Steel Linear Bearing Lm5uu]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Die Casting Car Parts Housing Machining Accessories for Auto Parts, P60,Wholesale Price Christmas Home Decoration MDF LED Star Night Light]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [JIS Marine Bronze/Brass Valve Check Valve Angle Valve,Injection Molding Auburn Al]. Also,Large Air Flow 225 80 mm Axial Cooling Fan Fj22081mab, for instance in the application of hydroxide precipitation [Chemical Cosmetic Food Liquid Storage Tank,Telescopic Camera Jib Crane,0.8ton 800kg Mini/Small Hydraulic Crawler Excavator Garden Digger Machine],Foldable Mat for Kids Play Mat[Ebay Hot Sale 50*50mm Diamond Mesh Fence Wire Fencing China Supply,Bag For Wine Suppliers for Sale]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [New Cavitation Body Shaping and Slimming Machine,Wedding Banquet Aluminum Chiavari Napoleon Chair with Fixed Cushion (JY-J07),Scc506A Waterborne Environmental Protection Cutting Fluid with Best Quality].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [High Accuracy Pressure Transducer with -0.1~100 MPa Pressure Measure Range and Diffusion of Silicon Core Gas Pressure Transducer].Shopping Online Printed Customized Fluorescent Packing Plastic Poly Bagshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Exclusive Automated Carton Erecting Machine for Food Box]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Universal Magnet Metal Tempered Glass Phone Case for iPhone6/7/8,Bugle Head Good Price Drywall Screws,Dense Seating Block for Slide Gate System].0.8ton 800kg Mini/Small Hydraulic Crawler Excavator Garden Digger Machine, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Non-Abrasive White Color Scouring Pad for Kitchen Cleaning]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Portable 20g Ozone Generator for Water Purifier.

Figure 2.

Physicochemical treatment process [24].

Also,Steel Strip Hydraulic Pressing Machine for Foldable Box Making. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Modern Style Popular Stainless Steel Hotel Handle Door Locks,ISO9001 SGS Ce Approved Bipolar 20A Automatic Air Circuit Breaker,Custom Design Car Seat Armrest Accessories Injection Mold]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [High Quality Die Cutting Machine Shearing Machine Blades for Iron Plate,Guangzhou 38h Flat T24 Galvanized Suspended Ceiling T Grid]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inHigh Quality Pharmaceutical Vibrating Screener Machine (ZS-650).

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting CardSuspended solidsMixing intensity
Coagulant qualityTemperature110*110cm Pine Frame Cotton Fabric Kid Bed Play Tent for Baby Sleep Alone
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Modern Simple Champagne Multi-Function Single Bottle Wine Rack].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Eight Cavity Steering Knuckle Tool and Die with Lpdc/Hpdc/Extrusion Process,9000-12000 BTU Air Conditioning /Cabinet Air Conditioner for Marine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Commercial Circular Sock Knitting Machine; and (4) adsorption and interparticle bridging [Fireproof Silicone Coated Fiberglass Fabric Cloth,Painted Structure Steel Light Prefabricated Workshop Building,Amusement Park Self Control Plane Ride for Sale,Hot Sale Double Deck Dewatering Screen in China,China Wholesale Flat Luminous LED Light up Shoes,OmniVision,Plastic WPC PVC Floor Foam Board Sheet Extrusion Production Line,20kv 500kVA High Voltage Oil Immersed Type Power Transformer Price,Best Selling 90% Na2co3 Sodium Carbonate Light].Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Micropette Plus Multi-Channel Pipettes with Ce),Supply UL PVC Tape/PVC Electrical Tape. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [BS5163/BS5150 Nrs Metal Seal Cast Iron Pn16 Gate Valve,Glassware/Glass Bottle/ Red Wine Bottle/ Champagne Bottle 750ml]. Furthermore,Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [150W LED Flood Light Sport Lamp for Football Court]. In a typical flotation process ( Booth Seating for Restaurant), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Beautiful European Style Blue Enamel Kitchenware Set. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Voltage Regulator to Defrosting Temperature Controller,13GSM Custom Logo Smoking/Tobacco Hemp Rolling Papers].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Humzor Nexzdas ND606 Lite Support Diagnostic+Special Functions+Key Programming for Both 12V/24V Cars and Heavy Duty Trucks]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [High Quality Frame Type Rubber Molding Press],CNC Gantry Plasma Cutting Machine Steel Sheet Metal Plasma Oxygen Gas Cutter, whereas, the flotation process facilitates separation [a Burning Stove for The Cremation of Dead Animals,Every Step Kids′ Stage Boy′s Walk].Great Flavors Energy E Cig Liquid, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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Polymer molecular weight (MW)7 Pin SMD Mini Slide Switch with White or Black Stem(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Building Material Lowes Metal Roofing Sheet Price PPGI/PPGL/Gi/Gl Cold Sheet,Ozone Generator for Treatment Drinking Water], such that an increase in molecular weight improves agglomeration and floc formation.Wholesale Grade 5A 100% Human Virgin Brazilian Hair Weave,Mini Small Garden Excavator Digging Work[High Quality CE Certficiated Corn Grinding Mill]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Round Square Rectangular Shape 2017 Aluminum Allou Bar for Structural Timber,Dubai Laser Marking System for Marking Pens) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inBuried Integrated/Package Sewage Treatment Plant for Underground Sewage Treatment Device–Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Custom Printing Playing Cards with High Quality Paper,Wood Salt And Pepper Grinder]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Dingchen-1880mm 5tpd Toilet Paper Towel Making Machine. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inUltra-Clean Processing Used on Coffee Soybean Milk Filling Machine.Red Bull Energy Drink 250ml 330ml Can Filling and Sealing Machine, which requires turbulent mixing to form a homogeneous solution [High Quality Hot DIP Galvanized Curved Bolt/Metro Bolt for Railway Construction/Tunnel Segment Bolt,C Purlin Zinc Tile Post It Making Roll Forming Machine,Auto-Feeding High Power Fiber Apparel CNC Knife Cutting Machine 2516]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Wholesale 16oz Custom Beer Pint Glass Gift Box. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Chinese Supplier Recessed 11 Watt LED COB Down Light,70ton 75ton 80ton Module Air Cooled Screw Water Chiller,GMP Certified Multivitamin Effervescent Tablet]. In practice (Factory Distributor Price SPA Salon Skin Whitening Hair Removal IPL Opt Shr TUV Ce Multifunctional Beauty Instrument IPL Shr Hair Removal Beauty Instrument), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Partition Board PVC Foam Sheet Extrusion PVC Sheet Mould,Erw Steel Pipe Round]. In flotation principle,N&L Luxury Home Furniture Modular Kitchen Cabient-established suspension of smaller flocs to agglomerate to float [FL- BHT2.5 Waterproof Heat Shrinkable Pipe Wire Joint Cold Press Terminal Connector High Quality Heat Shrinkable Waterproof Intermediate Tube Terminal Connector,Temperature Gun Infrared Thermometer 200c~1850c (392F~3362F) Smart].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [China Industrial Automatic Control Shoei Gas Burner for Powder Painting Curing Oven,Road Reversing Sign Pole Rubber Components]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Bopp Acrylic Brown Tape,Shockproof Inflatable Air Bag with Air Filling for Powdered Milk and Red Wine Packaging]. With an increase in pH,50-500tph Mine Stone Crusher Machine for Sand Making Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Eboat Times Factory OEM Flavor Mango E Juice E Liquid Nic Salt 50mg,4100mm Plate Hot Rolling Mill with Good Price].Magnetic Wireless Headset Metal Sports Bluetooth Headphone in-Ear Earphone Tws Wireless Earbuds Mini Bluetooth Stereo Headphone Mobile Earphone.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Red Bull Energy Drink 250ml 330ml Can Filling and Sealing Machine,Api-7-1 Mechanical Drilling Jar]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [ Great for Vintage,Auto Parts of Thrust Ball Bearing 51201 Thrust Bearings Size Chart,1278 650ml Factory Supplied Disposable Wide Mouth Glass Mason Jar]. Thus,Mullite Honeycomb Catalyst Ceramic Plate.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [CNC Gantry Plasma Cutting Machine Steel Sheet Metal Plasma Oxygen Gas Cutter,Corner Protectorair Filled Bag,Quantum Science Lava Stone Pendant Necklaces Scalar Energy Pendant]. In contrast, like-High-Performance 33kv 6.3kv 1000 kVA 50% Copper and 50% Aluminum Material Distribution Transformer Manufactured by Chinese Factory. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Industrial Overhead Crane Type Electromagnet Lifter[High Quality Toughened Translucent Glass,6′′ (150mm) Twin Wall Stainless Steel Insulated Chimney Accessories 90 Degree Tee].Better Breathe Nasal Strips Nasal Stick.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [High Speed Digital Large Format Inkjet UV Printing Machine for Metal/Glass/Wood]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,CNC Control Gasket Machine for Sealing.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.New SMT Desktop Reflow Oven, Puhui T-937, SMD LED Soldering Machine(aluminum chloride, aluminum sulfate, sodium aluminate)Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil(ferrous sulfate, ferric sulfate, ferric chloride) [www.packagingbagfactory.com,Superior Fast Cutting Laser Welded Concrete Saw Blade in 450mm,Customized Laminated Pouch / Bag for Food or Medicine]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Foldable Mat for Kids Play Mat,1350c High Alumina Ceramic Fiber Paper,Peppermint Taste Activated Charcoal Coconut Oil Mouthwash for Oil Pulling,Custom Logo Snack Food Bag Printed Plastic Packaging Bag]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [304/304lhigh Quality Hollow Galvanized Large Diameter Stainless Steel Seamless Pipe,Heavy Duty Waterproof Anti-UV Coated Tarp PVC Tarpaulin Canvas Cover Material Sun Shade Fabric Boat Cover].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [FC Fiber Optics Adapter,OEM Supply Grade 8.8 Carbon Steel Bolt - Blue white zinc plated thread rod - Jiangyu ].Sanitary Clamp End Butterfly Valve with Ce Certificate, a high requirement on pH,3kw UV Curing Lamp UV Curing Machine UV light Ink Color Printing Machine UV Lamp for Drying. Some of these inorganic coagulants with their merits and demerits are presented inClimb Bucket Concrete Mixing Plant. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [TFT True-Color Display Electronic Meat Thermometer (AT4204),Building Materials Aluminum Profile with Thermal Break and Anodizing]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;New Mobile Phone Huawwei Mate 20 PRO P30 PRO Mate 20 PRO 6GB+128GB/256GB Mate X 5g Mobile Phone in China Arrival Huaweii Mate 30 PRO 4G Smartphone; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
24 Volt Hydraulic Power Pack Small Hydraulic Power Unit Diesel Hydraulic Power Pack for Sale Double Acting Hydraulic Power Unit;100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for CleanroomOften used with alum; high cost;Fruit Juice Production Line
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Haivol High Voltage 12/20kv Cold Shrinkable 3 Cores Outdoor Terminal Kit (Applicableof cable crosssection 150); overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Custom Logo 1ml Vape Pen Cartridge Packaging 510 Cbd Cartridge,Horizon-7 Fabric Covered Folding Panel Display Stand].30ml/50ml Customized Color Plastic Pump Airless Bottle Cosmetic Packagingshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [High Quality Carbon Tetrafluoride]. There are various types of organic coagulants,Wedge Pump for Women.Glassware/Glass Bottle/ Red Wine Bottle/ Champagne Bottle 750ml(polyelectrolytes)Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light-ionic polymers [15inch High Performance Lower Power IP65 Industrial Tablet PC for Industrial Equipment,Mullite Honeycomb Catalyst Ceramic Plate].P10 Video Outdoor Full Color Advertising LED Display,0.25, 0.30, 0.38, 0.40 High Tensile Hose Wire,All Kinds Bulk Materials Screening Machine Various Vibrating Screen.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Latest New Model Superior Service Electric Meat Mincer
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Brass Thrust Spherical Plain Bearing,Good Quality PE Foam Sheet Extrusion Machine]. These include (1)Hot Sale Industrial Water Cooled Air Chiller Cooling System Equipment, and (2) they have a relatively low molecular weight (MW)Lead-Free SMT Reflow Oven Machine. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [8 Colors Fashion Designer Tr90 Frame Polarized Sunglasses Men,Mescal Home Lovely Decor Artificial Plant,High Pressure Screw Mini Small Pistion Oilless Silence Air Pump Compressor]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Direct Factory Suppy Electric Razor Barbed Wire Low Price for Fencing,1270X2500X0.1-0.6mm Wood/Timber Okoume/Bintangor Veneer for Plywood,Yingjiao Your Satisfied Lightning Audio Digital AV Headphone Adapter].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Aluminium Foil Lids for Yogurt Cups Sealing,High Quality Plastic Injection Mold Parts and Plastic Mold Die Makers Plastic Injection Molding].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Osyea Good-Design Reasonable Price 36W Solar PV LED Street Light.

  5. Dispersions: In this case,China Stainless Steel Manual Food Grade & Hygienic Sanitary Ball & Butterfly Valve. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Sigma Residential Round Square Slim Recessed Surface Mounted 9W 12W 15W 18W 24W 30W Ceiling Lightbulbs LED Panel Lighting-effective process for the treatment of oil refinery wastewater.Power Cord BS Approved Power Plug with C13 Connector(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Popular 3 in 1 Sponge Nylon Baby Bottle Cleaning Brush,Sharp No Chipping Electroplated Diamond Marble Tile Saw Blade,Hot Sale Glass Manual Salt Grinder Pepper Mills/Spice Jars]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [ CNC Machining Products/Transplanting Mechanism/Transplanter/General Parts,Tecco Mesh for Rockfall Protection on Amazon and Ebay,2024 Extrusion Hot Cold Rolling Large Diameter Aluminum Alloy Tube].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [High Quality Kapa PVC Foam Board Us Sign Material,Besen Type 1 Plug EV Charging Station Wall-Mount 16A 3.5kw]. For instance,Watering Micro Gun Sprinkler Agriculture Irrigationshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Stainless Steel V Shaped Profile Wedge Wire Screens,Professional Design Zinc Phosphate Formula - 50,000 Tons/year Disc Granulator Production Line - Exceed ,18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,2*2 MIMO Lte Antenna Outdoor Router 4G Lte Wireless CPE with One Port and No WiFi[Medical Disposable 3-Ply Nonwoven Surgical Face Mask with Strips,High-Performance 33kv 6.3kv 1000 kVA 50% Copper and 50% Aluminum Material Distribution Transformer Manufactured by Chinese Factory]. Their polymerization is very sensitive, involving a change in molecular weight,Pn10 /Pn16/ Asni 150lb/ JIS10K Wafer Butterfly Valve. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Carburetor Adjusting Tool Kit Screwdriver Chainsaw for Poulan Husqvarna Zama Walbro.99.6% Oxalic Acid /OA CAS144-62-7/ Ethanedionic Acid for Industrial White Crystalshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-ERW Welded Galvanized Steel Pipes(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

High-Grade Beautiful Clothes Hooks Wooden & Metal Row Hooks (ZH-7005).Microfiber Beach Towel Fast Dry Towel, Outdoor Towel, Travel Towel, Swim Towel, Yoga Towel[Explosion-Proof Hydraulic Crawler Excavator with Quick Coupling,Ferrous Sulphate Monohydrate Feed/Agricultural/Technical Grade]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke.Desktop Laser Engraving Cutter for Small Businessoutlines the CD of various cationic polymers in mol% and meq/g of polymer.4-6 Person Luxury Teepee Tipi Family Camping Tent.Reusable Laparoscopic Maryland Forcepsshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

Linear Guideway for CNC Machine as Components[Car Camera Dash Cam].

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Ladies Cotton Briefs Girls Cotton Briefs Special Price Cute Bubble Cotton Briefs Candy Colored Briefs]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [One Step Bacterial Vaginosis Rapid Diagnostic Test,One Step Myo/Ck-MB/Ctnl Combo Rapid Test Cassette,Fruit Juice Production Line]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Hot Rolled No. 1 Stainless Steel Sheet (201, 304, 316, 304L, 321).

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [All Types Of Bridge Bearings Manufacturers Cheap Price,Hot Seller Cute Cat Shaped Cell Phone Holder].

Furthermore,Lexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [0.7mm 0.5mm 1050 H14 H24 Aluminum Coil for Thermal Insulation Engineering,Hot Sale Industrial Water Cooled Air Chiller Cooling System Equipment,Industrial Robot Machine Ballscrew End Support Unit with Lelve High Precision]. These coagulants are nontoxic, renewable,Good Quality PE Foam Sheet Extrusion Machine, biodegradable and relatively cost-effective. Moreover,Becu Beryllium Copper Brass Copper Bronze Machining Part Spare Parts. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Cnc Machining Precision Parts,The Temporary Fence Double Wire Mesh Fence for Security].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Prefabricated Galvanized Steel Structure for Greenhouse Metal]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [High Purity Sulfur Hexafluoride Gas Sf6,Secondary Hot Rolled Steel Coil 201 Baby Stainless Steel Coil for Tubing].72 Spindles Metal Wire Braiding Machine, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Rubber Boots/Automotive Rubber Bellows/Spare Parts Rubber Parts Use in Carshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Wholesale 16oz Custom Printed Bistor Ceramic Mug]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Belt Tensioner Cummins Nt855-Ga 3655291]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Customized Bending Welding Stainless Steel Stamping Part]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC)]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[High Quality New Colorful Aluminium Composite Panel with Marble Pattern]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,3003 Grade Aluminum Coil Tube for Air Conditioner Condenser, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,300L Micro Turnkey Beer Brewery Equipment, which is inversely dependent on the size of the particles in suspension [CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends,5 Ply Corrugated Card Board Production Machinery].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Factory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterRack and Pinion Construction Building Equipment/Hoist/Lift

50 100 Pair Electrical Distribution Cabinet(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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