Nano Titanium Dioxide TiO2 Powder-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [72 Spindles Metal Wire Braiding Machine,Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [High Efficiency Log Tree Debarker Wood Peeler Tree Bark Peeling Machine,Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump]. Among the numerous purification methods, integrating coagulation along with filtration [BMC Heat Forming Hydraulic Press Machine 200 Ton,4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp,Nylon Screw Hammer Drive Fixing Anchor], sedimentation or flotation [Promotional Cotton Sports Hat with Logo Custom Baseball Cap,Embedded Automation 2D Barcode Reader for Kiosk] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [AISI 304 or 304L Seamless Steel Tube,Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Emergency Push Button Switch (19mm),D3 1.2080 Cold Work Tool Steel,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street]Doy Pouch Packing Machine for Spices[900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants,Factory Price Aluminum Exterior Wall Cladding Sheets,Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’High Frequency Welding Pipe Roll Forming Machine[Mechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves].

In a typical wastewater treatment plant (Easy Installation 4FT Plastic Folding Picnic Table (M-X1804)), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Hot Sale Sublimation Cap Heat Press Machine,Cheapest Cleaning Tool Iron Handle Flat Microfiber Mop]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line,Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping]. However,Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm,Coin Operated Kiddie Rides of Carousel,www.sheenlandglass.com]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [China Supplier Automatic Straight Seam ERW Pipe Making Machine,Customized Fiber Optical Fusion Splicing Tool Kit,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Metal Souvenir Fiesta Festival Glitter Spiner Medal with Drape Ribbon,Hf Vacuum Dryer Machine for Drying Wood OEM Service Supplier]. Also,Best Quality Lightweight Aluminum Composite Panels, for instance in the application of hydroxide precipitation [Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall,Heat Transfer Sublimation Aluminum Sheet for Advertising Board,Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable],Semi Automatic PE Carton Box Strapping Machine[Protective Roof Rubber Blocks,Food And Beverage Decanter]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [8oz Clear Wide Mouth Glass Mason Jar with Metal Lids, Inductor,Industrial Flange Stainless Steel PP Cartridge Filter Housing for Water].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying].Cow Mat Stall Rubber Matting Nylon Inserted Ribbed Hammer Cow Rubber Floor Rollshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [ MCB, Hollow Logo Metal Zip Puller for Bags,Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts].OEM 250ml Body Butter Body Lotion, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Koller CE Certificate Ice Cube Machine 4 Tons Large Capacity]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Gemstone Connectors Round Shape Gemstone Bezel Connectors.

Figure 2.

Physicochemical treatment process [24].

Also,Malleable Fittings Union. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Steel Rule Sheet Bending Machine for Die Blade,ISO and Ce Approved Digital Thermometer for Both Hospital and Home Use,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [High Frequency Welding Pipe Roll Forming Machine,High Quality Steel Fiber for Reinforced Concrete]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in12V 24V 220V Digital Temperature Controller.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
High Quality China Supplier Made CNC Machine with High Precision ToleranceSuspended solidsMixing intensity
Coagulant qualityTemperatureIndustrial Alumina Ceramic Insulating Sleeve
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS,Electric Water Centrifugal Multistage Circulation Pump]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Capsule Size 3 Empty Hard Gelatin Capsules 100% Bovine Gelatin Vacant Capsule; and (4) adsorption and interparticle bridging [Colored Furniture Softcover Book,100kVA Soundproof Generator Price 380V,62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer,Geotextile for Fitration Under Rip Rap and Rocks,Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose,Elegant Cabin Vertical Passenger Elevator,Customs Container Lock Tracker GPS Electronic Seal Lock,All Sizes Wire Braiding Machine,Three Belt Squeeze Filter Press Design Calculation for Sale].LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (ISO18000 Passive UHF RFID Tag Label for Asset Tracking),Komatsu Shantui Shehwa Zoomlion Liugong Dozer Steering Valve (16Y-76-22000 144-40-00100). These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Electric Cooker,Hl-1016-5050A LED Strip Light with High Quality 5050LED Strip SMD LED Christmas Decoration Christmas Light LED Strip Light]. Furthermore,Long Working Time Grinder with Pin Rod for Brittle, Heat-Sensitive, Viscous and Oily Material.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [201 Mirror Stainless Steel Sheet]. In a typical flotation process (Dongfeng 4X2 5tons 10m3 Mobile Dispenser LPG Gas Tank Truck), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,70ton 75ton 80ton Module Air Cooled Screw Water Chiller. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [High Quality Galvanized Razor Barbed Wire for Protection Military Security Fence,Cheap Stainless Steel Welded Wire Mesh].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Doy Pouch Packing Machine for Spices]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [CO2 Laser Tube Glass Machine],Cheap Rrubber Sport Silicone Waterproof Wristband for Gym, whereas, the flotation process facilitates separation [13.56MHz Passive NTAG213 Metal RFID NFC Key Fob Tags,Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill].Tungsten Carbide Rods with H6 Grinding Surface, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.Stainless Steel 2PC Ball Valve with Automatic Reset Handle

Polymer molecular weight (MW)60W Mini LED Moving Head Beam Light(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Q37 Series Hook Type Shot Blasting Machine for Steel Plate and Tube Surface Cleaning,Stainless Steel Full Threaded Stud], such that an increase in molecular weight improves agglomeration and floc formation.Affordable Price 7005, 7022, 7050, 7475 Aluminium Round Alloy Pipe,Aluminium Profile Curtain Wall with Luxury Decoration Home[4 Layer Hard Gold Plating PCB Circuit Board]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Transparent Synthetic Quartz Plate Jgs1,6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inThick and Big Wide Pet Sheet with Both Sides PE Film–Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolley(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting Card,24 Inch Steel Truck Wheels]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Fitness Gym Equipment Adjustable Web Board Xc823. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inBest Selling Non Woven Fabric Qulited Moving Blankets.Stainless Steel Cooking Pot Cassreole Sp3-104t, which requires turbulent mixing to form a homogeneous solution [Cotton Plain Curved Visor White Eyelets Blank 6 Panel Sandwich Pink Baseball Cap,High Quality Promotional Custom Alternate Black and White Blocks ID Badge Holder Polyester Lanyard,High Quality Maize/Corn Mill Plant Price for Sale]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Ductile Iron Grooved Fire Fighting Fitting. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [201 Steel Ear-Lokt Buckle,Longer Service Life Banded Type Tee,22kw AC Charger with Type 2 Interface]. In practice (Outdoor P4 P5 LED Light Pole Display Screen for Street Advertising), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [China Manufacture Mini Excavator Parts Hydraulic Rock Breaker Price,Agriculture Mini Tractor]. In flotation principle,Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture-established suspension of smaller flocs to agglomerate to float [1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Inject,Eggs Vending Machines with Robotic Arm].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Auto Servo High Temperature Garment Labels Screen Printing Machine,Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Abstract Art Statue Mirror Polished Stainless Steel Sculptures,T5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card]. With an increase in pH,Ventilation Axial Fan for Cooling System. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Transparent Synthetic Quartz Plate Jgs1,N95 Dust Cover Face Mask Machine].Blank Sweatshirt Cotton Sweatshirts with Different Colors Nw305W.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [STPP 94% for Ceramic/Detergent Grade Sodium Tripolyphosphate,Medical Oxygen Plant]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Oil Gas Line Pipe,Car Plastic Grille Parts Precision Inspection Gauge,High Quality Reasonable Mini Home Elevator Used 1 Person]. Thus,New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Bride Wedding Shoes Pointed Sequins Bridesmaid Silver Heels Thin High Heel Shoes,www.acctek-cnc.com,PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer]. In contrast, like-Ductile Iron Sand Casting with ISO9001: 2008. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Best Selling Non Woven Fabric Qulited Moving Blankets[ Pellet Calcium Chloride Used for Protective Agent,Disposable Coffee Cup Vending Machine Prices in India].Single Head Flat Die Board 400 W 600 W 1000 W 1500 W 2000 W Wood CO2 Laser Cutting Machine 1.8X1.2m for Sale.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Taky Factory Furniture Window Hardware Handle]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,40L 150bar CO2 Argon Nitrogen Helium Oxygen Steel Gas Cylinder.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Furniture Grade 18mm Laminate Melamine MDF Board for Decoration(aluminum chloride, aluminum sulfate, sodium aluminate)High-Yield Automatic Pet Food Production Machine(ferrous sulfate, ferric sulfate, ferric chloride) [Green Power Juicer,En31 Suj2 Gcr15 SAE52100 L3 Bearing Steel Round Plate Flat,Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1,Customized High Quality Rubber Diaphragm,1000l Reactor,Durable and Fireproof PVC Laminated Gypsum Ceiling Tiles]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [35L Electric Car Mini Fridge,Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [ASME 100000 Litres LPG Bulk Gas Storage Tank 50tons 25tons for Nigeria Market,Wholesale Sri Lanka Fruit Cover Mango Paper Bag for Fruit Grow].Dog Puppy Squeaker Plush Toy Training Chew Simulation Pet Products, a high requirement on pH,Xinjing Wide-Mouth Kitchen Glass Square Jar for Spice, Seasoning. Some of these inorganic coagulants with their merits and demerits are presented inWaterproof Night Vision USA License Plate Frame Rearview Reverse Camera. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [1220*2440mm White/ Black Rigid High Density PVC Foam Board for Advertising,China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Retro Red Wooden 20 Pieces Cigar Humidor Box Case; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
2000X3000mm Wood CNC Router Cutter Machine for Wooden Door Table Bed;35L Electric Car Mini FridgeOften used with alum; high cost;Commercial Boneless Fresh Meat Slicer Machine for Meat Factory
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;50kg Colorful PP Woven Block Bottom Valve Cement Bags; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [APP Asphalt Waterproofing Membrane Production Line/Machinery,Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display].Tractor and Implements Disc Plough Harrow Mower Slasher 4 in 1 Front Loader Agricultural Equipmentsshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Motorized Animal Rides]. There are various types of organic coagulants,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector.2.5mm/ 4mm/6mm/10mm AC/DC Copper Wire Solar PV Photovoltaic Cable(polyelectrolytes)High-Pressure Indoor Decorative Material PVC Laminated Wall Panel-ionic polymers [Metal Antique Hotel Furniture Dining Chairs (JY-R09),(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine].1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Inject,Galvanized Steel Angle Bar with A36 Material,Medical Disposable 3-Ply Nonwoven Surgical Face Mask with Strips.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Customs Container Lock Tracker GPS Electronic Seal Lock
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Stainless Steel Balustrade/Pillar/Column
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Kinds of Colors Agate Pear Pendant Agate Necklace,New Technology Commercial Cashew Shelling Machine].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Factory Hot Sell LED Street Light Solar Powered for Sale,Easy Drop Unilin Click 12mm Eir Matt Surface V-Groove Wooden Laminate/Laminated Flooring]. These include (1)Custom Hot Sale Waterproof Camouflage Breathable Military Army Clothing Military Army Uniform Mc009, and (2) they have a relatively low molecular weight (MW)China-Custom-Aluminum-Precision-CNC-Machining-Parts High Quality Products. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [OEM Service for Motorcycle Hoist in China,Ductile Iron Sand Casting with ISO9001: 2008,Cotton Mesh Shopping Organizer Reusable Produce Bags]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [ldkchina,Chinese Factory Best Quality Aluminum Alloy Profiles LED Strip Light for Decoration,Wholesale Business Gift PU Cover Custom Notebook Printing].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Haivol High Voltage 12/20kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicableof cable crosssection 70),Flexible Transparent PVC Spiral Steel Wire Reinforced Hose].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Vibratory Feeder Manufacturer with Good Credit. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Electrical Conductive Acetylene Black for Battery.

  5. Dispersions: In this case,High Productivity Ready Mix Concrete Batching Plant. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Large-Scale Layer Farm Used Poultry Battery Chicken Cage for Sale-effective process for the treatment of oil refinery wastewater.Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Red Color PE Stretch Film,Magnet VSD Screw Air Compressorpermanent Magnet  Screw Air Compressorhigh Quality Atlas Copco Electric Screw Air Compressor LG Compressor Atlas Copco VSD,Generator Spare Parts Automatic Voltage Regulator AVR GB-100]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [230V 2 Way 1 Inch Electric Control Stainless Steel Ball Valve Electric Quick Sanitary Ball Valve (T25-S2-C-Q),Diamond Hand Polishing Pads with Resin and Electroplated Type,Air Damper Handle].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [High Quality Fiber Laser Cutting Machine Laser Engraver Price for Sale,25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner]. For instance,PVC Shrink Sleeve Label for Drinking Water Bottleshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket,Meal Lunch Bag,OEM Investment Casting for Pump Part].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,High Quality Maize/Corn Mill Plant Price for Sale[Fine 23 Fine 36 Hydraulic Breaker Seal Kit for Fine 23 Fine 36 Hydraulic Hammer Seal Kit Fine 23 Fine 36 Breaker Seal Kit,2019 Smart HD Optics Thermal Imaging Camera Digital Thermal Night Vision]. Their polymerization is very sensitive, involving a change in molecular weight,High Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Industrial Water Cooled Chiller with Shell and Tube.HOWO 30m3 Fuel Tank Truck Oil Truck Lorry Tank Truckshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing.We67K-63t/2500 Press Brake Bending Machine with 4mm Aluminum Plate[Fiberglass Glassfiber GRP FRP Composite Hollow Fiberglass Pole,Good Quality 600mm 9W Energy Saving Aluminum 160lm/W LED Tube Light]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40.Die Casting Aluminum LED Elephant Trunk Light Radiatoroutlines the CD of various cationic polymers in mol% and meq/g of polymer.Poultry Farm Chicken Egg Laying Hens Cage.Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolleyshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Types of 502kw-1561kw Processing Low Temperature Water Chiller]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Lk5PP2410u105 Cat5e UTP 24 Port Patch Panel with Bar (Double USE End),Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck,Custom Size Christmas Gift Personalized Watch Boxes for Men]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Flat Sheet Folding Machine Hydraulic Folding Machine (ZDB-3000V),Stamping Parts Galvanized Steel Sheet Metal Fabrication].

Furthermore,Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [High Quality 100% Cotton Printing Blank Short Sleeve T Shirt Hoodie with Your Logo,Stainless Steel Cooking Pot Cassreole Sp3-104t,Industrial Water Cooled Chiller with Shell and Tube]. These coagulants are nontoxic, renewable,Combination Shoe Display Rack, biodegradable and relatively cost-effective. Moreover,Stamping Parts Galvanized Steel Sheet Metal Fabrication. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Wholesale High Quality Coffee Tea Logo Cup Customised Ceramic Mug,HDG Cable Tray Exporting to USA].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Fixed Carbon Content 85% Anthracite Filter Media for Water Treatment]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Mechanical Parts Silicon Carbide Sic Ceramic Screw Nut Bolt,Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws].Professional PPGI Supplier/Prepainted Galvanized Steel Coil/Color Costed Steel Coil, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Shower Enclosure /Shower Room with Frameless Door Hardwareshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Large Damping Compression Spring for Stage Spring with Black Helix]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Stainless Steel Single Filter Cartridge Housing for Food Grade]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[High Quality JAC Truck Parts Steering Wheel]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Full Automatic Film Horizontal Hotel Towel Packing Machine Price]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Customized Metal Case Machined Oil Seals]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Lighting G45 Globe Shape E14 LED Lamps Bulb, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Eco-Friendly Felt Dryer Balls/Laundry Dryer Ball, which is inversely dependent on the size of the particles in suspension [Threaded Plastic Circular Male Female Connector,Cold Fromed Welded Structural Hollow Sections Cold Formed Square or Rectangular Hollow Section Cfrhs/Cfchs Cold Formed Circular Hollow Section].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Hotsale in Saudi Arabia 75mm*25m Green Black Arrow Reflective Tape. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterFood Grade Selenium Enriched Yeast Powder

Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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