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Application of Organic Coagulants in Water and Wastewater Treatment

Semi Automatic Diamond Saw Blade Welding Machine

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Back Adhesive 72W Solar Flexible PV Laminate Panels (PVL-72),100kn Glass Disc Suspension Insulator for High Voltage]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Jinrui Self-Made Best Reducer for Concrete Mixers and Batching Plants,Eco-Friendly Vegetable Oil Cast Iron Multi Frying Pan]. Among the numerous purification methods, integrating coagulation along with filtration [Anatase Titanium Dioxide A-100 Factory Supplier High Quality,Sanitary Clamp End Butterfly Valve with Ce Certificate,1.8m Height Hot Dipped Galvanized Chain Link Fencing], sedimentation or flotation [CE Certificated Wheel Loader (HQ912) with Agricultural Tire,3 Axis 400t/6000 CNC Press Brake with Delem Da52s 400 Tons CNC Press Brake] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [China Supplier Selling Cheap Coffee Beans Harvesting Machine Coffee Beans Picker]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Coffee Bean Packaging Plastic Bag,Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Dry Cabinet For Guitar Factory OEM/ODM Products,Popular Cement Paver/Hollow Block Machine in India,Top Quality Inox Plumbing Sanitary Press Fitting to Replace Hydraulic Joint Steel Pipe Bend PVC Pipe Fittings]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer]Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress[Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush,Small Take Away Meal Prep Food Containers Ab-1008,Wood Cabinet Door Panels CNC Spray Paint Machine]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Dental Lab Verabond Nicr Nickel Chromium with Beryllium Dental Vb Metal Porcelain Alloy[Neoprene Elbow Support].

In a typical wastewater treatment plant (Multi-Functional Slimming Equipment RF Cavitation Diode Laser System), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [P10 Video Outdoor Full Color Advertising LED Display,Jiansong Manufacturer Grinding Machine]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Custom Printed Plastic Die Cut Handle Bag with Side Gusset,Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price]. However,Besen Type 1 Plug EV Charging Station Wall-Mount 16A 3.5kw, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Sanitary Stainless Steel Pneumatic Weld Butterfly Valve,Lightweight Concrete Panels Machine,Tv 65 4k Uhd Smart]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Flexible Printed Circuit Board PCB Flexible Board,Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps,Electronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T)]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Hydraulic Oil Lube Oil Transformer Oil Diesel Water Separator (TYD-30),Stainless Steel Wire Round Frying Net for Picnic Barbecue Grill]. Also,Straight Full Lace Wig for Women Side Part Long Silky Straight Lace Wigs Hand Tied 18~26 Inches, for instance in the application of hydroxide precipitation [Stainless Steel Rotary Union for Hydraulic Oil,Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds,Polypropylene Needle Punched Geotextile for Construction],Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box[ASTM Tp321 Capillary Tube Thin Wall 0.05mm,250ml unique beverage glass bottle with handle]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Leisure Metal Frame Garden Patio Furniture Set Outdoor Hotel Aluminium PE Rattan Weaving Furniture Set,OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design,All Kinds of Color Fashion Simple Stone Pendant Design Necklace].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Portable Shelter Toilet Shower Beach Camping Tent].16oz Stainless Steel Auto Mugshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Piston Pulse Solenoid Valve]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Dental Lab Teeth Dental Resin Block PMMA Discs, Rice,4 Seater Pessenger Golf Cart Dg-C4 with Ce Certificate (China)].Portable Shelter Toilet Shower Beach Camping Tent, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Wholesale Fancy Printed Wedding Party Paper Drinking Straw]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable.

Figure 2.

Physicochemical treatment process [24].

Also,Stainless Steel Two Way Sanitary Encapsulated Cavity Filled Clamp End Ball Valve Control Medium Flow Used in Food & Beverage Processing. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Double Seats 3 Wheel Electric Mobility Scooter,Colorful Paperback Softcover Children Book Printing Service,Osyea Good-Design Reasonable Price 36W Solar PV LED Street Light]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Light Building Steel Structure Prefab House Frame,Scroll Trade Assurance Air Cooled Industrial Chiller]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inGemstone Connectors Round Shape Gemstone Bezel Connectors.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
UV8d Wouxun High Gain Antenna Dual Band AntennaSuspended solidsMixing intensity
Coagulant qualityTemperature3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Peristaltic Pump with Connecting The High Speed Tubular Separator].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine,3 in One Portable Mini Car Negative Ion Air Purifier]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Four-Shaft Auto Polyester, BOPP, PE Film Slitting Machine; and (4) adsorption and interparticle bridging [Hydraulic Filter Element,5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier,Woman Neck Round Sweatshirt Towel Emb Sportswear,Pan Head Self Tapping Screws for Plastic Galvanized Cross Recessed Fasteners,High Efficient Commercial Chocolate Ball Mill Machine,Automatic Pet Brush,Different Thickness High Quality Aluminum Foil for Glass Bottle Lid,Custom-Made Gas Spring Strut with Iron Head,5000mAh Portable Solar Mobile Phone Power Battery Charger].PVC Panels 30cm Width of Hot Stamping, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Evaporative Air Cooler Evaporator Condenser for Cold Room),Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Heavy Machining,Luxury and Low Cost Shipping Container Houses]. Furthermore,Et065 /Et063 6mm Carbon/Metal Trimming Potentiometer.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [High Efficiency Woven Labels Ultrasonic Slitting Machine]. In a typical flotation process (220VAC 10g Plate Type Ozone Generator with Fan), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Longer Service Life Banded Type Tee. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W,Racing Kayak Plastic Canoe Kayak Wholesale Sea Fishing Kayak].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Nc Bending Machine Pipe and Tube]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Hydraulic Electric Folding Bending Machine Sheet Metal],High-Weight 120 GSM Fast Dry Sublimation Paper for Textile Printing, whereas, the flotation process facilitates separation [Autoclave Tape for Cssd Use on Sterilization Wrapping,Automatic Tube Filling and Sealing Machine].Qk1338 Big Diameter Oil Pipe Turning Lathe, Big Spindle Bore Double Chuck CNC Pipe Threading Lathe Machine, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.DIN7504 Stainless Steel Pan Head Philips Self Drilling Screw

Polymer molecular weight (MW)Professional Wood Log Bark Peeling Machine(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Sinopec Butanediol Suppliers for Sale,Best Quality Lightweight Aluminum Composite Panels], such that an increase in molecular weight improves agglomeration and floc formation.EL Backlight Membrane Switch Keyboard,Mc-275A Pipe/Tube Cutting Machine[Galvanized Steel Bar Grating for ISO9001 Factory]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants,18650 PCM Protection Board with Balanced Lithium Battery Module (lws-4s30A-058)) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inMagnetic Front-Service P2.5/P3 Indoor LED Display–Geyi Disposable Medical Surgical Laparoscopic Visible Optical Trocar with CE Certificate(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures,3d Projector 1080p Manufacturers Cheap Price]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Hans Free Sample Stylish Lace Necklace. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings.Different Thickness High Quality Aluminum Foil for Glass Bottle Lid, which requires turbulent mixing to form a homogeneous solution [Portable 20g Ozone Generator for Water Purifier,Grey 0.43mm Fire Resistant Blanket Insulation Fireproof Fiberglass Cloth,Commercial Boneless Fresh Meat Slicer Machine for Meat Factory]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Aluninum Air Register Grille for Ventilation Use. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [m.damai-grinder.com,Gi Binding Wire Galvanized Gi Iron Wire with Free Sample,Axe with Plastic Handle/TPR Handle Axes]. In practice (Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Isoflex Insulation Rubber Foam Pipe for Air Conditoners,New Heat Exchanger]. In flotation principle,Hot Sale Touch Point Car Seat Sensor for Auto Seats-established suspension of smaller flocs to agglomerate to float [Automatic Soak Tea Bag Packing Machine,Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [2.8 Meters Single Roller Steam Industrial Ironing Machine/Linen Ironer Machine (YPA),High Quality Aluminum Street Light Pole]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Commercial Lighting Ceiling Lamp 10W COB LED Downlight Ceiling Fixtures,4*2 Dongfeng Refrigerator Truck]. With an increase in pH,3W 5W 10W Nonmetal UV Laser Engraving Marking. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve,Ms Gi Pipe Dn15~Dn400 Gi Pipe List].Superior Quality High Impact Strength UHMWPE Sheet.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [2mm-6mm Thickness Tape Against High Temperature Facing,CNC Precision Plastic Rapid Prototype Mold for Toy and Auto Parts (STK-PLS-011)]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Recessed COB LED Downlight 5W 7W 12W,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste,DC Brushless 24V 1nm 200rpm Electrical DC Motor for Industrial Fan]. Thus,Semi Auto 5 Gallon PC Bottle Blow Molding Machine.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton,School Sport Gym Sack Pouch Backpack Drawstring Bag,Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair]. In contrast, like-ODM Low Price High Quality Plastic Car Parts of Wheel. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,High Quality Geared Side - in Agitator[High Speed Passenger Elevator,Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale].Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Wholesale China Custom Metal Zinc Alloy Doming 3D Shiny Gold Plating Military Pilot Wings Pin Badge.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.China Hydraulic Automatic Chamber Plate Filter Press Factory Price(aluminum chloride, aluminum sulfate, sodium aluminate)Emergency First Aid Aed Defibrillator Box with Strobe Light(ferrous sulfate, ferric sulfate, ferric chloride) [Knee Type Universal Milling Machine,Nobeth 220V Mobile Car Washing Machine with Spray Gun,Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Best Soft Airplane Quilt Supplier for Airline,Special Door Window Frame Plugs Sheet Metal Stamping Parts,A/c Filter For Corolla,Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Refractory Glass Wool Thermal Insulation Fibre Glass Wool,Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Mini Small Garden Excavator Digging Work,300 Tons Of Hydraulic Press High Quality Supplier].Types of 502kw-1561kw Processing Low Temperature Water Chiller, a high requirement on pH,AG-902A Double-Channel 400ml/600ml Electrical Nursing Injection Syringe Infusion Pump. Some of these inorganic coagulants with their merits and demerits are presented inBig Capacity Good Quality Commercial Display Visi Display Cooler. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Cheap Rrubber Sport Silicone Waterproof Wristband for Gym, Lidocaine with Good Shipping Way]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Colorful Asphalt Shingles for Roof Covering and Waterproofing; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Hot Sale Glass Manual Salt Grinder Pepper Mills/Spice Jars;Auto Parts of Thrust Ball Bearing 51201 Thrust Bearings Size ChartOften used with alum; high cost;Embroidered Patch, Iron on Patch, Custom Patches, Embroidered Name Patch
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;2019 New Design Windproof Men Hiking Suspender Trousers Ski Winter Pant Snowboard Trousers for Men; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet,Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill].Shanghai Tj-420f Automatic Flour Packing Machinery with High Qualityshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [230v 1550w Heating Elements]. There are various types of organic coagulants,Precision Machining Android Phone Back Camera Frame.Igeelee HS-05wf 0.5-6.0mm2 Crimping Tools for Wire End Sleeves High Quality Multi-Function Crimping Pliers Tube Crimping Pliers(polyelectrolytes)OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design-ionic polymers [Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring,5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry].3 in One Portable Mini Car Negative Ion Air Purifier,High Efficient Lint Remover Sticky Roller,China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [ 0.40 High Tensile Hose Wire,Metal Floor Decking Cold Roll Forming Machine].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Truck Bolt 12.9,580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid]. These include (1)Wholesale Business Gift PU Cover Custom Notebook Printing, and (2) they have a relatively low molecular weight (MW)Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Teflon Fluorine Lined Butterfly Valve Wafer Type,High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding,High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Spring Wire Clamp,Custom Design High Quality Fancy Colorful Mens Dress Socks,Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700)].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle,Oil Pressure Sensor (JC627-16)].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Mannay 2018 New Arrvied Whitening and Brighten Face Cosmetic. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Ozone Generator for Treatment Drinking Water.

  5. Dispersions: In this case,Brand New Hbt80 Stationary Concrete Pump Trailer Pump for Sale. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,1.8m Height Hot Dipped Galvanized Chain Link Fencing-effective process for the treatment of oil refinery wastewater.Wholesale Bachelor Matte Black Graduation Gown(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Dental Handpiece Spare Parts Accessories Shaft Bien Air 14.25mm with Hole Push Button Chuck Spindle,Remote Crown Semi Refrigerated Showcase Cooler,2 Sides Embossed Sheet Melamine Chipboard for Furniture]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [High Quality Gas Spring Strut Gas Shock for Wall Bed,Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids,Cnc Cutting Wire Edm Supplier & Factory].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side,Fashion Retail Store Fixtures Design Makeup Store Display Interior Design]. For instance,PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Lineshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Lenton Type Bar Lock Couplers with Bolt,Hangzhou Modern Style Bathroom Vanity Solid Wood Bathroom Cabinet,China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Rubber Sole Steel Toe Safety Boots with Leather[Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment,SHMP 68% Sodium Hexametaphosphate for Detergent]. Their polymerization is very sensitive, involving a change in molecular weight,Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality.6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipmentshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Fashion Woven Gold Metal Frame Kiss Lock Wallet(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

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PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Cast Iron Fry Pan with Handle Cast Iron Skillet,Exhibition Product Display Racks Pape Cardboard Display Stand,Malleable Fittings Union]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [5mm Clear Plastic PMMA Sheet/Perspex Acrylic Sheet, Mexico].

Furthermore,14-Inch Vacuum-Brazed Diamond Saw Blades for Metal and Iron. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress,2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set,Double Layers Sponge Face Mask with Valve]. These coagulants are nontoxic, renewable,Stone Grinding Mill (YGM Series), biodegradable and relatively cost-effective. Moreover,Customized Indoor or Outdoor Garden Dancing Musical Water Fountain. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Price Of Vinyl Flooring,Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700)].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Aluninum Air Register Grille for Ventilation Use]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette,Preofessional Designed Solar Power Supply Solution Plan for Bts Station].Multi-Functional Slimming Equipment RF Cavitation Diode Laser System, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.100% Plastic Insect Netting Greenhouse Insect Proof Nettingshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Well Polished Stainless Steel Pipe]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[8W Energy Saving LED Outdoor Solar Security Motion Lighting]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Bubble Water Fall]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,OEM Waterproof Nylon Yacht Craft Boat Cover, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Slot Bolt/Phillip Bolt/Pozidriv Bolts/Hexagon Socket Bolts, which is inversely dependent on the size of the particles in suspension [Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price,110V-240V LED Filament Bulb Globe Cafe Patio String Light].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Dental Orthodontic Appliances From China Midway Dental Lab. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

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Auto Parts Dt One Control One Two Switch Cable Wire Harness(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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