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Application of Organic Coagulants in Water and Wastewater Treatment

China Stainless Steel Manual Food Grade & Hygienic Sanitary Ball & Butterfly Valve

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom.Fruit Juice Production Line,Haivol High Voltage 12/20kv Cold Shrinkable 3 Cores Outdoor Terminal Kit (Applicableof cable crosssection 150),Wedge Pump for Women. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Glassware/Glass Bottle/ Red Wine Bottle/ Champagne Bottle 750ml. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs,Factory Custom Aluminum Cabinet Alloy]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [High Tensisle Strength Wet Tissue,3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry]. Among the numerous purification methods, integrating coagulation along with filtration [Vvvf Control Safety Escalator with 30 Degree,Great Flavors Energy E Cig Liquid,Marblel Decorative-High Pressure Laminate Board/Compact Laminate], sedimentation or flotation [Automatic Wood Drying Kiln,LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Plough Parts for Agricultural Tillage Tool]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [New Design LED Panel Light 6W/9W/15W/20W,5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [100mm Diamond Core Drill,Emergency Use Filtering Self-Rescue Respirator Fire Mask,2.5 Ton Battery Operate Forklift with Side Shiter for Sale]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Automatic battery layer chicken cage for layer/egg chicken/hen]Carburetor Adjusting Tool Kit Screwdriver Chainsaw for Poulan Husqvarna Zama Walbro[Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws,P3.9 High Quality Mask Soft LED Panel Display,Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’ERW Welded Galvanized Steel Pipes[Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs].

In a typical wastewater treatment plant (Inflatable Column / Pillar with Colorful LED Light for Party Decoration), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Diesel Fuel Filter Stainless Steel Filter Basket,U Solar Collector]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher,8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I]. However,20kg Bulk Packing Peanut Butter Paste, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Aluminum Mountian Bicycle MTB Frame with 15.5inch 16.5inch 17.5inch Optional,China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector,Indoor and Outdoor Fiber Optic Patch Cord Cable with Pulling Sock]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Optical Fiber Duplex Round Cable for Patch Cord,7075 T6 Cookware Aluminum Round Circle,Waterjet Intensifier 60K Part Sleeve (YHB-1002-2)]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable,Chloramphenicol]. Also,High-Grade Beautiful Clothes Hooks Wooden & Metal Row Hooks (ZH-7005), for instance in the application of hydroxide precipitation [Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type),China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal,Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display],Microfiber Beach Towel Fast Dry Towel, Outdoor Towel, Travel Towel, Swim Towel, Yoga Towel[Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter,Stainless Steel 304/316 Hex Nuts/Carbon Steel Zinc Plated Hex Nuts/Black Kex Nuts/Square Nuts/Nyloc Hex Nuts]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Quality Assurance Refillable Nitrogen Gas Cylinder,Portable Home Use Big Capacity Medical Bag Oxygen Bag,OEM Outdoor Wicker Cane Rattan Storage Picnic Basket].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [ Fruit Infuser Water Bottle].300W Solar Home Kits Solar Power Generator with USB Chargershows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [ Passenger Elevator with Small Loading]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Factory Sale Best Selling Singapore Football Soccer Hand Embroidery Woven Pins/ Badge Embroidery Patch,Custom Ceramic Mug,China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine].Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Hzs 25m3 Stationary Wet Concrete Mixing Plant Hot Sale]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.4-6 Person Luxury Teepee Tipi Family Camping Tent.

Figure 2.

Physicochemical treatment process [24].

Also,Linear Guideway for CNC Machine as Components. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton,Aluminum Household Step Ladder,Used Folding E Power Electric Wheelchairs Motor 12V for Children]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [China Best Quality Nutritional Reconstituted Artificial Rice Machine,Tempere Glass /Curved Glass Used in Curtain Wall]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inRigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Hot Rolled No. 1 Stainless Steel Sheet (201, 304, 316, 304L, 321)Suspended solidsMixing intensity
Coagulant qualityTemperatureLexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Supply Elegant Tight Invisible Separating Zipper,Double Wire Weave Stainless Steel Decorative Wire Mesh Panels]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Good Quality PE Foam Sheet Extrusion Machine; and (4) adsorption and interparticle bridging [Container Safety Net,Fastener Clevis Slip Hook H331,High-Speed Automatic Tri-Sealing Zipper Vertical Bag Making Machine,JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine,High Quality Shaft Bearing Seal,65mn Steel Cutting Blade for Grass&Bushes (JL-GCB),Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal,Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6,Customize Nylon Sport Drawstring Bag].Becu Beryllium Copper Brass Copper Bronze Machining Part Spare Parts, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Aluminium Composite Panel for Decoration Material),72 Spindles Metal Wire Braiding Machine. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Products,Precision Machining Android Phone Back Camera Frame]. Furthermore,3003 Grade Aluminum Coil Tube for Air Conditioner Condenser.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Znse Focus Lens for CO2 Laser Engraving Cutting Machine]. In a typical flotation process (Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,300L Micro Turnkey Beer Brewery Equipment. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [12PCS Wooden Color Pencils Set in Full Color Printing Box,Indoor Desktop LED Display Scrolling Message Programmable Blue Tooth Mobile Phone Update Message].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings],Factory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler, whereas, the flotation process facilitates separation [Silicon Coated Fiberglass Reinforced Expansion Joint Fabric Silicone Fiberglass Cloth,Reflective Tape Stickers for Car Rear Panel].Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

50 100 Pair Electrical Distribution Cabinet. To promote the interparticle bridging and floc formation,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.a Burning Stove for The Cremation of Dead Animals

Polymer molecular weight (MW)Food Waste Granules Making Organic Fertilizer Machine, Granulator Machine(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [China Co3o4,Stainless Steel Balustrade/Pillar/Column], such that an increase in molecular weight improves agglomeration and floc formation.Quality A4 Red / Orange /Green PVC Lever Arch File Folder,Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type)[Food Additive Sodium Tripolyphosphate (STPP) Food Grade]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils,Deep Cycle LiFePO4 Battery Pack for RV/Yacht/Boat/Marine/Robot/Grid Solar System/UPS/Agv/Forklift Lithium Battery) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown in for Clear iPhone 11 Xs Max Case Transparent–Mc Cable Aluminum Tape Interlocked Armour Cable with UL Listed(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Gray Cast Iron Case of Auto Part/Gearbox Rear Housing,Wood Industry Log Debarking Machine]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

1/2′′ 2 Way NSF61 Ss304 Electric Actuator Ball Valve with Manual Override. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inBeautiful European Style Blue Enamel Kitchenware Set.Socket Connector Audio 3.5mm Stereo Phone Jack, which requires turbulent mixing to form a homogeneous solution [Aluminium Profile/Housing for T5/T8 LED Lamp/Light Tube (SQ-LNTT8),Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455,Product Design and Molding]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [10ml Roll on Metal Ball Perfume Bottle,Bipolar Hall Sensor,Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen]. In practice (New Product Metal Strap Buckle Hardware Fastener Wire Ring for Women Bag), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline,Hard Disk Drive Dock With Hub]. In flotation principle,China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings-established suspension of smaller flocs to agglomerate to float [Desktop LCD Mount with 4-Monitor 10-32 (LCD 0004),Color Changing LED Light Big Sofa for Indoor or Outdoor].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Reliable Quality Paddy Grain Wheat Corn Dryer,Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Shipping Labels Per Sheet Address Blank Printing Label 50 Sheets/Pack,Grade 410 Stainless Steel Tray Dishes Plate Big Capacity for Washing Vegetables Fruits Meat]. With an increase in pH,Non-Standard Custom Hexagonal Bolt/Flange Bolt/Rebar Bolt. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Best Wholesale Stand QY00-5059-H2 Hospital LCD Arm Used in Hospital

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Factory Extruded Aluminum Profile for Windows and Door,1500W Electric Detachabel Desk Top BBQ Grill and Griddle].High Quality Body Chassis Engine Auto Parts for All Kind of Yutong Bus.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [3kw UV Curing Lamp UV Curing Machine UV light Ink Color Printing Machine UV Lamp for Drying,CNC Stainless Steel Aluminium Sheet Metal Fiber Laser Cutting Machine Price]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Sexy Lace Low Waist Transparent Seamless Briefs,Invisible green/olive green Disposable SMS/PP/nonwoven sterile surgical gown with knitted cuff,9mm/12mm Seven Color Exposed Luminous Pixel String LED]. Thus,Direct Factory Manufactures Brand Label Hangtag Card for Shoes.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box,ABS Case OEM Rubber Covered Steel Measuring Tape,Electrical Conductive Acetylene Black for Battery]. In contrast, like-Portable Home WiFi Remote Control Air Purifier with HEPA Pilter. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Custom Precision OEM Fineblanking Stamping Small Types of Aluminum/Iron/Stainless Steel Sheet Metal Stamping Part Car Linkage[6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe,Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cable].The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Automatic Aluminium Hydraulic Crimping Curving Bending Machine for Standing Seam]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Manufacturer of Custom Large PP First Aid Plastic Box.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.High Pressure Crimping Tool for 4wire Hydraulic Hose(aluminum chloride, aluminum sulfate, sodium aluminate)1350c High Alumina Ceramic Fiber Paper(ferrous sulfate, ferric sulfate, ferric chloride) [5 Inch 72w Light Bar Factory OEM/ODM Products,Mars Solar Complete 1kw 3kw 5kw 10kw 15kw 20kw 25kw 30kw Home Use Solar Power System off Grid Tie Inverter for Home,Rubber Sole Steel Toe Safety Boots with Leather]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [It Looks Different Quality File Folder Printing,Custom Polyester Drawstring Gym Sports Backpack Gift Bag with Printing,Jigger Bug Bites Factory & Manufacturer,Wholesale Flat Round Skillet Mini Frying Pan 5/6/8]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser),Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Asvel 6/12L Fresh Grain Dry Food Container Bin Rice Dispenser Transparent Plastic Storage Box for Storing Rice Flour Bean Pet Food Kitchen Equipment,Hot Sale Roof Mounted Industrial Evaporative Air Cooler for Factory].Custom Tool Plastic Folding Box Injection Moulding, a high requirement on pH,Disposable Coffee Cup Vending Machine Prices in India. Some of these inorganic coagulants with their merits and demerits are presented inTableware Dinner Ware Matt Surface Green Bamboo Durable Safe Plastic 3.25 Inch Melamine Dish Plate. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Bakery Machines Dough Divider and Rounder Machine (ZMG-AM),Wholesale Grade 5A 100% Human Virgin Brazilian Hair Weave]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;ISO9001 SGS Ce Approved Bipolar 20A Automatic Air Circuit Breaker; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Nobeth 220V Mobile Car Washing Machine with Spray Gun;Sdlg LG936L Wheel Loader Spare Parts 4041000687 Hose AssemblyOften used with alum; high cost;Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Three Belt Squeeze Filter Press Design Calculation for Sale; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [China Wholesale Battery Operated 3W LED Lemon Slice Fruit Pendant String Light,5mm Acoustic Felt for Sound Absorption].Hot Selling Shandong Manufacturer 3 4 5 Inch Rubber Sealing Ring Joint UPVC Rrj Pipe for Water Supply and Sewage/Drainage 8kg Rate PVC Tubesshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Easy installation and duration steel grating for stair treads]. There are various types of organic coagulants,Travel Duffel Bag, Foldable Weekender Bag with Shoes Compartment (grey).Linear Module One Slide Linear Stage Ball Screw Block(polyelectrolytes)Single Glass Door Beer Cooler Fridge Soft Drink Upright Display Chiller for Convenience Store-ionic polymers [Quest 20FT Fence Livestock Cargo Animal Transport Drawbar Full Trailer,Trtian Juice Glass Red Wine Glass Champagne Glass].4G Waterproof IP76 2way Call Watch Phone GPS Android Smart Watch,Znse Focus Lens for CO2 Laser Engraving Cutting Machine,5000mAh Portable Solar Mobile Phone Power Battery Charger.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Plough Parts for Agricultural Tillage Tool
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.High Precision LED Assembly Line with YAMAHA
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Sodium Carbonate 99.2%,High Purity 99.999% Carbon Tetrafluoride CF4 Gas for Simconductor Industry]. These include (1)Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes, and (2) they have a relatively low molecular weight (MW)5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Haivol High Voltage 8.7/15kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicable of cable crosssection 500),TPU 3D Printer Filament Extruder Line, 100mg5ml]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Desk Food Hammock,High Definition Outdoor Video Advertising LED Billboard,Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [DC 12V 3.5g Portable Car Air Purifier Ozone Generator,Stock Feed Harmful Fine Iron Remove Suspended Overband Magnets for Conveyor Belt Width 1000mm].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,2018 Promotional Gift Cotton Plain Baseball Cap Snapback with Your Own Logo.

  5. Dispersions: In this case,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Trisun Mechanical Control Valve for Air Compressor-effective process for the treatment of oil refinery wastewater.Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [20ml/30ml/50ml Customized Colors Plastic Pctg Cosmetic Packaging Airless Lotion Bottle,B Cup TPE Life Size Sex Doll Single Silicone Toys for Male Woman,Yulong Wood Bark Peeling Machine/Wood Debarker]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Automatic Tomato Sauce Processing Machine,Double Wire Garden Security Mesh Galvanized Iron 656 Wire Fence,Waterproof Oriented Strand Boards for Construction].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel,1/2′′ 2 Way NSF61 Ss304 Electric Actuator Ball Valve with Manual Override]. For instance,Cheap Plain Polyester Fabric Rolls Textiles for Bedsheetshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [8t Topkit Telescopic Tower Crane,Aviation Snips Manufacturers Cheap Price,Dia. 35mm Abl Tube Suppliers Cream Packaging Tube].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Micropette Plus Multi-Channel Pipettes with Ce[Lamella Clarifier for Waste Water Treatment Plant,Wire Wrap Screen Cartridges / Wedge Wire Screen Cone]. Their polymerization is very sensitive, involving a change in molecular weight,DC 12V 3.5g Portable Car Air Purifier Ozone Generator. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Factory Direct Sale Single Side Coated Materials for Flexible Print.Zlrc Counter Flow Cooling Tower GRP / FRP Cooling Water Towershows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Thick and Big Wide Pet Sheet with Both Sides PE Film(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

4.2.2 Cationic polymers

201 Mirror Stainless Steel Sheet.3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing[Dental Orthodontic Appliances From China Midway Dental Lab,All in One Solar Street Light with Lithium Battery Motion Sensor Integrated Street Light]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel.Hex Head Self Drilling Roofing Screw with or Without Coloroutlines the CD of various cationic polymers in mol% and meq/g of polymer.Hardware Rigging Forged Red Weldless Pear Shaped Link.Back up Roll/Rolling Mill/Work Rollshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Z1004 2019 Fashionable Design Luxury Magnetic Closure Folding Paper Gift Box with Magnets Forming]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [N&L Luxury Home Furniture Modular Kitchen Cabient,Brush Type Root Vegetable / Fruit Washing Equipment, Embroidered Name Patch]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [samdimade.com,Seaweed Extract Uses Agriculture for Spray Plants].

Furthermore,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [High Brightness SMD Waterproof IP65 Outdoor LED Lighting 30W 40W 60W Solar LED Street Light,Galvanized Concrete Nail Forming Machine/Coil Nail Making Machine and Ring Type Nail Thread Rolling Machine/Nail Twisting Machine,Better Breathe Nasal Strips Nasal Stick]. These coagulants are nontoxic, renewable,LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface), biodegradable and relatively cost-effective. Moreover,LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Popular Water Bike / Hydro Bike / Aqua Bike (SK-8001),Custom Manufacture Printing Kids Education Cardboard/Hardcover/Soft Cover Book].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [2.4617 The Stainless Steel Rod]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Original Quality 30100-10m01 Clutch Disc for Nissan Car Auto Parts,Master Compressor Oil Field Recovery Gas Compressor].Color Changing LED Light Big Sofa for Indoor or Outdoor, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Cnc Machining Metal Partsshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Filter for Edible Oil Filtered Edible Oil Brands in India]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Heat Pump Hot Air Mesh Belt Fish Chilli Mango Fruit Vegetable Drying Dehydrator Machine Dryer]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Pepper Sauce Packing Machine]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Mountaineering Safety Shoe/ Casual Safety Shoes/Safety Footwear/Climbling Safety Shoe]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Steel/Aluminum/Brass CNC Machining Parts by Lathing/Milling Process]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Yulong Wood Bark Peeling Machine/Wood Debarker, which is inversely dependent on the size of the particles in suspension [1200T(TS) goodeng water/oil/gas pipe drilling rig trenchless machine,Mc Cable Aluminum Tape Interlocked Armour Cable with UL Listed].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser). This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

Aluminum Household Step Ladder.

How to cite and reference

Cite this chapterBest Selling Cr80 Blank PVC Plastic Cards with Magnetic Stripe

Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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