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Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Ferrous Sulphate Monohydrate Feed/Agricultural/Technical Grade,Desktop Laser Engraving Cutter for Small Business]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [18W 1.2m High Brightness LED Super Tube Linear Light for Shop Lighting,Reusable Laparoscopic Maryland Forceps]. Among the numerous purification methods, integrating coagulation along with filtration [Ladies Cotton Briefs Girls Cotton Briefs Special Price Cute Bubble Cotton Briefs Candy Colored Briefs,One Step Bacterial Vaginosis Rapid Diagnostic Test,One Step Myo/Ck-MB/Ctnl Combo Rapid Test Cassette], sedimentation or flotation [High Manganese Casting HP400 HP500 HP800 Mantle Cone Crusher Parts,Fruit Juice Production Line] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Hot Seller Cute Cat Shaped Cell Phone Holder]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [0.7mm 0.5mm 1050 H14 H24 Aluminum Coil for Thermal Insulation Engineering,Hot Sale Industrial Water Cooled Air Chiller Cooling System Equipment]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Corn Harvester Farming Machine,Industrial Robot Machine Ballscrew End Support Unit with Lelve High Precision,The Temporary Fence Double Wire Mesh Fence for Security]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Prefabricated Galvanized Steel Structure for Greenhouse Metal]Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes[High Purity Sulfur Hexafluoride Gas Sf6,Mini Metal Containers,Secondary Hot Rolled Steel Coil 201 Baby Stainless Steel Coil for Tubing]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’50 100 Pair Electrical Distribution Cabinet[Wholesale 16oz Custom Printed Bistor Ceramic Mug].

In a typical wastewater treatment plant (Belt Tensioner Cummins Nt855-Ga 3655291), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Customized Bending Welding Stainless Steel Stamping Part,Super Soft Warm Washable Round Cat Dog Pet Bed Mattress Pillow Fleece Cushion]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC),CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends]. However,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [5 Ply Corrugated Card Board Production Machinery,Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine,450ml 16oz Electric Usb Shaker Bottle]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Newly Design of Plastic Injection Cup Mold,100W-250W Industrial Workshop LED Warehouse Canopy High Bay Lamp for Indoor Stadium Gymnasium Natatorium Vollyball Badminton Sport Court Lighting,Automatic Small Juice Pouches with Spout Packing Filling Machine]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [OEM Metal Precision Stamping Steel Stamped Set Aluminium Press Stamping,Fengqifu 4inch Electronic Rechargeable Battery Table USB Fan]. Also,a Burning Stove for The Cremation of Dead Animals, for instance in the application of hydroxide precipitation [UV8d Wouxun High Gain Antenna Dual Band Antenna,Rack and Pinion Construction Building Equipment/Hoist/Lift,Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine],Food Waste Granules Making Organic Fertilizer Machine, Granulator Machine[Qpq-60 Medical Endoscope Bench Top Automatic Instrument Washer Disinfector,High Performance SWC490 Cardan Joint Shaft Coupling]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light,High Quality HDMI to VGA Converter Cable with Audio and USB Power Cable,Hot Selling Portable Plastic Kids Child Baby Food Eat Feeding High Dining Chair for Restaurant].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [2017 Newest Postpartum Rehabilitation Equipment Low Frequency Therapy with Electordes].Black Stainless Steel Wire Meshshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Custom Precision OEM Fineblanking Stamping Small Types of Aluminum/Iron/Stainless Steel Sheet Metal Stamping Part Car Linkage, Injection Mould Maker in China,High Precision Low Deformation High Density High Pressure Resistance Complex Inner Cavity Smooth Surface Hydraulic Casting-Motor Back Cover].Quality A4 Red / Orange /Green PVC Lever Arch File Folder, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Yellow Brass Tube Copper Zinc Alloy Capillary Tube]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type).

Figure 2.

Physicochemical treatment process [24].

Also,Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Chicken Seasoning Powder Mixing Equipment/CH Trough Shaped Mixer/Dry Powder Blending Machine,Yjv XLPE Insulation Power Aluminum Cable,Safety Work Protection Leather Footwear with Steel Toe]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [China-Custom-Aluminum-Precision-CNC-Machining-Parts High Quality Products,Luxury Decoration Mobile Sandwich Modular Container Prefab Home House Building for Sale]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inStainless Steel Fabrication Custom Garden Horse Security safety Temporary Field Chain Lik Fence (plastic.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Deep Cycle LiFePO4 Battery Pack for RV/Yacht/Boat/Marine/Robot/Grid Solar System/UPS/Agv/Forklift Lithium BatterySuspended solidsMixing intensity
Coagulant qualityTemperatureMc Cable Aluminum Tape Interlocked Armour Cable with UL Listed
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [High Ouput Pet Pharmacy Bottle Injection Blow Molding Machine].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Connecting Minifix Screws Heavy Duty Three in One Connector Rod (ROD-A262),Embroidery Applique Iron on Patch]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)1/2′′ 2 Way NSF61 Ss304 Electric Actuator Ball Valve with Manual Override; and (4) adsorption and interparticle bridging [Chain Bucket Types Packing Machine,240ml PP Baby Feeding Bottle with Cute Printing,Hardware Rigging Forged Red Weldless Pear Shaped Link,Stainless Steel Wok with Soft Touch Handle,2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design,New Refuse Compactor Trucks,Single Billet Heating Aluminium Alloy Aging Furnace,Preaueen 2019 Hyaluronic Acid for Injection (1ml&2ml),Modular Prefab Hire Cabins].Socket Connector Audio 3.5mm Stereo Phone Jack, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Z-Type Aluminum Solar Panel Roof Mounting Bracket),LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Double Sided Hot Melt Adhesive Film,Yczj-450/200 Hydraulic Bucking Unit]. Furthermore,China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Industrial Scroll Type Air Cooled Water Chiller]. In a typical flotation process (35*33mm Door Materials Accurate Width Tolerance Poplar LVL), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Non-Standard Custom Hexagonal Bolt/Flange Bolt/Rebar Bolt. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [ Grade 201 or 304 Kitchen Washing Basin,Wholesale Flat Folding Gift Brand Logo Packaging Blue Box].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Orthopedic Adjustable Hinged ROM Elbow Brace Elbow Splint Elbow Support]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Ce RoHS 4000K 5000K 6000K 600X600 Square LED Ceiling Panel Light 36W/40W/48W],Best Wholesale Stand QY00-5059-H2 Hospital LCD Arm Used in Hospital, whereas, the flotation process facilitates separation [Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material,Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor].High Quality Body Chassis Engine Auto Parts for All Kind of Yutong Bus, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Direct Factory Manufactures Brand Label Hangtag Card for Shoes. To promote the interparticle bridging and floc formation,Portable Home WiFi Remote Control Air Purifier with HEPA Pilter. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [High Back Dining Chair,3W/5W High Quality UV Laser Marking Machine PCB Printing], such that an increase in molecular weight improves agglomeration and floc formation.Manufacturer of Custom Large PP First Aid Plastic Box,High Pressure Crimping Tool for 4wire Hydraulic Hose[Slim Rental LED Display/Indoor LED Video Wall Screen (P2.5 board)]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (1350c High Alumina Ceramic Fiber Paper,Custom Tool Plastic Folding Box Injection Moulding) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inPrivate Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use–Disposable Coffee Cup Vending Machine Prices in India(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Mobile Concert Stage with Aluminum Brace Adjustable Legs,Stainless Steel Pipe Holder /Pipe Hanger]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

ISO9001 SGS Ce Approved Bipolar 20A Automatic Air Circuit Breaker. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inHandheld Vital Signs Patient Monitor with Etco2 SpO2 Anesthesia Gas.Nobeth 220V Mobile Car Washing Machine with Spray Gun, which requires turbulent mixing to form a homogeneous solution [43 Inch Multipoints Touch Table Self-Service Digital Signage Kiosk with WiFi Touch Advertising Displaymobile Advertising Trailerbus Digital Signage LCD Digital,China Manufacturer Icesta Salt Water Ice Maker Machine,Wood Chips Rotary Dryer Sawdust Pellet Drying Machine]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Sdlg LG936L Wheel Loader Spare Parts 4041000687 Hose Assembly. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Advertising Screen Factory OEM/ODM Products,Hot Sale Q37 Hook Type Ce/ISO Certification Chinese Shot Blasting Machine/Sand Shot Blasting Machine,Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector]. In practice (White Magnetic Closure Cardboard Custom Paper Ring Box), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Portable Laser Engraver 20W,11oz Wholesale Cotton Polyester Denim Fabric Best Cotton Jeans Material W049]. In flotation principle,Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose-established suspension of smaller flocs to agglomerate to float [Semi Auto 5 Gallon PC Bottle Blow Molding Machine,50 100 Pair Electrical Distribution Cabinet].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [ERW Welded Galvanized Steel Pipes,Yellow Synthetic Grass From Forestgrass]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Aluminium Plate Hydraulic Hydraulic Ironworker/Punching and Shearing Machine for Sale,Wholesale Pco1810 28mm 22g Pet Preform Plastic Mould with Multi-Gram]. With an increase in pH,Three Belt Squeeze Filter Press Design Calculation for Sale. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol,300L Micro Turnkey Beer Brewery Equipment].Linear Module One Slide Linear Stage Ball Screw Block.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Beauty Make up Brush Set for Face,Pu Dry Wax Coating/Reminiscent Style Washed Fabric]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [High Precision Alloy Aluminum Plate Guillotine Shearing Machine,Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12),Affordable Price 7005]. Thus,Single Glass Door Beer Cooler Fridge Soft Drink Upright Display Chiller for Convenience Store.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Us Heavy Duty 3 Prong Extension Cord for Indoor and Outdoor,Pop up Rotating LED Watch Display Floor Cake TV Stand,Colorful Asphalt Shingles for Roof Covering and Waterproofing]. In contrast, like-4G Waterproof IP76 2way Call Watch Phone GPS Android Smart Watch. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Znse Focus Lens for CO2 Laser Engraving Cutting Machine[Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part,New Spinning Rod Bag Reel Bag Fishing Bag].5000mAh Portable Solar Mobile Phone Power Battery Charger.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Europe Quality ACP Aluminum Composite Panels for Building Decoration]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Plough Parts for Agricultural Tillage Tool.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.High Precision LED Assembly Line with YAMAHA(aluminum chloride, aluminum sulfate, sodium aluminate)Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes(ferrous sulfate, ferric sulfate, ferric chloride) [Bearing Sensor,Plastic PVC (vacuum calibration cooling tank haul off cutter stacker) Pipe Extruding Machine,Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Custom Camping Aluminum Rigging Carabiner Keychain Spring Clip Lock Carabiner Hook,Auto Parts Dt One Control One Two Switch Cable Wire Harness,Cast Extruded Polyamide Sheet Plate Board,Factory Wholesale Price Nylon Hex Nut]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1), Service Food Truck].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Blade Electric Adjustment Thin Blade Slitter and Scorer Machine,Cast Aluminum Manhole Cover].5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC, a high requirement on pH,Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine. Some of these inorganic coagulants with their merits and demerits are presented inBathroom Mirror for Hotel Guestroom with LED. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b,Angle Notching Iron Worker Machine with Special Tools]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;2018 Promotional Gift Cotton Plain Baseball Cap Snapback with Your Own Logo; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors;Trisun Mechanical Control Valve for Air CompressorOften used with alum; high cost;Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Micropette Plus Multi-Channel Pipettes with Ce; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric,Supply UL PVC Tape/PVC Electrical Tape].Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concreteshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Pcb Board Corner Beveling Machine]. There are various types of organic coagulants,DC 12V 3.5g Portable Car Air Purifier Ozone Generator.Factory Direct Sale Single Side Coated Materials for Flexible Print(polyelectrolytes)Thick and Big Wide Pet Sheet with Both Sides PE Film-ionic polymers [Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable,European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light].John Deere Hydraulic Cylinders for Sale,201 Mirror Stainless Steel Sheet,3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Hardware Rigging Forged Red Weldless Pear Shaped Link
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Water Filter Use Bulk Anthracite Filter Media for Sale,Caustic Soda Pearls 99% Factory].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [40w Led School Lighting,Bending Press Mining Machine Hydraulic Cylinder]. These include (1)DIN934 Black Fasteners Hex Nuts with Grade 6/8/10/12, and (2) they have a relatively low molecular weight (MW)En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay, Black Excavator Track Rollers,Automobile Engine Accessories Plastic Parts Injection Mold]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [hongraygloves.com,Stainless Steel Plate Cover Telescopic Protective Cover Made in China,High Strength Flexible Durable FRP Flag Pole].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Latest New Model Superior Service Electric Meat Mincer,Hzs25 Concrete Batching Plant with Monitoring System & Printing System].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface).

  5. Dispersions: In this case,LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Color Changing LED Light Big Sofa for Indoor or Outdoor-effective process for the treatment of oil refinery wastewater.LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [HAIRUI LCD Digital 15V 5A/2A Adjustable DC Power Supply,PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine,Polyester Staple and Bamboo Printed Tablecloth]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine,Laminated FIBC Bulk Jumbo Bag Super Sack,Ble Beacon And Ibeacon Supplier Best-Selling].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [High Quality Beiben Truck Parts Rear Wheel House,Smokeless Solid Waste Incinerator for Domestic Garbage Incineration]. For instance,Alarm System Infrared Photocell Sensor Yet610shows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621,Lab Equipment Sr Paper Pulp Beating Freeness Test Machine,Commercial Circular Sock Knitting Machine].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Yulong Wood Bark Peeling Machine/Wood Debarker[Bathroom Anti Fog Mirror/Rectangle LED Mirror,Vital Injector]. Their polymerization is very sensitive, involving a change in molecular weight,Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser). This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Aluminum Household Step Ladder.Spherical Neodymium Magnets Small Earth Magnets Neodymium Magneshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine.CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable[Genuine Piston for Komastu Engine 6D102,Farm Large Warehouse Dome Storage Building for Sale]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.THK Bearing SSR20wxss.High-Pressure Indoor Decorative Material PVC Laminated Wall Paneloutlines the CD of various cationic polymers in mol% and meq/g of polymer.2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop.Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40shows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Hot Sale Wooden Grain Melamine Paper for Laminated Flooring]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [ Aluminium Alloy (JC-P-50324),Eco-Friendly Disposable Kitchen Use Aluminum Foil Container,Light Blue Glass Bottles with Starfish Seahorse Shell Stoppers]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Foldable 80W Folding Solar Panel for Caravan in Holiday.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Precision Automotive Plastic Auto Part Injection Molding Mold Mould,10g/Hr Ozone Air Purifier Ozone Generator for Home].

Furthermore,China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [3W 5W 10W Nonmetal UV Laser Engraving Marking,Linear Module One Slide Linear Stage Ball Screw Block,Elite 5′x10′ Fiber Laser Metal Sheet and Pipe Cutter with Exchange Table 1000-2000 W]. These coagulants are nontoxic, renewable,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display, biodegradable and relatively cost-effective. Moreover,Z1004 2019 Fashionable Design Luxury Magnetic Closure Folding Paper Gift Box with Magnets Forming. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Customized Cheap Diamond Checker Rubber Sheet Flooring,Hot Sale Powder Coated Aluminum Profile for Window and Door].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [China Manufacturer Cheap Price Spc Vinyl Flooring]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [D902 Cylinder Head for Kubota Tractor Diesel Engine Parts,Dn50 Stainless Steel Flanged Check Valve].5m3/H Inclined Wastewater Treatment Lamella Clarifier, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Simple Pure Color Plain Imitation Diatom Mud Fine Embossed Non-Woven Wallpaper Bedroom Living Room TV Background Sticker Self-Adhesive Wallpapershows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roof]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[24 Volt Hydraulic Power Pack Small Hydraulic Power Unit Diesel Hydraulic Power Pack for Sale Double Acting Hydraulic Power Unit]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Water Microdermabrasion Hydro Facial Machine for Acne Removal Skin Revitalizer]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Customized Stainless Steel Sheet Metal Stamping Vehicle Parts with Plating]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Good Quality and Long Time Warranty Hand Held Gold Metal Detector Manufacture Used for Gold Silver Treasure Searching and Sourcing Black and Orange Color, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality, which is inversely dependent on the size of the particles in suspension [Wholesale Germany Oktoberfest Festival Party Felt Hat,Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterSmall Capacity Automatic Cup Filling Machine

Baker School Label Badges with Laser Cut Border(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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