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Application of Organic Coagulants in Water and Wastewater Treatment

China Stainless Steel Manual Food Grade & Hygienic Sanitary Ball & Butterfly Valve

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom.Fruit Juice Production Line,Haivol High Voltage 12/20kv Cold Shrinkable 3 Cores Outdoor Terminal Kit (Applicableof cable crosssection 150),Wedge Pump for Women. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Glassware/Glass Bottle/ Red Wine Bottle/ Champagne Bottle 750ml. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Outdoor RGB 7 LED Solar Powered Flame Lawn Landscape Solar Garden Light. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Colorful Asphalt Shingles for Roof Covering and Waterproofing,Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [12.5inch Walking Measuring Wheel with Counter (WW-MW219-7),New Spinning Rod Bag Reel Bag Fishing Bag]. Among the numerous purification methods, integrating coagulation along with filtration [Europe Quality ACP Aluminum Composite Panels for Building Decoration,Plastic PVC (vacuum calibration cooling tank haul off cutter stacker) Pipe Extruding Machine,Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights], sedimentation or flotation [Gymnastics Inflatable Trampoline Tumble Track Mattress,Custom Camping Aluminum Rigging Carabiner Keychain Spring Clip Lock Carabiner Hook] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Auto Parts Dt One Control One Two Switch Cable Wire Harness]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Factory Wholesale Price Nylon Hex Nut,Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1)]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Die Cutting Machines for Children′s Cap Making, Service Food Truck,Blade Electric Adjustment Thin Blade Slitter and Scorer Machine]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Bathroom Mirror for Hotel Guestroom with LED]Carburetor Adjusting Tool Kit Screwdriver Chainsaw for Poulan Husqvarna Zama Walbro[Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b,m.tjhstech.com,Angle Notching Iron Worker Machine with Special Tools]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’ERW Welded Galvanized Steel Pipes[Outdoor Greenhouse Cover 70% Shading Rate Cool Energy Saving Aluminium Sun Shade].

In a typical wastewater treatment plant (Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric,PE HDPE PP PPR Mine Pipe Extruding Manufacturing Line Machine]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Supply UL PVC Tape/PVC Electrical Tape,Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete]. However,20kg Bulk Packing Peanut Butter Paste, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable,European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light,Astm A53 2 Inch Steel Pipe]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Water Filter Use Bulk Anthracite Filter Media for Sale,Caustic Soda Pearls 99% Factory,Bending Press Mining Machine Hydraulic Cylinder]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay,m.gz-sourcing.com]. Also,High-Grade Beautiful Clothes Hooks Wooden & Metal Row Hooks (ZH-7005), for instance in the application of hydroxide precipitation [ Black Excavator Track Rollers,Automobile Engine Accessories Plastic Parts Injection Mold,Stainless Steel Plate Cover Telescopic Protective Cover Made in China],Microfiber Beach Towel Fast Dry Towel, Outdoor Towel, Travel Towel, Swim Towel, Yoga Towel[High Strength Flexible Durable FRP Flag Pole,Bamboo Floor Lamp Wholesaler Quotes & PriceList]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Latest New Model Superior Service Electric Meat Mincer,Hzs25 Concrete Batching Plant with Monitoring System & Printing System,PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Polyester Staple and Bamboo Printed Tablecloth].Medical Rubbish Disposal with Microwave Disinfection Equipment Hospital Rubbish Sterilizer 3shows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Laminated FIBC Bulk Jumbo Bag Super Sack,High Quality Beiben Truck Parts Rear Wheel House,Smokeless Solid Waste Incinerator for Domestic Garbage Incineration].Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Memory Foam Pocket Spring Mattress From China Manufacturer]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.4-6 Person Luxury Teepee Tipi Family Camping Tent.

Figure 2.

Physicochemical treatment process [24].

Also,Linear Guideway for CNC Machine as Components. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Alarm System Infrared Photocell Sensor Yet610,Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621,Commercial Circular Sock Knitting Machine]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Bathroom Anti Fog Mirror/Rectangle LED Mirror,Stainless Steel 410 Wire]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inVital Injector.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Hot Rolled No. 1 Stainless Steel Sheet (201, 304, 316, 304L, 321)Suspended solidsMixing intensity
Coagulant qualityTemperatureLexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Genuine Piston for Komastu Engine 6D102,Farm Large Warehouse Dome Storage Building for Sale]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Good Quality PE Foam Sheet Extrusion Machine; and (4) adsorption and interparticle bridging [Low Handpiece,High-Pressure Indoor Decorative Material PVC Laminated Wall Panel,Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40,Hot Sale Wooden Grain Melamine Paper for Laminated Flooring, Aluminium Alloy (JC-P-50324),CD4017be DIP16 Inline 16 Pin IC Chip 4017 New High Quality Electronics,Eco-Friendly Disposable Kitchen Use Aluminum Foil Container,Light Blue Glass Bottles with Starfish Seahorse Shell Stoppers,10g/Hr Ozone Air Purifier Ozone Generator for Home].Becu Beryllium Copper Brass Copper Bronze Machining Part Spare Parts, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (3W 5W 10W Nonmetal UV Laser Engraving Marking),72 Spindles Metal Wire Braiding Machine. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Stainless Steel Pipe & Tube,Linear Module One Slide Linear Stage Ball Screw Block]. Furthermore,3003 Grade Aluminum Coil Tube for Air Conditioner Condenser.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Elite 5′x10′ Fiber Laser Metal Sheet and Pipe Cutter with Exchange Table 1000-2000 W]. In a typical flotation process (Hot Sale Powder Coated Aluminum Profile for Window and Door), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,300L Micro Turnkey Beer Brewery Equipment. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [China Manufacturer Cheap Price Spc Vinyl Flooring,www.dmgstainless.com].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [D902 Cylinder Head for Kubota Tractor Diesel Engine Parts]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Dn50 Stainless Steel Flanged Check Valve],Factory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler, whereas, the flotation process facilitates separation [2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roof,24 Volt Hydraulic Power Pack Small Hydraulic Power Unit Diesel Hydraulic Power Pack for Sale Double Acting Hydraulic Power Unit].Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

50 100 Pair Electrical Distribution Cabinet. To promote the interparticle bridging and floc formation,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)Food Waste Granules Making Organic Fertilizer Machine, Granulator Machine(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Home Fragrance Decoration 150ml Perfume Hotel Air Freshener Aroma Reed Essential Oil Air Diffuser,Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock], such that an increase in molecular weight improves agglomeration and floc formation.Quality A4 Red / Orange /Green PVC Lever Arch File Folder,Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type)[Water Microdermabrasion Hydro Facial Machine for Acne Removal Skin Revitalizer]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils,Deep Cycle LiFePO4 Battery Pack for RV/Yacht/Boat/Marine/Robot/Grid Solar System/UPS/Agv/Forklift Lithium Battery) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inWholesale Germany Oktoberfest Festival Party Felt Hat–Mc Cable Aluminum Tape Interlocked Armour Cable with UL Listed(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl,Different Size Capsule]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

1/2′′ 2 Way NSF61 Ss304 Electric Actuator Ball Valve with Manual Override. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in39799515 Air Compressor Spare Parts After Oil Cooler Core China Supplier.Socket Connector Audio 3.5mm Stereo Phone Jack, which requires turbulent mixing to form a homogeneous solution [Disposable Blood Transfusion Set IV Set for Blood Infusion Set,LED Emergency Exit Light Rechargeable 220V,Yellow Corrugated PE-Al-PE Gas Pipe with Size 16mm to 32mm]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Solid Color Blackout Curtain,Steel Countersunk Cross Recessed Zinc Plated M4 Flat Head Self Tapping Screw,St3.5*13 Color-Zinc Plated Hexagonal Self-Drilling Screws with Washer]. In practice (Small Capacity Automatic Cup Filling Machine), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [MPO Fiber Cable Fiber Optic Patch Cord for Data Center,Classical Outdoor 4 Player Children Wooden Croquet for Family W01d004]. In flotation principle,China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings-established suspension of smaller flocs to agglomerate to float [Stable Quality Cbp60m Mobile Wet Mix Concrete Batching Plant,Makute Electric Fan Air Blower with Ce].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Abaya Custom Islamic Party Dress Embroider Bead Muslim Evening Dress for Women, New Zealand]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Used Rotary Horizontal Directional Drilling Rig Machine,6 Tracks Granule Desiccant Powder Seasoning Sugar Coffee Packing Machine]. With an increase in pH,Non-Standard Custom Hexagonal Bolt/Flange Bolt/Rebar Bolt. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Custom Plastic Injection Mould for Injection Moulding Mechanical Parts,Termway SMT Pick and Place Machine LED Light Produciton Line].High Quality Body Chassis Engine Auto Parts for All Kind of Yutong Bus.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Hotsale in Saudi Arabia 75mm*25m Green Black Arrow Reflective Tape,Thrusting Dildo]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Z60 Smart Watch Steel Belt Pedometer Health Monitoring Information Push Social Entertainment Smart Reminder,New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate,Powder/Spices Powder Packing Machine with Four/Three Side Seal]. Thus,Direct Factory Manufactures Brand Label Hangtag Card for Shoes.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [2019 New Designed Luggage Electric Scooter,anebon,3tons Four Wheel Drive Mini Dumper SD30]. In contrast, like-Portable Home WiFi Remote Control Air Purifier with HEPA Pilter. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Custom Precision OEM Fineblanking Stamping Small Types of Aluminum/Iron/Stainless Steel Sheet Metal Stamping Part Car Linkage[New Design Fishing Bag Fishing Lure Bag,Fashion Cotton Baby/Kid Hat (DH-BF332)].The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Manufacturer of Custom Large PP First Aid Plastic Box.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.High Pressure Crimping Tool for 4wire Hydraulic Hose(aluminum chloride, aluminum sulfate, sodium aluminate)1350c High Alumina Ceramic Fiber Paper(ferrous sulfate, ferric sulfate, ferric chloride) [Regular Size Gear Hobbing Machine Y3150/3,Supplier of Carbon Additive Used in Foundry Industry,Customizable High Quality Transparent PP Plastic Fruit Container for Food Packaging]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Stainless Steel Honeycomb Core for Air Ventilation,Retro Red Wooden 20 Pieces Cigar Humidor Box Case,Wall-Mounted LED Front-Lighted Bathroom Vanity Mirror 72 Wide X 36 Tall for Hospitality Grade,Factory Supply FC Sc St LC MT-RJ Mu Fiber Optic Adapter]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Stacker High Speed Ultrasonic Label Cutter (Alc-108h),Chinese Manufacturer Double King Size Wooden Bed for Hotel Bedroom].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Outdoor Armoured 6 Core GYTA53 Direct Buried Fiber Optic Cable,12W Dimmable LED Retrofit Downlight SMD2835 Lighting Fixture].Custom Tool Plastic Folding Box Injection Moulding, a high requirement on pH,Disposable Coffee Cup Vending Machine Prices in India. Some of these inorganic coagulants with their merits and demerits are presented inTantalum Clad Steel Plate Sheet Manufacturer. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Android 6.0 Wall-Mounted 75 Interactive Smart Board For Meeting,LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;ISO9001 SGS Ce Approved Bipolar 20A Automatic Air Circuit Breaker; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Nobeth 220V Mobile Car Washing Machine with Spray Gun;Sdlg LG936L Wheel Loader Spare Parts 4041000687 Hose AssemblyOften used with alum; high cost;Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Three Belt Squeeze Filter Press Design Calculation for Sale; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils,Thick Vinyl Flooring Quality Vinyl Flooring Kitchen Vinyl Flooring Vinyl Sheet Vinyl Flooring Bathroom].Twin Wall Insulated Stainless Steel Juice Tumbler Vacuum Water Tumbler Metal Straw Cup Inox Straw Tumblershows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Wholesale Modern Aluminum Glass Garage Door and Polycarbonate Garage Door]. There are various types of organic coagulants,Travel Duffel Bag, Foldable Weekender Bag with Shoes Compartment (grey).Linear Module One Slide Linear Stage Ball Screw Block(polyelectrolytes)Single Glass Door Beer Cooler Fridge Soft Drink Upright Display Chiller for Convenience Store-ionic polymers [The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof,Body Jewelry Surgical Stainless Steel Mens Cartilage Barbell Earrings Stud].4G Waterproof IP76 2way Call Watch Phone GPS Android Smart Watch,Znse Focus Lens for CO2 Laser Engraving Cutting Machine,5000mAh Portable Solar Mobile Phone Power Battery Charger.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Plough Parts for Agricultural Tillage Tool
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.High Precision LED Assembly Line with YAMAHA
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [High Quality Gas Lift Strut for Industrial Equipment,Lightweight M370-27speed Aluminum Alloy Mantis Mountain Bike 29er].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Clay Graphite Crucible Wholesaler Quotes/PriceList,Sc Round Type Fiber Optic Adapter Bare Fiber Connector]. These include (1)Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes, and (2) they have a relatively low molecular weight (MW)5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [BSMI Test and Certification for LED Lamps,Aluminum Mounted Flag Pole with Rotating Finial for Flag Hoisting,High Temperature Alternative Stainless Steel Band in Different Package]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Jinrui Self-Made Best Reducer for Concrete Mixers and Batching Plants,Scale Labels 40*30*1000 Supermarket Waterproof Direct Thermal Self-Adhesive,60W Mini LED Moving Head Beam Light].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Toughened Railing Glass,Good Quality Good Price China Plastic Injection Molding Machine].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,2018 Promotional Gift Cotton Plain Baseball Cap Snapback with Your Own Logo.

  5. Dispersions: In this case,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Trisun Mechanical Control Valve for Air Compressor-effective process for the treatment of oil refinery wastewater.Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [CE Certificated Wheel Loader (HQ912) with Agricultural Tire,Black Leather Men Weekend Carry Luggage Travel Bag Duffle Bag,T Series 90 Degree Helical Cone Bevel Agricultural Gearbox]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Stripe Tape Cami and Dolphin Hem Shorts Camo Fitness & Yoga Wear,Massage Table Tattoo Therapy Beauty Couch Bed,Dry Cabinet For Guitar Factory OEM/ODM Products].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [AAAC Conductor Line AAAC - All Aluminum Alloy Conductor All Aluminium Alloy Conductors (AAAC) AAAC-S Cable,Customized Walk in Temperature Humidity Environment Test Chamber]. For instance,Modbus Digital Type Temperature Probe for General Industrial Fieldsshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Multifunction Rubber O-Rings in Various Colors and Sizes for Faucets,Small Take Away Meal Prep Food Containers Ab-1008,Love Stainless Steel Bangle Bracelet with Heart Lobster Clasp].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Micropette Plus Multi-Channel Pipettes with Ce[General Pitch Thread 16er AG60 Threading Turning Inserts,Sodium Lauryl Ether Sulfate SLES 70% Factory Supplier in China]. Their polymerization is very sensitive, involving a change in molecular weight,DC 12V 3.5g Portable Car Air Purifier Ozone Generator. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Factory Direct Sale Single Side Coated Materials for Flexible Print.Customized New Acrylic Bird Feeder for Garden Decorationshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Thick and Big Wide Pet Sheet with Both Sides PE Film(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

John Deere Hydraulic Cylinders for Sale[Jiansong Manufacturer Grinding Machine].

4.2.2 Cationic polymers

201 Mirror Stainless Steel Sheet.3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing[Square Tube Cold Formed Steel Channel for American Market Construction,OEM Waterproof Nylon Yacht Craft Boat Cover]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel.Deep Cycle LiFePO4 Battery Pack for RV/Yacht/Boat/Marine/Robot/Grid Solar System/UPS/Agv/Forklift Lithium Batteryoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Hardware Rigging Forged Red Weldless Pear Shaped Link.Stc-1000 Two Relay Output LCD Digital Temperature Controller with Sensorshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

DIN934 Black Fasteners Hex Nuts with Grade 6/8/10/12[Tv 65 4k Uhd Smart].

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [New Collection W03 Full Frame Walk-in Shower Door]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Office Furniture Executive Desk Smart Artificial Stone Office Working Table,Komatsu Shantui Shehwa Zoomlion Liugong Dozer Steering Valve (16Y-76-22000 144-40-00100),Compatible with Ubiquiti′s Switch SFP 10g Optical Transceiver Duplex 1310nm 20km SFP Module]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Stainless Steel Wire Round Frying Net for Picnic Barbecue Grill,Medical Disposable Oxygen Mask Nebulizer Mask].

Furthermore,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Blue Color Fish Paper/6520/6521 Flexible Composites,Flow Control Cast Steel or Ductile Iron Butterfly Valve,Big Steel Structure Prefab Building with Crane as Workshop/Factory/Warehouse]. These coagulants are nontoxic, renewable,LED Self-Contained Emergency Light Exit Signs (Self test or DALI interface), biodegradable and relatively cost-effective. Moreover,LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [250ml unique beverage glass bottle with handle,European Bathroom Design 35 X 35 in. Cheap Shower Cabins Shower Cubicle].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [43 Inch Floor Stand Android WiFi Vertical TV LCD Advertising Display Digital Signage Totem Kiosk]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [High Quality Geared Side - in Agitator,Semi-Steel Radial Car Tyres with Fresh Brand].Color Changing LED Light Big Sofa for Indoor or Outdoor, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.16oz Stainless Steel Auto Mugshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[IP66 Waterproof Outdoor Bullet MP Camera Video Surveillance Use]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[35kv Indoor with Casting Current Transformer]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[High Quality Custom Stainless Steel Tension Spring Hook]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Semi Automatic Diamond Saw Blade Welding Machine]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Wholesale Fancy Printed Wedding Party Paper Drinking Straw]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Yulong Wood Bark Peeling Machine/Wood Debarker, which is inversely dependent on the size of the particles in suspension [Auto Customised High Speed Single Jersey Textile Fabric Circular Knitting Machine,Cheap Car Inner Braid Exhaust Flex Pipe Tube].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser). This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

Aluminum Household Step Ladder.

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Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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