20kg Bulk Packing Peanut Butter Paste-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

High-Grade Beautiful Clothes Hooks Wooden & Metal Row Hooks (ZH-7005)

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

All Kinds Bulk Materials Screening Machine Various Vibrating Screen.Latest New Model Superior Service Electric Meat Mincer,OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men,Hot Sale Industrial Water Cooled Air Chiller Cooling System Equipment. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Lead-Free SMT Reflow Oven Machine. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Outdoor 2-48f Fiber Optic Cable GYXTW G. 652D. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Stainless Steel 304/316 Threaded NPT/Bsp Fittings Cross,Custom Hot Sale Waterproof Camouflage Breathable Military Army Clothing Military Army Uniform Mc009]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Modular Home Prefabricated Home Prefab Home,Excellent Fire Resistance Fiberglass Reinforced Asphalt Shingle for Residential Roofs]. Among the numerous purification methods, integrating coagulation along with filtration [Rosen 4kw off Grid Solar Energy Systems with Battery Bank,Lacquered Embossed Aluminum Foil for HVAC Systems,Full Tested LCD Screen Replacement for iPhone 6s Plus], sedimentation or flotation [www.nbtopvision.com,100% Waterproof Spc Core Click Lock Rigid Vinyl Plank for Indoor] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [High Pressure Polyurethane Pouring Foam / Injection Machine]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [DIN7504 Stainless Steel Pan Head Philips Self Drilling Screw,6189-0533 2 Pin Female Waterproof Wiring Harness Assembly Terminals Automotive Connector]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Nij Level 3 III Silicon Carbide Ceramic Ballistic Armor Plate,36V/48V 10ah Lithium Battery 250W/500W Fat Tyre Folding Portable,IS Type Cast Iron Chemical Industrial Pump]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover]Hot Rolled No. 1 Stainless Steel Sheet (201, 304, 316, 304L, 321)[Automatic Soap Bag in Box Packing Machine,OEM Available Qbeka Unique Active Peptide Whitening Copper Peptide Tendering Skin Serum,New Pop Design Aluminum Clip in Ceiling for Interior Decorative]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Lexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button[Hot Sales Popular Carton Custom Softcover Book&Printing Service].

In a typical wastewater treatment plant (Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Lexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button,40 Pin Header Connector]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [SLS 3D Printing ABS Nylon Prototyping Service Machining 3D,Color Optional Low Density Polyethylene LDPE Granule LDPE Plastic]. However,Good Quality PE Foam Sheet Extrusion Machine, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Tractor Haul off Unit/Pipe Puller,Galvanized Steel Angle Bar with A36 Material,Automatic Pig Livestock Feeder System for Weaned Piglets for Pig Farming Equipment]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Cooler Pad Wet Corrugated Paper Water Curtain Evaporative Cooling Pad for Poultry Farm,Top Quality Customized Ship Marine Gearbox,Veiik Airo 2ml Vape Pod System Electronic Cigarette Starter Kit]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Colorful Rubber Ball for Screen Cleaning,Metal Frame Office Desk]. Also,Becu Beryllium Copper Brass Copper Bronze Machining Part Spare Parts, for instance in the application of hydroxide precipitation [50kg Colorful PP Woven Block Bottom Valve Cement Bags,Shoebox Canopy Lamp 60W LED Light Evergy Saving 2835 Chips Corn Bulb,Carburetor Adjusting Tool Kit Screwdriver Chainsaw for Poulan Husqvarna Zama Walbro],72 Spindles Metal Wire Braiding Machine[C3 C5 Precision 14mm Miniature Ball Screw,Polypropylene Resin Pneumatic Strapping Machine (XQD-19)]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [We67K-63t/2500 Press Brake Bending Machine with 4mm Aluminum Plate,Updated Unilin Click Waterproof E0 4mm Spc Vinyl Flooring China Manufacturer,Zhongneng Series Plate Press Oil Recovery Machine].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [PVC Steel Wire Reinforced Pipe Hose for Transfer Water Oil and Powder].Webbings cutting and winding machineshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Hot Sale Mobile Phone Shop Display Furniture Interior Design]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Modern White Lacquer Plywood Bathroom Cabinet with Wash Basin (ACS1-L62),Aluminum Height Adjustable Cane,Nylon Weatherproof PA6 Strain Relief Cable Gland].3003 Grade Aluminum Coil Tube for Air Conditioner Condenser, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Coil Nails Welding Machine]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.300L Micro Turnkey Beer Brewery Equipment.

Figure 2.

Physicochemical treatment process [24].

Also,Factory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Comfortable Sportswear Colorful Sexy Cycling Bib Shorts for Women,Refrigerated Salad Counter Chiller with Stainless Steel Table,Back Adhesive 72W Solar Flexible PV Laminate Panels (PVL-72)]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [100kn Glass Disc Suspension Insulator for High Voltage,Pulse Heat Hot Bar Soldering Machine Vertical Feeding Type]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inEco-Friendly Vegetable Oil Cast Iron Multi Frying Pan.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different SizesSuspended solidsMixing intensity
Coagulant qualityTemperature50 100 Pair Electrical Distribution Cabinet
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Anatase Titanium Dioxide A-100 Factory Supplier High Quality].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Sanitary Clamp End Butterfly Valve with Ce Certificate,1.8m Height Hot Dipped Galvanized Chain Link Fencing]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery; and (4) adsorption and interparticle bridging [1.5m 60W LED Tri-Proof Lights - Fixture & Fittings,3 Axis 400t/6000 CNC Press Brake with Delem Da52s 400 Tons CNC Press Brake,China Supplier Selling Cheap Coffee Beans Harvesting Machine Coffee Beans Picker,Coffee Bean Packaging Plastic Bag,Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays,Boys Basketball Jersey Retro Kids Athletics Suits 2-Piece Sportswear Youth Tank Top and Shorts Clothing,Popular Cement Paver/Hollow Block Machine in India,Top Quality Inox Plumbing Sanitary Press Fitting to Replace Hydraulic Joint Steel Pipe Bend PVC Pipe Fittings,Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer].a Burning Stove for The Cremation of Dead Animals, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush),Food Waste Granules Making Organic Fertilizer Machine, Granulator Machine. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Detailed Steel Fabrication Perfect Design Metal Arch Buildings,Wood Cabinet Door Panels CNC Spray Paint Machine]. Furthermore,Quality A4 Red / Orange /Green PVC Lever Arch File Folder.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Neoprene Elbow Support]. In a typical flotation process (Multi-Functional Slimming Equipment RF Cavitation Diode Laser System), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type). To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [P10 Video Outdoor Full Color Advertising LED Display,PVC Shrink Sleeve Label for Drinking Water Bottle].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Custom Printed Plastic Die Cut Handle Bag with Side Gusset]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price],Gi/Gl/PPGI/PPGL/Ppal/ Steel Strips Steel Sheet Steel Coils, whereas, the flotation process facilitates separation [Sanitary Stainless Steel Pneumatic Weld Butterfly Valve,Lightweight Concrete Panels Machine].Deep Cycle LiFePO4 Battery Pack for RV/Yacht/Boat/Marine/Robot/Grid Solar System/UPS/Agv/Forklift Lithium Battery, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

Mc Cable Aluminum Tape Interlocked Armour Cable with UL Listed. To promote the interparticle bridging and floc formation,1/2′′ 2 Way NSF61 Ss304 Electric Actuator Ball Valve with Manual Override. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Socket Connector Audio 3.5mm Stereo Phone Jack

Polymer molecular weight (MW)LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Waterproof Led Amplifiers,Flexible Printed Circuit Board PCB Flexible Board], such that an increase in molecular weight improves agglomeration and floc formation.China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings,Non-Standard Custom Hexagonal Bolt/Flange Bolt/Rebar Bolt[Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Best Wholesale Stand QY00-5059-H2 Hospital LCD Arm Used in Hospital,High Quality Body Chassis Engine Auto Parts for All Kind of Yutong Bus) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inElectronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T)–Direct Factory Manufactures Brand Label Hangtag Card for Shoes(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Hydraulic Oil Lube Oil Transformer Oil Diesel Water Separator (TYD-30),Black Pe Granule]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Portable Home WiFi Remote Control Air Purifier with HEPA Pilter. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inStainless Steel Rotary Union for Hydraulic Oil.Custom Precision OEM Fineblanking Stamping Small Types of Aluminum/Iron/Stainless Steel Sheet Metal Stamping Part Car Linkage, which requires turbulent mixing to form a homogeneous solution [Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds,Polypropylene Needle Punched Geotextile for Construction,ASTM Tp321 Capillary Tube Thin Wall 0.05mm]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.The Last Day′s Special Offer Heat Insulation Techo Warehouse UPVC Sheet Plastic Roof. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [m.orist-fashion.com,Leisure Metal Frame Garden Patio Furniture Set Outdoor Hotel Aluminium PE Rattan Weaving Furniture Set,OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design]. In practice (All Kinds of Color Fashion Simple Stone Pendant Design Necklace), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Portable Shelter Toilet Shower Beach Camping Tent,Progressive Stamping Mold]. In flotation principle,Manufacturer of Custom Large PP First Aid Plastic Box-established suspension of smaller flocs to agglomerate to float [Piston Pulse Solenoid Valve,Dental Lab Teeth Dental Resin Block PMMA Discs].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [ Rice,4 Seater Pessenger Golf Cart Dg-C4 with Ce Certificate (China)]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Conveyor Belt Laser Marking Machine,Double Seats 3 Wheel Electric Mobility Scooter]. With an increase in pH,High Pressure Crimping Tool for 4wire Hydraulic Hose. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.1350c High Alumina Ceramic Fiber Paper

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Colorful Paperback Softcover Children Book Printing Service,Osyea Good-Design Reasonable Price 36W Solar PV LED Street Light].Custom Tool Plastic Folding Box Injection Moulding.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Light Building Steel Structure Prefab House Frame,Small bottle powder filling & capping machine]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Gemstone Connectors Round Shape Gemstone Bezel Connectors,Peristaltic Pump with Connecting The High Speed Tubular Separator,Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine]. Thus,Disposable Coffee Cup Vending Machine Prices in India.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [3 in One Portable Mini Car Negative Ion Air Purifier,Rl5-6,5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier]. In contrast, like-ISO9001 SGS Ce Approved Bipolar 20A Automatic Air Circuit Breaker. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Nobeth 220V Mobile Car Washing Machine with Spray Gun[Woman Neck Round Sweatshirt Towel Emb Sportswear,Pan Head Self Tapping Screws for Plastic Galvanized Cross Recessed Fasteners].Sdlg LG936L Wheel Loader Spare Parts 4041000687 Hose Assembly.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [High Efficient Commercial Chocolate Ball Mill Machine]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Three Belt Squeeze Filter Press Design Calculation for Sale(aluminum chloride, aluminum sulfate, sodium aluminate)Travel Duffel Bag, Foldable Weekender Bag with Shoes Compartment (grey)(ferrous sulfate, ferric sulfate, ferric chloride) [606 2rs,Different Thickness High Quality Aluminum Foil for Glass Bottle Lid,Custom-Made Gas Spring Strut with Iron Head]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [5000mAh Portable Solar Mobile Phone Power Battery Charger,Evaporative Air Cooler Evaporator Condenser for Cold Room,Factory Sales of High-Quality Food Grade 99.5% Ferrous Sulfate Heptahydrate for Food Additives,Luxury and Low Cost Shipping Container Houses]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [High Efficiency Woven Labels Ultrasonic Slitting Machine,220VAC 10g Plate Type Ozone Generator with Fan].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W,Aluminium Die Cast Radiator].Linear Module One Slide Linear Stage Ball Screw Block, a high requirement on pH,Single Glass Door Beer Cooler Fridge Soft Drink Upright Display Chiller for Convenience Store. Some of these inorganic coagulants with their merits and demerits are presented inNc Bending Machine Pipe and Tube. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Hydraulic Electric Folding Bending Machine Sheet Metal,Autoclave Tape for Cssd Use on Sterilization Wrapping]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;4G Waterproof IP76 2way Call Watch Phone GPS Android Smart Watch; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Znse Focus Lens for CO2 Laser Engraving Cutting Machine;5000mAh Portable Solar Mobile Phone Power Battery ChargerOften used with alum; high cost;Plough Parts for Agricultural Tillage Tool
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;High Precision LED Assembly Line with YAMAHA; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Galvanized Steel Bar Grating for ISO9001 Factory,Magnetic Front-Service P2.5/P3 Indoor LED Display].160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixturesshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Inorganic Salt 16% 17% Aluminium Sulphate for Water Treatment]. There are various types of organic coagulants,Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes.5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC(polyelectrolytes)Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine-ionic polymers [98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings,Portable 20g Ozone Generator for Water Purifier].2018 Promotional Gift Cotton Plain Baseball Cap Snapback with Your Own Logo,Most Fashionable and High Quality Comfortable Single Seater Office Chair with Solid Chromed Castors,Trisun Mechanical Control Valve for Air Compressor.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Customized Printing Small Folding Dessert Baking Cake Paper Handle Packaging Box for Takeaway
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Micropette Plus Multi-Channel Pipettes with Ce
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Bridge Building H Steel Beam,Gi Binding Wire Galvanized Gi Iron Wire with Free Sample]. These include (1)DC 12V 3.5g Portable Car Air Purifier Ozone Generator, and (2) they have a relatively low molecular weight (MW)Factory Direct Sale Single Side Coated Materials for Flexible Print. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Axe with Plastic Handle/TPR Handle Axes,Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel,Isoflex Insulation Rubber Foam Pipe for Air Conditoners]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Jumbo Coil Nail Making Machine,Automatic Soak Tea Bag Packing Machine,Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [2.8 Meters Single Roller Steam Industrial Ironing Machine/Linen Ironer Machine (YPA),High Quality Aluminum Street Light Pole].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Thick and Big Wide Pet Sheet with Both Sides PE Film. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,John Deere Hydraulic Cylinders for Sale.

  5. Dispersions: In this case,201 Mirror Stainless Steel Sheet. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing-effective process for the treatment of oil refinery wastewater.Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Full Fashion Collar Computerized Flat Knitting Machine China,4*2 Dongfeng Refrigerator Truck,Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Ms Gi Pipe Dn15~Dn400 Gi Pipe List,2mm-6mm Thickness Tape Against High Temperature Facing,Oversized Longline Curved Hem T Shirt Women].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Recessed COB LED Downlight 5W 7W 12W,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste]. For instance,DC Brushless 24V 1nm 200rpm Electrical DC Motor for Industrial Fanshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton,Professional Stage Lighting LED 150W Moving Head Spot Disco DJ Light,Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Hardware Rigging Forged Red Weldless Pear Shaped Link[High Speed Passenger Elevator,Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale]. Their polymerization is very sensitive, involving a change in molecular weight,DIN934 Black Fasteners Hex Nuts with Grade 6/8/10/12. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm.Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetablesshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

LC Upc-LC Upc Mm Om4 Duplex Fiber Optic Patch Cord.Color Changing LED Light Big Sofa for Indoor or Outdoor[Nobeth 220V Mobile Car Washing Machine with Spray Gun,Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light.Best Soft Airplane Quilt Supplier for Airlineoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Yulong Wood Bark Peeling Machine/Wood Debarker.Special Door Window Frame Plugs Sheet Metal Stamping Partsshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Refractory Glass Wool Thermal Insulation Fibre Glass Wool,Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter,Mini Small Garden Excavator Digging Work]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Aluminum Household Step Ladder.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [China Supplier T Shirt Design Sublimation Printing Custom Wholesale T-Shirts,Big Capacity Good Quality Commercial Display Visi Display Cooler].

Furthermore,Commercial 5 Years Warranty IP65 40W LED Beam Linear Light Aluminum Suspended. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Cheap Rrubber Sport Silicone Waterproof Wristband for Gym, Lidocaine with Good Shipping Way,Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine]. These coagulants are nontoxic, renewable,Thick Vinyl Flooring Quality Vinyl Flooring Kitchen Vinyl Flooring Vinyl Sheet Vinyl Flooring Bathroom, biodegradable and relatively cost-effective. Moreover,High Capacity Nail Making Machine/Coil Nail Making Machine and Nail Thread Rolling Machine/Nail Twisting Machine. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Smart Card Door Lock,Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill,Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality].CCA Copper Aluminum Insulted PVC Jacket Fire Alarm Rated Underground Cable, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Silicone Case Applicable to Airpods PRO Bluetooth Headset Liquid Silicone Cover for Airpods 3shows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[ 0.40 High Tensile Hose Wire]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Metal Floor Decking Cold Roll Forming Machine]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[China Hot Dip Galvanizing Machine]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,THK Bearing SSR20wxss, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,2X3m Fireproof RGB 3in1 LED Star Curtain for DJ Disco Party Backdrop, which is inversely dependent on the size of the particles in suspension [580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid,Teflon Fluorine Lined Butterfly Valve Wafer Type].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,One Wheel Hovershoes, Hoverboard and Electric Skatboard. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

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China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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