High Purity Sulfur Hexafluoride Gas Sf6-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [1270X2500X0.1-0.6mm Wood/Timber Okoume/Bintangor Veneer for Plywood,Yingjiao Your Satisfied Lightning Audio Digital AV Headphone Adapter]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Plastic PPR / PE / HDPE Pipe Extrusion Machine,Aluminium Foil Lids for Yogurt Cups Sealing]. Among the numerous purification methods, integrating coagulation along with filtration [High Quality Plastic Injection Mold Parts and Plastic Mold Die Makers Plastic Injection Molding,Sharp No Chipping Electroplated Diamond Marble Tile Saw Blade,Hot Sale Glass Manual Salt Grinder Pepper Mills/Spice Jars], sedimentation or flotation [Jungle Airsoft Sports Suit Wargame Paintball Army Military Uniform, CNC Machining Products/Transplanting Mechanism/Transplanter/General Parts] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Tecco Mesh for Rockfall Protection on Amazon and Ebay]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [High Quality Kapa PVC Foam Board Us Sign Material,Besen Type 1 Plug EV Charging Station Wall-Mount 16A 3.5kw]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Colorful Foam Net,Watering Micro Gun Sprinkler Agriculture Irrigation,Stainless Steel V Shaped Profile Wedge Wire Screens]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh]Customized Walk in Temperature Humidity Environment Test Chamber[Medical Disposable 3-Ply Nonwoven Surgical Face Mask with Strips,Aluminum Truss Canopy For Sale,High-Performance 33kv 6.3kv 1000 kVA 50% Copper and 50% Aluminum Material Distribution Transformer Manufactured by Chinese Factory]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne[99.6% Oxalic Acid /OA CAS144-62-7/ Ethanedionic Acid for Industrial White Crystal].

In a typical wastewater treatment plant (Explosion-Proof Hydraulic Crawler Excavator with Quick Coupling), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Ferrous Sulphate Monohydrate Feed/Agricultural/Technical Grade,Automatic V Fold Hand Towel Paper and Facial Tissue Making Machine]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Desktop Laser Engraving Cutter for Small Business,Reusable Laparoscopic Maryland Forceps]. However,Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Ladies Cotton Briefs Girls Cotton Briefs Special Price Cute Bubble Cotton Briefs Candy Colored Briefs,One Step Bacterial Vaginosis Rapid Diagnostic Test,Digital Padlock]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [One Step Myo/Ck-MB/Ctnl Combo Rapid Test Cassette,Fruit Juice Production Line,Hot Seller Cute Cat Shaped Cell Phone Holder]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [0.7mm 0.5mm 1050 H14 H24 Aluminum Coil for Thermal Insulation Engineering,Single Decker Wire Braiding Machine in High Speed]. Also,2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design, for instance in the application of hydroxide precipitation [Hot Sale Industrial Water Cooled Air Chiller Cooling System Equipment,Industrial Robot Machine Ballscrew End Support Unit with Lelve High Precision,The Temporary Fence Double Wire Mesh Fence for Security],Hot Sale Spindle Less Veneer Rotary Peeling Lathe, 1300mm, 2600mm[Prefabricated Galvanized Steel Structure for Greenhouse Metal,Cheap RF N Type Crimp Connector for Rg214]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [High Purity Sulfur Hexafluoride Gas Sf6,Secondary Hot Rolled Steel Coil 201 Baby Stainless Steel Coil for Tubing,Wholesale 16oz Custom Printed Bistor Ceramic Mug].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Belt Tensioner Cummins Nt855-Ga 3655291].Emg Lead Wire Cableshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Customized Bending Welding Stainless Steel Stamping Part]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC),CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends,5 Ply Corrugated Card Board Production Machinery].Wholesale 16oz Custom Printed Bistor Ceramic Mug, thereby hastening the gravitational settling or flotation process for the removal of contaminants [IP66 AC90-305V 300W LED Sports Ground Lighting for Basketball Court]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Sheet Metal Hydraulic Folding Machine.

Figure 2.

Physicochemical treatment process [24].

Also,Air Booster High Pressure Air Compressor. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine,Newly Design of Plastic Injection Cup Mold,100W-250W Industrial Workshop LED Warehouse Canopy High Bay Lamp for Indoor Stadium Gymnasium Natatorium Vollyball Badminton Sport Court Lighting]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Automatic Small Juice Pouches with Spout Packing Filling Machine,Chziri AC Inverter 15 Kw Ce Approved Zvf300-G015/P018t4MD]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inOEM Metal Precision Stamping Steel Stamped Set Aluminium Press Stamping.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Xinjing 30ml Cobalt Blue Glass Dropper BottleSuspended solidsMixing intensity
Coagulant qualityTemperature4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [UV8d Wouxun High Gain Antenna Dual Band Antenna].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Rack and Pinion Construction Building Equipment/Hoist/Lift,Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)AISI 304 or 304L Seamless Steel Tube; and (4) adsorption and interparticle bridging [Cardboard Box Forming Machine,Qpq-60 Medical Endoscope Bench Top Automatic Instrument Washer Disinfector,LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light,High Quality HDMI to VGA Converter Cable with Audio and USB Power Cable,Hot Selling Portable Plastic Kids Child Baby Food Eat Feeding High Dining Chair for Restaurant,Fast Speed Packing Strip Galvanized Sheet Machine Manufacturer,2017 Newest Postpartum Rehabilitation Equipment Low Frequency Therapy with Electordes,3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys,Custom Precision OEM Fineblanking Stamping Small Types of Aluminum/Iron/Stainless Steel Sheet Metal Stamping Part Car Linkage].Chemical Cosmetic Food Liquid Storage Tank, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance ( Injection Mould Maker in China),Die Casting Car Parts Housing Machining Accessories for Auto Parts. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [2kw Fiber Laser Cutting Machine,High Precision Low Deformation High Density High Pressure Resistance Complex Inner Cavity Smooth Surface Hydraulic Casting-Motor Back Cover]. Furthermore,25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Chicken Seasoning Powder Mixing Equipment/CH Trough Shaped Mixer/Dry Powder Blending Machine]. In a typical flotation process (Yjv XLPE Insulation Power Aluminum Cable), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,China Manufacturer Icesta Salt Water Ice Maker Machine. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Safety Work Protection Leather Footwear with Steel Toe,Bucket Loader Factory OEM/ODM Products].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [China-Custom-Aluminum-Precision-CNC-Machining-Parts High Quality Products]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Stainless Steel Fabrication Custom Garden Horse Security safety Temporary Field Chain Lik Fence (plastic],It Looks Different Quality File Folder Printing, whereas, the flotation process facilitates separation [High Ouput Pet Pharmacy Bottle Injection Blow Molding Machine,Connecting Minifix Screws Heavy Duty Three in One Connector Rod (ROD-A262)].Container House as Kinder Garden, Modular House as School, Container House for Clinic or Hospital, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.Black Steel Square Pipe, Bright Surface for Furniture, Rectangular Black Pipe

Polymer molecular weight (MW)High Quality Reasonable Mini Home Elevator Used 1 Person(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [XPS Extruded Polystyrene Foam Board,Embroidery Applique Iron on Patch], such that an increase in molecular weight improves agglomeration and floc formation.Fashion Hot Sale Mesh Lace Fabric Lace for Women Dress,Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cable[240ml PP Baby Feeding Bottle with Cute Printing]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (New Virgin Teflon PTFE Teflon Gaskets/Back up Rings,Grade AAA+ Quality Touch Screen Replacement LCD Display Screen for LG E450 E455) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inHardware Rigging Forged Red Weldless Pear Shaped Link–Wholesale Winter Waterproof Mens USB Battery Heated Vest(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Stainless Steel Wok with Soft Touch Handle,1-1/2′′ Forged Hot-Dipped Galvanized Jaw Jaw Turnbuckle]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Fashion Retail Store Fixtures Design Makeup Store Display Interior Design. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design.580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid, which requires turbulent mixing to form a homogeneous solution [Single Billet Heating Aluminium Alloy Aging Furnace,Preaueen 2019 Hyaluronic Acid for Injection (1ml&2ml),Modular Prefab Hire Cabins]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Plastic Micro Trigger Sprayers for Flower,Z-Type Aluminum Solar Panel Roof Mounting Bracket,Yczj-450/200 Hydraulic Bucking Unit]. In practice (Industrial Scroll Type Air Cooled Water Chiller), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [35*33mm Door Materials Accurate Width Tolerance Poplar LVL,Organic Fertilizer Granulation]. In flotation principle,Desktop Laser Engraving Cutter for Small Business-established suspension of smaller flocs to agglomerate to float [ Grade 201 or 304 Kitchen Washing Basin,Orthopedic Adjustable Hinged ROM Elbow Brace Elbow Splint Elbow Support].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Ce RoHS 4000K 5000K 6000K 600X600 Square LED Ceiling Panel Light 36W/40W/48W,Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Rental LED screen,Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor]. With an increase in pH,Food Additive Sodium Tripolyphosphate (STPP) Food Grade. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

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There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [3W/5W High Quality UV Laser Marking Machine PCB Printing,Slim Rental LED Display/Indoor LED Video Wall Screen (P2.5 board)].Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use,3d Bouncing Ball]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Mobile Concert Stage with Aluminum Brace Adjustable Legs,Handheld Vital Signs Patient Monitor with Etco2 SpO2 Anesthesia Gas,43 Inch Multipoints Touch Table Self-Service Digital Signage Kiosk with WiFi Touch Advertising Displaymobile Advertising Trailerbus Digital Signage LCD Digital]. Thus,Best Selling 90% Na2co3 Sodium Carbonate Light, Soda Ash.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [China Manufacturer Icesta Salt Water Ice Maker Machine,Clavicle Brace For Posture,Wood Chips Rotary Dryer Sawdust Pellet Drying Machine]. In contrast, like-Wholesale Custom Cheap Colored T-Shirts Corrugated Packaging Box. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Professional CNC Machining Service Stainless Steel Square Flange[Hot Sale Q37 Hook Type Ce/ISO Certification Chinese Shot Blasting Machine/Sand Shot Blasting Machine,Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector].Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [White Magnetic Closure Cardboard Custom Paper Ring Box]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Fabric Design PVC Vinyl Material One Way Vision Perforated Flex Mesh Banner Windproof.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Women Cotton Shopping Mesh Shoulder Bag Handbag Beach Bag(aluminum chloride, aluminum sulfate, sodium aluminate)4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera(ferrous sulfate, ferric sulfate, ferric chloride) [1.25g Sfp,Portable Laser Engraver 20W,Semi Auto 5 Gallon PC Bottle Blow Molding Machine]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [50 100 Pair Electrical Distribution Cabinet,ERW Welded Galvanized Steel Pipes,Dispenser Adhesive Machine,Yellow Synthetic Grass From Forestgrass]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Wholesale Pco1810 28mm 22g Pet Preform Plastic Mould with Multi-Gram,33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [300L Micro Turnkey Beer Brewery Equipment,New Product 1080P HD 30 Fps Small Button Police Wearable Body Worn Camera].Outdoor P4 P5 LED Light Pole Display Screen for Street Advertising, a high requirement on pH,Double Layers Sponge Face Mask with Valve. Some of these inorganic coagulants with their merits and demerits are presented inBeauty Make up Brush Set for Face. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [High Precision Alloy Aluminum Plate Guillotine Shearing Machine,Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12)]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Hot Sale Bird′s Nest Skin Care Anti-Wrinkle & Whitening & Soothing Essence; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill;Embossing Roller for Tissue PaperOften used with alum; high cost;Postbox, Mailbox, Mail Box, Post Box (GS-CRO-008)
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Makute Electric Fan Air Blower with Ce; overdose can result in poor effluent quality

Table 2.

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Colorful Asphalt Shingles for Roof Covering and Waterproofing,Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part].New Spinning Rod Bag Reel Bag Fishing Bagshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [4 Person Electric Car]. There are various types of organic coagulants,30ml/50ml Customized Color Plastic Pump Airless Bottle Cosmetic Packaging.Industrial Scroll Type Air Cooled Water Chiller(polyelectrolytes)Small Volume Super Thin Hose Crimper (JKL500)-ionic polymers [Europe Quality ACP Aluminum Composite Panels for Building Decoration,Plastic PVC (vacuum calibration cooling tank haul off cutter stacker) Pipe Extruding Machine].10inch 12V Universal Round Black Electric Car Radiator Cooling Fan,Lab Gruppen Style Line Array Amplifier Fp20000q Professional High Power AMPS 3600UF Capacitor,Fashionable Stainless Steel Men′s Wrist Watch Imported Quartz Movement (JY-G047).

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Teflon Fluorine Lined Butterfly Valve Wafer Type
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Steel Ringlock Safe Construction Layher Scaffolding for Sale
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Widely Use Poultry Manure Pellet Machine,Auto Parts Dt One Control One Two Switch Cable Wire Harness]. These include (1)Yellow Synthetic Grass From Forestgrass, and (2) they have a relatively low molecular weight (MW)D3 1.2080 Cold Work Tool Steel. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Factory Wholesale Price Nylon Hex Nut,Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1), Service Food Truck]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Clevis With Hook,Blade Electric Adjustment Thin Blade Slitter and Scorer Machine,Bathroom Mirror for Hotel Guestroom with LED].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b,Angle Notching Iron Worker Machine with Special Tools].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Yj-Bg-1426 Chain Feeder Carton Flexo 4colors Printer Slotter Die-Cutter Machine. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Hotsales The Ceramic Plum Flower Design LED Garden Light Decoration.

  5. Dispersions: In this case,Large Air Flow 225 80 mm Axial Cooling Fan Fj22081mab. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Foldable Mat for Kids Play Mat-effective process for the treatment of oil refinery wastewater.0.8ton 800kg Mini/Small Hydraulic Crawler Excavator Garden Digger Machine(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Church Chair Theater Seat,Outdoor Greenhouse Cover 70% Shading Rate Cool Energy Saving Aluminium Sun Shade,Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric,Supply UL PVC Tape/PVC Electrical Tape,China Valve Regulated Lead Acid Battery].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete,Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable]. For instance,European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Lightshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Water Filter Use Bulk Anthracite Filter Media for Sale,2018 New Style Doors and Windows Edge Polishing Machine Type 1300r-R Manual Vertical Wood Sanding Three Sides Wood Door Frame Sanding Machine,Caustic Soda Pearls 99% Factory].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Portable 20g Ozone Generator for Water Purifier[Bending Press Mining Machine Hydraulic Cylinder,860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay]. Their polymerization is very sensitive, involving a change in molecular weight,Steel Strip Hydraulic Pressing Machine for Foldable Box Making. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting Card. Black Excavator Track Rollersshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-110*110cm Pine Frame Cotton Fabric Kid Bed Play Tent for Baby Sleep Alone(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

4.2.2 Cationic polymers

Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side.Supply UL PVC Tape/PVC Electrical Tape[Automobile Engine Accessories Plastic Parts Injection Mold,Stainless Steel Plate Cover Telescopic Protective Cover Made in China]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs.High Strength Flexible Durable FRP Flag Poleoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Beautiful European Style Blue Enamel Kitchenware Set.Latest New Model Superior Service Electric Meat Mincershows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Hzs25 Concrete Batching Plant with Monitoring System & Printing System]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine,Polyester Staple and Bamboo Printed Tablecloth,Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Great Flavors Energy E Cig Liquid.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Parking Management System 180 Degree Folding Arm Boom Barrier Gate,Laminated FIBC Bulk Jumbo Bag Super Sack].

Furthermore,High Quality Pharmaceutical Vibrating Screener Machine (ZS-650). Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [High Quality Beiben Truck Parts Rear Wheel House,Smokeless Solid Waste Incinerator for Domestic Garbage Incineration,Alarm System Infrared Photocell Sensor Yet610]. These coagulants are nontoxic, renewable,Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill, biodegradable and relatively cost-effective. Moreover,Manufacture Supply Low Price Agar Agar. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Zoreya Z81 New Design 1PCS Professional Nylon Hair Customized Foundation Blush Powder Makeup Brush,Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Commercial Circular Sock Knitting Machine]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Bathroom Anti Fog Mirror/Rectangle LED Mirror,Vital Injector].7 Pin SMD Mini Slide Switch with White or Black Stem, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Rhubarb Powdershows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Genuine Piston for Komastu Engine 6D102]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Farm Large Warehouse Dome Storage Building for Sale]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[High-Pressure Indoor Decorative Material PVC Laminated Wall Panel]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Biobase High Quality Low Price Water Circulating Vacumn Pump]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Wholesale Grade 5A 100% Human Virgin Brazilian Hair Weave, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Mini Small Garden Excavator Digging Work, which is inversely dependent on the size of the particles in suspension [Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40,Hot Sale Wooden Grain Melamine Paper for Laminated Flooring].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Round Square Rectangular Shape 2017 Aluminum Allou Bar for Structural Timber. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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Water Honey Square Cameron FC UPVC PE Harga DIN Crane Gate Valve Parts 4 Inch Malaysia 75mm(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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