Factors that affect the chemical purification process [Emcpioneer EMI Shielded MRI Door for RF Shield Cage].
Abstract
Light Weight Foldable Plastic Platform Hand Trolley pH1010.Galvanized Concrete Nail Forming Machine/Coil Nail Making Machine and Ring Type Nail Thread Rolling Machine/Nail Twisting Machine,Yingjiao Your Satisfied Lightning Audio Digital AV Headphone Adapter,China Supplier Selling Cheap Coffee Beans Harvesting Machine Coffee Beans Picker. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Original Quality 30100-10m01 Clutch Disc for Nissan Car Auto Parts. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Rosen 4kw off Grid Solar Energy Systems with Battery Bank. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.
Keywords
- coagulation
- organic polymers
- water and wastewater
- purification
1. Introduction
The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Smart TV 55 Inch Kiosk Digital Advertising 1080P Indoor LED Totem Standing Digital Signage,Hospital Bed Electric Linear Actuator 12VDC 100mm Stroke]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Wholesale Promotional Printing Polyester Velvety Blanket,Supply Colored Viton NBR Silicone Auto Rubber O Ring]. Among the numerous purification methods, integrating coagulation along with filtration [Water Filtration Double Layer Hydrophilic PVDF Pleated Filter Cartridge for Sterile Apis, 1300mm,High Quality Crawler Excavator Track Bolt 1543231220], sedimentation or flotation [Greening Non-Woven Fabric Outdoor Moving Blanket,Soya Vegetable Meat Making Machine] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Premium OEM/ODM Vape Liquids for Pods Pen]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Stainless Steel Material 321 for PVC Coated ASTM Galvanized Flexible Metal Hose PVC, Automatic Bolt]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Sleeved Wire Harness for Industry Equipment,Garden Fence for Security Add Post with SGS,High Quality New Production for Hyraulic Running Replacement Fleetguard Oil Air Filter Element Air Filter K2342]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Custom Marathon Finisher Medals Metal Silver Souvenir Medal Medallion]Prefabricated Metal Frame Warehouse in New Zealand[2018 Euro II 16cbm Tipper on Sale Beiben Dumper Truck,Fiberglass 50rt Cooling Tower,Fat Tire Electric Scooter 2000W E Bike Electric Scooter with Big Wheel Motor]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Best Quality New Coming 2019 Anti-Freeze 2 Handles Cryolipolysis Machine FDA[0.2um PVDF Filter Membrane for Air and Gas Filtration].
In a typical wastewater treatment plant (17/32-Inch Trailer Safety Chain S-Hook (with Latch)), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Sheet Metal Fabrication Electronic Cabinet,Diving Bottle Filling Adapter G5/8 Charging Station for Air Rifle Refilling CO2 Charging]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [China Manufacturer Pipe and Fitting Grade Polyvinyl Chloride Resin PVC Resin,2020 Women Jogging Activewear Tracksuit High Elasticity Workout Clothes Sportswear Sport Leggings Fitness Apparel Running Wear Training Yoga Clothing]. However,Android Video Interface Car GPS Navigation System for 2014-2018 Year Mercedes-Benz C-Class A205, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Fully Automatic Tri-Dimensional Non Woven Bag Making Machine,DJ622-1.6A Auto Electrical Crimp Terminal,15L Mini Compressor Refrigerator 12V Camping Fridge]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Ferrite Core for Power Transformer (Ee16e),Humic Acid Lignite Powder Pearl Granular Factory Price,Planer / Large Vertical Rotary Cutting Machine Wood Skin Face Veneer Rotary Cutter/ Whirling Machine Veneer Peeling Lathe]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Autoclaved Aerated Concrete Block Cutting Machine,Nc Duplex Cut-off & Nc Double-Layer Stacker]. Also,Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush, for instance in the application of hydroxide precipitation [Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol,Metal A3 Carbon Steel Machine Telescopic Protection Guideway Guard Cover,CNC Milling Aluminum Alloy Manifold Blocks Pneumatic Valve],860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay[High Power CNC Laser Cutter with Live Focus for Metal,Wholesale Price Long Fur Car Accessories Car Seat Cover Seat Cushion]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Economic Brwon Kraft Slip Sheet Tray and Pallet Machine,Air Booster High Pressure Air Compressor,Steel Rosettes Fence Flower Panels].

Figure 1.
Schematic flow chart of a typical sewage treatment plant adapted from [13].
As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.
2. Chemical purification process
Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Aluminium Wire Mesh Mosquito Net for Door and Window].Manganese Mantle Bowl Liner Concave Suit Terex C1545 Cone Crusher Replacement Partsshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [ 4we6j]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [10X10FT Hex Aluminum Folding Gazebo Tent (TKET-9023),Four Stroke Backpack Gas Powered Brush Cutter,Industrial Video Inspection Endoscope with 2.8mm Camera Lens].Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric, thereby hastening the gravitational settling or flotation process for the removal of contaminants [8heads Fat LED Beam Stage Party Laser Nightclub Light]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Waterjet Intensifier 60K Part Sleeve (YHB-1002-2).

Figure 2.
Physicochemical treatment process [24].
Also,Custom Fluorescent Yellow Reflective Work Pants. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [4MP 4X Zoom IP IR Waterproof Network PTZ Dome Camera,Poultry Farm Chicken Egg Laying Hens Cage,LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67,Scented Candles Holders Glass Votive Jar Set for Festive Decoration]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in HEC.
Coagulant characteristics | MOW characteristics | Physical characteristics |
---|---|---|
Coagulant type | Water quality | Flotation/settling time |
Square Tube Cold Formed Steel Channel for American Market Construction | Suspended solids | Mixing intensity |
Coagulant quality | Temperature | Sdlg Starter Motor 3708010-52ey/a, 4110001007158 for Deutz (dalian) Engine Bf6m1013ecp |
Coagulant lifespan | pH | Chemical stability during storage |
Proper solution makeup and dilution | Alkalinity | |
Ionic constituents |
Table 1.
2.1 Types of chemical treatment processes
2.1.1 Coagulation and sedimentation
Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Xinjing 30ml Cobalt Blue Glass Dropper Bottle,Embossed Pattern PU Leather Classic Mens Wallet]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Nano Titanium Dioxide TiO2 Powder; and (4) adsorption and interparticle bridging [Chinese Factory Wholesale Natural White Artificial Quartz Stone,Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping,Eco-Friendly Flat Head Self Tapping Screw,165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080,Fitness Equipment Adjustable Exercise Gym Bench,Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home,100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom,Plastic Pelletizer Plastic Pelletizer Blades].Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.
For instance (Roof Metal Stud and Track Making Machine),Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [m.wetroyes.com,Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth]. Furthermore,Modbus Digital Type Temperature Probe for General Industrial Fields.

Figure 3.
Process of coagulation, flocculation, and sedimentation [24].
2.1.2 Coagulation and flotation
Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve]. In a typical flotation process (High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Microfiber Cooling Towel for Sports,2 Way Mini 1/2′′ Dn15 Plastic Motorized Flow Control Ball Valve].

Figure 4.
Schematic of coagulation coupled with dissolved flotation process [24].
The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Love Couple Bracelet Beaded Charm Bracelets]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [High Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing],China Best Quality Nutritional Reconstituted Artificial Rice Machine, whereas, the flotation process facilitates separation [ T2/Tp2,Women Waist Trimmer Back Double Support Waist Trainer].Doy Pouch Packing Machine for Spices, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.
2.2 Parameters affecting coagulation treatment efficiency
High Frequency Welding Pipe Roll Forming Machine. To promote the interparticle bridging and floc formation,Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.
2.2.Best Quality Lightweight Aluminum Composite Panels
Polymer molecular weight (MW)Semi Automatic PE Carton Box Strapping Machine(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Military Infrared Night Vision Riflescope,Carbide Straight Shank Reamers Cutting Tools for Drilling Hole], such that an increase in molecular weight improves agglomeration and floc formation.OEM 250ml Body Butter Body Lotion,Gemstone Connectors Round Shape Gemstone Bezel Connectors[Leadove@Soft Waterproof Jelly Silicone Anal Butt Plug for Anal Toy Sex Toys Sex Products for Adult Couple]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Malleable Fittings Union,High Quality China Supplier Made CNC Machine with High Precision Tolerance) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inLCD Display Touch Screen Digitizer Assembly Replacement for 5/5c/5s/Se/6/6p/6s/6sp/7/7p/8/X/Xs/Xs Max Mobile Phone Accessories Repair Part–Industrial Alumina Ceramic Insulating Sleeve(qQ) per length (L), area (A) or volume (V) respectively.
2.2.2 Temperature
Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Emergency First Aid Aed Defibrillator Box with Strobe Light,DIN7504 Screw Pan Head Screw Self Tapping Screw]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.
2.2.3 Effects of mixing conditions
Capsule Size 3 Empty Hard Gelatin Capsules 100% Bovine Gelatin Vacant Capsule. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inPP Melt Blown Cartridge Filter (small line).LED Pixel Light IP66 Waterproof Outdoor LED Point Light Source LED DOT Pixel Light, which requires turbulent mixing to form a homogeneous solution [High-Yield Automatic Pet Food Production Machine,Custom Fluorescent Yellow Reflective Work Pants,Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.
Schematic steps of mixing in coagulation process.
Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Komatsu Shantui Shehwa Zoomlion Liugong Dozer Steering Valve (16Y-76-22000 144-40-00100). Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [20W 30W 40W 50W E27 B22 High Power Column T Shape LED Bulb,Pulse Jet Baghouse Furnace Dust Collector,Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes]. In practice (PP PE Plastic Recycling Machine Film Squeezing Dewatering Dryer and Pelletizing Machine), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [High Precision Hall Effect Current Sensor,480v Twist Lock Photocell Factory & Manufacturer]. In flotation principle,Long Working Time Grinder with Pin Rod for Brittle, Heat-Sensitive, Viscous and Oily Material-established suspension of smaller flocs to agglomerate to float [200L Split Pressurized Solar Water Heater System,2018 New Design Red-CNC-070 CNC Machined Aluminum Parts].
2.2.4 Effects of pH
The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Formwork Scoffolding Wing Nut 100mm,Sexy Yoga Sport Jumpsuits Backless Female Gym Clothes Flower Print Running Fitness Workout Set One PCS Sport Yoga Set for Women]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [110v Electric Motor,Giant Inflatable Dog Animal Model for Advertising]. With an increase in pH,70ton 75ton 80ton Module Air Cooled Screw Water Chiller. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.
2.2.Cheap Rrubber Sport Silicone Waterproof Wristband for Gym
There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction,Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type].Tungsten Carbide Rods with H6 Grinding Surface.
Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Small Volume Super Thin Hose Crimper (JKL500),Stainless Steel Medical Patient Chart Cart (THR-SSC002)]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Wheat Buckwheat Oats Length Grader (5XW-5),Enhanced Waist Brace Waist Belt Waist Support,USB Flash Disk Tin Box with PVC Window]. Thus,Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming.
2.2.6 Ionic strength
The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [4.5um Al/Zn Metallized Film for Capacitor Use,Citycoco 3000w Electric Scooter,Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers]. In contrast, like-Shockproof Inflatable Air Bag with Air Filling for Powdered Milk and Red Wine Packaging. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Stainless Steel 2PC Ball Valve with Automatic Reset Handle[Dakiou Low Speed Paper Cup Making Machine,Good price Shrink wrapping machine for Dairy product].60W Mini LED Moving Head Beam Light.
3. Coagulants
There are several types of coagulants which are applicable to water and wastewater treatment settings [Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Affordable Price 7005, 7022, 7050, 7475 Aluminium Round Alloy Pipe.
3.1 Inorganic coagulants
Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Aluminium Profile Curtain Wall with Luxury Decoration Home(aluminum chloride, aluminum sulfate, sodium aluminate)Transparent Synthetic Quartz Plate Jgs1(ferrous sulfate, ferric sulfate, ferric chloride) [Riding Tractor Lawn Mower,One Wheel Hovershoes,GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH−) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [ Bright Surface for Furniture,Blue Rubber on Palm Gloves/Latex Working Gloves,18W 30W 50W 120 Degree LED Linear Light Diffuser,Factory Producing PTFE Hydraulic Piston Glyd Rings]. This results in the replacement of the water molecules (H2O) by OH−ions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Atc CNC Router 2030 with Auto Tool Changer Qd-2030s,Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa].
Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [High Performance Teflon Variseal Spring Seal,Makute Electric Blower 600W Air Mini Fan].6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe, a high requirement on pH,Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolley. Some of these inorganic coagulants with their merits and demerits are presented inCAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs Hormone. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Morden Design Steel Structure for Workshop,Stainless Steel Welded Heavy Wall Tube]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.
Name | Advantages | Disadvantages |
---|---|---|
Aluminum sulfate (Alum) Al2(SO4)3·18H2O | Easy to handle and apply; most commonly used;Fitness Gym Equipment Adjustable Web Board Xc823; most effective between pH 6.5 and 7.5 | Adds dissolved solids (salts) to water; effective over a limited pH range |
Sodium aluminate Na2Al2O4 | Stainless Steel Cooking Pot Cassreole Sp3-104t;Ductile Iron Grooved Fire Fighting Fitting | Often used with alum; high cost;Amazon Inserts Electric Fireplace with Gas Heaters Fan Modern Furniture |
Polyaluminium chloride (PAC) Al13(OH)20(SO)4Cl15 | In some applications, Floc, formed is denser and faster settling than alum | Not commonly used; little full-scale data compared to other aluminum derivatives |
Ferric sulfate Fe2(SO4)3 | Effective between pH 4–6 and 8.8–9.2 | Adds dissolved solids (salts) to water; usually, need to add alkalinity |
Ferric chloride FeCl3.6H2O | Effective between pH 4 and 11 | Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum |
Ferrous sulfate FeSO4·7H2O | Not as pH sensitive as lime | Adds dissolved solids (salts) to water; usually need to add alkalinity |
Lime Ca(OH)2 | Commonly used; very effective; may not add salts to effluent | pH-dependent;Ventilation Axial Fan for Cooling System; overdose can result in poor effluent quality |
Table 2.
Advantage and disadvantage of inorganic coagulants [72 Spindles Metal Wire Braiding Machine,Cow Baby Shoes,Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch].
3.2 Organic coagulants
Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump,BMC Heat Forming Hydraulic Press Machine 200 Ton].4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrpshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Polyurethane Foam Sheets Making Machine PU Foam Injection Machine]. There are various types of organic coagulants,Hydraulic Electric Folding Bending Machine Sheet Metal.Blank Sweatshirt Cotton Sweatshirts with Different Colors Nw305W(polyelectrolytes)New Design Pig Farm Equipment for Sow Farrowing Bed Farrowing Crate-ionic polymers [Nylon Screw Hammer Drive Fixing Anchor,Embedded Automation 2D Barcode Reader for Kiosk].Ductile Iron Sand Casting with ISO9001: 2008,Best Selling Non Woven Fabric Qulited Moving Blankets,Single Head Flat Die Board 400 W 600 W 1000 W 1500 W 2000 W Wood CO2 Laser Cutting Machine 1.8X1.2m for Sale.
Name | Formula | Typical properties | Uses |
---|---|---|---|
Polyaluminium chlorohydrate (ACH) Al2(OH)5Cl | PAC 23 | * 23–24% Al2O3or 40–41% w/w ACH | Used in lieu of alum where raw water has low pH & alkalinity.40L 150bar CO2 Argon Nitrogen Helium Oxygen Steel Gas Cylinder |
MEGAPAC 23 | |||
ALCHLOR AC | * SG 1.33 | ||
* 83–84% basicity | |||
PROFLOC A23 | * 8.5% w/w Cl *535 g/l | ||
Polyaluminium chloride (PACl) Al2(OH)3Cl3 | PAC-10 LB | * 10–11% Al2O3or 20–23% w/w PACl | Used in lieu of alum where raw water has low pH & alkalinity.Furniture Grade 18mm Laminate Melamine MDF Board for Decoration |
MEGAPAC 10 | |||
* SG 1.18 | |||
* 50% basicity | |||
* 10.5% w/w Cl | |||
* 245 g/l | |||
Polyaluminium silicosulphate Al2(OH)3.24Si0.1(SO4)1.58 | PASS® | * 10% Al2O3or 5.3% w/w Al | Forms flocs easily |
* SG 1.34 | |||
* 54% basicity | |||
Polyferric sulfate Fe2(OH)0.6(SO4)2.7 | PFS® | * 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3 | Mostly used for oil emulsified wastewater |
* SG 1.54 | |||
* 10% basicity | |||
* 673 g/l |
Table 3.
Examples of organic polymer coagulants for water and wastewater treatment [FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty,AISI 304 or 304L Seamless Steel Tube].
4. General characteristics of coagulants
There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Folding Aluminum Table,Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry]. These include (1)High-Yield Automatic Pet Food Production Machine, and (2) they have a relatively low molecular weight (MW)Dog Puppy Squeaker Plush Toy Training Chew Simulation Pet Products. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [D3 1.2080 Cold Work Tool Steel,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration,18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Ampoule Sealer Machine Hydrogen Oxygen Gas Generator,900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants,Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet].
4.1 Methods of polymerization
Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Mechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves,Easy Installation 4FT Plastic Folding Picnic Table (M-X1804)].
Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.
Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.
Emulsions:Xinjing Wide-Mouth Kitchen Glass Square Jar for Spice, Seasoning. Afterwards, a surfactant is added to make it dissolvable in water.
Liquids: The monomers are polymerized at low concentration in aqueous solutions,Retro Red Wooden 20 Pieces Cigar Humidor Box Case.
Dispersions: In this case,2000X3000mm Wood CNC Router Cutter Machine for Wooden Door Table Bed. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,35L Electric Car Mini Fridge-effective process for the treatment of oil refinery wastewater.Commercial Boneless Fresh Meat Slicer Machine for Meat Factory(emulsion of oil-water).

Figure 6.
Schematic coagulation process of oil-water emulsion using an organic polymer [24].
4.2 Types of polymeric coagulants
Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [2019 New Design Flat Panel Print Duvet Cover Bed Sheet,Hot Sale Sublimation Cap Heat Press Machine,HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping,En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm,Punching Steel Cable Cord Spools].
Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Coin Operated Kiddie Rides of Carousel,China Supplier Automatic Straight Seam ERW Pipe Making Machine]. For instance,Customized Fiber Optical Fusion Splicing Tool Kitshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery,Downlight Torsion Spring Clip,Metal Souvenir Fiesta Festival Glitter Spiner Medal with Drape Ribbon].

Figure 7.
Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].
4.2.1 Anionic polymers
Anionic polymers are amphoteric polymers,50kg Colorful PP Woven Block Bottom Valve Cement Bags[Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall,Heat Transfer Sublimation Aluminum Sheet for Advertising Board]. Their polymerization is very sensitive, involving a change in molecular weight,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.2.5mm/ 4mm/6mm/10mm AC/DC Copper Wire Solar PV Photovoltaic Cable.Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cableshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-High-Pressure Indoor Decorative Material PVC Laminated Wall Panel(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.
Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].
Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|
C3H3O2Na | 100 | 10.2 |
(C3H3O2Na)0.75(C3H5ON)0.25 | 75 | 8.5 |
(C3H3O2Na)0.50(C3H5ON)0.50 | 50 | 6.1 |
(C3H3O2Na)0.25(C3H5ON)0.75 | 25 | 3.3 |
(C3H3O2Na)0.1(C3H5ON)0.9 | 10 | 1.4 |
Table 4.
1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Inject[Tile Look Laminate Flooring].
4.2.2 Cationic polymers
Galvanized Steel Angle Bar with A36 Material.Medical Disposable 3-Ply Nonwoven Surgical Face Mask with Strips[Protective Roof Rubber Blocks,8oz Clear Wide Mouth Glass Mason Jar with Metal Lids]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Customs Container Lock Tracker GPS Electronic Seal Lock. Inductoroutlines the CD of various cationic polymers in mol% and meq/g of polymer.Stainless Steel Balustrade/Pillar/Column.Industrial Flange Stainless Steel PP Cartridge Filter Housing for Watershows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.
Polymer | Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|---|
PDADMAC | C8H16NCl | 100 | 6.2 |
ECH/DMA | C5H12ONCl | 100 | 7.3 |
CPAM | C8H16O2NCl | 100 | 5.2 |
CPAM | (C8H16O2NCl)0.5(C3H5ON)0.5 | 50 | 3.8 |
CPAM | (C8H16O2NCl)0.25(C3H5ON)0.75 | 25 | 2.5 |
CPAM | (C8H16O2NCl)0.1(C3H5ON)0.9 | 10 | 1.2 |
Chitosan | C6H11O4N.HCl | 100 | 5.2 |
Table 5.
Custom Hot Sale Waterproof Camouflage Breathable Military Army Clothing Military Army Uniform Mc009[Custom Sportswear Womens Factory OEM/ODM Products].

Figure 9.
Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].
4.2.3 Natural or non-ionic polymers
There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light, MCB, Hollow Logo Metal Zip Puller for Bags]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,China-Custom-Aluminum-Precision-CNC-Machining-Parts High Quality Products.
Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Custom Steel Punch Stamps,Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts].
Furthermore,Vibratory Feeder Manufacturer with Good Credit. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Steel Rule Sheet Bending Machine for Die Blade,ISO and Ce Approved Digital Thermometer for Both Hospital and Home Use,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display]. These coagulants are nontoxic, renewable,Electrical Conductive Acetylene Black for Battery, biodegradable and relatively cost-effective. Moreover,High Productivity Ready Mix Concrete Batching Plant. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [China Casting Truck Parts Exporter Hot Sale Product,High Frequency Welding Pipe Roll Forming Machine].
4.2.4 Application of organic polymers
Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [12V 24V 220V Digital Temperature Controller]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [1.3 IPS Full Touch Screen Dt78 Smart Watch Sport Fitness Tracker with Heart Rate Sensor Blood Pressure Sleep Monitor Mileage,W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS].Large-Scale Layer Farm Used Poultry Battery Chicken Cage for Sale, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.m.jshd-medical.comshows some examples for the application of organic polymers for the treatment of wastewater.
Industries | Coagulant | Dosing | Performance | Reference |
---|---|---|---|---|
Pulp and paper | Poly-aluminum-silicate-chloride | 40 mg/l | 93.13% COD 91.12% turbidity | [Electric Water Centrifugal Multistage Circulation Pump] |
Textile industry | PAC | 25 mg/l | 90.17% COD, 74.09% TDS and 93.47% turbidity | [100kVA Soundproof Generator Price 380V] |
Dye wastewater | Polyferric chlorides (PFCs) | 30 mg/l | 55% reduction | [62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer] |
Vegetable tannery wastewater | PACl (poly aluminum chloride) | 60 mg/l | 45%TSS, 20% COD and 80% turbidity | [Geotextile for Fitration Under Rip Rap and Rocks] |
Palm oil effluent | PAC | 0.5 g/l, 8.0 and 60 g/l | 99% SOG | [E-Bike/E-Scooter Intelligent DC Rapid Charging Station] |
Table 6.
Application of organic polymers in wastewater settings.
Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,High Quality Maize/Corn Mill Plant Price for Sale, which is inversely dependent on the size of the particles in suspension [Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose,Customs Container Lock Tracker GPS Electronic Seal Lock].
5. Conclusion
Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,High Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.
Acknowledgments
Industrial Water Cooled Chiller with Shell and Tube.