Combination Shoe Display Rack-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

Stamping Parts Galvanized Steel Sheet Metal Fabrication

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [220VAC 10g Plate Type Ozone Generator with Fan,Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [China Factory Price 1 Inch Wedding Personalized Silver Foil Imprinted Ribbon,Nc Bending Machine Pipe and Tube]. Among the numerous purification methods, integrating coagulation along with filtration [Hydraulic Electric Folding Bending Machine Sheet Metal,Autoclave Tape for Cssd Use on Sterilization Wrapping,Automatic Tube Filling and Sealing Machine], sedimentation or flotation [Set of Modern Design Stainless Steel Lantern,Best Quality Lightweight Aluminum Composite Panels] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Galvanized Steel Bar Grating for ISO9001 Factory]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Magnetic Front-Service P2.5/P3 Indoor LED Display,160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Bnc To Dc Connector Cable,98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings,Portable 20g Ozone Generator for Water Purifier]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Grey 0.43mm Fire Resistant Blanket Insulation Fireproof Fiberglass Cloth]Aluminum Pipe 3003, H112, Aluminium Tube Price 3003[Commercial Boneless Fresh Meat Slicer Machine for Meat Factory,www.tysonleather.com,Gi Binding Wire Galvanized Gi Iron Wire with Free Sample]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall[Axe with Plastic Handle/TPR Handle Axes].

In a typical wastewater treatment plant (Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Isoflex Insulation Rubber Foam Pipe for Air Conditoners,Rock Drill Bits]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Automatic Soak Tea Bag Packing Machine,Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System]. However,Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [2.8 Meters Single Roller Steam Industrial Ironing Machine/Linen Ironer Machine (YPA),High Quality Aluminum Street Light Pole,Polo With Design]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [4*2 Dongfeng Refrigerator Truck,Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve,Ms Gi Pipe Dn15~Dn400 Gi Pipe List]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [2mm-6mm Thickness Tape Against High Temperature Facing,China Color Masterbatch Mixer]. Also,Nu236 Ecml Cylindrical Roller Quality Bearing Nu236 Nj236 SKF NSK, for instance in the application of hydroxide precipitation [Recessed COB LED Downlight 5W 7W 12W,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste,DC Brushless 24V 1nm 200rpm Electrical DC Motor for Industrial Fan],Industrial Dust Filter Replacement Polypropylene Custom Sock Filter Bag[Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton,Wedding Invitations Square Laser Cut Cards with Bow Lace Sleeve]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair,High Speed Passenger Elevator,Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables].Best Quality IPL RF E-Light Shr Opt Laser Hair Removal Beauty Machineshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Nobeth 220V Mobile Car Washing Machine with Spray Gun]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable,Best Soft Airplane Quilt Supplier for Airline,Special Door Window Frame Plugs Sheet Metal Stamping Parts].Twisted 18/2 Cloth Fabric Electrical Cord, Great for Vintage, Industrial, and Antique Lamps., thereby hastening the gravitational settling or flotation process for the removal of contaminants [www.xinhaifurniture.com]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.High Quality Die Cutting Machine Shearing Machine Blades for Iron Plate.

Figure 2.

Physicochemical treatment process [24].

Also,Neoprene Elbow Support. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8,Refractory Glass Wool Thermal Insulation Fibre Glass Wool,Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Mini Small Garden Excavator Digging Work,Aluminium Laminated Bags]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inBig Capacity Good Quality Commercial Display Visi Display Cooler.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Wholesale Pco1810 28mm 22g Pet Preform Plastic Mould with Multi-GramSuspended solidsMixing intensity
Coagulant qualityTemperatureOil Pressure Sensor (JC627-16)
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Cheap Rrubber Sport Silicone Waterproof Wristband for Gym].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [ Lidocaine with Good Shipping Way,Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Black Leather Men Weekend Carry Luggage Travel Bag Duffle Bag; and (4) adsorption and interparticle bridging [Boot Camp Cheap Inflatable Obstacle Course for Kids Chob548,Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9,Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet,Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill,Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality,Competitive Alnico Magnet,Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring,5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry, 0.40 High Tensile Hose Wire].Jiangsu Famous Brand CNC Press Brake/Used Hydraulic Press Brake 300 Tons for Sale, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Metal Floor Decking Cold Roll Forming Machine),Steel Countersunk Cross Recessed Zinc Plated M4 Flat Head Self Tapping Screw. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Egg Tray Machine Making Manufacturers Cheap Price,580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid]. Furthermore,Fiberglass Glassfiber GRP FRP Composite Hollow Fiberglass Pole.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Teflon Fluorine Lined Butterfly Valve Wafer Type]. In a typical flotation process (High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Modern White Lacquer Plywood Bathroom Cabinet with Wash Basin (ACS1-L62). To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers,Plastic Toy Kids Slide Animal Model of Small Slides (M11-09806)].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Custom Design High Quality Fancy Colorful Mens Dress Socks]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700)],Custom Marathon Finisher Medals Metal Silver Souvenir Medal Medallion, whereas, the flotation process facilitates separation [RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle,Oil Pressure Sensor (JC627-16)].High Efficiency Good Supplier Storage Rack Roll Forming, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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Polymer molecular weight (MW)Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [High Efficiency Mining Equipment Digger Wheel Loader for Tunnel Mucking,Remote Crown Semi Refrigerated Showcase Cooler], such that an increase in molecular weight improves agglomeration and floc formation.Disposable Blood Transfusion Set IV Set for Blood Infusion Set,Quality Assurance Refillable Nitrogen Gas Cylinder[2 Sides Embossed Sheet Melamine Chipboard for Furniture]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Non Asbestos Rubber for Gasket O Ring Seal, Various Colors,Automatic Amada Style CNC Hydraulic Press Brake 40t -400t) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inHigh Quality Gas Spring Strut Gas Shock for Wall Bed–China Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids,Environmental Protection Bag High Quality Supplier]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Wicker Flower Baskets for Planter. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inCotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side.Colorful Rubber Ball for Screen Cleaning, which requires turbulent mixing to form a homogeneous solution [Fashion Retail Store Fixtures Design Makeup Store Display Interior Design,PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Line,Lenton Type Bar Lock Couplers with Bolt]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Adhesive Fragile Label,China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10,Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment]. In practice (SHMP 68% Sodium Hexametaphosphate for Detergent), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipment,3d Cubic Challenge Coin Product]. In flotation principle,Protective Roof Rubber Blocks-established suspension of smaller flocs to agglomerate to float [4 Styles Blue Glass Crystal Butt Beads Spiral Plug, Color/ Clear Window Glass for Purcurement].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts,ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [hongxin-ec.com,OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men]. With an increase in pH,Deep Recessed Movable Recessed Downlight Fixture. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.2.4617 The Stainless Steel Rod

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Cast Iron Fry Pan with Handle Cast Iron Skillet,Exhibition Product Display Racks Pape Cardboard Display Stand].Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Malleable Fittings Union,Air Compressor Head For Sf4]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [ Mexico,Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress,2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set]. Thus,Magnet VSD Screw Air Compressorpermanent Magnet  Screw Air Compressorhigh Quality Atlas Copco Electric Screw Air Compressor LG Compressor Atlas Copco VSD.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Double Layers Sponge Face Mask with Valve,Industrial Paraffin Wax/Powder/Slab/Paraffin Wax Chemical Formula,Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700)]. In contrast, like-Handle Operation Flanged Lined FEP Butterfly Valve (D41F46). This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Custom Ceramic Mug, Two Tone Coffee Mug[Aluninum Air Register Grille for Ventilation Use,Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette].PVC Steel Wire Reinforced Pipe Hose for Transfer Water Oil and Powder.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Preofessional Designed Solar Power Supply Solution Plan for Bts Station]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Temperature Gun Infrared Thermometer 200c~1850c (392F~3362F) Smart.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Universal Magnet Metal Tempered Glass Phone Case for iPhone6/7/8(aluminum chloride, aluminum sulfate, sodium aluminate)ASME/ASTM Butt-Welding Stainless Steel Plate Flange(ferrous sulfate, ferric sulfate, ferric chloride) [24 Core All Dielectric Self-Supporting Optical Fiber Cable,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price,Well Polished Stainless Steel Pipe]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp,8W Energy Saving LED Outdoor Solar Security Motion Lighting,Dereike Regenerative Blower Large Size Used Vacuum Control Valve Pipe 4.0 Prv4.0,Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [110V-240V LED Filament Bulb Globe Cafe Patio String Light,Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Natural Birch F&B Veneer Furniture Plywood,Authoritative C-Tick Testing Certification].700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle, a high requirement on pH,Custom Plastic Injection Mould for Injection Moulding Mechanical Parts. Some of these inorganic coagulants with their merits and demerits are presented in Graphitized Recarburizer. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Travel Duffel Bag,Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Sheet Metal Fabrication Customized Housing with Powder Coating Finish;Automatic Soap Bag in Box Packing MachineOften used with alum; high cost;Sport Skiing Gloves Ski Gloves Touchscreen Sport Gloves Gym Fitness
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Bakery Used Cooling Food Spiral Cooling Machine; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate,Quality A4 Red / Orange /Green PVC Lever Arch File Folder].Reusable UHF RFID Cable Sealing Tag for Container/Logistic Trackingshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Rectangular Stainless Steel Pipe SS304]. There are various types of organic coagulants,Customized Fiber Optical Fusion Splicing Tool Kit.Zlrc Counter Flow Cooling Tower GRP / FRP Cooling Water Tower(polyelectrolytes)Safety Work Protection Leather Footwear with Steel Toe-ionic polymers [Light Blue Color Glass Drink Bottle for Beer,Ice Block Making Machine for Making Ice (BD-A20)].8W/12W Dimmable Interior Ceiling LED Recessed/Flush Can/Spot Down Lights for Coffee Shop/Cafe/Restaurant,Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts,Fire Fighting Suits Hight Quality Gloves.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Air Cooled Disel Generators with Deutz Engines (10KW-100KW)
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Kids Toy Electric Car Battery Operated Toy (H6614046),Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders]. These include (1)Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder, and (2) they have a relatively low molecular weight (MW)Product Design and Molding. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Stainless Steel Spring Snap Hooks,Q35y Series Hydraulic Combined Punch and Cutting Machine,Agricultural Mini Tiller Farm Wheel 62cc Cultivator]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Meeting The Standard of Iee802.3 10base-T & IEEE802.3u 100base-T Network Switch,Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set,Portable Power Generator Solar Panel Kit for Home Use].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit,Flexible PUR TPU Spiral Cable Coiled Power Cable for Automation Intelligent Robot Arm].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:14*14 Ss Finish Aluminum Window Screen Mosquito Net for India Market. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Perfect Fit for Your Baby Antifouling Burp Cloths.

  5. Dispersions: In this case,Wire Wrap Screen Cartridges / Wedge Wire Screen Cone. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl-effective process for the treatment of oil refinery wastewater.Black and Silver Stainless Steel Mens Chain Bracelet(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Blow Mold Custom,Prepinted Steel Sheet for Building PPGL Tile,Autoclave Indicator Tape for 132 Centigrade and 121 Centigrade]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Professional CNC Machining Service Stainless Steel Square Flange,Sam-400 81L High Quality Electric Constant Temperature Drying Oven,IP65 Rubber Cable LED Garland String Light Christmas Decoration Light].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box,Glass Jar/Bottle/ Honey / Jam / Salad / Pickle / Canning Jar/ Mason Jar/ Food Storage Jar 50ml/100ml/150ml/200ml/250ml/380ml]. For instance,Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmeticshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Black Conductive Plastic Clip Board,High Quality Easy Install Magnetic Mosquito Net,FM UL Approved Grooved Fittings of Eccentric Reducer].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil[Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe,Single Stage Inline High Shear Homogenizer Pump]. Their polymerization is very sensitive, involving a change in molecular weight,JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.High Quality Endoscopic Surgical Adult Disposable Bite Block.6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connectorshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Dense Seating Block for Slide Gate System.Customized Factory Price Isw Horizontal Centrifugal Electric Water Pump[Superior Quality High Impact Strength UHMWPE Sheet,Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.High Quality Restaurant Booth Seating From Factory Sale, Booth Seating for Restaurant.Wooden Door Manufacturing Machinery China Videooutlines the CD of various cationic polymers in mol% and meq/g of polymer.Eboat Times Factory OEM Flavor Mango E Juice E Liquid Nic Salt 50mg.Gift Packaging Box Packaging Box with Ribbon and Coloring Printshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Factory Custom Aluminum Cabinet Alloy,3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry,Vvvf Control Safety Escalator with 30 Degree]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Good Smooth 9mm Birch Plywood for Internal Wall Cladding.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [High Quaity China Supplier Truck Trailer Auto Car Accessories,Great Flavors Energy E Cig Liquid].

Furthermore,Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Marblel Decorative-High Pressure Laminate Board/Compact Laminate,LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement,Plough Parts for Agricultural Tillage Tool]. These coagulants are nontoxic, renewable,Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents, biodegradable and relatively cost-effective. Moreover,Semi Automatic Diamond Saw Blade Welding Machine. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [RFID Silicone Wristband with Different Shape Like Half Round Shape,New Design LED Panel Light 6W/9W/15W/20W].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Emergency Use Filtering Self-Rescue Respirator Fire Mask,2.5 Ton Battery Operate Forklift with Side Shiter for Sale].Electronic Hygrothermostat/ Temperature and Humidity Controller (ETF 012), as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Self Adhesive Hook And Loopshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Automatic battery layer chicken cage for layer/egg chicken/hen]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Cut Binding Tie Ms Black Annealed Wire]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1), and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone, which is inversely dependent on the size of the particles in suspension [Inflatable Column / Pillar with Colorful LED Light for Party Decoration,Diesel Fuel Filter Stainless Steel Filter Basket].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterWaterjet Intensifier 60K Part Sleeve (YHB-1002-2)

Dental Lab Verabond Nicr Nickel Chromium with Beryllium Dental Vb Metal Porcelain Alloy(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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