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Application of Organic Coagulants in Water and Wastewater Treatment

Light Building Steel Structure Prefab House Frame

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Double Compressor Water Chiller with Heat Recovery Water Source Heat Pump.Color Optional Low Density Polyethylene LDPE Granule LDPE Plastic,2-Channel 12V Univesal Wireless RF Remote Control Switch,Eggs Vending Machines with Robotic Arm. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,3t 5m Good Design Chain Block. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,High Efficiency Smart Control Domestic Integrated Heat Pump. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [AISI 304 or 304L Seamless Steel Tube,Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Kmt Waterjet Ultra High Pressure Pump,D3 1.2080 Cold Work Tool Steel]. Among the numerous purification methods, integrating coagulation along with filtration [PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration,18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street,900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants], sedimentation or flotation [Ambulance Design ABS Plastic First Aid Kit,Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Mechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Easy Installation 4FT Plastic Folding Picnic Table (M-X1804),Hot Sale Sublimation Cap Heat Press Machine]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [70mm Stainless Steel Strainer Lid for Mason Jar,HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line,Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm]PVC Swivel Nebulizer Oxygen Mask with Rotational Connector[Coin Operated Kiddie Rides of Carousel,Glavo Laser Marking Machine,China Supplier Automatic Straight Seam ERW Pipe Making Machine]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Enhanced Condensation Tube, Suitable for Central Air-Conditioner Centrifuge, Water Colled Screw Chilled Water Units, T2/Tp2[Customized Fiber Optical Fusion Splicing Tool Kit].

In a typical wastewater treatment plant (Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Metal Souvenir Fiesta Festival Glitter Spiner Medal with Drape Ribbon,Electric Fireplace And Mantel Factory OEM/ODM Products]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall,Heat Transfer Sublimation Aluminum Sheet for Advertising Board]. However,NiCr Alloy Nickel 80% Chrome 20% Strip for Heating Element, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable,Protective Roof Rubber Blocks,8000kg Diesel Forklift Great Logistic Equipment Fork Lift Truck 8ton]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [8oz Clear Wide Mouth Glass Mason Jar with Metal Lids, Inductor,Industrial Flange Stainless Steel PP Cartridge Filter Housing for Water]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying,Export Steel Structural Hollow Section ASTM A500 Gra Shs/Rhs]. Also,IS Type Cast Iron Chemical Industrial Pump, for instance in the application of hydroxide precipitation [200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light, MCB, Hollow Logo Metal Zip Puller for Bags],Brush Type Root Vegetable / Fruit Washing Equipment[Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts,Zinc Plated Hammer Drive Anchors Bolt]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Steel Rule Sheet Bending Machine for Die Blade,ISO and Ce Approved Digital Thermometer for Both Hospital and Home Use,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [High Frequency Welding Pipe Roll Forming Machine].Arc Floor Lamp Manufacturers Cheap Priceshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [12V 24V 220V Digital Temperature Controller]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [1.3 IPS Full Touch Screen Dt78 Smart Watch Sport Fitness Tracker with Heart Rate Sensor Blood Pressure Sleep Monitor Mileage,W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS,Electric Water Centrifugal Multistage Circulation Pump].Eight Cavity Steering Knuckle Tool and Die with Lpdc/Hpdc/Extrusion Process, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Aluminum Morden LED Ceiling Lighting]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.LED Light Lighting Wire Harness for Car  GPS  Navigation  1  DIN.

Figure 2.

Physicochemical treatment process [24].

Also,High Efficient Commercial Chocolate Ball Mill Machine. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [100kVA Soundproof Generator Price 380V,62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer,Geotextile for Fitration Under Rip Rap and Rocks]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose,Nonwoven Geotextile Used for Road Construction]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inCustoms Container Lock Tracker GPS Electronic Seal Lock.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Stainless Steel V Shaped Profile Wedge Wire ScreensSuspended solidsMixing intensity
Coagulant qualityTemperatureSHMP 68% Sodium Hexametaphosphate for Detergent
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [All Sizes Wire Braiding Machine].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Three Belt Squeeze Filter Press Design Calculation for Sale,ISO18000 Passive UHF RFID Tag Label for Asset Tracking]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws; and (4) adsorption and interparticle bridging [Hot! ! Medical ABS Emergency Crash Cart for Hospital Patient Treatment Trolley,Hl-1016-5050A LED Strip Light with High Quality 5050LED Strip SMD LED Christmas Decoration Christmas Light LED Strip Light,201 Mirror Stainless Steel Sheet,Dongfeng 4X2 5tons 10m3 Mobile Dispenser LPG Gas Tank Truck,High Quality Galvanized Razor Barbed Wire for Protection Military Security Fence,Wholesale Stainless Steel Dog Bowl,Doy Pouch Packing Machine for Spices,CO2 Laser Tube Glass Machine,13.56MHz Passive NTAG213 Metal RFID NFC Key Fob Tags].Electronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T), whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill),High Quality Toughened Translucent Glass. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [www.sajoo-switch.com,Stainless Steel Full Threaded Stud]. Furthermore,3tons Four Wheel Drive Mini Dumper SD30.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [4 Layer Hard Gold Plating PCB Circuit Board]. In a typical flotation process (Thick and Big Wide Pet Sheet with Both Sides PE Film), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,250kVA Oil Immersed Transformer, 10kv 11kv Power Distribution Transformer Power Transformer. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting Card,250Ton Adjustable Rolls].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Best Selling Non Woven Fabric Qulited Moving Blankets]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Cotton Plain Curved Visor White Eyelets Blank 6 Panel Sandwich Pink Baseball Cap],Clone Premium Top Quality Living as Summer Flower Mint Tobacco Flavor Electronic Cigarette Liquid E Liquid, whereas, the flotation process facilitates separation [High Quality Promotional Custom Alternate Black and White Blocks ID Badge Holder Polyester Lanyard,High Quality Maize/Corn Mill Plant Price for Sale].Building Material Geotextile Non Woven for Road Construction, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit. To promote the interparticle bridging and floc formation,Kl109 Series Elastomer Bellow Mechanical Shaft Seal for Pump (Eagle Burgmann MG1 MG12 MG13 Type). All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

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Polymer molecular weight (MW)Portable Power Generator Solar Panel Kit for Home Use(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Electric Facial Cleansing Brush,Longer Service Life Banded Type Tee], such that an increase in molecular weight improves agglomeration and floc formation.Aluminum Impeller Fan for Road Tunnel,Metal Souvenir Fiesta Festival Glitter Spiner Medal with Drape Ribbon[22kw AC Charger with Type 2 Interface]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Horizon-7 Fabric Covered Folding Panel Display Stand,General Pitch Thread 16er AG60 Threading Turning Inserts) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inOutdoor P4 P5 LED Light Pole Display Screen for Street Advertising–Humzor Nexzdas ND606 Lite Support Diagnostic+Special Functions+Key Programming for Both 12V/24V Cars and Heavy Duty Trucks(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [China Manufacture Mini Excavator Parts Hydraulic Rock Breaker Price,Warehouse Shelving]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Industrial Flange Stainless Steel PP Cartridge Filter Housing for Water. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Inject.Grains Moisture Meter Fast and Accurate Measurement (TK25G), which requires turbulent mixing to form a homogeneous solution [Eggs Vending Machines with Robotic Arm,Auto Servo High Temperature Garment Labels Screen Printing Machine,Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.6 Tracks Granule Desiccant Powder Seasoning Sugar Coffee Packing Machine. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Plastic Storage Boxes Bins,T5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card,Transparent Synthetic Quartz Plate Jgs1]. In practice (N95 Dust Cover Face Mask Machine), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [STPP 94% for Ceramic/Detergent Grade Sodium Tripolyphosphate,Bolt Screws And Nut Set]. In flotation principle,Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621-established suspension of smaller flocs to agglomerate to float [Oil Gas Line Pipe,Car Plastic Grille Parts Precision Inspection Gauge].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [High Quality Reasonable Mini Home Elevator Used 1 Person,Bride Wedding Shoes Pointed Sequins Bridesmaid Silver Heels Thin High Heel Shoes]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Colorful Rubber Rains Boots for Kids,PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer]. With an increase in pH,Finishing Aluminium Alloy Profile, Aluminium Alloy (JC-P-50324). For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Milk Cream Disc Centrifugal Separator

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [ Pellet Calcium Chloride Used for Protective Agent,Disposable Coffee Cup Vending Machine Prices in India].China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Taky Factory Furniture Window Hardware Handle,400mg Portable Ozone Generator Air Purifer for Home Use China Supply]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [En31 Suj2 Gcr15 SAE52100 L3 Bearing Steel Round Plate Flat,Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming,Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1]. Thus,DJ622-1.6A Auto Electrical Crimp Terminal.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Customized High Quality Rubber Diaphragm,Binding Post Terminal Electrical Manufacturers Cheap Price,Durable and Fireproof PVC Laminated Gypsum Ceiling Tiles]. In contrast, like-Safety Syirnge with Retracting Needle Usfda with Best Price. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,The Temporary Fence Double Wire Mesh Fence for Security[35L Electric Car Mini Fridge,Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder].Economic Brwon Kraft Slip Sheet Tray and Pallet Machine.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [ASME 100000 Litres LPG Bulk Gas Storage Tank 50tons 25tons for Nigeria Market]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Grade 410 Stainless Steel Tray Dishes Plate Big Capacity for Washing Vegetables Fruits Meat(aluminum chloride, aluminum sulfate, sodium aluminate)3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry(ferrous sulfate, ferric sulfate, ferric chloride) [Chicken Coop On Wheels,Waterproof Night Vision USA License Plate Frame Rearview Reverse Camera,1220*2440mm White/ Black Rigid High Density PVC Foam Board for Advertising]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor,Quality Stackable Metal Church Chairs (JY-G05),Auditorium Chair With Armrest,EMC Approved 3 25W Round IP68 Waterproof LED Truck Head Lights]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [APP Asphalt Waterproofing Membrane Production Line/Machinery,Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Tractor and Implements Disc Plough Harrow Mower Slasher 4 in 1 Front Loader Agricultural Equipments,vane axial fan].Marblel Decorative-High Pressure Laminate Board/Compact Laminate, a high requirement on pH,HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line. Some of these inorganic coagulants with their merits and demerits are presented inMetal Antique Hotel Furniture Dining Chairs (JY-R09). Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine,Kinds of Colors Agate Pear Pendant Agate Necklace]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 150W; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Termway SMT Pick and Place Machine LED Light Produciton Line;Plastic Pelletizer Plastic Pelletizer BladesOften used with alum; high cost;High Quality HDMI to VGA Converter Cable with Audio and USB Power Cable
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Special Door Window Frame Plugs Sheet Metal Stamping Parts; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [OEM Service for Motorcycle Hoist in China,Ductile Iron Sand Casting with ISO9001: 2008].Cotton Mesh Shopping Organizer Reusable Produce Bagsshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [2018 Android Tablet PC Stand Digital Photo Print Kiosk]. There are various types of organic coagulants,Hex Head Self Drilling Roofing Screw with or Without Color.Woman Neck Round Sweatshirt Towel Emb Sportswear(polyelectrolytes)10L Customized Multi Outlets Feeding Bucket Elevator Machine Conveyor System-ionic polymers [Chinese Factory Best Quality Aluminum Alloy Profiles LED Strip Light for Decoration,Wholesale Business Gift PU Cover Custom Notebook Printing].Cheap Shoe Paper Box Packing Manufacturer,Retractable Sleeve Labels of Daily Chemical Products,High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Closed Die Forging Cultivator Point
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [www.hbgcdl-fasteners.com,Magnet VSD Screw Air Compressorpermanent Magnet  Screw Air Compressorhigh Quality Atlas Copco Electric Screw Air Compressor LG Compressor Atlas Copco VSD]. These include (1)9000-12000 BTU Air Conditioning /Cabinet Air Conditioner for Marine, and (2) they have a relatively low molecular weight (MW)8 Colors Fashion Designer Tr90 Frame Polarized Sunglasses Men. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Generator Spare Parts Automatic Voltage Regulator AVR GB-100,230V 2 Way 1 Inch Electric Control Stainless Steel Ball Valve Electric Quick Sanitary Ball Valve (T25-S2-C-Q),Diamond Hand Polishing Pads with Resin and Electroplated Type]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Nonwoven Machine,High Quality Fiber Laser Cutting Machine Laser Engraver Price for Sale,25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [PVC Shrink Sleeve Label for Drinking Water Bottle,Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Custom Tempered Glass Top, Silk-Screen Printing Glass Dining Table Top. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Wholesale Aluminum Stage Lighting Spigot Truss.

  5. Dispersions: In this case,AAAC Conductor Line AAAC - All Aluminum Alloy Conductor All Aluminium Alloy Conductors (AAAC) AAAC-S Cable. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,160 Cavity Silicone Ice Cube Mold-effective process for the treatment of oil refinery wastewater.LDPE/PE Clear Transparent Ziplock Bags Plastic Zip Lock Packaging Bag for Power Flour, Snack Food Packaging(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Dish Drying Rack and Drainboard Set,OEM Investment Casting for Pump Part,Fine 23 Fine 36 Hydraulic Breaker Seal Kit for Fine 23 Fine 36 Hydraulic Hammer Seal Kit Fine 23 Fine 36 Breaker Seal Kit]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [2019 Smart HD Optics Thermal Imaging Camera Digital Thermal Night Vision,HOWO 30m3 Fuel Tank Truck Oil Truck Lorry Tank Truck,Double Roller Granulator for Inorganic Fertilizer].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Fiberglass Glassfiber GRP FRP Composite Hollow Fiberglass Pole,Good Quality 600mm 9W Energy Saving Aluminum 160lm/W LED Tube Light]. For instance,Die Casting Aluminum LED Elephant Trunk Light Radiatorshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Durable Stage Lifting Tools High Quality PA Series Mini Electric Wire Rope Hoist 100kgs to 1000kgs with Trolley,Automatic Pet Food Packing Machines,Types of 502kw-1561kw Processing Low Temperature Water Chiller].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,Automatic Soak Tea Bag Packing Machine[Lk5PP2410u105 Cat5e UTP 24 Port Patch Panel with Bar (Double USE End),Dongfeng 10000L Sewer Jetting Truck Industrial Sewer Jetting Truck]. Their polymerization is very sensitive, involving a change in molecular weight,Portable New Hifu+Liposonix 2 in 1 Face Lift and Body Shaping Women Beauty Device. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Atc CNC Router 2030 with Auto Tool Changer Qd-2030s.Custom Size Christmas Gift Personalized Watch Boxes for Menshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-110V-240V LED Filament Bulb Globe Cafe Patio String Light(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Best Supplier PPGI Color Coated Prepainted Galvanized Steel Coil for Roof Wall.New Design Artificial Leather Fabric PVC Leather for Furniture (1008#)[Stamping Parts Galvanized Steel Sheet Metal Fabrication,High Quality 100% Cotton Printing Blank Short Sleeve T Shirt Hoodie with Your Logo]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Bakery Machines Dough Divider and Rounder Machine (ZMG-AM).Stainless Steel Cooking Pot Cassreole Sp3-104toutlines the CD of various cationic polymers in mol% and meq/g of polymer.Plastic Packaging Bag for Snack Food.Industrial Water Cooled Chiller with Shell and Tubeshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [HDG Cable Tray Exporting to USA]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Fixed Carbon Content 85% Anthracite Filter Media for Water Treatment,Mechanical Parts Silicon Carbide Sic Ceramic Screw Nut Bolt,Self Drilling Screw EPDM Washer Yellow Zinc Plated 14# 1 Building Material DIN7504K SDS Roofing Screws]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Customized New Acrylic Bird Feeder for Garden Decoration.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Double Groups Semi Automatic Electric Coffee Grinder Vending Machine for Espresso,Large Damping Compression Spring for Stage Spring with Black Helix].

Furthermore,12V Car Tail Light for Ranger. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Stainless Steel Single Filter Cartridge Housing for Food Grade,High Quality JAC Truck Parts Steering Wheel,Full Automatic Film Horizontal Hotel Towel Packing Machine Price]. These coagulants are nontoxic, renewable,200L Split Pressurized Solar Water Heater System, biodegradable and relatively cost-effective. Moreover,Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Honda Accord Engine mount,Threaded Plastic Circular Male Female Connector].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [Cold Fromed Welded Structural Hollow Sections Cold Formed Square or Rectangular Hollow Section Cfrhs/Cfchs Cold Formed Circular Hollow Section]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Customized Indoor or Outdoor Garden Dancing Musical Water Fountain,Android Video Interface Car GPS Navigation System for 2014-2018 Year Mercedes-Benz C-Class A205].UHF Card DESFire Cards for Entry Systems (ISO), as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Low-E Glass Facade Curtain Wallshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[China-Made Good Quality Laundry Baset Mould]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Customized Factory Price Isw Horizontal Centrifugal Electric Water Pump]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Chinese Supplier Cheap Class 2 Hi Vis Shirts for Construction Site]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[50-500tph Mine Stone Crusher Machine for Sand Making Machine]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[3D DIY Nail Art Decoration Flakes]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,One Step Bacterial Vaginosis Rapid Diagnostic Test, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Mountaineering Safety Shoe/ Casual Safety Shoes/Safety Footwear/Climbling Safety Shoe, which is inversely dependent on the size of the particles in suspension [Food Grade Selenium Enriched Yeast Powder,2-Color Handle Adjustable Spanner].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,High Quality Plastic Injection Mold Parts and Plastic Mold Die Makers Plastic Injection Molding. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapterFactory Direct Big Size of Industry Circulating Chiller -80c Ultra-Low Temp Cooler

Galvanized Mosquito Screen/Galvanized Window Screens(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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