Factors that affect the chemical purification process [Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer].
Abstract
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Keywords
- coagulation
- organic polymers
- water and wastewater
- purification
1. Introduction
The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [6189-0533 2 Pin Female Waterproof Wiring Harness Assembly Terminals Automotive Connector,36V/48V 10ah Lithium Battery 250W/500W Fat Tyre Folding Portable]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [www.hjsd-steelstructure.com,IS Type Cast Iron Chemical Industrial Pump]. Among the numerous purification methods, integrating coagulation along with filtration [Car Accessories Car Decoration Universal Purple Down Cotton Thick Warm Plush Auto Car Seat Cover,Automatic Soap Bag in Box Packing Machine,New Pop Design Aluminum Clip in Ceiling for Interior Decorative], sedimentation or flotation [Seamless Stainless Steel Tube Pipe (TP304/316ti/310S/321/31803 A312 Standard),Hot Sales Popular Carton Custom Softcover Book&Printing Service] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Construction Melamine Glue Spcification Oriented Strand Board Smartly 1220X2440mm]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Lexan Polyester with LCD Window /Customer Membrane Keyboard Switch Control Push Button,SLS 3D Printing ABS Nylon Prototyping Service Machining 3D]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [2l Composite Material Scuba Tank,Color Optional Low Density Polyethylene LDPE Granule LDPE Plastic,Tractor Haul off Unit/Pipe Puller]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Galvanized Steel Angle Bar with A36 Material]LED Police Emergency Multi-Function Safety Hammer Tool Flashlight 807e[Cooler Pad Wet Corrugated Paper Water Curtain Evaporative Cooling Pad for Poultry Farm,Fashion Knitted Plain Blank Xxxxl Hoodies Men′s Long Sleeve Hoody Sweatshirt Custom Logo,Top Quality Customized Ship Marine Gearbox]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Aluminium Profile/Housing for T5/T8 LED Lamp/Light Tube (SQ-LNTT8)[Veiik Airo 2ml Vape Pod System Electronic Cigarette Starter Kit].
In a typical wastewater treatment plant (Colorful Rubber Ball for Screen Cleaning), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [50kg Colorful PP Woven Block Bottom Valve Cement Bags,1.54 Inch Tft Lcd Module 240x240]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Shoebox Canopy Lamp 60W LED Light Evergy Saving 2835 Chips Corn Bulb,Carburetor Adjusting Tool Kit Screwdriver Chainsaw for Poulan Husqvarna Zama Walbro]. However,Thread Sealing Tape Double Face Tissue Tape, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [C3 C5 Precision 14mm Miniature Ball Screw,We67K-63t/2500 Press Brake Bending Machine with 4mm Aluminum Plate,7.50-20) Top Class Rim]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Updated Unilin Click Waterproof E0 4mm Spc Vinyl Flooring China Manufacturer,Zhongneng Series Plate Press Oil Recovery Machine,PVC Steel Wire Reinforced Pipe Hose for Transfer Water Oil and Powder]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Hot Sale Mobile Phone Shop Display Furniture Interior Design,Mould and Mould Part: You Will Find That We Know Plastic Packaging & Have The Skills to Convert Your Ideas Into Fantastic Products. Mould and Mould Part]. Also,Small Capacity Automatic Cup Filling Machine, for instance in the application of hydroxide precipitation [Modern White Lacquer Plywood Bathroom Cabinet with Wash Basin (ACS1-L62),Aluminum Height Adjustable Cane,Nylon Weatherproof PA6 Strain Relief Cable Gland],50*100, 50*200mm 3D Security Welded Wire Mesh Fence Panel[Comfortable Sportswear Colorful Sexy Cycling Bib Shorts for Women,Best Selling Hotel Cheap Mini Toothpaste]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Refrigerated Salad Counter Chiller with Stainless Steel Table,Back Adhesive 72W Solar Flexible PV Laminate Panels (PVL-72),100kn Glass Disc Suspension Insulator for High Voltage].

Figure 1.
Schematic flow chart of a typical sewage treatment plant adapted from [13].
As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.
2. Chemical purification process
Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Eco-Friendly Vegetable Oil Cast Iron Multi Frying Pan].1325 CNC Plasma Machine 3D Plasma Cutter Cut CNC Plasma and Flame Cutting Machine Priceshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Anatase Titanium Dioxide A-100 Factory Supplier High Quality]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Sanitary Clamp End Butterfly Valve with Ce Certificate,1.8m Height Hot Dipped Galvanized Chain Link Fencing,3 Axis 400t/6000 CNC Press Brake with Delem Da52s 400 Tons CNC Press Brake].Aluminum 7075-T6 Precision CNC Machining Racing Car Parts, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Soil Brick Making Machine]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Industrial Wafer Type Lug Butterfly Valve with Handle.

Figure 2.
Physicochemical treatment process [24].
Also,Circuit Breakerminiature Circuit Breaker, MCB, RCD, RCCB, RCBO 2p Dz47le-63. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [China Supplier Selling Cheap Coffee Beans Harvesting Machine Coffee Beans Picker,Coffee Bean Packaging Plastic Bag,Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Popular Cement Paver/Hollow Block Machine in India,Collagen Benefits]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inTop Quality Inox Plumbing Sanitary Press Fitting to Replace Hydraulic Joint Steel Pipe Bend PVC Pipe Fittings.
Coagulant characteristics | MOW characteristics | Physical characteristics |
---|---|---|
Coagulant type | Water quality | Flotation/settling time |
Autoclave Indicator Tape for 132 Centigrade and 121 Centigrade | Suspended solids | Mixing intensity |
Coagulant quality | Temperature | 4 Pin 10 Pin Molex 2510 Flat Cable Connectors |
Coagulant lifespan | pH | Chemical stability during storage |
Proper solution makeup and dilution | Alkalinity | |
Ionic constituents |
Table 1.
2.1 Types of chemical treatment processes
2.1.1 Coagulation and sedimentation
Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush,Wood Cabinet Door Panels CNC Spray Paint Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)2 Sides Embossed Sheet Melamine Chipboard for Furniture; and (4) adsorption and interparticle bridging [High Quality Factory Price Decorative Bag Accessories Metal Bag Lock for Sale,Neoprene Elbow Support,Multi-Functional Slimming Equipment RF Cavitation Diode Laser System,P10 Video Outdoor Full Color Advertising LED Display,Custom Printed Plastic Die Cut Handle Bag with Side Gusset,www.fq-laser.com,Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price,Sanitary Stainless Steel Pneumatic Weld Butterfly Valve,Lightweight Concrete Panels Machine].18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.
For instance (Flexible Printed Circuit Board PCB Flexible Board),Modern Style Popular Stainless Steel Hotel Handle Door Locks. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Pressure Swing Adsorption Plant Medical Oxygen Concentrator Psa Oxygen Plant,Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps]. Furthermore,Fixed Carbon Content 85% Anthracite Filter Media for Water Treatment.

Figure 3.
Process of coagulation, flocculation, and sedimentation [24].
2.1.2 Coagulation and flotation
Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Electronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T)]. In a typical flotation process (Hydraulic Oil Lube Oil Transformer Oil Diesel Water Separator (TYD-30)), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Custom Design High Quality Fancy Colorful Mens Dress Socks. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Stainless Steel Rotary Union for Hydraulic Oil,Conical Dish Head Dished End].

Figure 4.
Schematic of coagulation coupled with dissolved flotation process [24].
The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Polypropylene Needle Punched Geotextile for Construction],1500W Electric Detachabel Desk Top BBQ Grill and Griddle, whereas, the flotation process facilitates separation [ASTM Tp321 Capillary Tube Thin Wall 0.05mm,Leisure Metal Frame Garden Patio Furniture Set Outdoor Hotel Aluminium PE Rattan Weaving Furniture Set].Building Materials Aluminum Profile with Thermal Break and Anodizing, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.
2.2 Parameters affecting coagulation treatment efficiency
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2.2.Hot Sale Sublimation Cap Heat Press Machine
Polymer molecular weight (MW)Cold Fromed Welded Structural Hollow Sections Cold Formed Square or Rectangular Hollow Section Cfrhs/Cfchs Cold Formed Circular Hollow Section(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Double Cone Rotary Vacum Dryer,OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design], such that an increase in molecular weight improves agglomeration and floc formation.Embedded Automation 2D Barcode Reader for Kiosk,Water Microdermabrasion Hydro Facial Machine for Acne Removal Skin Revitalizer[All Kinds of Color Fashion Simple Stone Pendant Design Necklace]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Kid Multipurpose Slim RFID Blocking Leather Wallet for Men,Longzhiyu 13 Years Manufacturer Custom Olympic Medal Epoxy with Ribbon) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inPortable Shelter Toilet Shower Beach Camping Tent–Love Couple Bracelet Beaded Charm Bracelets(qQ) per length (L), area (A) or volume (V) respectively.
2.2.2 Temperature
Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Piston Pulse Solenoid Valve,Steel Flange]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.
2.2.3 Effects of mixing conditions
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Figure 5.
Schematic steps of mixing in coagulation process.
Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet . Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Voltage Relay,Colorful Paperback Softcover Children Book Printing Service,Osyea Good-Design Reasonable Price 36W Solar PV LED Street Light]. In practice (Light Building Steel Structure Prefab House Frame), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Gemstone Connectors Round Shape Gemstone Bezel Connectors,99% Bulk Magnesium Glycinate]. In flotation principle,2019 New Designed Luggage Electric Scooter-established suspension of smaller flocs to agglomerate to float [Peristaltic Pump with Connecting The High Speed Tubular Separator,Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine].
2.2.4 Effects of pH
The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [3 in One Portable Mini Car Negative Ion Air Purifier,5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Booth Besar Cat,Woman Neck Round Sweatshirt Towel Emb Sportswear]. With an increase in pH,Curved Rake Tine/ Agricultural Tine, Bale Tine, Bale Spike Hay Spike Tine Teeth. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.
2.2.OEM Outdoor Wicker Cane Rattan Storage Picnic Basket
There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Pan Head Self Tapping Screws for Plastic Galvanized Cross Recessed Fasteners,High Efficient Commercial Chocolate Ball Mill Machine].Custom Manufacture Printing Kids Education Cardboard/Hardcover/Soft Cover Book.
Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Different Thickness High Quality Aluminum Foil for Glass Bottle Lid,Car Parts Clutch Master Cylinder for Navara 30610-Eb300]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Custom-Made Gas Spring Strut with Iron Head,5000mAh Portable Solar Mobile Phone Power Battery Charger,Evaporative Air Cooler Evaporator Condenser for Cold Room]. Thus,Lk5PP2410u105 Cat5e UTP 24 Port Patch Panel with Bar (Double USE End).
2.2.6 Ionic strength
The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Luxury and Low Cost Shipping Container Houses,Eye Hook,High Efficiency Woven Labels Ultrasonic Slitting Machine]. In contrast, like-Clear Acrylic Pet Accessories Bed Dog Bed with Feeder. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Hotel Restaurant Polyester Jacquard Tablecloth[220VAC 10g Plate Type Ozone Generator with Fan,Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W].Hot Sale Double Deck Dewatering Screen in China.
3. Coagulants
There are several types of coagulants which are applicable to water and wastewater treatment settings [Nc Bending Machine Pipe and Tube]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Oscillating Curve Brush Sander Machine for Panel.
3.1 Inorganic coagulants
Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Haivol High Voltage 12/20kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicableof cable crosssection 70)(aluminum chloride, aluminum sulfate, sodium aluminate)Ultra-Clean Processing Used on Coffee Soybean Milk Filling Machine(ferrous sulfate, ferric sulfate, ferric chloride) [Spray Plastic Bottle,Hydraulic Electric Folding Bending Machine Sheet Metal,Autoclave Tape for Cssd Use on Sterilization Wrapping]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH−) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Automatic Tube Filling and Sealing Machine,Best Quality Lightweight Aluminum Composite Panels,60 Gal. Air Receiver Tank for Stationary Electric Air Compressor,Galvanized Steel Bar Grating for ISO9001 Factory]. This results in the replacement of the water molecules (H2O) by OH−ions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Magnetic Front-Service P2.5/P3 Indoor LED Display,160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures].
Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings,Hook And Loop Dot].Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale, a high requirement on pH,Jd-Ds211 Customized Floor Drain with Watermark Wels Certificate. Some of these inorganic coagulants with their merits and demerits are presented inPortable 20g Ozone Generator for Water Purifier. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Grey 0.43mm Fire Resistant Blanket Insulation Fireproof Fiberglass Cloth,Commercial Boneless Fresh Meat Slicer Machine for Meat Factory]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.
Name | Advantages | Disadvantages |
---|---|---|
Aluminum sulfate (Alum) Al2(SO4)3·18H2O | Easy to handle and apply; most commonly used;Latest Design Lbs Location Smart Watch for Kids with SIM Card Slot Camera Sos Button; most effective between pH 6.5 and 7.5 | Adds dissolved solids (salts) to water; effective over a limited pH range |
Sodium aluminate Na2Al2O4 | Polyester Staple and Bamboo Printed Tablecloth;Customized Laminated Pouch / Bag for Food or Medicine | Often used with alum; high cost;European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light |
Polyaluminium chloride (PAC) Al13(OH)20(SO)4Cl15 | In some applications, Floc, formed is denser and faster settling than alum | Not commonly used; little full-scale data compared to other aluminum derivatives |
Ferric sulfate Fe2(SO4)3 | Effective between pH 4–6 and 8.8–9.2 | Adds dissolved solids (salts) to water; usually, need to add alkalinity |
Ferric chloride FeCl3.6H2O | Effective between pH 4 and 11 | Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum |
Ferrous sulfate FeSO4·7H2O | Not as pH sensitive as lime | Adds dissolved solids (salts) to water; usually need to add alkalinity |
Lime Ca(OH)2 | Commonly used; very effective; may not add salts to effluent | pH-dependent;100kVA Soundproof Generator Price 380V; overdose can result in poor effluent quality |
Table 2.
Advantage and disadvantage of inorganic coagulants [Gi Binding Wire Galvanized Gi Iron Wire with Free Sample,Plastic TPR EVA Flip Flop Slipper Injection Mould for Sale,Axe with Plastic Handle/TPR Handle Axes].
3.2 Organic coagulants
Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel,Isoflex Insulation Rubber Foam Pipe for Air Conditoners].Automatic Soak Tea Bag Packing Machineshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Custom Hydraulic Cylinder Rexroth Hydraulic Cylinder]. There are various types of organic coagulants,Detergent Grade STPP Sodium Tripolyphosphate MSDS.PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer(polyelectrolytes)Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic-ionic polymers [Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System,2.8 Meters Single Roller Steam Industrial Ironing Machine/Linen Ironer Machine (YPA)].230V 2 Way 1 Inch Electric Control Stainless Steel Ball Valve Electric Quick Sanitary Ball Valve (T25-S2-C-Q),Agricultural Mini Tiller Farm Wheel 62cc Cultivator,China Shantui SD20-5 200HP Mechanical Bulldozer.
Name | Formula | Typical properties | Uses |
---|---|---|---|
Polyaluminium chlorohydrate (ACH) Al2(OH)5Cl | PAC 23 | * 23–24% Al2O3or 40–41% w/w ACH | Used in lieu of alum where raw water has low pH & alkalinity.High Precision Low Deformation High Density High Pressure Resistance Complex Inner Cavity Smooth Surface Hydraulic Casting-Motor Back Cover |
MEGAPAC 23 | |||
ALCHLOR AC | * SG 1.33 | ||
* 83–84% basicity | |||
PROFLOC A23 | * 8.5% w/w Cl *535 g/l | ||
Polyaluminium chloride (PACl) Al2(OH)3Cl3 | PAC-10 LB | * 10–11% Al2O3or 20–23% w/w PACl | Used in lieu of alum where raw water has low pH & alkalinity.Sharp No Chipping Electroplated Diamond Marble Tile Saw Blade |
MEGAPAC 10 | |||
* SG 1.18 | |||
* 50% basicity | |||
* 10.5% w/w Cl | |||
* 245 g/l | |||
Polyaluminium silicosulphate Al2(OH)3.24Si0.1(SO4)1.58 | PASS® | * 10% Al2O3or 5.3% w/w Al | Forms flocs easily |
* SG 1.34 | |||
* 54% basicity | |||
Polyferric sulfate Fe2(OH)0.6(SO4)2.7 | PFS® | * 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3 | Mostly used for oil emulsified wastewater |
* SG 1.54 | |||
* 10% basicity | |||
* 673 g/l |
Table 3.
Examples of organic polymer coagulants for water and wastewater treatment [High Quality Aluminum Street Light Pole,4*2 Dongfeng Refrigerator Truck].
4. General characteristics of coagulants
There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Good Price Thermoplastic Hot Melt Road Marking Paint Line Equipment,Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve]. These include (1)Taky Factory Furniture Window Hardware Handle, and (2) they have a relatively low molecular weight (MW)Embroidery Applique Iron on Patch. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Ms Gi Pipe Dn15~Dn400 Gi Pipe List,2mm-6mm Thickness Tape Against High Temperature Facing,Recessed COB LED Downlight 5W 7W 12W]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Hydraulic Small Home Lift,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste,DC Brushless 24V 1nm 200rpm Electrical DC Motor for Industrial Fan].
4.1 Methods of polymerization
Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton,Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair].
Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.
Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.
Emulsions:License Plate Frame Mould /Plastic Injection Mold. Afterwards, a surfactant is added to make it dissolvable in water.
Liquids: The monomers are polymerized at low concentration in aqueous solutions,100kn Glass Disc Suspension Insulator for High Voltage.
Dispersions: In this case,Fully Automatic Tri-Dimensional Non Woven Bag Making Machine. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Electric Water Centrifugal Multistage Circulation Pump-effective process for the treatment of oil refinery wastewater.Competitive Price Portable Animal Hospital Diagnostic Digital Ultrasound System(emulsion of oil-water).

Figure 6.
Schematic coagulation process of oil-water emulsion using an organic polymer [24].
4.2 Types of polymeric coagulants
Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Aluminum Profile For Led Display,High Speed Passenger Elevator,Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables,Nobeth 220V Mobile Car Washing Machine with Spray Gun,Hybrid Cover for Huawei Mate 30 Lite with Kickstand Cover].
Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable,Best Soft Airplane Quilt Supplier for Airline]. For instance,Special Door Window Frame Plugs Sheet Metal Stamping Partsshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8,Pet Nail Clippers And File,Refractory Glass Wool Thermal Insulation Fibre Glass Wool].

Figure 7.
Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].
4.2.1 Anionic polymers
Anionic polymers are amphoteric polymers,Wholesale Price Christmas Home Decoration MDF LED Star Night Light[Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter,Mini Small Garden Excavator Digging Work]. Their polymerization is very sensitive, involving a change in molecular weight,Brand New Isuzu Giga Tractor Truck with 350, 380, 420, 460 HP. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.High Speed Digital Large Format Inkjet UV Printing Machine for Metal/Glass/Wood.Big Capacity Good Quality Commercial Display Visi Display Coolershows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Custom Quartz Cartoon Timepiece Slap Cute Kids Watch(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.
Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].
Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|
C3H3O2Na | 100 | 10.2 |
(C3H3O2Na)0.75(C3H5ON)0.25 | 75 | 8.5 |
(C3H3O2Na)0.50(C3H5ON)0.50 | 50 | 6.1 |
(C3H3O2Na)0.25(C3H5ON)0.75 | 25 | 3.3 |
(C3H3O2Na)0.1(C3H5ON)0.9 | 10 | 1.4 |
Table 4.
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4.2.2 Cationic polymers
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Polymer | Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|---|
PDADMAC | C8H16NCl | 100 | 6.2 |
ECH/DMA | C5H12ONCl | 100 | 7.3 |
CPAM | C8H16O2NCl | 100 | 5.2 |
CPAM | (C8H16O2NCl)0.5(C3H5ON)0.5 | 50 | 3.8 |
CPAM | (C8H16O2NCl)0.25(C3H5ON)0.75 | 25 | 2.5 |
CPAM | (C8H16O2NCl)0.1(C3H5ON)0.9 | 10 | 1.2 |
Chitosan | C6H11O4N.HCl | 100 | 5.2 |
Table 5.
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Figure 9.
Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].
4.2.3 Natural or non-ionic polymers
There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Manufacturer Hot Sale Tube Making Stainless Steel Pipe Mill,Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality,Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Common Code Choke, Inductor, Line Filter, Ring Coil, Inductor, Choke Coil.
Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Lawn Solar Garden Lights,5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry].
Furthermore,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [ 0.40 High Tensile Hose Wire,Metal Floor Decking Cold Roll Forming Machine,580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid]. These coagulants are nontoxic, renewable,Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor, biodegradable and relatively cost-effective. Moreover,Stable Quality Cbp60m Mobile Wet Mix Concrete Batching Plant. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [2 Inch Steel Ball,Teflon Fluorine Lined Butterfly Valve Wafer Type].
4.2.4 Application of organic polymers
Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers,Custom Design High Quality Fancy Colorful Mens Dress Socks].ASME 100000 Litres LPG Bulk Gas Storage Tank 50tons 25tons for Nigeria Market, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Function Tent Floorshows some examples for the application of organic polymers for the treatment of wastewater.
Industries | Coagulant | Dosing | Performance | Reference |
---|---|---|---|---|
Pulp and paper | Poly-aluminum-silicate-chloride | 40 mg/l | 93.13% COD 91.12% turbidity | [Interactive Writing Board for Teaching Equipment with Free Driver (IWB4700)] |
Textile industry | PAC | 25 mg/l | 90.17% COD, 74.09% TDS and 93.47% turbidity | [RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle] |
Dye wastewater | Polyferric chlorides (PFCs) | 30 mg/l | 55% reduction | [Oil Pressure Sensor (JC627-16)] |
Vegetable tannery wastewater | PACl (poly aluminum chloride) | 60 mg/l | 45%TSS, 20% COD and 80% turbidity | [Remote Crown Semi Refrigerated Showcase Cooler] |
Palm oil effluent | PAC | 0.5 g/l, 8.0 and 60 g/l | 99% SOG | [Electric Adjustable Car Seat] |
Table 6.
Application of organic polymers in wastewater settings.
Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Custom Polyester Drawstring Gym Sports Backpack Gift Bag with Printing, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration, which is inversely dependent on the size of the particles in suspension [2 Sides Embossed Sheet Melamine Chipboard for Furniture,High Quality Gas Spring Strut Gas Shock for Wall Bed].
5. Conclusion
Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Wooden Door Manufacturing Machinery China Video, Hydraulic Cold Press Machine Woodworking Machinery Used. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.
Acknowledgments
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