Cheap Shoe Paper Box Packing Manufacturer-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

Retractable Sleeve Labels of Daily Chemical Products

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

Economic Brwon Kraft Slip Sheet Tray and Pallet Machine.Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b,Grade 410 Stainless Steel Tray Dishes Plate Big Capacity for Washing Vegetables Fruits Meat,3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,Marblel Decorative-High Pressure Laminate Board/Compact Laminate. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.

Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [3 Axis 400t/6000 CNC Press Brake with Delem Da52s 400 Tons CNC Press Brake,China Supplier Selling Cheap Coffee Beans Harvesting Machine Coffee Beans Picker]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [New 18*8.5j Aluminum Benz Car 5*112 Replica Alloy Wheels,Coffee Bean Packaging Plastic Bag]. Among the numerous purification methods, integrating coagulation along with filtration [Promotion Price RGB LED P7.62 Display Panel Full Color Video Displays,Popular Cement Paver/Hollow Block Machine in India,Top Quality Inox Plumbing Sanitary Press Fitting to Replace Hydraulic Joint Steel Pipe Bend PVC Pipe Fittings], sedimentation or flotation [Colorful Fashion Design Shiny Silver Silk Thermal Merino Woman Wool Socks,Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Hot Sales Beauty Products Cosmetics Make up Face Blush Brush Makeup Brush]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Wood Cabinet Door Panels CNC Spray Paint Machine,Neoprene Elbow Support]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [OEM Aluminium Gravity Die Casting Product,Multi-Functional Slimming Equipment RF Cavitation Diode Laser System,P10 Video Outdoor Full Color Advertising LED Display]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Custom Printed Plastic Die Cut Handle Bag with Side Gusset]8 Colors Fashion Designer Tr90 Frame Polarized Sunglasses Men[Vvvf Passenger Home Observationvilla Glass House Sightseeing Golden Elevator with Good Price,2017 New Design Mold Welding Machine and Equipment for Metal,Sanitary Stainless Steel Pneumatic Weld Butterfly Valve]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Custom Tempered Glass Top, Silk-Screen Printing Glass Dining Table Top[Lightweight Concrete Panels Machine].

In a typical wastewater treatment plant (Flexible Printed Circuit Board PCB Flexible Board), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps,cnsdgt.com]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Electronic Stainless Steel Plate Temperature & Humidity Testing Chamber (HD-150T),Hydraulic Oil Lube Oil Transformer Oil Diesel Water Separator (TYD-30)]. However,Wholesale Aluminum Stage Lighting Spigot Truss, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Stainless Steel Rotary Union for Hydraulic Oil,Wholesale Shutter Windows / Wholesale Roller Shutters/Electric Tubular Motor/Roller Blinds,Carbon Block Manufacturer]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Polypropylene Needle Punched Geotextile for Construction,ASTM Tp321 Capillary Tube Thin Wall 0.05mm,Leisure Metal Frame Garden Patio Furniture Set Outdoor Hotel Aluminium PE Rattan Weaving Furniture Set]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [OEM Ad Player Inch Multi-Touch Ad Player 43 Inch on Alibaba Top Manufacturer LCD Digital Signage Outdoor Food Kiosk Design,Energy Saving Tire Recycling Rubber Powder Line]. Also,AAAC Conductor Line AAAC - All Aluminum Alloy Conductor All Aluminium Alloy Conductors (AAAC) AAAC-S Cable, for instance in the application of hydroxide precipitation [All Kinds of Color Fashion Simple Stone Pendant Design Necklace,Portable Shelter Toilet Shower Beach Camping Tent,Piston Pulse Solenoid Valve],160 Cavity Silicone Ice Cube Mold[Dental Lab Teeth Dental Resin Block PMMA Discs,Aluminium Alloy Precession Vortex Flow Meter for Measure Compressed Air]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [ Rice,4 Seater Pessenger Golf Cart Dg-C4 with Ce Certificate (China),Double Seats 3 Wheel Electric Mobility Scooter].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Colorful Paperback Softcover Children Book Printing Service].Paper Printingshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Osyea Good-Design Reasonable Price 36W Solar PV LED Street Light]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Light Building Steel Structure Prefab House Frame,Gemstone Connectors Round Shape Gemstone Bezel Connectors,Peristaltic Pump with Connecting The High Speed Tubular Separator].LDPE/PE Clear Transparent Ziplock Bags Plastic Zip Lock Packaging Bag for Power Flour, Snack Food Packaging, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Multi Color Changing APP Smart Bulb Remote Control RGB Color Changing Lamp WiFi LED Light Bulb]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Automatic Soak Tea Bag Packing Machine.

Figure 2.

Physicochemical treatment process [24].

Also,Portable New Hifu+Liposonix 2 in 1 Face Lift and Body Shaping Women Beauty Device. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Good Price Automatic Liquid Sachet Juice Milk Drinking Water Pouch Filling Packing Packaging Machine,3 in One Portable Mini Car Negative Ion Air Purifier,5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Woman Neck Round Sweatshirt Towel Emb Sportswear,Hospital Bed For Patients]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inPan Head Self Tapping Screws for Plastic Galvanized Cross Recessed Fasteners.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Atc CNC Router 2030 with Auto Tool Changer Qd-2030sSuspended solidsMixing intensity
Coagulant qualityTemperature110V-240V LED Filament Bulb Globe Cafe Patio String Light
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [High Efficient Commercial Chocolate Ball Mill Machine].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Different Thickness High Quality Aluminum Foil for Glass Bottle Lid,Custom-Made Gas Spring Strut with Iron Head]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Aluminium Glass Dropper for Glass Dropper Bottle; and (4) adsorption and interparticle bridging [Electric Portable Small Piston Air Compressor,5000mAh Portable Solar Mobile Phone Power Battery Charger,Evaporative Air Cooler Evaporator Condenser for Cold Room,Luxury and Low Cost Shipping Container Houses,High Efficiency Woven Labels Ultrasonic Slitting Machine,Bakelite Handle Machine Tool Accessories,220VAC 10g Plate Type Ozone Generator with Fan,Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W,Nc Bending Machine Pipe and Tube].Best Supplier PPGI Color Coated Prepainted Galvanized Steel Coil for Roof Wall, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Hydraulic Electric Folding Bending Machine Sheet Metal),New Design Artificial Leather Fabric PVC Leather for Furniture (1008#). These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Flange Globe Valve,Autoclave Tape for Cssd Use on Sterilization Wrapping]. Furthermore,Bakery Machines Dough Divider and Rounder Machine (ZMG-AM).

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Automatic Tube Filling and Sealing Machine]. In a typical flotation process (Best Quality Lightweight Aluminum Composite Panels), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Plastic Packaging Bag for Snack Food. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Galvanized Steel Bar Grating for ISO9001 Factory,www.antpackaging.com].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Magnetic Front-Service P2.5/P3 Indoor LED Display]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [160lm/W Die-Casting Aluminum UFO 200W LED High Bay Light Fixtures],St3.5*13 Color-Zinc Plated Hexagonal Self-Drilling Screws with Washer, whereas, the flotation process facilitates separation [98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings,Portable 20g Ozone Generator for Water Purifier].Customized New Acrylic Bird Feeder for Garden Decoration, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

12V Car Tail Light for Ranger. To promote the interparticle bridging and floc formation,200L Split Pressurized Solar Water Heater System. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine

Polymer molecular weight (MW)UHF Card DESFire Cards for Entry Systems (ISO)(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [www.cablecreation.com,Grey 0.43mm Fire Resistant Blanket Insulation Fireproof Fiberglass Cloth], such that an increase in molecular weight improves agglomeration and floc formation.One Step Bacterial Vaginosis Rapid Diagnostic Test,Mountaineering Safety Shoe/ Casual Safety Shoes/Safety Footwear/Climbling Safety Shoe[Commercial Boneless Fresh Meat Slicer Machine for Meat Factory]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (High Quality Plastic Injection Mold Parts and Plastic Mold Die Makers Plastic Injection Molding,Used Folding E Power Electric Wheelchairs Motor 12V for Children) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inGi Binding Wire Galvanized Gi Iron Wire with Free Sample–Galvanized Mosquito Screen/Galvanized Window Screens(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Axe with Plastic Handle/TPR Handle Axes,Control Globe Type Valve With Diaphragm Actuator]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

High Precision Alloy Aluminum Plate Guillotine Shearing Machine. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inProfessional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel.Emcpioneer EMI Shielded MRI Door for RF Shield Cage, which requires turbulent mixing to form a homogeneous solution [Isoflex Insulation Rubber Foam Pipe for Air Conditoners,Automatic Soak Tea Bag Packing Machine,Molyboard Hot Sale Smart Interactive Whiteboard for Conference or Education System]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Ck6150 Horizontal Metal CNC Lathe Machine. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [m.sdjtec.com,2.8 Meters Single Roller Steam Industrial Ironing Machine/Linen Ironer Machine (YPA),High Quality Aluminum Street Light Pole]. In practice (4*2 Dongfeng Refrigerator Truck), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Auto Power off Motor Rotary Sifter Machinery Vibrating Sieve,Grey Wood Tv Stand]. In flotation principle,Genuine Piston for Komastu Engine 6D102-established suspension of smaller flocs to agglomerate to float [Ms Gi Pipe Dn15~Dn400 Gi Pipe List,2mm-6mm Thickness Tape Against High Temperature Facing].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Recessed COB LED Downlight 5W 7W 12W,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Small Metal Laser Cutting Machine Price Fiber,DC Brushless 24V 1nm 200rpm Electrical DC Motor for Industrial Fan]. With an increase in pH,Oil Gas Line Pipe, API 5L Spec 5L Steel Pipe, Grade B or X42 12m Steel Tube. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Top Quality Customized Ship Marine Gearbox

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton,Modern Dining Garden Outdoor Camping Beach Party Folding Plastic Chair].Bluefish Micro DC 12V Low Noise Safety Long Life Fish Pond Amphibious Pumps for Water Return.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [High Speed Passenger Elevator,Commercial 2 Door Kitchen Under Counter Refrigerator]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Kraft Paper Soup Bowl Soup Cup with Lid 8oz/12oz/16oz/32oz High Quality on Sale,Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables,Nobeth 220V Mobile Car Washing Machine with Spray Gun]. Thus,Customized Flexible Spring Coiled Wire and Retractable Power Cord Spiral Cable with PU Insulation.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Indoor/Outdoor Waterproof Pigtail Fiber Optic Cable,lanyard strap,Best Soft Airplane Quilt Supplier for Airline]. In contrast, like-BMC Heat Forming Hydraulic Press Machine 200 Ton. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Exclusive Automated Carton Erecting Machine for Food Box[Special Door Window Frame Plugs Sheet Metal Stamping Parts,Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8].Filter for Edible Oil Filtered Edible Oil Brands in India.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Refractory Glass Wool Thermal Insulation Fibre Glass Wool]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Hot Rolled/Cold Rolled ERW, Hollow Section, Square Pipe, En 10210/En10219, Carbon Steel Pipe.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Stainless Steel 304/316 Threaded NPT/Bsp Fittings Cross(aluminum chloride, aluminum sulfate, sodium aluminate)Liaoning Shenyang Densen Customized Economic Silicon Carbide Resistance Induction Sintering Furnace Vhs 449(ferrous sulfate, ferric sulfate, ferric chloride) [Safety Edge Sensor for Agv Automated Guided Vehicle,Fd4.0 Ton Forklift Truck with Chinese Engine and Side Shifter,Mini Small Garden Excavator Digging Work]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Big Capacity Good Quality Commercial Display Visi Display Cooler,Cheap Rrubber Sport Silicone Waterproof Wristband for Gym,China Led Bulb Oem Odm Factory, Lidocaine with Good Shipping Way]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Column or Pillar Type Rubber Curing Press Machine/PLC Control Rubber Vulcanizing Machine,Small Economic CNC Vertical Machining Center/CNC Milling Machine Tc-960/V9].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet,Hip Pop Snapback Cap Hat].Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry, a high requirement on pH,Luxury and Low Cost Shipping Container Houses. Some of these inorganic coagulants with their merits and demerits are presented inManufacturer Hot Sale Tube Making Stainless Steel Pipe Mill. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Shanghai Tj-420f Automatic Flour Packing Machinery with High Quality,Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Gray Cast Iron Case of Auto Part/Gearbox Rear Housing; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Trtian Juice Glass Red Wine Glass Champagne Glass;Purple Color Fire Pit Glass Recycled Crushed Glass Mirror CulletOften used with alum; high cost;Buried Integrated/Package Sewage Treatment Plant for Underground Sewage Treatment Device
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Reusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Metal Floor Decking Cold Roll Forming Machine,580ml Glass Drinking Water Bottle with Silicone Sleeve&Stainless Steel Lid].Teflon Fluorine Lined Butterfly Valve Wafer Typeshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Bicycle From China]. There are various types of organic coagulants,ERW Steel Pipe Hydroponic Modern Greenhouse.Double Pet Bowl Set in Bone Shape Antiskid Silicone Tray(polyelectrolytes)Stainless Steel Full Threaded Stud-ionic polymers [High Precision Custom OEM ODM Plastic Auto Parts Injection Moulding,High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers].High Precision Laser Cutting/Bending/Welding Sheet Metal Batch Fabrication,W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS,25cbm LPG Gas Tank Truck 25m3 LPG Filling Truck for Nigeria Market.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.2010 Used Foton Truck Mixer
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Chinese Supplier Cheap Class 2 Hi Vis Shirts for Construction Site
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [3d Printer Supplier South Africa,RF EMS Mesogun Injector Mesotherapie Gun Injection Machine Rejuvenation Wrinkle]. These include (1)High Pressure Screw Mini Small Pistion Oilless Silence Air Pump Compressor, and (2) they have a relatively low molecular weight (MW)Invisible green/olive green Disposable SMS/PP/nonwoven sterile surgical gown with knitted cuff. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Oil Pressure Sensor (JC627-16),Remote Crown Semi Refrigerated Showcase Cooler,2 Sides Embossed Sheet Melamine Chipboard for Furniture]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [12.5inch Walking Measuring Wheel with Counter (WW-MW219-7),High Quality Gas Spring Strut Gas Shock for Wall Bed,Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Cotton/Polyester 7 Gauge Safety String Knitted Work Glove with PVC Dotted on Both Side,Fashion Retail Store Fixtures Design Makeup Store Display Interior Design].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:5052 / 6061 /7075 / 5083 Custom Parts /Machining Aluminum Parts Automation Industry. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Wheel Loaders Drive Axle Parts 100-27-00030 Floating Oil Seals.

  5. Dispersions: In this case,Dongfeng 4X2 5tons 10m3 Mobile Dispenser LPG Gas Tank Truck. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Waterproof Night Vision USA License Plate Frame Rearview Reverse Camera-effective process for the treatment of oil refinery wastewater.Ce Certification New Multifunction 4 in 1 Mini Hydraulic Torque Converter Bucket Backhoe Loader Small Tractor Backhoe 3ton 4ton 5ton 6ton 7ton 8ton(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Gymnastics Inflatable Trampoline Tumble Track Mattress,PVC+PMMA/ ASA Coloured Glazed Roof Ridge Tile Plastic Production Line,Lenton Type Bar Lock Couplers with Bolt]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [China Supplier PVC Pressure Pipe Fitting Rubber Ring Joint Pn10,Bioplasm Nls Bioresonance Body Scaning and Analysis Physical Therapy Equipment,Die Cutting Machines for Children′s Cap Making].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [SHMP 68% Sodium Hexametaphosphate for Detergent,6D Galvanic Facial Machine Eye Lifting Skin Care Beauty Equipment]. For instance,4 Styles Blue Glass Crystal Butt Beads Spiral Plugshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [ Color/ Clear Window Glass for Purcurement,m.tjhstech.com,Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,240ml PP Baby Feeding Bottle with Cute Printing[ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross,OEM Wholesaler Custom Logo Blank Oversize Sweatshirt Men]. Their polymerization is very sensitive, involving a change in molecular weight,Silicon Coated Fiberglass Reinforced Expansion Joint Fabric Silicone Fiberglass Cloth. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.43 Inch Multipoints Touch Table Self-Service Digital Signage Kiosk with WiFi Touch Advertising Displaymobile Advertising Trailerbus Digital Signage LCD Digital.Cast Iron Fry Pan with Handle Cast Iron Skilletshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Stainless Steel Single Filter Cartridge Housing for Food Grade(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Full Automatic Electrical Product Assembly Machine.High Quality Gas Spring Strut Gas Shock for Wall Bed[Exhibition Product Display Racks Pape Cardboard Display Stand,Malleable Fittings Union]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Double Wire Garden Security Mesh Galvanized Iron 656 Wire Fence. Mexicooutlines the CD of various cationic polymers in mol% and meq/g of polymer.Blue Color Fish Paper/6520/6521 Flexible Composites.Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dressshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [2019 Latest Designs 120GSM Luxury Quality Bed in a Bag Comforter Set]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Double Layers Sponge Face Mask with Valve,Jinan Sunny Aluminum Double Head Cutting Saw for Aluminum (LJZ2-450X3700),Aluninum Air Register Grille for Ventilation Use]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,High Stability Series High Power Inductor.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [m.gz-sourcing.com,Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette].

Furthermore,Medical Disposable Oxygen Mask Nebulizer Mask. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Preofessional Designed Solar Power Supply Solution Plan for Bts Station,Roll Paper to Sheet Paper Cutting Machine Paper Cutter Price,Well Polished Stainless Steel Pipe]. These coagulants are nontoxic, renewable,Clear Black Empty 15ml 30ml 50ml 100ml Frosted White Square Glass Perfume Bottles, biodegradable and relatively cost-effective. Moreover,4 Inch Resin Bond Abrasive Cutting Disc for Stainless Steel and Inox. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Bamboo Floor Lamp Wholesaler Quotes & PriceList,Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [8W Energy Saving LED Outdoor Solar Security Motion Lighting]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Vertical H Frame Hydraulic Press Machine Deep Drawing Press Price,110V-240V LED Filament Bulb Globe Cafe Patio String Light].Grey 0.43mm Fire Resistant Blanket Insulation Fireproof Fiberglass Cloth, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Medical Rubbish Disposal with Microwave Disinfection Equipment Hospital Rubbish Sterilizer 3shows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Factory of Bq Nq Hq Pq Reaming Shell with 3%Discount]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Natural Birch F&B Veneer Furniture Plywood]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[ Graphitized Recarburizer]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[Travel Duffel Bag]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Memory Foam Pocket Spring Mattress From China Manufacturer]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Compatible with Ubiquiti′s Switch SFP 10g Optical Transceiver Duplex 1310nm 20km SFP Module, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,High Quality Strong Permanent Magnet AlNiCo, which is inversely dependent on the size of the particles in suspension [Sheet Metal Processing Stainless Steel Galvanized Metal Parts Stamping Bending Production,Hotel Restaurant Polyester Jacquard Tablecloth].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Liyuan 4 Inch Stainless Steel Impeller Submersible Water Pumps. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

17/32-Inch Trailer Safety Chain S-Hook (with Latch).

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High Quality Gas Lift Strut for Industrial Equipment(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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