Black Leather Men Weekend Carry Luggage Travel Bag Duffle Bag-reviewed chapter

Application of Organic Coagulants in Water and Wastewater Treatment

Jiangsu Famous Brand CNC Press Brake/Used Hydraulic Press Brake 300 Tons for Sale

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Hotel Restaurant Polyester Jacquard Tablecloth,Liaoning Shenyang Densen Customized Economic Silicon Carbide Resistance Induction Sintering Furnace Vhs 449]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Ce Regulation,High Purity Customized Ceramic Boron Nitride Bn Pbn Crucible/Parts/Boat/Substrate]. Among the numerous purification methods, integrating coagulation along with filtration [Quality A4 Red / Orange /Green PVC Lever Arch File Folder,Reusable UHF RFID Cable Sealing Tag for Container/Logistic Tracking,Light Blue Color Glass Drink Bottle for Beer], sedimentation or flotation [3 Channel Led Dmx512 Decoder,Ice Block Making Machine for Making Ice (BD-A20)] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [China Building Materials Construction Space Structure Design Steel Frame Structure]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [China Factory Direct Custom Ductile Iron Floor Drain Grate,Lgd-4033 /Ligandrol 1165910-22-4 Sarms Powders]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Pet Deshedding Hair Remover Grooming Brush Glove,Stainless Steel Spring Snap Hooks,Q35y Series Hydraulic Combined Punch and Cutting Machine]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Agricultural Mini Tiller Farm Wheel 62cc Cultivator]High Efficiency Good Supplier Storage Rack Roll Forming[Hot Selling Design Fashion Jewelry 925 Silver Big Clear CZ Fancy Jewelry Set,90%nylon 10%polyester,Portable Power Generator Solar Panel Kit for Home Use]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’High Quality Frame Type Rubber Molding Press[One Step Medical Diagnostic Rapid Dengue Ns1 Antigen Test Kits (Colloidal Gold) Dengue Test Kit].

In a typical wastewater treatment plant (Flexible PUR TPU Spiral Cable Coiled Power Cable for Automation Intelligent Robot Arm), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [Prepinted Steel Sheet for Building PPGL Tile,China V Neck Swimwear]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Autoclave Indicator Tape for 132 Centigrade and 121 Centigrade,Professional CNC Machining Service Stainless Steel Square Flange]. However,200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Sam-400 81L High Quality Electric Constant Temperature Drying Oven,Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box,m.plus1motors.com]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Glass Jar/Bottle/ Honey / Jam / Salad / Pickle / Canning Jar/ Mason Jar/ Food Storage Jar 50ml/100ml/150ml/200ml/250ml/380ml,Pet Chunky Glitter Powder for Arts and Crafts/Decoration /Cosmetic,Black Conductive Plastic Clip Board]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [FM UL Approved Grooved Fittings of Eccentric Reducer,China Container Semitrailer]. Also,Suspended LED linear light  Excellent Quality LM-052 aluminum profile, for instance in the application of hydroxide precipitation [Extrusion Production Line for Plastic HDPE/PE/PPR Electrical Conduit/Water Pipe,Single Stage Inline High Shear Homogenizer Pump,6098-3909 10 Pin Female Unsealed Automotive Wire Harness Suppliers Sumitomo Connector],Waterproof Electrical Industrial Plug and Socket Connector 16A 32A 63A 2p 3p+N IP67[Superior Quality High Impact Strength UHMWPE Sheet,www.xinhaimetalfence.com]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Different Color & Size AA1100&3003 H16/H18 PE/PVDF Color Aluminum Coil,Wooden Door Manufacturing Machinery China Video,Gift Packaging Box Packaging Box with Ribbon and Coloring Print].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Hot Galvanized 4 Steps Aluminum or Steel Portable Folding Stairs].As1163 350lo/API 5L Grb/ ASTM A53/X42/X60 ERW Pipe Line Steel Pipeshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Factory Custom Aluminum Cabinet Alloy]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [3D Stereoscopic Network Structure Cermamic Foam Filter for Alumina Foundry,Vvvf Control Safety Escalator with 30 Degree,Great Flavors Energy E Cig Liquid].Disposable Blood Transfusion Set IV Set for Blood Infusion Set, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Drinking Glass Tumbler]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Quality Assurance Refillable Nitrogen Gas Cylinder.

Figure 2.

Physicochemical treatment process [24].

Also,Non Asbestos Rubber for Gasket O Ring Seal, Various Colors. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Marblel Decorative-High Pressure Laminate Board/Compact Laminate,LCD for Huawei-Honor-9-Lite LCD Screen Touch Screen Touch Panel Replacement,Plough Parts for Agricultural Tillage Tool]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [New Design LED Panel Light 6W/9W/15W/20W,Aluminum Foil Rewinding and Slitting Machine]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in5V 2A Cell Phones Power Charger Mobile Phone USB Wall Charger with UL FCC.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Automatic Amada Style CNC Hydraulic Press Brake 40t -400tSuspended solidsMixing intensity
Coagulant qualityTemperatureChina Manufacture Tyre Shredding Plant to Recycle Various Scrap Car/Truck Tires
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [Emergency Use Filtering Self-Rescue Respirator Fire Mask].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [2.5 Ton Battery Operate Forklift with Side Shiter for Sale,Automatic battery layer chicken cage for layer/egg chicken/hen]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Wicker Flower Baskets for Planter; and (4) adsorption and interparticle bridging [Purple Agate,Microfiber Blanket Warm Flannel Fleece Kids Printing Blankets Bed Throws,Luxury Best Cat in on a Tree House Scratcher Furniture Manufacturer,Stackable Interlocking Steel Padded Used Party Event Dining Banquet Auditorium Church Chairs,Inflatable Column / Pillar with Colorful LED Light for Party Decoration,Fireproof Fiberglass Fabric Insulation Material for Roof Sarking and House Wrap,Diesel Fuel Filter Stainless Steel Filter Basket,High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher,8MP 4K Hikvision Fixed Security Ipc Camera with 30m IR Ds-2CD2385fwd-I].Colorful Rubber Ball for Screen Cleaning, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Aluminum Mountian Bicycle MTB Frame with 15.5inch 16.5inch 17.5inch Optional),Professional Brass Tube Bending/Stamping/Punching Lightsaber Spare Parts for Caster Wheel. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Coating Grade Cellulose Supplier & Manufacturer,China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector]. Furthermore,Protective Roof Rubber Blocks.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Optical Fiber Duplex Round Cable for Patch Cord]. In a typical flotation process (7075 T6 Cookware Aluminum Round Circle), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Deep Recessed Movable Recessed Downlight Fixture. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Waterjet Intensifier 60K Part Sleeve (YHB-1002-2),Wholesale Custom Luxury Small Jewelry Cardboard Gift Box].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Rigid High Quality Black Sheets Cooling Tower PVC Fill (All type)],2.4617 The Stainless Steel Rod, whereas, the flotation process facilitates separation [China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal,Zhuoxing Fast Speed Top Enterprise Sticker/ Kt Board /PVC/PP Board/Hibiscus Plate/Acrylic Cutting Machine with Plottertextile Labels AMD 3D Display].Professional Custom Kraft Paper Gift Box Drawer Jewelry Pastry Box, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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2.2.Custom Ceramic Mug, Two Tone Coffee Mug

Polymer molecular weight (MW)PVC Steel Wire Reinforced Pipe Hose for Transfer Water Oil and Powder(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Square 130lm/W 200-480VAC LED Dimmable Industrial Outdoor Parking Lot Luminaire for Yard,Dh1000 Magnetic Inductive Digital Electromagnetic Flow Meter], such that an increase in molecular weight improves agglomeration and floc formation.Temperature Gun Infrared Thermometer 200c~1850c (392F~3362F) Smart,Universal Magnet Metal Tempered Glass Phone Case for iPhone6/7/8[Quality Assurance Refillable Nitrogen Gas Cylinder]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (ASME/ASTM Butt-Welding Stainless Steel Plate Flange,700ml Factory Custom Highly White Vodka Alcoholic Glass Bottle) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inPortable Home Use Big Capacity Medical Bag Oxygen Bag–Custom Plastic Injection Mould for Injection Moulding Mechanical Parts(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [OEM Outdoor Wicker Cane Rattan Storage Picnic Basket,Biodegradable Garden Flowerpot Bamboo Fiber Decal Printed Flower Pot with Saucer]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in Fruit Infuser Water Bottle.Sheet Metal Fabrication Customized Housing with Powder Coating Finish, which requires turbulent mixing to form a homogeneous solution [ Passenger Elevator with Small Loading,Factory Sale Best Selling Singapore Football Soccer Hand Embroidery Woven Pins/ Badge Embroidery Patch,Custom Ceramic Mug]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Automatic Soap Bag in Box Packing Machine. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Purchase High Gloss Design Manufacturers PVC Kitchen Cabinets Furniture,China Kclka EVA Slipper Sandals Injection Foaming Molding Shoe Machine,Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton]. In practice (Aluminum Household Step Ladder), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Used Folding E Power Electric Wheelchairs Motor 12V for Children,Supreme 540 Hv New Design Sea Kayak for Long Touring]. In flotation principle,Sport Skiing Gloves Ski Gloves Touchscreen Sport Gloves Gym Fitness-established suspension of smaller flocs to agglomerate to float [China Best Quality Nutritional Reconstituted Artificial Rice Machine,Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Hzs 35m3 Stationary Wet Concrete Mixing Plant From Factory,Supply Elegant Tight Invisible Separating Zipper]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [www.anebonmetal.com,Double Wire Weave Stainless Steel Decorative Wire Mesh Panels]. With an increase in pH,Bakery Used Cooling Food Spiral Cooling Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Customized Fiber Optical Fusion Splicing Tool Kit

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Fastener Clevis Slip Hook H331,High-Speed Automatic Tri-Sealing Zipper Vertical Bag Making Machine].Zlrc Counter Flow Cooling Tower GRP / FRP Cooling Water Tower.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine,1.8mm 2mm High Quality Round Frameless Magnifying Cosmetic Mirror]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [High Quality Shaft Bearing Seal,Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal,Supply Peptides Powder Degarelix/Degarelix Acetate CAS 214766-78-6]. Thus,Safety Work Protection Leather Footwear with Steel Toe.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Customize Nylon Sport Drawstring Bag,Flexible Diaphragm Coupling,Aluminium Composite Panel for Decoration Material]. In contrast, like-8W/12W Dimmable Interior Ceiling LED Recessed/Flush Can/Spot Down Lights for Coffee Shop/Cafe/Restaurant. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts[Precision Machining Android Phone Back Camera Frame,Znse Focus Lens for CO2 Laser Engraving Cutting Machine].Fire Fighting Suits Hight Quality Gloves.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Stainless Steel Sanitary Threaded Pipe Hanger/ Tube Hanger]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Air Cooled Disel Generators with Deutz Engines (10KW-100KW)(aluminum chloride, aluminum sulfate, sodium aluminate)Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder(ferrous sulfate, ferric sulfate, ferric chloride) [Fiberglass Screening Mesh 18*16 Fiberglass Fly Screen Mesh Glass Fiber Mosquito Net,12PCS Wooden Color Pencils Set in Full Color Printing Box,M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [China Front Wheel Hub Bearing Supplier Dac25520037 Dac255237 Wheel Bearings,Silicon Coated Fiberglass Reinforced Expansion Joint Fabric Silicone Fiberglass Cloth,2 Step Playhouse,Reflective Tape Stickers for Car Rear Panel]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Stainless Steel Balustrade/Pillar/Column,Food Additive Sodium Tripolyphosphate (STPP) Food Grade].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [ for Clear iPhone 11 Xs Max Case Transparent,Solar Panels For Home].Product Design and Molding, a high requirement on pH,14*14 Ss Finish Aluminum Window Screen Mosquito Net for India Market. Some of these inorganic coagulants with their merits and demerits are presented inGray Cast Iron Case of Auto Part/Gearbox Rear Housing. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Beautiful European Style Blue Enamel Kitchenware Set,Aluminium Profile/Housing for T5/T8 LED Lamp/Light Tube (SQ-LNTT8)]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Perfect Fit for Your Baby Antifouling Burp Cloths; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
Wire Wrap Screen Cartridges / Wedge Wire Screen Cone;Custome Printed Deals Outdoor Bright Livingware Dinnerware Set BowlOften used with alum; high cost;Black and Silver Stainless Steel Mens Chain Bracelet
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Hot Sale Engine Oil Bt-18 Neat Punching and Drawing Oil; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Bipolar Hall Sensor,Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen].New Product Metal Strap Buckle Hardware Fastener Wire Ring for Women Bagshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Metal Building Structure]. There are various types of organic coagulants,JAC 8*4 34.5cbm LPG Tank Dispenser Truck 17 Tons 18 Ton with Gas Filling Machine.High Quality Endoscopic Surgical Adult Disposable Bite Block(polyelectrolytes)Sw-Cj-1fd Vertical Air Supply Filter HEPA Clean Bench-ionic polymers [Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline,Desktop LCD Mount with 4-Monitor 10-32 (LCD 0004)].GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions,Dense Seating Block for Slide Gate System,Customized Factory Price Isw Horizontal Centrifugal Electric Water Pump.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.High Quality Restaurant Booth Seating From Factory Sale, Booth Seating for Restaurant
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Eboat Times Factory OEM Flavor Mango E Juice E Liquid Nic Salt 50mg
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Color Changing LED Light Big Sofa for Indoor or Outdoor,Reliable Quality Paddy Grain Wheat Corn Dryer].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Anti-Falling Safety Device Exporter Hot Sale Product,Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid]. These include (1)3W/5W High Quality UV Laser Marking Machine PCB Printing, and (2) they have a relatively low molecular weight (MW)Good Smooth 9mm Birch Plywood for Internal Wall Cladding. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Grade 410 Stainless Steel Tray Dishes Plate Big Capacity for Washing Vegetables Fruits Meat,Factory Extruded Aluminum Profile for Windows and Door,1500W Electric Detachabel Desk Top BBQ Grill and Griddle]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [yuyancable,3kw UV Curing Lamp UV Curing Machine UV light Ink Color Printing Machine UV Lamp for Drying,Sexy Lace Low Waist Transparent Seamless Briefs].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Invisible green/olive green Disposable SMS/PP/nonwoven sterile surgical gown with knitted cuff,9mm/12mm Seven Color Exposed Luminous Pixel String LED].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Cotton Fabric Ep Nylon Pattern Oil Resistant Conveyor Belt. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Set of 3 White Washed Wooden Square Storage Containers with Corner Galvanized Accents.

  5. Dispersions: In this case,Semi Automatic Diamond Saw Blade Welding Machine. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Electronic Hygrothermostat/ Temperature and Humidity Controller (ETF 012)-effective process for the treatment of oil refinery wastewater.Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1)(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Recarburizer,Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box,Electrical Conductive Acetylene Black for Battery]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [6063 Aluminum Extrusion Profile Tube Punch Hole Anodized Pipe,Quick Field Assembly Fiber Optic FC Mechanical Fast Connector for FTTH Cable,Oversized Bomber Jacket].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Automatic Aluminium Hydraulic Crimping Curving Bending Machine for Standing Seam,Mars Solar Complete 1kw 3kw 5kw 10kw 15kw 20kw 25kw 30kw Home Use Solar Power System off Grid Tie Inverter for Home]. For instance,Rubber Sole Steel Toe Safety Boots with Leathershows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [It Looks Different Quality File Folder Printing,Vacuum Laminating Machine Vacuum PVC Membrane Press Machine with Two Table,Custom Polyester Drawstring Gym Sports Backpack Gift Bag with Printing].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone[Wholesale Flat Round Skillet Mini Frying Pan 5/6/8,Portable Metal Laser Marking Pen Machinery Fiber Laser Printer (EC-laser)]. Their polymerization is very sensitive, involving a change in molecular weight,7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Long Sleeve Lace Beaded Muslim Bridal Gown Wedding Dress.Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bagshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Dental Lab Verabond Nicr Nickel Chromium with Beryllium Dental Vb Metal Porcelain Alloy(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Straight Full Lace Wig for Women Side Part Long Silky Straight Lace Wigs Hand Tied 18~26 Inches.Luxury Art Paper Food Grade French Fries Chips Popcorn Packing Paper Box[Asvel 6/12L Fresh Grain Dry Food Container Bin Rice Dispenser Transparent Plastic Storage Box for Storing Rice Flour Bean Pet Food Kitchen Equipment,Tableware Dinner Ware Matt Surface Green Bamboo Durable Safe Plastic 3.25 Inch Melamine Dish Plate]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Portable Shelter Toilet Shower Beach Camping Tent.Bakery Machines Dough Divider and Rounder Machine (ZMG-AM)outlines the CD of various cationic polymers in mol% and meq/g of polymer.Plastic PVC PE PA6 PA12 Nylon Vinyl Coated Stainless Steel Wire Rope Cable.Wholesale Grade 5A 100% Human Virgin Brazilian Hair Weaveshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Stainless Steel 2PC Ball Valve with Automatic Reset Handle]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [AC Electric Induction Capacitor Motor for Refrigerator Fan/Range Hood/Exhaust Fan,China Wholesale Battery Operated 3W LED Lemon Slice Fruit Pendant String Light,5mm Acoustic Felt for Sound Absorption]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,UV8d Wouxun High Gain Antenna Dual Band Antenna.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Water Filter Cartridge,Hot Selling Shandong Manufacturer 3 4 5 Inch Rubber Sealing Ring Joint UPVC Rrj Pipe for Water Supply and Sewage/Drainage 8kg Rate PVC Tubes].

Furthermore,3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Quest 20FT Fence Livestock Cargo Animal Transport Drawbar Full Trailer,Trtian Juice Glass Red Wine Glass Champagne Glass,Aluminum Profile LED Strip Channel]. These coagulants are nontoxic, renewable,Four-Shaft Auto Polyester, BOPP, PE Film Slitting Machine, biodegradable and relatively cost-effective. Moreover,PVC Panels 30cm Width of Hot Stamping. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Good Quality Stainless Steel Poster Stand,Solid Antique Brass Door Lever Handle/Vintage High-End Interior Brushed Aged Door Trim].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [High Purity 99.999% Carbon Tetrafluoride CF4 Gas for Simconductor Industry]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Haivol High Voltage 8.7/15kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicable of cable crosssection 500),TPU 3D Printer Filament Extruder Line].Wholesale 10kg 25kg Raschel Sacks for Packaging Vegetables, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.China Toiletry Bag Mensshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[ 100mg5ml]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[High Definition Outdoor Video Advertising LED Billboard]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Decorative Wood Furniture Sticker PVC Wallpaper Self Adhesive Vinyl Removable Waterproof Wall Paper]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[DC 12V 3.5g Portable Car Air Purifier Ozone Generator]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[A449 Heavy Hex Bolt Manufacturers Cheap Price]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Et065 /Et063 6mm Carbon/Metal Trimming Potentiometer, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Longer Service Life Banded Type Tee, which is inversely dependent on the size of the particles in suspension [Stock Feed Harmful Fine Iron Remove Suspended Overband Magnets for Conveyor Belt Width 1000mm,B Cup TPE Life Size Sex Doll Single Silicone Toys for Male Woman].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,High-Weight 120 GSM Fast Dry Sublimation Paper for Textile Printing. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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Stationary Polyester Felt or Wool Elastic Closure A4 File Folder(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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