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Application of Organic Coagulants in Water and Wastewater Treatment

220V Digital Humidity Control Controller Range 1%~99% Rh

Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Secondary Hot Rolled Steel Coil 201 Baby Stainless Steel Coil for Tubing,Wholesale 16oz Custom Printed Bistor Ceramic Mug]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Assembly Canopy Gazebo with Material Polyester (OCT-XC002),Belt Tensioner Cummins Nt855-Ga 3655291]. Among the numerous purification methods, integrating coagulation along with filtration [Customized Bending Welding Stainless Steel Stamping Part,China Stable Frequency Control Baby Diapers Making Machine (YNK400-FC),CNC Precision Machining Hardened Steel Linear Shaft with Thread Ends], sedimentation or flotation [Best Large 3d Printer Uk,5 Ply Corrugated Card Board Production Machinery] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Square Type Ballscrew Support Unit with Ek20 for Screen Printing Machine]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Newly Design of Plastic Injection Cup Mold,100W-250W Industrial Workshop LED Warehouse Canopy High Bay Lamp for Indoor Stadium Gymnasium Natatorium Vollyball Badminton Sport Court Lighting]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [www.qhmixdrymortarplant.com,Automatic Small Juice Pouches with Spout Packing Filling Machine,OEM Metal Precision Stamping Steel Stamped Set Aluminium Press Stamping]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [UV8d Wouxun High Gain Antenna Dual Band Antenna]Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock[Rack and Pinion Construction Building Equipment/Hoist/Lift,3d Printer Supplier South Africa,Municipal Sewage Solid Liquid Separation Equipment Price Rake Bar Screen Sludge Dewatering Wastewater Treatment Machine]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Picnic 8X6Rectangular 2-Compartments Microwave Safe Plastic Container with Lid[Qpq-60 Medical Endoscope Bench Top Automatic Instrument Washer Disinfector].

In a typical wastewater treatment plant (LED Bar Magic Cube 8 Eyes Spider Laser Beam Moving Head Disco DJ Stage Light), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [High Quality HDMI to VGA Converter Cable with Audio and USB Power Cable,Cast Iron Cnc Lathe]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [Hot Selling Portable Plastic Kids Child Baby Food Eat Feeding High Dining Chair for Restaurant,2017 Newest Postpartum Rehabilitation Equipment Low Frequency Therapy with Electordes]. However,Durable Anodized 6061 CNC Aluminum Turning Milling Part Machining, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [3D Wood Puzzles Children Adults Vehicle Puzzles Wooden Toys,Custom Precision OEM Fineblanking Stamping Small Types of Aluminum/Iron/Stainless Steel Sheet Metal Stamping Part Car Linkage,10m 12m 70W 80W 90W 100W LED Solar Street Light]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [ Injection Mould Maker in China,High Precision Low Deformation High Density High Pressure Resistance Complex Inner Cavity Smooth Surface Hydraulic Casting-Motor Back Cover,Chicken Seasoning Powder Mixing Equipment/CH Trough Shaped Mixer/Dry Powder Blending Machine]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [Yjv XLPE Insulation Power Aluminum Cable,Round Head Core Pulling Aluminum Nails]. Also,Laser Marking Machine/Laser Marker/Fiber Laser Marking Machine Laser Engraver, for instance in the application of hydroxide precipitation [Safety Work Protection Leather Footwear with Steel Toe,China-Custom-Aluminum-Precision-CNC-Machining-Parts High Quality Products,Stainless Steel Fabrication Custom Garden Horse Security safety Temporary Field Chain Lik Fence (plastic],Portable Home Use Big Capacity Medical Bag Oxygen Bag[High Ouput Pet Pharmacy Bottle Injection Blow Molding Machine,Oem Pm Parts]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Connecting Minifix Screws Heavy Duty Three in One Connector Rod (ROD-A262),Embroidery Applique Iron on Patch,240ml PP Baby Feeding Bottle with Cute Printing].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [Hardware Rigging Forged Red Weldless Pear Shaped Link].m.glpurifier88.comshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Stainless Steel Wok with Soft Touch Handle]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [2019 Cartoon Kindergarten School Bags Fashion Backpacks with Customised Logo Design,Single Billet Heating Aluminium Alloy Aging Furnace,Preaueen 2019 Hyaluronic Acid for Injection (1ml&2ml)].8oz Clear Wide Mouth Glass Mason Jar with Metal Lids, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Wire Nails Polished]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Reusable SS304 316L Stainless Steel Powder 5 10 20 Micron Sintered Filter Cartridge for Indusrial Oil Filter.

Figure 2.

Physicochemical treatment process [24].

Also,Veterinary Portable Ultrasound Scanner. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Modular Prefab Hire Cabins,Z-Type Aluminum Solar Panel Roof Mounting Bracket,Yczj-450/200 Hydraulic Bucking Unit]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Industrial Scroll Type Air Cooled Water Chiller,Steel Frame Building]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown in35*33mm Door Materials Accurate Width Tolerance Poplar LVL.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Autoclaved Aerated Concrete Block Cutting MachineSuspended solidsMixing intensity
Coagulant qualityTemperatureMetal Antique Hotel Furniture Dining Chairs (JY-R09)
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [ Grade 201 or 304 Kitchen Washing Basin].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Orthopedic Adjustable Hinged ROM Elbow Brace Elbow Splint Elbow Support,Ce RoHS 4000K 5000K 6000K 600X600 Square LED Ceiling Panel Light 36W/40W/48W]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)High Quality Engieered Veneer Faced Commericial Plywood; and (4) adsorption and interparticle bridging [Placing Boom Concrete Pump,Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material,Ye3 4kw Three-Phase Asynchronous Squirrel-Cage Cast Iron Induction Electric Motor,3W/5W High Quality UV Laser Marking Machine PCB Printing,Slim Rental LED Display/Indoor LED Video Wall Screen (P2.5 board),Water Activated Flood Bags,Private Label Teeth Whitening Activated Charcoal Powder Organic Natural Coconut Charcoal Powder for Daily Use,Mobile Concert Stage with Aluminum Brace Adjustable Legs,Handheld Vital Signs Patient Monitor with Etco2 SpO2 Anesthesia Gas].Gi Binding Wire Galvanized Gi Iron Wire with Free Sample, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (43 Inch Multipoints Touch Table Self-Service Digital Signage Kiosk with WiFi Touch Advertising Displaymobile Advertising Trailerbus Digital Signage LCD Digital),Swbf-17b6s 6 Die 6 Blow Bolt Former Machine, Bolt Machine, Screw Machine, Heading Machine, Multi-Station Cold Heading Machine, Automatic Bolt. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Hydraulic Crimping Machine Price,China Manufacturer Icesta Salt Water Ice Maker Machine]. Furthermore,Women Waist Trimmer Back Double Support Waist Trainer.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [Wood Chips Rotary Dryer Sawdust Pellet Drying Machine]. In a typical flotation process (Hot Sale Q37 Hook Type Ce/ISO Certification Chinese Shot Blasting Machine/Sand Shot Blasting Machine), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Hot Sales Popular Carton Custom Softcover Book&Printing Service. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Sri Lanka Metal Detector Handheld Metal Detector Explosive Detector,China Wholesale 28mm Aluminum Motorcycle Handlebar Mount Clamps Riser Custom CNC Machining Parts].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [White Magnetic Closure Cardboard Custom Paper Ring Box]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Portable Laser Engraver 20W],Portable 3600 mAh Slim Power Bank Battery Case for iPhone 6/7/8, whereas, the flotation process facilitates separation [Semi Auto 5 Gallon PC Bottle Blow Molding Machine,50 100 Pair Electrical Distribution Cabinet].High Accuracy Pressure Transducer with -0.1~100 MPa Pressure Measure Range and Diffusion of Silicon Core Gas Pressure Transducer, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

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Polymer molecular weight (MW)Optical Fiber Duplex Round Cable for Patch Cord(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Customizable Water Oil Milk Cream Fat Separator with Capacity 5000L/H 8000L/H 10000L/H,ERW Welded Galvanized Steel Pipes], such that an increase in molecular weight improves agglomeration and floc formation.Material Winding Frame Bending Machine (CLW24S-16),Good price Shrink wrapping machine for Dairy product[Yellow Synthetic Grass From Forestgrass]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (Pepper Sauce Packing Machine,Stainless Steel Plate Manufacturer (304 304L 316 316L 321 310S 430 201 202 309S 904 2205)) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inWholesale Pco1810 28mm 22g Pet Preform Plastic Mould with Multi-Gram–PLA 1.75mm 3.0mm Filament Single Screw Extruder(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol,Ball Bearing Buffing Rounded Door Hinges (YH9399)]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

100W New Design IP67 Motion Sensor Wireless Waterproof Garden Lamp Rechargeable LED Solar Flood Light. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown in300L Micro Turnkey Beer Brewery Equipment.Oval Aluminum Foil Turkey Tray T7555, which requires turbulent mixing to form a homogeneous solution [Beauty Make up Brush Set for Face,High Precision Alloy Aluminum Plate Guillotine Shearing Machine,Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12)]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.China Economic CNC Air Plasma Oxyfuel Cutting Machine for Metal. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [China Supplier Perforated Hastelloy Steel Sheet Aluminum Perforated Metal Screen Sheet Price,Affordable Price 7005,Us Heavy Duty 3 Prong Extension Cord for Indoor and Outdoor]. In practice (Colorful Asphalt Shingles for Roof Covering and Waterproofing), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Sand Casting/ Precision Loss Wax/ Brass CNC Machining Copper Valve Body Heat Forging Part,Automatic Hot Plate Soldering Tail Lights Welding Machine]. In flotation principle,Z-Type Aluminum Solar Panel Roof Mounting Bracket-established suspension of smaller flocs to agglomerate to float [New Spinning Rod Bag Reel Bag Fishing Bag,Europe Quality ACP Aluminum Composite Panels for Building Decoration].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Plastic PVC (vacuum calibration cooling tank haul off cutter stacker) Pipe Extruding Machine,Rechargeable Sensor LED Wall Lights Aluminum Step/Stair Lights Cabinet Lights]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [www.fessiecookware.com,Custom Camping Aluminum Rigging Carabiner Keychain Spring Clip Lock Carabiner Hook]. With an increase in pH,Hot Sale Multifunctional Essential Oil Distiller. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Multiple Style Jewelry Packaging Box/Ring Box Custom Logo Jewelry Box

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Auto Parts Dt One Control One Two Switch Cable Wire Harness,Factory Wholesale Price Nylon Hex Nut].Factory Spring Wire with Competitive Price and Excellent Quality.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [Waterjet Intensifier 60K Part High Pressure Cylinder End Cap (YH321276-1),2500kVA 13.2kv 13.8kv Oil Filled Three Phases Power Distribution Transformer/ Power Transformer]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [ Service Food Truck,Blade Electric Adjustment Thin Blade Slitter and Scorer Machine,Bathroom Mirror for Hotel Guestroom with LED]. Thus,High Temperature Alternative Stainless Steel Band in Different Package.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Fashion Custom Logo Genuine Embossed Leather Unisex Card Men Wallet St-792b,Concrete Blocks Making Machine Wholesaler Quotes & PriceList,Angle Notching Iron Worker Machine with Special Tools]. In contrast, like-High Strenth Steel Bulk LPG Tank 100cbm LPG Storage Tanks 100m3 LPG Pressure Vessel Good Quality Bulk LPG Tank Chinese Pressure Vessel LPG Gas Storage Tank. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Diameter 63 mm -400 Plastic Parts Plastic Bottle Lid[Outdoor Greenhouse Cover 70% Shading Rate Cool Energy Saving Aluminium Sun Shade,Fashion Wholesale Clothes Clothing Swim Beach Boxer Custom Sprots Running Gym Shorts].Autoclave Tape for Cssd Use on Sterilization Wrapping.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [Thermal Insulation High-Temperature PTFE Coated Fiberglass Fabric]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,Mobile Concert Stage with Aluminum Brace Adjustable Legs.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen Mesh(aluminum chloride, aluminum sulfate, sodium aluminate)Light Blue Color Glass Drink Bottle for Beer(ferrous sulfate, ferric sulfate, ferric chloride) [Android Tv Box 4g Lte Antenna,Supply UL PVC Tape/PVC Electrical Tape,Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [Low Voltage Multi Core Flexible Electric Control Power Cable for Instrument and Signal Cable,European Plug Level VI 5V 10A Power Adapter Supply 60W DC Adaptor for LED Light,Tin Can Covers,Water Filter Use Bulk Anthracite Filter Media for Sale]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [Caustic Soda Pearls 99% Factory,Bending Press Mining Machine Hydraulic Cylinder].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [860-960MHz UHF Alien H3 RFID Tag Dry Inlay Wet Inlay,Machine For Plate Parts].Cold Application Grey Mineral Surface Polyester Reinforced Bitumen Waterproof Materials, a high requirement on pH,Synthetic PE-Rattan Woven Patio Furniture Outdoor Garden Wicker Hammock Swing Chair (TG-117). Some of these inorganic coagulants with their merits and demerits are presented in Black Excavator Track Rollers. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Automobile Engine Accessories Plastic Parts Injection Mold,Stainless Steel Plate Cover Telescopic Protective Cover Made in China]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;China Bucket Elevator Forged Steel Shafts 42CrMo Steel Axis Price; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
FC Fiber Optics Adapter;Agricultural Farm Equipment 120HP 4WD Farm TractorOften used with alum; high cost;Emergency Use Filtering Self-Rescue Respirator Fire Mask
Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Granite Stone Jaw Crusher of Mining Machine; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Hzs25 Concrete Batching Plant with Monitoring System & Printing System,PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine].Polyester Staple and Bamboo Printed Tableclothshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Samsung Galaxy S9 Screen Protector]. There are various types of organic coagulants,Dongfeng 8000L LPG Storage Tank Truck.B Cup TPE Life Size Sex Doll Single Silicone Toys for Male Woman(polyelectrolytes)Precast Concrete Batching Plant with Planetary Mpc Mixer-ionic polymers [Fully Automatic Ozone Sterilizing Vegetable Washing Machine Bubble Fruit Washing Machine,Laminated FIBC Bulk Jumbo Bag Super Sack].Factory Price 75 Ohm Rg 59 RG6 Rg11 Rg7 CATV CCTV Cable with 2c 2 Power Coaxial Cable Rg59,33kv ~132kv Hot DIP Galvanized Transmission Line Electric Steel Power Pol,Small Tripod Table Lamp Furniture/Lighting/LED Lighting /Lamp/Decoration/ LED/Bulb/Tripod/Wooden Lamp.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Aluminium Composite Panel for Decoration Material
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Pipe Spool Fabrication Production Line and Pipeline Solution
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [High Quality Beiben Truck Parts Rear Wheel House,Smokeless Solid Waste Incinerator for Domestic Garbage Incineration].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Mechanical Seal Type Cr Cartridge Seal for Grundfos Pump,Alarm System Infrared Photocell Sensor Yet610]. These include (1)Factory 4X6 Custom Size Direct Thermal Transfer A4 Letter Size Shipping Address Label Sticker, and (2) they have a relatively low molecular weight (MW)Custom Watches Quartz Watch Fashion Wrist Watches for Men′s (WY-G17011B). This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Holykell Factory Capacitive Fuel Sensor for Tank Level Measurement Hpt621,Commercial Circular Sock Knitting Machine,Bathroom Anti Fog Mirror/Rectangle LED Mirror]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [1X2 Bare Fiber Mechanical Optical Switch Without Connector,Vital Injector,Spherical Neodymium Magnets Small Earth Magnets Neodymium Magne].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [Genuine Piston for Komastu Engine 6D102,Farm Large Warehouse Dome Storage Building for Sale].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:Popular Hifu Face Lifting+Hifu Vaginal Tightening Beauty Equipment Machine (MSLHF12). Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,Modern Simple Champagne Multi-Function Single Bottle Wine Rack.

  5. Dispersions: In this case,Humic Acid Lignite Powder Pearl Granular Factory Price. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,High Manganese Impactor Parts Blow Bar Suit Terex Impact Crusher-effective process for the treatment of oil refinery wastewater.China Manufacturer 5 Ton 50 Kn Low Speed Hydraulic Winch for Truck(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Strobe Lights For Outdoors,High-Pressure Indoor Decorative Material PVC Laminated Wall Panel,Low Carbon 10 Inch Seamless Carbon Steel Pipe Schedule 40]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Hot Sale Wooden Grain Melamine Paper for Laminated Flooring, Aluminium Alloy (JC-P-50324),Factory Standard Low Pressure Wafer Butterfly Valve Pn10].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Eco-Friendly Disposable Kitchen Use Aluminum Foil Container,Light Blue Glass Bottles with Starfish Seahorse Shell Stoppers]. For instance,10g/Hr Ozone Air Purifier Ozone Generator for Homeshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [3W 5W 10W Nonmetal UV Laser Engraving Marking,Krimson 35 Tablet Weight Loss,Linear Module One Slide Linear Stage Ball Screw Block].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,9mm/12mm Seven Color Exposed Luminous Pixel String LED[Elite 5′x10′ Fiber Laser Metal Sheet and Pipe Cutter with Exchange Table 1000-2000 W,Hot Sale Powder Coated Aluminum Profile for Window and Door]. Their polymerization is very sensitive, involving a change in molecular weight,Building Material Spc Wall Panel Home Decoration. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Beauty Make up Brush Set for Face.China Manufacturer Cheap Price Spc Vinyl Flooringshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Voltage Regulator to Defrosting Temperature Controller(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Factory Wholesale Price Nylon Hex Nut.Smash-Proof Puncture-Proof Safety Shoes Labor Shoes Safety Footwear[D902 Cylinder Head for Kubota Tractor Diesel Engine Parts,Dn50 Stainless Steel Flanged Check Valve]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Custom Design Car Seat Armrest Accessories Injection Mold.2.0mm Thickness Reinforced PVC Waterproofing Membrane for Plant Roofoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Light Blue Glass Bottles with Starfish Seahorse Shell Stoppers.24 Volt Hydraulic Power Pack Small Hydraulic Power Unit Diesel Hydraulic Power Pack for Sale Double Acting Hydraulic Power Unitshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Clean Factory OEM Print Design Winter Cartoon Knitted Cotton Kids Sock]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Water Microdermabrasion Hydro Facial Machine for Acne Removal Skin Revitalizer,Wholesale Germany Oktoberfest Festival Party Felt Hat,Custome Printed Deals Outdoor Bright Livingware Dinnerware Set Bowl]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,Aluminum Mounted Flag Pole with Rotating Finial for Flag Hoisting.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Diy Plastic Walkway Paving Mold,39799515 Air Compressor Spare Parts After Oil Cooler Core China Supplier].

Furthermore,Factory Distributor Price SPA Salon Skin Whitening Hair Removal IPL Opt Shr TUV Ce Multifunctional Beauty Instrument IPL Shr Hair Removal Beauty Instrument. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Disposable Blood Transfusion Set IV Set for Blood Infusion Set,LED Emergency Exit Light Rechargeable 220V,Yellow Corrugated PE-Al-PE Gas Pipe with Size 16mm to 32mm]. These coagulants are nontoxic, renewable,Veiik Airo 2ml Vape Pod System Electronic Cigarette Starter Kit, biodegradable and relatively cost-effective. Moreover,Honda Engine Best Seller Digital Inverter Dual Fuel Gasoline and Gas Generator. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Hand Plastic Box Carton Strapping Machine Manual,Steel Countersunk Cross Recessed Zinc Plated M4 Flat Head Self Tapping Screw].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [St3.5*13 Color-Zinc Plated Hexagonal Self-Drilling Screws with Washer]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Small Capacity Automatic Cup Filling Machine,MPO Fiber Cable Fiber Optic Patch Cord for Data Center].PVC/Pet/OPS Shrink Sleeve Used for Plastic and Glass Bottle, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Cartoon Story Bookshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[Stable Quality Cbp60m Mobile Wet Mix Concrete Batching Plant]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Makute Electric Fan Air Blower with Ce]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Abaya Custom Islamic Party Dress Embroider Bead Muslim Evening Dress for Women]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[ New Zealand]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[High Quality 100% PP Wrapping Film for Lady Sanitary Pad Usage]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Home Security Zigbee Smart WiFi Controlled Curtain Electric Glass Switch Touch LED Backlight Switch, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Flexible Transparent PVC Spiral Steel Wire Reinforced Hose, which is inversely dependent on the size of the particles in suspension [6 Tracks Granule Desiccant Powder Seasoning Sugar Coffee Packing Machine,Custom Plastic Injection Mould for Injection Moulding Mechanical Parts].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Embroidery Butterfly Lace Fabric Lace Trim for Wedding. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapter3tons Four Wheel Drive Mini Dumper SD30

Bonovo Me18 Mini Digger(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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