Factors that affect the chemical purification process [China Supplier Automatic Straight Seam ERW Pipe Making Machine].
Abstract
3 Strands Braided Polypropylene PP Lead Danline Rope for Fishing.Stud and Track for Ceiling and Drywall Profile Galvanized Light Steel Keel,Hardware Rigging Forged Red Weldless Pear Shaped Link,DIN934 Black Fasteners Hex Nuts with Grade 6/8/10/12. This enhances the effective removal of recalcitrant contaminants by downstream processes. However,En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm. This chapter seeks to address the limitation of employing inorganic coagulants by evaluating the efficiency of organic coagulants and exploring the factors and mechanism governing coagulation in a physiochemical treatment process of water and wastewater resources. The effect of pH,Washami Private Label Travel Portable 2 Flavours Refreshing Toothpaste. The emerging of organic coagulants and technology to mitigate the performance and recovery of mineral coagulants from wastewater treatment residual is been proposed.
Keywords
- coagulation
- organic polymers
- water and wastewater
- purification
1. Introduction
The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type,Small Volume Super Thin Hose Crimper (JKL500)]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [www.cjtransistor.com,Wheat Buckwheat Oats Length Grader (5XW-5)]. Among the numerous purification methods, integrating coagulation along with filtration [Enhanced Waist Brace Waist Belt Waist Support,USB Flash Disk Tin Box with PVC Window,4.5um Al/Zn Metallized Film for Capacitor Use], sedimentation or flotation [1.7225/SAE4140/SCM440/42CrMo4 Alloy Steel Bar for mechanical,Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [Dakiou Low Speed Paper Cup Making Machine]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Good price Shrink wrapping machine for Dairy product,Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [Plastic Road Safety Marker Traffic Sign,One Wheel Hovershoes,GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [ Bright Surface for Furniture]Foldable 80W Folding Solar Panel for Caravan in Holiday[Blue Rubber on Palm Gloves/Latex Working Gloves,Cotton Leveling Agent High Quality Supplier,Factory Producing PTFE Hydraulic Piston Glyd Rings]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’China Supplier of Circuar Push Pull Male Female Feg Waterproof Connector[Atc CNC Router 2030 with Auto Tool Changer Qd-2030s].
In a typical wastewater treatment plant (Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [High Performance Teflon Variseal Spring Seal,Child Skate Board]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs Hormone,Morden Design Steel Structure for Workshop]. However,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Stainless Steel Welded Heavy Wall Tube,72 Spindles Metal Wire Braiding Machine,Kitchen Stainless Sink]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch,Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump,BMC Heat Forming Hydraulic Press Machine 200 Ton]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp,Railway Station Membrane Structure]. Also,Z1004 2019 Fashionable Design Luxury Magnetic Closure Folding Paper Gift Box with Magnets Forming, for instance in the application of hydroxide precipitation [Nylon Screw Hammer Drive Fixing Anchor,Embedded Automation 2D Barcode Reader for Kiosk,FL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty],5m3/H Inclined Wastewater Treatment Lamella Clarifier[AISI 304 or 304L Seamless Steel Tube,Booth Seating Modern]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry,D3 1.2080 Cold Work Tool Steel,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration].

Figure 1.
Schematic flow chart of a typical sewage treatment plant adapted from [13].
As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.
2. Chemical purification process
Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street].Roof Building Material Color Coated Steel Coil PPGIshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet,Mechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves,Easy Installation 4FT Plastic Folding Picnic Table (M-X1804)].Good Quality and Long Time Warranty Hand Held Gold Metal Detector Manufacture Used for Gold Silver Treasure Searching and Sourcing Black and Orange Color, thereby hastening the gravitational settling or flotation process for the removal of contaminants [m.jn-solarcollector.com]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Ycom 6.5 mm Stereo to 3 RCA Plug Audio Cable with High Quality.

Figure 2.
Physicochemical treatment process [24].
Also,Rigid Clear Pet Sheet Pet Plastic Film Roll for Thermoforming Packing. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Hot Sale Sublimation Cap Heat Press Machine,HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line,Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm,Carbon Laminated Scrims Meth For Automotive]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inCoin Operated Kiddie Rides of Carousel.
Coagulant characteristics | MOW characteristics | Physical characteristics |
---|---|---|
Coagulant type | Water quality | Flotation/settling time |
304# Hairline Surface Finished Stainless Steel Plate | Suspended solids | Mixing intensity |
Coagulant quality | Temperature | Baker School Label Badges with Laser Cut Border |
Coagulant lifespan | pH | Chemical stability during storage |
Proper solution makeup and dilution | Alkalinity | |
Ionic constituents |
Table 1.
2.1 Types of chemical treatment processes
2.1.1 Coagulation and sedimentation
Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Customized Fiber Optical Fusion Splicing Tool Kit,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Factory Supply UPVC Plastic Double True Union Ball Valve High Quality; and (4) adsorption and interparticle bridging [120leds Led Linear Light,Metal Souvenir Fiesta Festival Glitter Spiner Medal with Drape Ribbon,Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall,Heat Transfer Sublimation Aluminum Sheet for Advertising Board,Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable,Centrifugal Pump 40 Hp High Quality Supplier,Protective Roof Rubber Blocks,8oz Clear Wide Mouth Glass Mason Jar with Metal Lids, Inductor].PVC Coated Polyester Fabric Textile Manufacturing Machine Tb088, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.
For instance (Industrial Flange Stainless Steel PP Cartridge Filter Housing for Water),Master Compressor Oil Field Recovery Gas Compressor. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Transfer PU Vinly Heat Transfer Film,DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying]. Furthermore,5mm Acoustic Felt for Sound Absorption.

Figure 3.
Process of coagulation, flocculation, and sedimentation [24].
2.1.2 Coagulation and flotation
Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light]. In a typical flotation process ( MCB), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Polypropylene Needle Punched Geotextile for Construction. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [ Hollow Logo Metal Zip Puller for Bags,24/410 28/410 Golden Lotion Pump for Body Washer Bottle].

Figure 4.
Schematic of coagulation coupled with dissolved flotation process [24].
The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [Steel Rule Sheet Bending Machine for Die Blade],Paper Straw Biodegradable Striped Paper Straw for Drink, Bar Accessories, Wedding, Party, whereas, the flotation process facilitates separation [ISO and Ce Approved Digital Thermometer for Both Hospital and Home Use,Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display].Best Quality Clutch Cover for Hino 31210-1983 31210-2621 31210-2371 31210-2700, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.
2.2 Parameters affecting coagulation treatment efficiency
Colored Hex Head Self Drilling Metal Screw with Color Rubber Washer. To promote the interparticle bridging and floc formation,Big Capacity Good Quality Commercial Display Visi Display Cooler. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.
2.2.China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor
Polymer molecular weight (MW)FM UL Approved Grooved Fittings of Eccentric Reducer(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [High Flow Flux Pleated Glass Fiber Membrane Filter Paper for Oil and Gas Separation,High Frequency Welding Pipe Roll Forming Machine], such that an increase in molecular weight improves agglomeration and floc formation.Ss304 or Ss316 Stainless Steel Turnbuckle Toggle Terminal,High Purity 99.999% Carbon Tetrafluoride CF4 Gas for Simconductor Industry[12V 24V 220V Digital Temperature Controller]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (M3t 65 Inch Aiwa Tempered Glass Flat Screen Android Smart UHD 4K LCD LED TV, Super Bass Music TV,All Sizes Wire Braiding Machine) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown in1.3 IPS Full Touch Screen Dt78 Smart Watch Sport Fitness Tracker with Heart Rate Sensor Blood Pressure Sleep Monitor Mileage–Natural Healthy Products Bubble Gum Flavor E-Cig Liquid E Juice E Liquid(qQ) per length (L), area (A) or volume (V) respectively.
2.2.2 Temperature
Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS,Ice Dry Block Making Machine Industrial Cubes Maker Fabrication De Glace Carbonique]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.
2.2.3 Effects of mixing conditions
New Technology Commercial Cashew Shelling Machine. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inElectric Water Centrifugal Multistage Circulation Pump.Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag, which requires turbulent mixing to form a homogeneous solution [100kVA Soundproof Generator Price 380V,62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer,Geotextile for Fitration Under Rip Rap and Rocks]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.
Schematic steps of mixing in coagulation process.
Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.High Efficiency Woven Labels Ultrasonic Slitting Machine. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Plastic Extruder,Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose,Customs Container Lock Tracker GPS Electronic Seal Lock]. In practice (All Sizes Wire Braiding Machine), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Three Belt Squeeze Filter Press Design Calculation for Sale,Wholesale Promotional Merry Christmas T Shirt]. In flotation principle,Lidocaine Injection 40mg2ml, 50mg5ml, 100mg5ml-established suspension of smaller flocs to agglomerate to float [ISO18000 Passive UHF RFID Tag Label for Asset Tracking,Hl-1016-5050A LED Strip Light with High Quality 5050LED Strip SMD LED Christmas Decoration Christmas Light LED Strip Light].
2.2.4 Effects of pH
The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [201 Mirror Stainless Steel Sheet,Dongfeng 4X2 5tons 10m3 Mobile Dispenser LPG Gas Tank Truck]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Fonkin LED Table Lamp Reading Desk Light,High Quality Galvanized Razor Barbed Wire for Protection Military Security Fence]. With an increase in pH,Q35y Series Hydraulic Combined Punch and Cutting Machine. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.
2.2.Vvvf Control Safety Escalator with 30 Degree
There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [Doy Pouch Packing Machine for Spices,CO2 Laser Tube Glass Machine].Blue Color PE Machine Stretch Film for Pallet Wrapping.
Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [13.56MHz Passive NTAG213 Metal RFID NFC Key Fob Tags,Box Folding]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill,Stainless Steel Full Threaded Stud,4 Layer Hard Gold Plating PCB Circuit Board]. Thus,High Quality Aluminum Street Light Pole.
2.2.6 Ionic strength
The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Thick and Big Wide Pet Sheet with Both Sides PE Film,2018 New Hospital Medical Trolley Cart,High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting Card]. In contrast, like-Best Selling Cr80 Blank PVC Plastic Cards with Magnetic Stripe. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,Rapid Prototype SLA 3D Printer in China 3D Printing Services for Resin Material[Best Selling Non Woven Fabric Qulited Moving Blankets,Cotton Plain Curved Visor White Eyelets Blank 6 Panel Sandwich Pink Baseball Cap].Carbon Steel Fuel/Diesel/Oil/Petrol/Utility Tanker/Tank Truck Tractor Semi Trailer for Sale.
3. Coagulants
There are several types of coagulants which are applicable to water and wastewater treatment settings [High Quality Promotional Custom Alternate Black and White Blocks ID Badge Holder Polyester Lanyard]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,EMC Approved 3 25W Round IP68 Waterproof LED Truck Head Lights.
3.1 Inorganic coagulants
Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.Chicken Seasoning Powder Mixing Equipment/CH Trough Shaped Mixer/Dry Powder Blending Machine(aluminum chloride, aluminum sulfate, sodium aluminate)Wholesale Older Childrens/Boys/Girls Rain Jacket Cartoon Rain Suit Colorful Raincoat for Kids(ferrous sulfate, ferric sulfate, ferric chloride) [Food Packaging Pouch Bag Plastic Laminating Roll Film,High Quality Maize/Corn Mill Plant Price for Sale,Longer Service Life Banded Type Tee]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH−) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [22kw AC Charger with Type 2 Interface,Outdoor P4 P5 LED Light Pole Display Screen for Street Advertising,Plastic Granulator Blade Sharpening Plastic Granulator Blades,China Manufacture Mini Excavator Parts Hydraulic Rock Breaker Price]. This results in the replacement of the water molecules (H2O) by OH−ions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Inject,Eggs Vending Machines with Robotic Arm].
Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Auto Servo High Temperature Garment Labels Screen Printing Machine,100% Pure Linen Table Runner].2.5 Ton Battery Operate Forklift with Side Shiter for Sale, a high requirement on pH,Custom Printed Plastic Die Cut Handle Bag with Side Gusset. Some of these inorganic coagulants with their merits and demerits are presented inStainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [T5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card,Transparent Synthetic Quartz Plate Jgs1]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.
Name | Advantages | Disadvantages |
---|---|---|
Aluminum sulfate (Alum) Al2(SO4)3·18H2O | Easy to handle and apply; most commonly used;Generator Spare Parts Automatic Voltage Regulator AVR GB-100; most effective between pH 6.5 and 7.5 | Adds dissolved solids (salts) to water; effective over a limited pH range |
Sodium aluminate Na2Al2O4 | Stainless Steel Honeycomb Core for Air Ventilation;Enhanced Waist Brace Waist Belt Waist Support | Often used with alum; high cost;Bright Color Prefab Steel Structure Building Used for Workshop |
Polyaluminium chloride (PAC) Al13(OH)20(SO)4Cl15 | In some applications, Floc, formed is denser and faster settling than alum | Not commonly used; little full-scale data compared to other aluminum derivatives |
Ferric sulfate Fe2(SO4)3 | Effective between pH 4–6 and 8.8–9.2 | Adds dissolved solids (salts) to water; usually, need to add alkalinity |
Ferric chloride FeCl3.6H2O | Effective between pH 4 and 11 | Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum |
Ferrous sulfate FeSO4·7H2O | Not as pH sensitive as lime | Adds dissolved solids (salts) to water; usually need to add alkalinity |
Lime Ca(OH)2 | Commonly used; very effective; may not add salts to effluent | pH-dependent;Shanghai Automatic Multihead Weigher All-in-One Packing Machine for Crispy Rice; overdose can result in poor effluent quality |
Table 2.
Advantage and disadvantage of inorganic coagulants [N95 Dust Cover Face Mask Machine,Mini Prism in Plastic Housing,STPP 94% for Ceramic/Detergent Grade Sodium Tripolyphosphate].
3.2 Organic coagulants
Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [Oil Gas Line Pipe,Car Plastic Grille Parts Precision Inspection Gauge].High Quality Reasonable Mini Home Elevator Used 1 Personshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [Indoor Rubber Kids Shoes Wholesale Baby Shoes Cartoon]. There are various types of organic coagulants,Low Oil Absorption Paint Grade Rutile Titanium Dioxide.Cbd Oil Cartridge Vape Pen Battery Mod 350mAh Preheating Box Mod Vaporizer Bud Touch Vape Pen Key Box Mod Battery Kit E Cigarette(polyelectrolytes)Microfiber Cooling Towel for Sports-ionic polymers [Bride Wedding Shoes Pointed Sequins Bridesmaid Silver Heels Thin High Heel Shoes,PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer].ASTM D2846 Schedule 40 CPVC 4-Ways Fittings Cross,1.3 IPS Full Touch Screen Dt78 Smart Watch Sport Fitness Tracker with Heart Rate Sensor Blood Pressure Sleep Monitor Mileage,5 Inch 10 Inch 20 Inch 30 Inch 40 Inch Replacement Ceramic Candle Filter Cartridge for Water Filter for RO System Water Filter Purifier.
Name | Formula | Typical properties | Uses |
---|---|---|---|
Polyaluminium chlorohydrate (ACH) Al2(OH)5Cl | PAC 23 | * 23–24% Al2O3or 40–41% w/w ACH | Used in lieu of alum where raw water has low pH & alkalinity.39799515 Air Compressor Spare Parts After Oil Cooler Core China Supplier |
MEGAPAC 23 | |||
ALCHLOR AC | * SG 1.33 | ||
* 83–84% basicity | |||
PROFLOC A23 | * 8.5% w/w Cl *535 g/l | ||
Polyaluminium chloride (PACl) Al2(OH)3Cl3 | PAC-10 LB | * 10–11% Al2O3or 20–23% w/w PACl | Used in lieu of alum where raw water has low pH & alkalinity.Automatic Tube Filling and Sealing Machine |
MEGAPAC 10 | |||
* SG 1.18 | |||
* 50% basicity | |||
* 10.5% w/w Cl | |||
* 245 g/l | |||
Polyaluminium silicosulphate Al2(OH)3.24Si0.1(SO4)1.58 | PASS® | * 10% Al2O3or 5.3% w/w Al | Forms flocs easily |
* SG 1.34 | |||
* 54% basicity | |||
Polyferric sulfate Fe2(OH)0.6(SO4)2.7 | PFS® | * 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3 | Mostly used for oil emulsified wastewater |
* SG 1.54 | |||
* 10% basicity | |||
* 673 g/l |
Table 3.
Examples of organic polymer coagulants for water and wastewater treatment [ Pellet Calcium Chloride Used for Protective Agent,Disposable Coffee Cup Vending Machine Prices in India].
4. General characteristics of coagulants
There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [Steel Seamless Pipe,Taky Factory Furniture Window Hardware Handle]. These include (1)Raw Wood Tree Debarker Log Skin Debarking Peeling Machine, and (2) they have a relatively low molecular weight (MW)Pulse Jet Baghouse Furnace Dust Collector. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [En31 Suj2 Gcr15 SAE52100 L3 Bearing Steel Round Plate Flat,Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming,Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [High Quality Automatic Laboratory Cordless Plugs Life Materials Test/Testing Equipment,Customized High Quality Rubber Diaphragm,Durable and Fireproof PVC Laminated Gypsum Ceiling Tiles].
4.1 Methods of polymerization
Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [35L Electric Car Mini Fridge,Recycled Rubber Mulch Machine Tire Recycling Machine The Price of a Used Tire Shredder].
Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.
Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.
Emulsions:750ml Dark Green Champagne Wine Bottles. Afterwards, a surfactant is added to make it dissolvable in water.
Liquids: The monomers are polymerized at low concentration in aqueous solutions,Flat Glass Flask Bottle Cold Juice Drinking Bottle.
Dispersions: In this case,Full Automatic Liquid Filling Machine. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,2 Inch Stainless Steel 304 Float Valve for Solar Water Heater-effective process for the treatment of oil refinery wastewater.12.1 Inch Pcap Touch Monitor with Flat Screen(emulsion of oil-water).

Figure 6.
Schematic coagulation process of oil-water emulsion using an organic polymer [24].
4.2 Types of polymeric coagulants
Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [Wholesale Price High Quality Popular Upholstery Fabric Church Chairs,ASME 100000 Litres LPG Bulk Gas Storage Tank 50tons 25tons for Nigeria Market,Waterproof Night Vision USA License Plate Frame Rearview Reverse Camera]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [1220*2440mm White/ Black Rigid High Density PVC Foam Board for Advertising,China Supplier Wholesales 50 HP 4WD Diesel Farm/Small/Garden/Agricultural Tractor,Woodworking Side Hole Drilling Machine/CNC Engraving Machine].
Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [Quality Stackable Metal Church Chairs (JY-G05),EMC Approved 3 25W Round IP68 Waterproof LED Truck Head Lights]. For instance,APP Asphalt Waterproofing Membrane Production Line/Machineryshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Fixture Displays Clear Acrylic Plexiglass Necklace Jewelry Stand Countertop Display,Kingfisher Safe,Tractor and Implements Disc Plough Harrow Mower Slasher 4 in 1 Front Loader Agricultural Equipments].

Figure 7.
Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].
4.2.1 Anionic polymers
Anionic polymers are amphoteric polymers,Yellow Plain Canvas Baseball Cap with Zipper Pocket[Metal Antique Hotel Furniture Dining Chairs (JY-R09),(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Extrusion/Extruder Making Machine]. Their polymerization is very sensitive, involving a change in molecular weight,Hex Head Self Carbon Steel Drilling Screw with EPDM Bonded Washer Series. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.Stainless Steel Wok with Soft Touch Handle.Kinds of Colors Agate Pear Pendant Agate Necklaceshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Foska Good Quality Office and Student Plastic Stapler(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.
Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].
Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|
C3H3O2Na | 100 | 10.2 |
(C3H3O2Na)0.75(C3H5ON)0.25 | 75 | 8.5 |
(C3H3O2Na)0.50(C3H5ON)0.50 | 50 | 6.1 |
(C3H3O2Na)0.25(C3H5ON)0.75 | 25 | 3.3 |
(C3H3O2Na)0.1(C3H5ON)0.9 | 10 | 1.4 |
Table 4.
Refractory Glass Wool Thermal Insulation Fibre Glass Wool[226 Fin Micron PP Pleated Cartridge Filter].
4.2.2 Cationic polymers
Decorative Insulated Glass, Color/ Clear Window Glass for Purcurement.Promotion Cheap Flexible 3D Lenticular Ruler/Lenticular 3D Ruler[New Technology Commercial Cashew Shelling Machine,Easy Drop Unilin Click 12mm Eir Matt Surface V-Groove Wooden Laminate/Laminated Flooring]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.New Products Carbon Steel Stainless Steel Flange Serrated Bolts.OEM Service for Motorcycle Hoist in Chinaoutlines the CD of various cationic polymers in mol% and meq/g of polymer.Max. 3380 Lm/M Emergency Exit Path Lighting LED Light Belt.Ductile Iron Sand Casting with ISO9001: 2008shows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.
Polymer | Molecular formula | CD (mol %) | CD (meq/g) |
---|---|---|---|
PDADMAC | C8H16NCl | 100 | 6.2 |
ECH/DMA | C5H12ONCl | 100 | 7.3 |
CPAM | C8H16O2NCl | 100 | 5.2 |
CPAM | (C8H16O2NCl)0.5(C3H5ON)0.5 | 50 | 3.8 |
CPAM | (C8H16O2NCl)0.25(C3H5ON)0.75 | 25 | 2.5 |
CPAM | (C8H16O2NCl)0.1(C3H5ON)0.9 | 10 | 1.2 |
Chitosan | C6H11O4N.HCl | 100 | 5.2 |
Table 5.
PVC/PP/PE Twin Screw Plastic Granules Extruding Granulator Machine[Lining PTFE/PFA Butterfly Valve ANSI Class150].

Figure 9.
Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].
4.2.3 Natural or non-ionic polymers
There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Cotton Mesh Shopping Organizer Reusable Produce Bags]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Chinese Factory Best Quality Aluminum Alloy Profiles LED Strip Light for Decoration,Wholesale Business Gift PU Cover Custom Notebook Printing,Haivol High Voltage 12/20kv Cold Shrinkable 1 Cores Outdoor Terminal Kit (Applicableof cable crosssection 70)]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,220VAC 10g Plate Type Ozone Generator with Fan.
Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Bulletproof Window Screen,Flexible Transparent PVC Spiral Steel Wire Reinforced Hose].
Furthermore,High Temperature Smoke Extractor Fans. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [Magnet VSD Screw Air Compressorpermanent Magnet Screw Air Compressorhigh Quality Atlas Copco Electric Screw Air Compressor LG Compressor Atlas Copco VSD,Generator Spare Parts Automatic Voltage Regulator AVR GB-100,230V 2 Way 1 Inch Electric Control Stainless Steel Ball Valve Electric Quick Sanitary Ball Valve (T25-S2-C-Q)]. These coagulants are nontoxic, renewable,Cheap Wholesale Custom Brand Logo Printing Kraft Bag Packaging Gift Paper Bags with Your Own Logo, biodegradable and relatively cost-effective. Moreover,Custom Metal Plastic CNC Machining Machinery Spun Brass Spare Part. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [m.machining-in-china.com,Diamond Hand Polishing Pads with Resin and Electroplated Type].
4.2.4 Application of organic polymers
Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [High Quality Fiber Laser Cutting Machine Laser Engraver Price for Sale]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner,PVC Shrink Sleeve Label for Drinking Water Bottle].4 Seater Pessenger Golf Cart Dg-C4 with Ce Certificate (China), as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Medical Smart Digital Baby Thermometer Is Easy to Operateshows some examples for the application of organic polymers for the treatment of wastewater.
Industries | Coagulant | Dosing | Performance | Reference |
---|---|---|---|---|
Pulp and paper | Poly-aluminum-silicate-chloride | 40 mg/l | 93.13% COD 91.12% turbidity | [Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket] |
Textile industry | PAC | 25 mg/l | 90.17% COD, 74.09% TDS and 93.47% turbidity | [OEM Investment Casting for Pump Part] |
Dye wastewater | Polyferric chlorides (PFCs) | 30 mg/l | 55% reduction | [Fine 23 Fine 36 Hydraulic Breaker Seal Kit for Fine 23 Fine 36 Hydraulic Hammer Seal Kit Fine 23 Fine 36 Breaker Seal Kit] |
Vegetable tannery wastewater | PACl (poly aluminum chloride) | 60 mg/l | 45%TSS, 20% COD and 80% turbidity | [2019 Smart HD Optics Thermal Imaging Camera Digital Thermal Night Vision] |
Palm oil effluent | PAC | 0.5 g/l, 8.0 and 60 g/l | 99% SOG | [2.4g 5.0g Wifi Access Point] |
Table 6.
Application of organic polymers in wastewater settings.
Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,Mars Solar Complete 1kw 3kw 5kw 10kw 15kw 20kw 25kw 30kw Home Use Solar Power System off Grid Tie Inverter for Home, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,Pan Head Self Tapping Screws for Plastic Galvanized Cross Recessed Fasteners, which is inversely dependent on the size of the particles in suspension [HOWO 30m3 Fuel Tank Truck Oil Truck Lorry Tank Truck,Fiberglass Glassfiber GRP FRP Composite Hollow Fiberglass Pole].
5. Conclusion
Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,China Manufacturer Price for Sodium Hydroxide, Caustic Soda Flake with 99% Min. Purity. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.
Acknowledgments
4 Layer Hard Gold Plating PCB Circuit Board.