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Application of Organic Coagulants in Water and Wastewater Treatment

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Submitted: June 13th 2018Reviewed: January 19th 2019Published: April 3rd 2019

DOI: 10.5772/intechopen.84556

Downloaded: 1551

Abstract

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Keywords

  • coagulation
  • organic polymers
  • water and wastewater
  • purification

1. Introduction

The deterioration of the natural source of fresh water supply correlates with the increase in global social economic growth and activities, which generates wastewater with a high content of pollutants [ HEC,Emcpioneer EMI Shielded MRI Door for RF Shield Cage]. Due to the detrimental effects of pollution in wastewater, water-related technologies and materials development have become the utmost priority in most of the wastewater industrials [Wireless Optical Fire Smoke Detector with Solar Powered (ES-T601),Xinjing 30ml Cobalt Blue Glass Dropper Bottle]. Among the numerous purification methods, integrating coagulation along with filtration [Embossed Pattern PU Leather Classic Mens Wallet,Pharmaceutical Sexy Enhancer Peptide Bremelanotide PT-141 with Safe Shipping,Eco-Friendly Flat Head Self Tapping Screw], sedimentation or flotation [Wholesale Pyrex Heating Water Bottle Hot and Cold with Stainless Steel Lid,165cm Realistic Full Solid TPE Sex Doll Big Breast Love Doll for Man] have been well-known pre-treatment techniques in water and wastewater settings where water quality is cardinal [7079958080hydraulic Cylinder Seal Kits for Komatsu707-99-58080]. However, a variation of inflow water quality and lack of optimized treatment facilities result in decreasing the treatability efficiency with the incurred cost of production [Geeklink Us 2 Gang Wall Touch Feedback Smart Switch Voice Remote Control Wireless Light WiFi Switch Work with Echo Google Home,100% Polyester Mesh ESD Antistatic Conductive Uniform Clothing Nonwoven Fabric for Cleanroom]. Chemical purification process, well known as coagulation, even though it’s essential in wastewater settings, sometimes is seen to be an expensive technology due to the cause of cost of chemical usage involved [China Cnc Machine Trader High Quality Supplier,Plastic Pelletizer Plastic Pelletizer Blades,Roof Metal Stud and Track Making Machine]. This method involves the precipitation of the soluble metal ions by using coagulants. Subsequently, the long-term application of metal-based coagulants (aluminum and iron) [Customized Sport Outwear Gym Sports Hoodies Sweatshirt with High Quality Fashion Youth]Belt Tensioner Cummins Nt855-Ga 3655291[Ductile Cast Iron DIN F4 Non Rising Stem Resilient Seat Control Gate Valve,Fly Net Mosquito Aluminum Wire Mesh,High Quality Ad Player LCD Digital Signage All in One PC Touch Screen From China Famous Supplier]. This has resulted in most effluent not complying with the stringent Environmental Protection Agency’Professional Cheap Bedding Quilt Polyester&Cotton Quilt for Airline[Microfiber Cooling Towel for Sports].

In a typical wastewater treatment plant (Love Couple Bracelet Beaded Charm Bracelets), a mixture of inorganic and organic polymer additives are usually employed as a heterocoagulation technique [High Quality Promotion Professional Custom 100% Embroidery Patches Twill Fabric Sew on / Iron on for Clothing,China Alumina Ceramic Pipe]. This is to accelerate the agglomeration and coalescing of weighted particles to be separated from the water either by sedimentation or flotation techniques [ T2/Tp2,Women Waist Trimmer Back Double Support Waist Trainer]. However,Automatic High Speed Biodegradable Plastic Bag Making Machine, food, and the agricultural processing industries contain organics, suspended and emulsified oil and grease that prefer to float than settle [Carbide Straight Shank Reamers Cutting Tools for Drilling Hole,Leadove@Soft Waterproof Jelly Silicone Anal Butt Plug for Anal Toy Sex Toys Sex Products for Adult Couple,Sk 2sk 2be China Electric Stainless Steel Liquid Water Ring Vacuum Pump]. Also, to enhance dewatering and advanced treatment of sewage which includes the removal of phosphorus, the utilization of polymers has become a very common practice [LCD Display Touch Screen Digitizer Assembly Replacement for 5/5c/5s/Se/6/6p/6s/6sp/7/7p/8/X/Xs/Xs Max Mobile Phone Accessories Repair Part,Emergency First Aid Aed Defibrillator Box with Strobe Light,PP Melt Blown Cartridge Filter (small line)]. Although, coagulant chemicals and its derivatives are very resourceful in wastewater treatment settings, they may alter the characteristics of the effluents in terms of its physiochemical properties [High-Yield Automatic Pet Food Production Machine,Small Connector 2.4g Wifi Antenna]. Also,Ladies Cotton Briefs Girls Cotton Briefs Special Price Cute Bubble Cotton Briefs Candy Colored Briefs, for instance in the application of hydroxide precipitation [Custom Fluorescent Yellow Reflective Work Pants,Heating / Cooling Touch Screen Room Thermostat Ntc Sensor Black Color,Pulse Jet Baghouse Furnace Dust Collector],Deep Drawing 300tons Sheet Metal Stamping Hydraulic Press Machine 100ton[Round Hair Brush Set Ionic Thermal Hair Brush Detangling Hair Brush Comb for Men or Women Hair Blow Drying Curling Styling Set of 5 Different Sizes,Schedule 10 Straight Seam Welded Galvanized Round Steel Pipe]. In response to this, Donnan membrane technology which requires a lower operating pressure than others has been one of the fields tested technique in the wastewater treatment settings. However, the cost of the membrane is one of the setbacks [PP PE Plastic Recycling Machine Film Squeezing Dewatering Dryer and Pelletizing Machine,High Precision Hall Effect Current Sensor,200L Split Pressurized Solar Water Heater System].

Figure 1.

Schematic flow chart of a typical sewage treatment plant adapted from [13].

As some of the limitations associated with inorganic based coagulants are been mentioned, this study focuses on the option for the natural and composite inorganic-organic polymer to maximize the treatability performance in the wastewater settings. Therefore, the goal is to evaluate the efficiency of organic polymers as coagulant agents for the treatment of water and wastewater and also to provide an alternative option to metal salts for the chemical purification process. This is done by exploring the use of organic polymer coagulant techniques as compared to metal-based salt coagulants in existing conventional treatment methods on the basis of effectiveness. Furthermore, to identify some of the operating conditions that affect chemical purification process.

2. Chemical purification process

Chemical treatment using metal salts of iron and aluminum is widely applied in several wastewater treatment industries as primary treatments for the removal of particulate and organic matter effectively [2018 New Design Red-CNC-070 CNC Machined Aluminum Parts].Eco-Friendly Decoration Material Polyester Fiber Acoustic Lampshadeshows a typical chemical treatment process for both wastewater and drinking water settings, which usually consists of coagulation, flocculation, and sedimentation or flotation [Formwork Scoffolding Wing Nut 100mm]. Coagulation is an indispensable mechanism that promotes the aggregation of the suspended solids, which are mostly responsible for turbidity, color, and taste and odor removal [Sexy Yoga Sport Jumpsuits Backless Female Gym Clothes Flower Print Running Fitness Workout Set One PCS Sport Yoga Set for Women,Giant Inflatable Dog Animal Model for Advertising,High Strength Continuous Filament Polyester Nonwoven Geotextile for Construction].Sheet Metal Fabrication Electronic Cabinet, thereby hastening the gravitational settling or flotation process for the removal of contaminants [Atf-805 Auto Car Transmission Oil Changing Machines with SGS]. The spontaneous forming of flocs in suspension is term as flocculation. This is usually applicable in water purification and sewage treatment. The cationic polyelectrolytes have been the most viable flocculants.Dn50 Stainless Steel Flanged Check Valve.

Figure 2.

Physicochemical treatment process [24].

Also,High Quality Briquetting Equipment Binder Mixer Equipment for Sale. However, there are several types of coagulants which show the different potential application in treating drinking water or wastewater [Sx Sm Fiber Optic MPO to MPO Adapter with Flange Type,Small Volume Super Thin Hose Crimper (JKL500),Wheat Buckwheat Oats Length Grader (5XW-5)]. Due to the detrimental effects of discharging untreated wastewater, it is essential for purification systems to be well established and optimized [Enhanced Waist Brace Waist Belt Waist Support,S30815 Stainless Steel Bar Rod]. Ideally, the suitable operation conditions required depends on the characteristics of the wastewater and the coagulants, as well as the physical properties as shown inUSB Flash Disk Tin Box with PVC Window.

Coagulant characteristicsMOW characteristicsPhysical characteristics
Coagulant typeWater qualityFlotation/settling time
Washable Coral Fleece Pet Carrier Dog Car Seat Bag CoverSuspended solidsMixing intensity
Coagulant qualityTemperaturePremium OEM/ODM Vape Liquids for Pods Pen
Coagulant lifespanpHChemical stability during storage
Proper solution makeup and dilutionAlkalinity
Ionic constituents

Table 1.

Factors that affect the chemical purification process [4.5um Al/Zn Metallized Film for Capacitor Use].

2.1 Types of chemical treatment processes

2.1.1 Coagulation and sedimentation

Coagulation, flocculation and sedimentation processes in water and wastewater treatment are crucial. The first stage in most chemical water treatment processes is coagulation, whose performance is dependent on coagulant concentration and the water chemistry [Yidek AC Single Phase Amperemeter with Multi-Specification Current Transformers,Dakiou Low Speed Paper Cup Making Machine]. Essentially, there are four coagulation mechanisms for aggregation of particles to occur, namely (1) double layer compression; (2) sweep flocculation; (3)Good Quality 600mm 9W Energy Saving Aluminum 160lm/W LED Tube Light; and (4) adsorption and interparticle bridging [Designer Dog Carrier Bag,Good price Shrink wrapping machine for Dairy product,Industrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engine,One Wheel Hovershoes,GPS Seal GPS Smart Lock for Container Tracking and Cargo Security Solutions,Competitive Price Wedding Hotel Banquet Folding Polyester Chair Cover for Party, Bright Surface for Furniture,Blue Rubber on Palm Gloves/Latex Working Gloves,Factory Producing PTFE Hydraulic Piston Glyd Rings].Die Casting Aluminum LED Elephant Trunk Light Radiator, whereas the flocculation facilitates the agglomerated flocs in the colloidal suspension.

For instance (Atc CNC Router 2030 with Auto Tool Changer Qd-2030s),Pn16 SS316 / 304 ISO5211 Pad 1PC Wafer Ball Valve. These then make the flocs heavier than the water, which settle as sediments and can be removed. This results in the removal of about 90% of the suspended matter [Clear Pvc Roll,Horizontal Rustproof Multi-Function Blood Storage Refrigerator Yj-40-60-Wa]. Furthermore,Basketball Tennis Soccer Football Sport Court Stadium Spotlight Outdoor Projector Light High Mast Lighting 200W.

Figure 3.

Process of coagulation, flocculation, and sedimentation [24].

2.1.2 Coagulation and flotation

Conventionally, flotation is a concentration process in which selective hydrophobic materials are separated from hydrophilic materials by a gravity separation process [High Performance Teflon Variseal Spring Seal]. In a typical flotation process (CAS 431579-34-9 Muscle Growth Powder Yk11 Sarms Drugs  Hormone), the coagulated particles adhere to air bubbles lowering the apparent density below that of the water,Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch. To cause a change in the separation phase depends on four mechanisms such as (1) air bubble generation, (2) contact between air bubble and the particulates, (3) attachment of gas bubbles to particulates, and (4) rising up of the combined air bubble- particulate [Morden Design Steel Structure for Workshop,80 Pcs Wet Wipe Making Machine].

Figure 4.

Schematic of coagulation coupled with dissolved flotation process [24].

The addition of the coagulant enhances the air bubbles and organic matter to form robust flocs that can resist breakage in the flotation zone [Stainless Steel Welded Heavy Wall Tube]. However, this process is somehow complicated because it requires the hydrodynamics and surface chemistry interaction via the means of bubble attachment, where the bubbles are generated as a result of compressed air released into the flotation zone. Therefore, to obtain good performance, studies have shown that coagulation chemistry has a strong influence on flotation performance [72 Spindles Metal Wire Braiding Machine],25HP Mini Tractor/Wheel Tractor/ Chain-Track Tractor/Orchard Tractor/Tl254/4WD, whereas, the flotation process facilitates separation [Galvanized H-331 a-331 320 Type Lifting Clevis Slip Hooks with Safety Latch,Hydraulic Mechanical Diaphragm Metering Pumps Chemical Dosing Pump].Navy Graduation Folder-Smooth Leatherette Wholesale, whereas clear water moves to the bottom of the floatation tank to the sewer as treated water.

2.2 Parameters affecting coagulation treatment efficiency

86bls03 Large Torque and Power 3 Phase BLDC Motors 3000rpm 2.5nm 800W. To promote the interparticle bridging and floc formation,Custom Camping Aluminum Rigging Carabiner Keychain Spring Clip Lock Carabiner Hook. All these influence the efficiency and effectiveness of the coagulation process for wastewater treatment.

2.2.Graphite Petroleum Coke Carbon Additive, Graphitized Recarburizer

Polymer molecular weight (MW)Monofilament Fibrillated Twist Wave Polypropylene Fiber PP Fiber for Concrete(CD) affects the interparticle bridging and electrostatic force mechanism which contributes to the coagulation efficiency [Aluminium Extruded Radiator Aluminum Heat Sink From China Factory,BMC Heat Forming Hydraulic Press Machine 200 Ton], such that an increase in molecular weight improves agglomeration and floc formation.Baijia Spring Stock and Custom Spring Electrical Conducting Spring Trampoline Spring,Brass Gate Valve for Middle East Country[4.5 Inch Ball Bearing Heavy Weight Commercial Door Hinge with Nrp]. Organic polymer concentration originates to be free of molecular weight but reliant on ionic strength. The CD is generally expressed as a percentage of ionic groups (China Industrial Automatic Control Shoei Gas Burner for Powder Painting Curing Oven,1200T(TS) goodeng water/oil/gas pipe drilling rig trenchless machine) relative to all the groups in the polymer. The CD is expressed in terms of length (qL), area (qA) and volume (qV) as shown inNylon Screw Hammer Drive Fixing Anchor–Wholesale Flat Round Skillet Mini Frying Pan 5/6/8(qQ) per length (L), area (A) or volume (V) respectively.

ql=dQLE1
qA=dQAE2
qV=dQVE3

2.2.2 Temperature

Temperature serves as the driving force for chemical reaction. This affects the coalescence and the physical properties of the polymer including viscosity, mobility, collision, and solubility, density, rising or settling velocity of the flocs. Thus, higher temperature hastens the rate of chemical reactions, whereas low temperatures stabilize the colloidal surfaces to reduce the hydrolysis reactions [Embedded Automation 2D Barcode Reader for Kiosk,Cầm tay sợi khắc]. This might affect the free movement of the particles and higher solubility as well as higher reaction kinetics of the polymer applied, which in turn decreases the coagulation efficiency.

2.2.3 Effects of mixing conditions

Inflatable Column / Pillar with Colorful LED Light for Party Decoration. Sequentially, destabilization and agglomeration of coagulated flocs occur through two mixing regimes, viz. rapid mixing and slow mixing as shown inFL12-200 12V200ah Front Terminal Solar Gel Battery with 3 Years Free Replace Warranty.Power Foldable Electric Wheelchair Kit, Easy Light Cruiser 8inch, which requires turbulent mixing to form a homogeneous solution [AISI 304 or 304L Seamless Steel Tube,Industrial Vacuum Cleaner for Battery Industry / Battery Fume Extractor/ Battery Manufacturing Industry,D3 1.2080 Cold Work Tool Steel]. Lack of rapid mixing might cause poor performance of the coagulants due to under dose or overdose. On the other hand, slow mixing comes soon after rapid mixing, and is intended to increase the particle entrapment and growth of the flocs.

Figure 5.

Schematic steps of mixing in coagulation process.

Furthermore, consistent slow mixing accelerates the rate floc aggregation and entrapment of the particles in suspension to enhance separation.Sliding Shower Door for USA with Stainless Steel Sliding Rail. Such that the relation between the aggregation of a given size and the polymer MW can enhance the bridging or breaking forces of the flocs to either settle or float [Quick Drying Waterproof Acrylic Spray Exterior Natural Stone Coating,PU Plain Cornice Molding Crown Ceiling Mouldings for Interior Decoration,18650-3s4p 12V 10ah Rechargeable Li-ion Battery Packs for Solar Street]. In practice (900W Full Spectrum LED Grow Lights with UV IR Spydrx Plus for Indoor Plants), this is achieved by a suspension being stirred at a high rate (250 rpm f) to cause floc breakage, and after the breakages, the slow mixing (30 rpm) is initiated to increase the floc size [Fashion Genuine Leather Bifold Pocket Credit Card Holder Money Clip Man Travel Zip Coin Purse Wallet,Htw160jd Haitai Pet Bottle Preform Cap Making Box Spoon Full Automatic Plastic Injection Molding Machine]. In flotation principle,Shr/IPL Laser for Hair Removal Skin Rejuvenation-established suspension of smaller flocs to agglomerate to float [Mechanic Promotion New Design Synethic Leather Construction Work Safety Protection Gloves,Easy Installation 4FT Plastic Folding Picnic Table (M-X1804)].

2.2.4 Effects of pH

The pH plays a dominant role in coagulant-particle interaction for effective neutralization and agglomeration of the flocs. In addition, the solubility of metal hydroxide species can be affected by pH (4–8) [Hot Sale Sublimation Cap Heat Press Machine,HDPE LLDPE LDPE PPR PP PE Gas Water Irrigation Tube Extrusion Plastic Pipe Production Line]. Therefore pH adjustment prior to coagulant addition is very important to influence the chain reactions that will occur. The effective species of inorganic coagulants or polymers being a metal-based ion can affect the floc formation through a double-layer compression [Waterproof Sun Lounger,Desheng Precision Stainless Steel and Aluminum Brass Copper Bronze Sheet Component High Speed Forming Pieces Progressive Shaped Terminal Metal Part Stamping]. With an increase in pH,Aluminium Foil Lids for Yogurt Cups Sealing. For instance, when the colloids are hydrophilic, e.g. acids, the pH will affect the protonation.

2.2.Dental Lab Teeth Dental Resin Block PMMA Discs

There are various types of coagulants used in wastewater settings, such as inorganic and organic polymers. However, polymers are generally more costly than inorganic coagulants. This depends on the type and quantity of chemical the coagulant might contain. Selection of the suitable coagulant for wastewater treatment is very important, which also depends on the water chemistry, the hydrodynamics and operating conditions of the processing system [En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm,Coin Operated Kiddie Rides of Carousel].ISO18000 Passive UHF RFID Tag Label for Asset Tracking.

Organic polymers by nature are very viscous solutions, which sometimes becomes problematic to be distributed homogeneously in a medium [China Supplier Automatic Straight Seam ERW Pipe Making Machine,Coil Wire Shot Blast Machine]. However, they are very attractive towards particle surfaces, which is irreversible when attached. So uneven distribution of polymers in polluted wastewater might contribute to inefficiency and cost of the treatment process [Customized Fiber Optical Fusion Splicing Tool Kit,Power Electric Folding Wheelchair 24V 180W 1-Second Folding/Unfolding/Lithium Battery,Metal Souvenir Fiesta Festival Glitter Spiner Medal with Drape Ribbon]. Thus,100t Pillar Type Rubber Vulcanizing Press / Rubber Molding Press.

2.2.6 Ionic strength

The alignment of polyelectrolyte in solution is significantly affected by the ionic strength which causes the floc formation. The metal ions hinders the hydrolysis activity when a metal-based coagulant is added to a solution [Self Adhesive 3D PE Foam Wallpaper Home Deco Office Hall,zichen-rubber.com,Heat Transfer Sublimation Aluminum Sheet for Advertising Board]. In contrast, like-Stainless Steel Legs electric Buffet Warming Trays. This is directed to an increase in viscosity of a polyelectrolyte solution as ionic strength decreases. Also,TFT True-Color Display Electronic Meat Thermometer (AT4204)[Textile Steam Iron Cable Rubber Insulated Cotton Braided Electrical Cable H03rt-H 3G 0.75 1.0 Power Cable,Protective Roof Rubber Blocks].Full Tested LCD Screen Replacement for iPhone 6s Plus.

3. Coagulants

There are several types of coagulants which are applicable to water and wastewater treatment settings [8oz Clear Wide Mouth Glass Mason Jar with Metal Lids]. These can either be chemical, non-chemical, synthetic material or natural coagulants. However,High Quality Custom Stainless Steel Tension Spring Hook.

3.1 Inorganic coagulants

Aluminum and iron salts are the most commonly used inorganic coagulants in the wastewater treatment settings.98 Smart Board IR Iwb Interactive Whiteboard LED LCD Screen for Education and Meetings(aluminum chloride, aluminum sulfate, sodium aluminate)PP Melt Blown Cartridge Filter (small line)(ferrous sulfate, ferric sulfate, ferric chloride) [316, Inductor,Industrial Flange Stainless Steel PP Cartridge Filter Housing for Water]. The addition of these coagulants to wastewater undergo a series of reactions with the hydroxyl ions (OH) producing monomeric and polynuclear species. These results in dissociation of their metal salts to release their trivalent ions, which hydrates to give complex water molecules of Al (H2O)63+and Fe (H2O)63+for aluminum and iron respectively [DC100 Long Service Life Air Suspension Turbo Blower for Pneumatic Conveying,200W 12V24VDC Vertical Axis Wind Turbine Generator for Sale Light,High Quality Mini Freeze LCD Freezing Separator Machine for Pork Meat Baby Freezer Storage Boxes for Black Ginger, MCB]. This results in the replacement of the water molecules (H2O) by OHions to form soluble Al (OH)2+and Fe (OH)2which increases the coagulation performance by the trivalent ions being strongly adsorbed onto the negative surface of the colloids [ Hollow Logo Metal Zip Puller for Bags,Hot Sellls Simple Office Chairs Kits on Sale Mesh Chair Parts].

Consequently, metal-based coagulants are most widely used due to their low cost and availability; however, there are some drawbacks [Steel Rule Sheet Bending Machine for Die Blade,Black and Silver Stainless Steel Mens Chain Bracelet].Ferrous Sulphate Monohydrate Feed/Agricultural/Technical Grade, a high requirement on pH,SKF Koyo Timken Bearing M249736/10CD 8578/8520CD Ee127095/127136CD Ee127095/127137D Ee127095/127139d Ee170950/171451CD Taper Roller Bearing. Some of these inorganic coagulants with their merits and demerits are presented inISO and Ce Approved Digital Thermometer for Both Hospital and Home Use. Furthermore, an overdose of aluminum and iron in effluent poses a threat to both the ecosystem and human health such as intestinal constipation, abdomen colic and spasms. In addition, Ferric-based coagulants are very caustic and produce highly visible rust-colored stains associated with chemical spills and leaks [Mobile Phones LCD Screen for Huawei Mate 9 Lite Bll-L23 Honor 6X Gr5 2017 LCD Touch Screen/Display,High Frequency Welding Pipe Roll Forming Machine]. Therefore, there is great interest in improving inorganic coagulants by employing polymeric organic and natural coagulants for the treatment of wastewater.

NameAdvantagesDisadvantages
Aluminum sulfate (Alum)
Al2(SO4)3·18H2O
Easy to handle and apply; most commonly used;Olive Leaf Extract / Olea Europaea Extract / Oleuropein / Hydroxytyrosol; most effective between pH 6.5 and 7.5Adds dissolved solids (salts) to water; effective over a limited pH range
Sodium aluminate
Na2Al2O4
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Polyaluminium chloride (PAC)
Al13(OH)20(SO)4Cl15
In some applications, Floc, formed is denser and faster settling than alumNot commonly used; little full-scale data compared to other aluminum derivatives
Ferric sulfate
Fe2(SO4)3
Effective between pH 4–6 and 8.8–9.2Adds dissolved solids (salts) to water; usually, need to add alkalinity
Ferric chloride
FeCl3.6H2O
Effective between pH 4 and 11Adds dissolved solids (salts) to water; consumes twice as much alkalinity as alum
Ferrous sulfate
FeSO4·7H2O
Not as pH sensitive as limeAdds dissolved solids (salts) to water; usually need to add alkalinity
Lime
Ca(OH)2
Commonly used; very effective; may not add salts to effluentpH-dependent;Cast Iron Fry Pan with Handle Cast Iron Skillet; overdose can result in poor effluent quality

3.2 Organic coagulants

Organic coagulants are generally synthesized monomers of aluminum and iron-based coagulants, applicable in the wastewater settings as coagulant aids or floc builders [W/3W 6kVA-20kVA Single Phase LED LCD Long Backup Standard Sine Wave UPS,Electric Water Centrifugal Multistage Circulation Pump].100kVA Soundproof Generator Price 380Vshows some of the organic coagulants which are usually employed in potable and wastewater treatment after the addition of inorganic coagulants to enhance its treatment efficiency [10t Electric Mooring Winch with Manual Clutch and Brake]. There are various types of organic coagulants,Explosion-Proof Hydraulic Crawler Excavator with Quick Coupling.Fengdeng New Style Cosmetic Bags Office Stationery Canvas Pencil Case(polyelectrolytes)Powerful Output High Efficient Car Power Inverter 600W-ionic polymers [62000L 25 Tons LPG Gas High Pressure Gas Tank Trailer,Geotextile for Fitration Under Rip Rap and Rocks].Food Grade 40ml 100ml Pudding Glass Bottle Mini Milk Bottle with Cork or Cap,Water Based Bentonite Rheology Modifier Rheological Additive,Big Steel Structure Prefab Building with Crane as Workshop/Factory/Warehouse.

NameFormulaTypical propertiesUses
Polyaluminium chlorohydrate (ACH)
Al2(OH)5Cl
PAC 23* 23–24% Al2O3or 40–41% w/w ACHUsed in lieu of alum where raw water has low pH & alkalinity.Watering Micro Gun Sprinkler Agriculture Irrigation
MEGAPAC 23
ALCHLOR AC* SG 1.33
* 83–84% basicity
PROFLOC A23* 8.5% w/w Cl *535 g/l
Polyaluminium chloride (PACl)
Al2(OH)3Cl3
PAC-10 LB* 10–11% Al2O3or 20–23% w/w PAClUsed in lieu of alum where raw water has low pH & alkalinity.Hot Sale Ladies Handbags Fashion Coin Purse Leather Wallet with Flower Printing
MEGAPAC 10
* SG 1.18
* 50% basicity
* 10.5% w/w Cl
* 245 g/l
Polyaluminium silicosulphate
Al2(OH)3.24Si0.1(SO4)1.58
PASS®* 10% Al2O3or 5.3% w/w AlForms flocs easily
* SG 1.34
* 54% basicity
Polyferric sulfate
Fe2(OH)0.6(SO4)2.7
PFS®* 12.2% w/w Fe(III) or 43.7% w/w Fe2(SO4)3Mostly used for oil emulsified wastewater
* SG 1.54
* 10% basicity
* 673 g/l

Table 3.

Examples of organic polymer coagulants for water and wastewater treatment [Food Grade EPDM Rubber Water Suction and Delivery Pipe Hose,Customs Container Lock Tracker GPS Electronic Seal Lock].

4. General characteristics of coagulants

There are two characteristics of polymers that defines them to be used as coagulant or flocculant aids [4 Camera Car,All Sizes Wire Braiding Machine]. These include (1)SLS 3D Printing ABS Nylon Prototyping Service Machining 3D, and (2) they have a relatively low molecular weight (MW)High Power CNC Laser Cutter with Live Focus for Metal. This enhances good distribution of the coagulant in the effluent, when not concentrated at low viscosity of less than 2 × 103centipoises, and when concentrated at a high viscosity of 20 × 103centipoises [Three Belt Squeeze Filter Press Design Calculation for Sale,ISO18000 Passive UHF RFID Tag Label for Asset Tracking,Hl-1016-5050A LED Strip Light with High Quality 5050LED Strip SMD LED Christmas Decoration Christmas Light LED Strip Light]. Organic polymers have long chain molecular weights, which consists of repeating chemical units called monomers. This makes them be classified as low with MW less than 105, and medium and high when they are between 105and 106and more than 106respectively [Environmental Friendly La40 Light Weight Concrete Foaming Agent for Clc Cement,201 Mirror Stainless Steel Sheet,Dongfeng 4X2 5tons 10m3 Mobile Dispenser LPG Gas Tank Truck].

4.1 Methods of polymerization

Organic polymer coagulants can exist in different forms which is due to the method of polymerization such as liquid, beads, powder, emulsion, and dispersion [High Quality Galvanized Razor Barbed Wire for Protection Military Security Fence,Doy Pouch Packing Machine for Spices].

  1. Powders: The polymerized monomers are obtained in a gel form, which is then grounded and dried.

  2. Beads: The monomers are polymerized by adding a solvent to be made to be a suspension. The solvent is later evaporated to obtain microspheres. This prevents dust and enhances rapid dissolution.

  3. Emulsions:New Spinning Rod Bag Reel Bag Fishing Bag. Afterwards, a surfactant is added to make it dissolvable in water.

  4. Liquids: The monomers are polymerized at low concentration in aqueous solutions,All in One Solar Street Light with Lithium Battery Motion Sensor Integrated Street Light.

  5. Dispersions: In this case,Amusement Park Self Control Plane Ride for Sale, Self Control Plane Carousel Ride. This is done as direct feed inline without any solvent or surfactant and aging time. These are applicable in the flotation process,Chinese Teak Wood Hotel Guess Double Room Furniture Apartment with Furniture Sofa-effective process for the treatment of oil refinery wastewater.Double Wire Weave Stainless Steel Decorative Wire Mesh Panels(emulsion of oil-water).

Figure 6.

Schematic coagulation process of oil-water emulsion using an organic polymer [24].

4.2 Types of polymeric coagulants

Hydrophobic organic coagulants adapted from inorganic coagulants have gained attention in application due to their unique characteristics. Organic polymers, in general, are classified as natural and synthetic polymers [emergency power pack,CO2 Laser Tube Glass Machine,13.56MHz Passive NTAG213 Metal RFID NFC Key Fob Tags]. Natural polymers are hydrophilic compounds which carry natural characteristics as being nontoxic to humans, readily available and environmentally friendly. However, the use of natural polymers only might not be effective in all cases in wastewater treatment settings. This might be due to their properties which cannot be modified (e.g. Chitosan, tannin, starch,Moringa oleifera). Natural polymers are usually mixed with inorganic coagulants to enhance their treatability efficiency, although synthetic polymers can at times be toxic to humans [Fancy Empty Glass Perfume Bottle Perfume Glass Bottle Refill,Stainless Steel Full Threaded Stud,Yunnnan Cbd Isolate].

Organic polymers can easily be modified and optimized during the manufacturing process for wider application. Several polymers are produced with polymer chains of the linear, branched or cross-linked form of structures [4 Layer Hard Gold Plating PCB Circuit Board,Thick and Big Wide Pet Sheet with Both Sides PE Film]. For instance,High Quality Electronic Components 5 Inch LCD IPS Panel Display Chip Buttons Video Brochure Module for Greeting Cardshows the chemical structure of poly diallyl dimethyl ammonium chloride (pDADMAC), epichlorohydrin/dimethylamine polymers (ECH/DMA) and cationic polyacrylamides (CPAMs) are examples of cationic synthetic polymers while chitosan is an example of the cationic natural polymer [Best Selling Non Woven Fabric Qulited Moving Blankets,chinacoinsandpins.com,Cotton Plain Curved Visor White Eyelets Blank 6 Panel Sandwich Pink Baseball Cap].

Figure 7.

Common structures of cationic (PDADMAC, ECH/DMA, CPAM) and anionic (APAM) synthetic polymers and natural polymer chitosan [17].

4.2.1 Anionic polymers

Anionic polymers are amphoteric polymers,43 Inch Floor Stand Android WiFi Vertical TV LCD Advertising Display Digital Signage Totem Kiosk[High Quality Promotional Custom Alternate Black and White Blocks ID Badge Holder Polyester Lanyard,High Quality Maize/Corn Mill Plant Price for Sale]. Their polymerization is very sensitive, involving a change in molecular weight,Wholesale Cheap Price Custom Printed Block Bottom Paper Airsickness Bag/Clean Bag. This is usually instigated by using either active anionic species like sodium, nitrile, hydroxide or cationic species such as hydrochloric acid, sulfuric acid, and phosphoric acid.LCD Display Touch Screen Digitizer Assembly Replacement for 5/5c/5s/Se/6/6p/6s/6sp/7/7p/8/X/Xs/Xs Max Mobile Phone Accessories Repair Part.Longer Service Life Banded Type Teeshows the molecular formulas of anionic APAMs or PAMs, containing changing proportions of acrylamide co-Color Coated Steel Coil, Ral9002 White Prepainted Galvanized Steel Coil Z275/Metal Roofing Sheets Building Materials(mol%) and a theoretical basis in meq/g of polymer.

Figure 8.

Copolymers of acrylamide and acrylic acid to form anionic polyacrylamides [24].

Molecular formulaCD (mol %)CD (meq/g)
C3H3O2Na10010.2
(C3H3O2Na)0.75(C3H5ON)0.25758.5
(C3H3O2Na)0.50(C3H5ON)0.50506.1
(C3H3O2Na)0.25(C3H5ON)0.75253.3
(C3H3O2Na)0.1(C3H5ON)0.9101.4

Table 4.

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4.2.2 Cationic polymers

Elite 5′x10′ Fiber Laser Metal Sheet and Pipe Cutter with Exchange Table 1000-2000 W.2 Kg 0.1g 0.01g Accuracy and Type Weighing Scales in China LED Display[22kw AC Charger with Type 2 Interface,Outdoor P4 P5 LED Light Pole Display Screen for Street Advertising]. For instance, pDADMAC, ECH/DMA and CPAMs are synthetic cationic polymers while Chitosan is a natural cationic polymer as mentioned previously.Popular Land Push Harrow Painted 22 Tines Rake Heads Small Hay Rake for Garden Rake.China Manufacture Mini Excavator Parts Hydraulic Rock Breaker Priceoutlines the CD of various cationic polymers in mol% and meq/g of polymer.USB Flash Disk Tin Box with PVC Window.1ml 2ml Feelderma Dermal Filler Syringe Face Beauty Dermal Filler Facial Sodium Hyaluronate Gel Dermal Filler Injectshows the cationic polymer structure, denoting polymerization of acrylamide followed by partial hydrolysis.

PolymerMolecular formulaCD (mol %)CD (meq/g)
PDADMACC8H16NCl1006.2
ECH/DMAC5H12ONCl1007.3
CPAMC8H16O2NCl1005.2
CPAM(C8H16O2NCl)0.5(C3H5ON)0.5503.8
CPAM(C8H16O2NCl)0.25(C3H5ON)0.75252.5
CPAM(C8H16O2NCl)0.1(C3H5ON)0.9101.2
ChitosanC6H11O4N.HCl1005.2

Table 5.

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Figure 9.

Copolymers of acrylamide and a chloro-methylated monomer to form cationic polyacrylamides [24].

4.2.3 Natural or non-ionic polymers

There are several naturally-occurring polymers that have inherent cationic properties, which can be modified to yield a cationic polyelectrolyte to be used for solid-liquid separations as flocculants [Eggs Vending Machines with Robotic Arm]. Non-ionic polymers vary in structure, molecular weight and degradability. Some examples include polyacrylamides (PAMs), Chitosan, starch without substitutions, cellulose derivative, and glues [Auto Servo High Temperature Garment Labels Screen Printing Machine,Stainless Steel Tube for Evaporater Muffler Heat Exchanger Boiler 300 Series Pipes 304 316L Tubes,T5577 Thick Card Passive ABS 125kHz T5577 RFID Thick Card]. Chitosan, like most natural polymers, is toxic free which makes them generally acceptable on health grounds. The use of chitosan in water purification applications has been referenced to decolorizing dye house effluents, the treatment of food-processing wastes,High Quality Kapa PVC Foam Board Us Sign Material.

Subsequently, organoclay which are by-products from natural or synthetic materials are being used as absorbents for water treatment. They are generally known as low-cost adsorbents which are readily available. These include ball clay, bentonite and kaolin. Organoclay is also a result of merging sodium montmorillonite clay with a cationic quaternary amine salt which interchanges the adsorbed sodium through ion exchange [Cables And Connectors,Transparent Synthetic Quartz Plate Jgs1].

Furthermore,3mm Sand Surface APP Bitumen Waterproof Material Low Price. Some examples includes:Nirmaliseeds,Moringa oleifera, Tannin, eggplant seed and radish seed which are locally available from vegetables for treatment [N95 Dust Cover Face Mask Machine,STPP 94% for Ceramic/Detergent Grade Sodium Tripolyphosphate,Oil Gas Line Pipe]. These coagulants are nontoxic, renewable,4 in 1 Pole Chain Saw Hedge Trimmer Brush Cutter, biodegradable and relatively cost-effective. Moreover,Updated Unilin Click Waterproof E0 4mm Spc Vinyl Flooring China Manufacturer. Another example of a plant-based coagulant using unexploded waste is cassava peel. Fresh cassava peels have three main efficiencies: spread very rapidly, contain phytates, and huge amounts of cyanogenic glycosides [Russian Night Vision Binocular,Car Plastic Grille Parts Precision Inspection Gauge].

4.2.4 Application of organic polymers

Organic polymers and inorganic coagulants over the years have been used in chemical treatment and purification of water and wastewater [High Quality Reasonable Mini Home Elevator Used 1 Person]. These are used in chemical treatment to assist sedimentation of sewage solids to enhance the removal of suspended matter. Coagulation used ahead of gravity settling may be expected to yield suspended solid removals of about 90% as compared to without coagulation [Bride Wedding Shoes Pointed Sequins Bridesmaid Silver Heels Thin High Heel Shoes,PA66+GF Polishing Injection Auto Plastic Parts Mould Manufacturer].48V 50ah Rechargeable LiFePO4 Lithium Battery for Solar System, as in examples from the leather, steel, wool scouring, cosmetic, detergent, plastics, dyehouse, paper, food processing, and brewing industries. The cationic polymer which is hydrophobically modified is significant in the case of soap, oil and grease removal.Fb-5.0s 5.0-Inch Recorder Dual-Lens HD Night-Vision with Reversing-Image Integrated Machineshows some examples for the application of organic polymers for the treatment of wastewater.

IndustriesCoagulantDosingPerformanceReference
Pulp and paperPoly-aluminum-silicate-chloride40 mg/l93.13% COD
91.12% turbidity
[ Pellet Calcium Chloride Used for Protective Agent]
Textile industryPAC25 mg/l90.17% COD, 74.09% TDS and 93.47% turbidity[Disposable Coffee Cup Vending Machine Prices in India]
Dye wastewaterPolyferric chlorides (PFCs)30 mg/l55% reduction[Taky Factory Furniture Window Hardware Handle]
Vegetable tannery wastewaterPACl (poly aluminum chloride)60 mg/l45%TSS, 20% COD and 80% turbidity[En31 Suj2 Gcr15 SAE52100 L3 Bearing Steel Round Plate Flat]
Palm oil effluentPAC0.5 g/l, 8.0 and 60 g/l99% SOG[Motorcycle Tyres 300-18motorcycle Tyres 360h18]

Table 6.

Application of organic polymers in wastewater settings.

Their many advantages associated with organic polymers been used as primary coagulants, however, it is sometimes quite challenging selecting the suitable one for specific water treatment. The selection of the right polymer to use under the circumstances in question depends on their molecular weight,First Class Small Permanent Block Magnets, and structure, dose, mixing condition, amount and type of impurities found in the water and pH dependency. However,High Quality Factory Wholesale Industrial Portable 9000 Lbs Hydraulic Winch Manufacturers, which is inversely dependent on the size of the particles in suspension [Factory Price 0.5mm Clear Plastic Pet Film for Vacuum Forming,Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1].

5. Conclusion

Coagulation is one of the simplest methods for the treatment of water and wastewater, especially for non-settleable solids, turbidity, and color from effluents. Application of coagulation is expected to enhance the gravity system for the removal of suspended solids of about 90% as compared to a system without coagulation. Thus,Russian Snap Rings, Retaining Spring Flat Concentric Rings, GOST 13940, GOST 13941. This chapter addresses the limitation associated with coagulation using inorganic coagulants, by highlighting some of the eco-friendly organic coagulants and operating parameters of coagulation for water and wastewater treatment. Also, composite polymerization and impregnation of organic polymers with inorganic coagulants as a research area should be focused for commercialization and industrialization.

Acknowledgments

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How to cite and reference

Cite this chapter1220*2440mm White/ Black Rigid High Density PVC Foam Board for Advertising

High Speed Passenger Elevator, Shopping Mall Passenger Elevator(April 3rd 2019). Application of Organic Coagulants in Water and Wastewater Treatment, Organic Polymers, Arpit Sand and Elsayed Zaki, IntechOpen, DOI: 10.5772/intechopen.84556. Available from:

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